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At least 127 records · Page 7

PCOR Partnership Atlas 6th Edition, Revised

The Plains CO 2 Reduction (PCOR) Partnership Atlas provides a profile of CO 2 sources and potential storage locations across the PCOR Partnership region. The revised sixth edition of the Atlas provides an up-to-date look at PCOR Partnership initiative activities, including additional regional characterization and updates on commercial projects. Additional background information on carbon capture, utilization, and storage (CCUS) is included to give a better understanding of how CCUS addresses concerns about climate change while allowing future energy needs to be met.

01 COAL, LIGNITE, AND PEAT↗

Parametric Study to Assess Technical Prospect Feasibility for Offshore CO 2 Storage

This report is a white paper on the parametric study to assess technical prospect feasibility for CO 2 storage with and without CO 2 -EOR. The SECARB Offshore GOM team reviewed key parameters that previous modeling experience suggests have the largest impact on CO 2 plume size and CO 2 -EOR performance (SSEB, 2019) These parameters include tectonic impacts (reservoir dip and fault block size), reservoir properties (permeability) and development strategies (well field payout, waterflood, and CO 2 flooding strategies). These parameters are further evaluated in this study in order to identify upper and lower boundary conditions for the parametric values. The boundary conditions are needed to set constraints for key parameters when performing modeling assessments. Understanding the key parametric values for the GOM will facilitate locating successful offshore carbon capture utilization and storage (CCUS) projects in terms of plume size, CO 2 stored and, in the case of EOR, oil recovery. Importantly, this white paper focuses on both technical factors (geologic and engineering), but does not address economic, commercial, or stakeholder considerations. The report is organized into four sections and includes a review of the datasets used to define the parameter ranges, the results of a full-physics reservoir simulation, a summary of a reduced order modeling approach to evaluate the impact of the study parameters, and, finally, a discussion of the work that will occur during the next phase of the project.

02 PETROLEUM↗

Wyoming CarbonSAFE Phase III: Site Characterization and Permitting Commercial-Scale Carbon Storage Complex Feasibility Study at Dry Fork Station, Wyoming

This report presents the findings of the technical and non-technical site characterization and permitting activities (“Phase III”) conducted under the Wyoming CarbonSAFE: Accelerating CCUS Commercialization and Deployment at Dry Fork Power Station (DFS) and the Wyoming Integrated Test Center project (“Wyoming CarbonSAFE”). Wyoming CarbonSAFE is part of the U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) Carbon Storage Assurance Facility Enterprise (“CarbonSAFE”) Initiative. The results of Phase III demonstrate that the Wyoming CarbonSAFE project - referred to as the Northern Powder River Basin Carbon Sequestration Hub (NPRB-CSH) - meets the technical, regulatory, and commercial feasibility requirements necessary to advance toward commercial development and construction. The activities completed under this project Phase make the NPRB-CSH one of the region’s most commercially ready carbon storage sites. Completion of this Phase included the finalization of all site surface and subsurface characterization activities, completion and testing of two Class VI standard wells, 10 draft Class VI permits-to construct to address the future needs of a storage complex, finalized NEPA assessments, transportation and capture FEED studies, and a full commercialization strategy with economic modeling, operation and site closure strategies. The NPRB-CSH meets all requirements to progress to a CarbonSAFE Phase IV program or advance to full commercial operations under the development of a business partner.

01 COAL, LIGNITE, AND PEAT↗

Optimizing Alabama’s CO 2 Storage in Shelby County (OASIS) (Final Report)

Optimizing Alabama’s CO 2 Storage in Shelby County (Project OASIS) is a CarbonSAFE Phase II designed to support the U.S. Department of Energy’s goals of reducing project risks and costs for future carbon dioxide (CO 2 ) capture, utilization, and storage (CCUS) projects, bringing more storage resources into commercial classifications that support business and financial decisions, and encouraging more rapid growth of a vibrant, geographically widespread industry for geologic carbon storage.

01 COAL, LIGNITE, AND PEAT↗

Semi‐Continuous Ex Situ Carbon Dioxide Mineralization in Produced Water for Calcite Production

ABSTRACT The mineralization of carbon dioxide (CO 2 ) to stable carbonate products is a desirable process for carbon capture utilization and storage (CCUS). However, improving the process economics through creative use of available reactants is necessary to develop a scalable mineralization process. This study details the development of a semi‐continuous CO 2 mineralization process that uses flue gas as a point CO 2 source, produced water (PW) as an alkaline source of Ca 2+ , and NaOH effluent (potentially sourced from integration with the chlor‐alkali process. Operating at a controlled pH allowed for both complete reaction of available Ca 2+ (100% carbonation potential or 9.9 g CO 2 .L –1 PW brine) and for reproducible control of the produced calcium carbonate (CaCO 3 ) product. A full factorial design of experiments was implemented to study the effects of reaction temperature, pH, and gaseous CO 2 concentration on the mineralization and CO 2 capture rates as well as product crystalline structure and morphology. A maximum CO 2 capture rate of 0.315 ± 0.007 kg.L –1 .d –1 was achieved at 25°C and 25% CO 2 . CO 2 gas to liquid phase mass transport is believed to be the rate limiting step. With improved reactor design and optimization, the proposed semi‐continuous mineralization process shows promise for scaling to a pilot scale CO 2 capture technology.

Bennett, Quinn [Institute for Sustainable Energy &↗

Carbon capture, utilization, and storage hub development on the Gulf Coast

Abstract The Gulf Coast of the United States hosts diverse power generation, refining, and petrochemical processing facilities, resulting in the nation's largest volumetric concentration of industrial CO 2 emissions, rivaled only by the Ohio River Valley. These emissions sources are concentrated in specific industrial clusters that allow combining emissions streams to achieve economies of scale. The region is currently undergoing globally significant industrial expansion and investment as a result of abundant and inexpensive regional unconventional natural gas availability, and is a growing exporter of liquefied natural gas (LNG). Opportunities to integrate CO 2 emission management within the diverse energy chains in the region are volumetrically significant and include both concentrated and dilute sources. Significant examples of capture, transport, and storage exist. Offshore storage is particularly attractive, as it provides simplified land leasing models (single governmental land owner), proven reservoir quality, and presents fewer risks to both protected groundwater and populated areas. Projects can now take advantage of recently expanded opportunities under section 45Q of the Internal Revenue Service tax code. The region continues to evolve as an active carbon‐handling hub, and is uniquely suited to justify additional investment in carbon capture, utilization, and storage (CCUS) technologies via a large‐scale integrated project development. Continued development of integrated projects will allow the region to continue to grow economically within its strong fossil‐fuel handling competence focus while advancing low‐carbon energy technologies that maintain globally competitiveness. © 2021 The Authors. Greenhouse Gases: Science and Technology published by Society of Chemical Industry and John Wiley & Sons Ltd.

45Q↗

A machine learning model for predicting the minimum miscibility pressure of CO 2 and crude oil system based on a support vector machine algorithm approach

CO 2 enhanced oil recovery (EOR) is a potential way for carbon capture, utilization and storage (CCUS). Though, the effect of CO 2 injection is greatly influenced by the reservoir conditions. Typically, Minimum miscible pressure (MMP) is selected as one of the key parameters for the screening and evaluation of prospective CO 2 flooding. Conventional slim tube test is both accurate and widely accepted but it is inefficient. Existing empirical formulas for MMPs are easy to be used but have been proved inaccurate and unreliable. Machine learning-based methods have great advantages in predicting MMP. However, only predication accuracy is discussed for most models without the screening of the main control factors and further validation of the model reliability. In this paper, a new prediction model based on support vector machine (SVM) was developed for pure/impure CO 2 and crude oil system. This study was based on 147 sets of MMP data from the literature with full information on reservoir temperature, oil composition and gas composition. The main control factors were screened by several statistical methods. Unlike the conventional prediction models that verified by only prediction accuracy, learning curve and single factor control variable analysis are further validated to obtain the optimum model.

02 PETROLEUM↗

Modeling CO 2 flow through faulted/fractured reservoirs using tEDFM in corner-point grids

The interest in underground CO 2 storage has increased significantly over the last decade because of the rising concern about global warming due to the growing levels of greenhouse gases in the atmosphere. Considering that CO 2 accounts for 80% of these greenhouse gases, carbon capture, utilization, and storage (CCUS) is regarded as one of the most direct approaches to achieving the net zero carbon target. Although CO 2 storage in deep saline aquifers and depleted gas reservoirs has been studied extensively, most studies use commercial simulators that model faults/fractures by simply modifying the transmissibility in the direction perpendicular to the fault surfaces. Here, this work shows that this simplistic approach ignores the accelerated flow in the directions parallel to the fault plane, leading to significantly higher leakage along the fault surface. To accurately model the flow of CO 2 in faulted reservoirs, we present the first transient embedded discrete fracture model for corner-point grids (tEDFM-CPG). By comparing the results of the tEDFM-CPG to high-resolution reference solutions, we show that this approach is accurate and efficient at predicting CO 2 flow in faulted/fractured reservoirs. Finally, this work presents the use of mixed reality (MR) to efficiently observe CO 2 gas migration in the interior of these corner-point grid systems.

25 ENERGY STORAGE↗

Oxygen Solubility in Aqueous Amine Solvents with Common Additives Used for CO 2 Chemical Absorption

Major sources of anthropogenic CO 2 are power generation and transportation industries where researcher continue to explore CO 2 emission mitigation strategies as applied to these CO 2 sources through carbon capture, utilization, and sequestration (CCUS). The most mature CO 2 capture technology is post-combustion carbon capture (PCCC) using aqueous amine solutions/solvents, however solvent degradation and regeneration costs are slowing the widespread adoption of PCCC. Solvent degradation of the aqueous amine solutions is mainly caused from the temperature gradient between the absorber and stripper columns and common flue gas components such as SOx, NOx, and oxygen (O 2 ). The two main classifications of solvent degradation are thermal degradation, occurring when the amine reacts with itself at elevated temperatures and anaerobic conditions and oxidative degradation. Oxidative degradation reactions can occur from oxygen mass transfer and free radical oxidation. Metals, such as iron from the corrosion of steel structures used in industrial applications such as PCCC, can help to catalyze these reactions. Various oxidative degradation studies have shown how O 2 concentrations in flue gas and, to a lesser extent, temperature influence the extent of oxidative degradation. Accurately measuring the O 2 solubility, commonly referred to as dissolved oxygen (DO), in a quick, continuous, and efficient manner in aqueous amine solvents should contribute to determine the effectiveness of mitigation strategies for oxidative degradation. Knowing that commercial PCCC amine solvents contain components beyond water, amine, carbonate species and CO 2 , this investigation was conducted to determine the oxygen solubility changes of common aqueous amines solutions with commonly used and published solvent additives. The impact of carbon loadings with and without the additives was also examined. A commercial dissolved oxygen probe was used to measure the DO concentrations and compared them against standard Winkler Method titration values. The results show that antifoam shows minimal change in [DO]. MBT yielded lower DO values, and NaVO 3 showed a higher DO concentration due to interferences. These results indicate that most common amine solvent additives should be expected to minimally impact oxygen solubility and amine oxidative degradation.

60 APPLIED LIFE SCIENCES↗

Modeling Co2 Flow Through Faulted/Fractured Reservoirs Using Tedfm in Corner-Point Grids

Interest in underground CO2 storage has increased significantly over the last decade, driven by growing concern about global warming and rising levels of greenhouse gases in the atmosphere. Given that CO2 accounts for 80% of these greenhouse gases, carbon capture, utilization, and storage (CCUS) is considered one of the most direct approaches to achieving the net-zero carbon target. Although CO2 storage in deep saline aquifers and depleted gas reservoirs has been studied extensively, most studies use commercial simulators that model faults/fractures by simply modifying the transmissibility in the direction perpendicular to the fault surfaces. This work shows that this simplistic approach ignores the accelerated flow in the directions parallel to the fault plane, leading to significantly higher leakage along the fault surface. To accurately model CO2 flow in faulted reservoirs, we present the first transient embedded discrete-fracture model for corner-point grids (tEDFM-CPG). By comparing the tEDFM-CPG results with high-resolution reference solutions, we show that this approach is accurate and efficient at predicting CO2 flow in faulted/fractured reservoirs. In conclusion, this work presents the use of mixed reality (MR) to efficiently observe CO2 gas migration in the interior of these corner-point grid systems.

02 PETROLEUM↗

InSAR Monitoring to Evaluate Surface Changes with CO 2 Storage in a Depleted Oil Field in Northern Michigan

Battelle evaluated the potential use of Interferometric Synthetic Aperture Radar (InSAR) for monitoring the outcome of injected CO 2 at the Dover 33 reef near Gaylord, Michigan. InSAR is a satellite-based technology that provides high-precision information on the movement of ground surface in areas with high radar coherence (e.g., roads, buildings, bare soils). Depending on the setting, this technique may provide a useful tool for characterizing reservoirs by measuring surface deformations from activities such as brine water disposal; production of water, oil, and/or gas; and carbon capture, utilization, and storage (CCUS).

47 OTHER INSTRUMENTATION↗

Enhanced Recovery Opportunities in the Appalachian Basin

The Midwest Regional Carbon Sequestration Partnership (MRCSP) has incorporated the work of geologic research teams (Geoteams) in its regional characterization, project planning and carbon dioxide (CO2) injection implementation work since the partnership was established by the U.S. Department of Energy (DOE) in 2003. Over this 16-year period, the cohort of Geoteams has grown from five to ten states and has contributed to the characterization of geologic sequestration opportunities, refinement of reservoir and seal data, and supported injection efforts through both predictive and post-injection assessments. The regional characterization work conducted by the Geoteams during the MRCSP Phase III project period (2010 – 2019) focused on the following tasks: (1) refinement of geologic seals/reservoir systems; (2) assessment of Atlantic Coastal Plain and offshore opportunities; (3) expanded assessments of oil and gas fields, particularly as they relate to enhanced recovery opportunities; (4) regional support for implementation of carbon capture utilization and storage (CCUS) in the partnership area; and (5) communication and data sharing. The findings of this work are summarized in the final report entitled Final Report of Geologic Carbon Capture Utilization and Storage Opportunities in the form of a state-by-state presentation for the MRCSP Region. In addition to the capstone deliverable mentioned above, the Geoteams have also prepared a series of topical reports to elaborate on specific geologic intervals and/or geographic areas of study completed during the Phase III project period. Specifically, these topical reports address: (1) the Atlantic Coastal Plain and adjacent offshore; (2) Cambro-Ordovician reservoirs/seals in the region; (3) enhanced oil and gas recovery opportunities in the Appalachian Basin; and (4) enhanced oil recovery (EOR) in the Michigan Basin. The remainder of this topical report presents our findings relative to enhanced recovery opportunities in the Appalachian Basin.

54 ENVIRONMENTAL SCIENCES↗

Regional Geologic Cross Sections for Potential Storage and Containment Zones in the MRCSP Region

The Midwest Regional Carbon Sequestration Partnership (MRCSP) has incorporated the work of geologic research teams (Geoteams) in its regional characterization, project planning and carbon dioxide (CO 2 ) injection implementation work since the partnership was established by the U.S. Department of Energy (DOE) in 2003. Over this 16-year period, the cohort of Geoteams has grown from five to ten states and has contributed to the characterization of geologic sequestration opportunities, refinement of reservoir and seal data, and supported injection efforts through both predictive and post-injection assessments. Five geologic cross sections (labeled A through E) were constructed onshore across the parts of the MRCSP Region west of the Valley and Ridge Province, and one section (labeled F) was constructed beginning onshore in New Jersey and running eastward to offshore areas examined for carbon storage. Regional and local stratigraphic units were used in these cross sections to show current nomenclature as well as highlighting specific units/features pertinent to carbon capture, utilization and storage (CCUS) opportunities in the region. Each cross section uses 15 to 25 deep wells and other geologic information to illustrate the relative depth, thickness and location of rock units in the subsurface.

01 COAL, LIGNITE, AND PEAT↗

Robust Carbon Dioxide Plume Imaging Using Joint Tomographic Inversion of Seismic Onset Time and Distributed Pressure and Temperature Measurements (Final Report)

We develop and demonstrate rapid and cost-effective methodologies for spatiotemporal tracking of CO2 plumes during geologic sequestration using joint inversion of seismic data and distributed pressure and temperature measurements. Key elements of our methodology are: (a) a computationally efficient approach to pressure and temperature propagation, (b) analysis of time lapse seismic data using a novel ‘seismic onset time’ approach to detect fluid front propagation, and (c) data assimilation and uncertainty assessment via joint inversion of pressure, temperature and time lapse seismic data, and (d) validating the numerical tomographic inversion using a CO2 injection demonstration projects, specifically data collected from the from the Petra Nova Parish Holdings CCUS project in the West Ranch Field, Texas and the Chester-16 reef CO2 injection site in Northern Michigan which is part of the DOE Midwestern Carbon Sequestration Project. The research team is led by Texas A&M University and includes Battelle as a subcontractor with support from Shell, Anadarko, Chevron and JX Nippon. A carbon dioxide (CO2) water-alternating-gas (WAG) pilot was conducted to gain insights into tertiary oil recovery potential via CO2 flood in the West Ranch Field as part of the Petra Nova project, the world’s largest post-combustion CO2 capture and utilization initiative. With a fluvial formation geology and large contrasts in permeability, this is a challenging and novel application of CO2 enhanced oil recovery (EOR). We build a predictive dynamic model of the subsurface that incorporates the multiphase and compositional data acquired during the pilot operation. The calibrated model is used for the carbon dioxide plume imaging. The study began with an initialization of the pilot sector model extracted from a calibrated full-field model. The pilot model calibration follows a two-step hierarchical workflow. First, we performed a large-scale update of the permeability distribution by integrating available bottomhole pressure and multiphase production data. In the second step, local permeability field is fine-tuned using a streamline-based method to match CO2 breakthrough times at the producers. The predictive capability of the calibrated model was verified through two blind validation tests: (1) the model showed good agreement with saturation logs acquired at two observation wells; and (2) the model reproduced the CO2 recovery as a fraction of the injected CO2. The use of seismic onset times has shown great promise for integrating near-continuous seismic surveys for updating geologic models. In this study, we analyze the impact of seismic survey frequency on the onset time approach aiming to extend the application of onset time to infrequent seismic surveys. In addition, we quantitatively examine the nonlinearity of the onset time method and compare it to the commonly used amplitude inversion method. We carry out a sensitivity analysis of seismic survey frequency based on the complete seismic survey data (over 175 surveys) of steam injection in a heavy oil reservoir (Peace River Unit) in Canada. Our results show that an adequate onset time map can be obtained from the infrequent seismic surveys by interpolation between seismic surveys as long as there is no change in the dominant underlying physics between the successive surveys. The study also shows that nonlinearity of the onset time method can be -smaller than that of the amplitude inversion method by several orders of magnitude. Application to the Brugge benchmark case shows that the onset time method obtains comparable permeability update as the traditional seismic amplitude inversion method with faster computation and improved convergence characteristics. We extend the streamline-based data integration approach to incorporate distributed temperature sensor (DTS) data using the concept of thermal tracer travel time. Then, a hierarchical workflow composed of evolutionary and streamline methods is employed to jointly history match the DTS and pressure data. Finally, CO2 saturation and streamline maps are used to visualize the CO2 plume movement during the sequestration process. The hierarchical workflow is applied to a carbon sequestration project in a carbonate reef reservoir within the Northern Niagaran Pinnacle Reef Trend in Michigan, USA. The monitoring data set consists of distributed temperature sensing (DTS) data acquired at the injection well and a monitoring well, flowing bottom-hole pressure data at the injection well, and time-lapse pressure measurements at several locations along the monitoring well. The history matching results indicate that the CO2 movement is mostly restricted to the intended zones of injection which is consistent with an independent warm-back analysis of the temperature data. In addition to employing simulation models and inverse methods for CO2 plume imaging, we also initialized a data-driven technology for detecting inter-well connectivity based on production and pressure data. Our machine-learning framework is built on the statistical recurrent unit (SRU) model and interprets well-based injection/production data into inter-well connectivity without relying on a geologic model. We test it on synthetic and field-scale CO2 EOR projects utilizing the water-alternating-gas (WAG) process. The validation of the proposed data-driven inter-well connectivity assessment is performed using synthetic data from simulation models where inter-well connectivity can be easily measured using the streamline-based flux allocation. The SRU model is shown to offer excellent prediction performance on the synthetic case. Despite significant measurement noise and frequent well shut-ins imposed in the field-scale case, the SRU model offers good prediction accuracy, the overall relative error of the phase production rates at most producers ranges from 10% to 30%. It is shown that the dominant connections identified by the data-driven method and streamline method are in close agreement. Texas A&M University, the lead organization in the project, was primarily responsible for the development of tomographic approaches for CO2 plume mapping in conjunction with distributed pressure, temperature and seismic onset time data. Battelle, as a subcontractor, was primarily responsible for the development of analytical and empirical methods for analyzing transient injection rate and pressure data from point/line sources such as injection and monitoring wells. An additional area of emphasis for Battelle was the use of machine learning for such tasks as inferring reservoir connectivity information from injection-production data, and identifying variable importance for machine learning-based proxy models developed from full-physics simulations. The two organizations also collaborated on the application of the tomographic inversion methodology for a field data set.

02 PETROLEUM↗

Stakeholder Analysis Technical Report for CarbonSAFE Illinois -- Macon County (Task 3)

Stakeholder engagement is considered a critical component for successful deployment of Carbon Capture Utilization and Storage (CCUS). Engagement builds awareness and understanding of the implications, both local and global, that deploying this technology entails. The CarbonSAFE Illinois – Macon County project presents unique challenges for engaging stakeholders as they have various and diverse options and perspectives that vary in influence and personal importance.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

CO 2 Intermediate Storage (CIS) Concept Overview

The objective of this overview is to provide a comprehensive set of qualitative considerations to inform future quantitative technical and economic CIS analyses. This overview focuses on CO 2 EOR as the end-user for CCUS supply chains that might implement CIS.

42 ENGINEERING↗

Front-End Engineering and Design: Project Tundra Carbon Capture System (Final Report)

As the next phase of Project Tundra, Minnkota Power Cooperative (MPC) completed a front-end engineering and design (FEED) study to install a post-combustion CO 2 capture system (CCS) at the MPC operated (Square Butte Electric Cooperative-owned) Milton R. Young Station (MRYS) Unit 2 (MRY2), a 477-MW power plant fueled by North Dakota lignite. The project team completed the FEED with Fluor’s Econamine FG Plus℠ (EFG+) technology and is taking the next steps leading up to start of construction. Team members included FEED technical lead Fluor Enterprises (Fluor); owner’s engineer and balance of plant (BOP) engineer Burns & McDonnell (BMcD); leading carbon capture consultants (David Greeson Consulting, Hunt International Energy Services); environmental consultants (AECOM, Agora Environmental), other BOP engineering consultants (Golder Associates, Nels); cost-share funding agency, the North Dakota Industrial Commission (NDIC); and the Energy & Environmental Research Center (EERC). Project Tundra’s goal is to implement carbon capture, utilization, and storage (CCUS) in North Dakota, while preserving the use of lignite. Future options could lead to revitalizing legacy oil fields and creating a new CO 2 enhanced oil recovery (EOR) industry. The topic of this report is the FEED study for the carbon dioxide capture portion of Project Tundra. Building on the findings of a pre-FEED study for MRY2, the key deliverables contained in this FEED study are: a) design, costing, and performance data needed to commence project financing activities; b) engineering and material balances required to file for all project permits; and c) a final project schedule. Based on the results of the previous pre-FEED study, MPC and its team evaluated two options to provide the large amount of steam needed to operate the CCS: 1) installation of new natural gas package boilers and a new pipeline to supply natural gas to the facility and 2) extraction of steam from the existing MRYS steam turbine generator. The FEED study was performed using the package boilers option, as it was deemed to have the lowest technical risk, overall cost, and cost uncertainty. A key feature of the design, however, was the mixing the natural gas boilers’ flue gas with the MRY2 flue gas. This increased the size of the CCS system. This design also enabled the tie-in of Unit 1 flue gas for times when Unit 2 is offline. The CCS was designed to capture a combined 12,978 short tons per day (STPD) of CO 2 from the flue gases produced by the existing MRY Unit 2 along with flue gas produced by the new boiler package within the CCS. The 12,978 STPD CO 2 capture is achieved by normally processing 100% of the total available MRY Unit 2 flue gas (considering full load operation) and 100% of the boiler package flue gas, then removing 90% of the CO 2 available from the processed flue gas streams.

01 COAL, LIGNITE, AND PEAT↗