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At least 127 records · Page 7

On the Importance of Laboratory Astrophysics and Astrochemistry and Interdisciplinary Research: Two Success Stories

Here we present two examples that demonstrate how cross-disciplinary research projects, where experimentalists, modelers and observers work together to answer science questions, allow expertise to be shared and misconceptions or missing key elements to be tackled by looking at the problem from different perspectives. They also show how, by working in unison, the group can accomplish more than the sum of its parts by combining results into a higher-level understanding of the chemical processes taking place. The first project is a collaborative study between experimentalists, modelers and observers to1) produce laboratory analogs of cosmic grains and planetary aerosols (Titan, Pluto...) from different gas mixtures in cold astrophysically relevant conditions (<200 K); and 2) characterize them with scanning electron microscopy and visible-to-far-infrared spectroscopy in order to assess the impact of the precursors on their growth structure and optical properties. We can then produce and study analogs that are representative of different formation stages or environments, and provide their complex refractive indices to the scientific community. We will show how, by using these experimental optical constants of more representative analogs in radiative transfer and reflectance spectra models, better interpretations of (exo)planetary atmosphere- and surface observations are possible. The second project is an interdisciplinary study of the formation of benzene clouds in the atmosphere of Saturn’s largest moon, Titan. We will show how combining Earth and Planetary Science laboratory expertise, modeling and observations has led to providing to the scientific community, for the first time, experimental vapor pressures for benzene at cold temperatures(<200K) relevant to Titan’s atmospheric conditions. These have been used in microphysical models instead of the higher temperature extrapolations used previously, allowing a better match to observations.

Ella Sciamma-o'Brien↗

Organic compounds in meteorites. II.

Aromatic compounds in benzene eluate fractions from carbonaceous chondrites by high resolution capillary gas-liquid chromatography

GAS CHROMATOGRAPHY↗

The Measurement of Fuel-air Ratio by Analysis of the Oxidized Exhaust Gas

An investigation was made to determine a method of measuring fuel-air ratio that could be used for test purposes in flight and for checking conventional equipment in the laboratory. Two single-cylinder test engines equipped with typical commercial engine cylinders were used. The fuel-air ratio of the mixture delivered to the engines was determined by direct measurement of the quantity of air and of fuel supplied and also by analysis of the oxidized exhaust gas and of the normal exhaust gas. Five fuels were used: gasoline that complied with Army-Navy Fuel Specification, No. AN-VV-F-781 and four mixtures of this gasoline with toluene, benzene, and xylene. The method of determining the fuel-air ratio described in this report involves the measurement of the carbon-dioxide content of the oxidized exhaust gas and the use of graphs or the presented equation. This method is considered useful in aircraft, in the field, or in the laboratory for a range of fuel-air ratios from 0.047 to 0.124

FUELS-TOLUENE↗

The polymorphic and mesomorphic behavior of four esters of cholesterol.

The techniques of differential scanning calorimetry, X-ray powder diffractometry, and positron annihilation have been used to study the polymorphic and mesomorphic behavior of the following esters of cholesterol: cholesteryl formate, cholesteryl butyrate, cholesteryl benzoate, and cholesteryl cinnamate. Each of these compounds exhibits a single mesophase of the cholesteric type. The solid phase formed from the melt for each ester was observed to be structurally different from the solid phase obtained from solution. Solvents from which the solution-grown samples were crystallized were as follows: cholesteryl formate and cholesteryl butyrate from acetone, cholesteryl benzoate from benzene, and cholesteryl cinnamate from 2-butanone.

Merritt, W. G.↗

Distribution and significance of carbon compounds on the moon.

Exploration of available information concerning carbon on the moon, following review of what is known about carbon on the earth, and consideration of the results of studies of meteorites, which have provided the first direct clues about extraterrestrial carbon. Carbon and carbon isotope composition data taken from Apollo 11 samples are tabulated. Carbon compounds produced by pyrolysis, extracted with benzene-methanol, extracted with water, and freed by acid treatment are discussed. Carbon and carbon compounds in lunar rocks and soils appear to be distributed heterogeneously.

Chang, S.↗

Development of space stable semitransparent polyquinoxaline films

Three polyphenylquinoxalines underwent preliminary study for potential use as coatings on aircraft and spacecraft. These polymers were prepared from the reaction of 3,3 prime, 4,4 prime-tetraaminodiphenyl ether with p,p prime-oxydibenzil and with m -bis (phenylglyoxalyl) benzene and from the reaction of 3,3 prime, 4,4 prime-tetraaminodiphenylsulfone with p,p prime-oxydibenzil. High purity reactants and solvents were used in polymer preparation to minimize color in the polymer films. High molecular weight polymers were prepared at ambient temperature at 12 to 15 percent concentration by upsetting the stoichiometry by 0.5 to 1.0 percent in favor of the bis (1,2-dicarbonyl) reactant. A portion of each polymer was endcapped with benzil and with o-phenylenediamine. Certain properties of the endcapped and unendcapped versions of each polymer are compared. Uniform films of 2.0 and 0.1 mil thickness were cast from solutions of the unendcapped and endcapped versions of each of the three polymers.

Hergenrother, P. M.↗

Quantitation of buried contamination by use of solvents

An investigation was made to determine (1) sporicidal properties of amine solvents that solubilize silicon resins, (2) recovery properties of a silicon potting compound (RTV 41) used in spacecraft, and (3) viability of spores during chemical curing of the potting compound. Results show that: (1) spores do remain viable during RTV 41 silicon potting chemical curing, and (2) spore recovery from cured silicon potting compound RTV 41 is very high when silicon rubber is dissolved in butylamine and series dilution with benzene prior to plate curing.

Pappas, S. P.↗

Evaluation of proposed Skylab and SSP soap products

Three personal hygiene cleansing agents and one laundry detergent (sodium dodecyl benzene sulfonate), which are all candidates for use on long-duration space missions, were evaluated in terms of dermatological effects on human subjects and effects on microbiological species. None of the four materials exhibited adverse dermatological effects from either skin patch tests of two weeks duration or a simulated Skylab personal hygiene regimen of up to four weeks duration. No significant alterations in skin microflora during the use regimen were found. None of the four materials were found to serve as microbiological support media for the species tested, but a species of air-borne mold was observed to grow rapidly in a neutralized aqueous solution. None of the candidate agents was found to be strongly biocidal.

Whitmore, F. C.↗

Development of polyphenylquinoxaline graphite composites

The potential of polyphenylquinoxaline (PPQ)/graphite composites to serve as structural material at 316 C (600 F)has been demonstrated using a block copolymer, BlCo(13), PPQ derivative. Initially, thirteen polyphenylquinoxalines were evaluated. From this work, four candidate polymers were selected for preliminary evaluation as matrices for HMS graphite fiber reinforced composites. The preliminary composite evaluation enabled selection of one of the four polymers for advanced composite preparation and testing. Using an experimentally established cure schedule for each of the four polymers, preliminary laminates of 50% resin volume content, prepared without postcure, were tested for flexure strength and modulus, interlaminar shear strength (short beam), and tensile strength and modulus at ambient temperature. A block copolymer (Bl Co 13) derived from one mole p-bis (phenylglyoxalyl) benzene, one fourth mole 3,3'-diaminobenzidine and three-fourths mole 3,3', 4,4'-tetraminobenzophenone was selected for extensive study. Tensile, flexural, and interlaminar shear values were obtained after aging and testing postcured BlCo(13) laminates at 316 C (600 F). The potential of PPQ/graphite laminates to serve as short term structural materials at temperatures up to 371 C (700 F) was demonstrated through weight loss experiments.

Hoggatt, J. T.↗

Development of system design information for carbon dioxide using an amine type sorber

Development work on system design information for amine type carbon dioxide sorber is reported. Amberlite IR-45, an aminated styrene divinyl benzene matrix, was investigated to determine the influence of design parameters of sorber particle size, process flow rate, CO2 partial pressure, total pressure, and bed designs. CO2 capacity and energy requirements for a 4-man size system were related mathematically to important operational parameters. Some fundamental studies in CO2 sorber capacity, energy requirements, and process operation were also performed.

Rankin, R. L.↗