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NASA NTRS2010

The Abundance Pattern in the Hot ISM of NGC 4472: Insights and Anomalies

Important clues to the chemical and dynamical history of elliptical galaxies are encoded in the abundances of heavy elements in the X-ray emitting plasma. We derive the hot ISM abundance pattern in inner (0.2.3R(sub e)) and outer (2.3.4.6R(sub e)) regions of NGC 4472 from analysis of Suzaku spectra, supported by analysis of co- spatial XMM-Newton spectra. The low background and relatively sharp spectral resolution of the Suzaku XIS detectors, combined with the high luminosity and temperature in NGC 4472, enable us to derive a particularly extensive abundance pattern that encompasses O, Ne, Mg, Al, Si, S, Ar, Ca, Fe, and Ni in both regions. We apply simple chemical evolution models to these data, and conclude that the abundances are best explained by a combination of alpha-element enhanced stellar mass loss and direct injection of Type Ia supernova (SNIa) ejecta. We thus confirm the inference, based on optical data, that the stars in elliptical galaxies have supersolar [alpha/Fe] ratios, but find that that the present-day SNIa rate is approximately 4.6 times lower than the standard value. We find SNIa yield sets that reproduce Ca and Ar, or Ni, but not all three simultaneously. The low abundance of O relative to Ne and Mg implies that standard core collapse nucleosynthesis models overproduce O by approximately 2.

Loewenstein, Michael↗
NASA NTRS2010

The Abundance of Iron-Peak Elements and the Dust Composition in eta Carinae: Manganese

We study the chemical abundances of the Strontium Filament found in the ejecta of (eta) Carinae. In particular, we derive the abundances of iron-peak elements front spectra of their singly ionized ions present in the optical/IR spectra. In this paper we analyze the spectrum of Mn II using a new non-LTE model for this system. In constructing this models we carried out theoretical calculations of radiative transition rates and electron impact excitation rate coefficients. We find that relative to Ni the gas phase abundance ratio of Mn is roughly solar, similar to the Cr abundance but in contrast to the large enhancements in the abundances of Sc and Ti. NVe interpret this result as an indication of non-equilibrium condensation in the ejecta of (eta) Carinae.

Bautista, M. A.↗
NASA NTRS2012

Primary Volatile Abundances in Comets from Infrared Spectroscopy: Implications for Reactions on Grain Surfaces in the Interstellar/Nebular Environment

Comets retain relatively primitive icy material remaining from the epoch of Solar System formation, however the extent to which they are modified from their initial state remains a key question in cometary science. High-resolution lR spectroscopy has emerged as a powerful tool for measuring vibrational emissions from primary volatiles (i.e., those contained in the nuclei of comets). With modern instrumentation, most notably NIRSPEC at the Keck II 10-m telescope, we can quantify species of astrobiological importance (e.g., H20, C2H2, CH4, C2H6, CO, H2CO, CH30H, HCN, NH3). In space environments, compounds of keen interest to astrobiology could originate from HCN and NH3 (leading to amino acids), H2CO (leading to sugars), or C2H6 and CH4 (suggested precursors of ethyl- and methylamine). Measuring the abundances of these precursor molecules (and their variability among comets) is a feasible task that contributes to understanding their delivery to Earth's early biosphere and to the synthesis of more complex pre biotic compounds. Over 20 comets have now been measured with IR spectroscopy, and this sample reveals significant diversity in primary volatile compositions. From this, a taxonomic classification scheme is emerging, presumably reflecting the diverse conditions experienced by pre-cometary grains in interstellar and subsequent nebular environs. The importance of H-atom addition to C2H2 on the surfaces of interstellar grains to produce C2H6 was validated by the discovery of abundant ethane in comet C/1996 B2 (Hyakutake) with C2H6/CH4 well above that achievable by gas-phase chemistry , and then in irradiation experiments on laboratory ices at 10 - 50 K. The large abundance ratios C2H6/CH4 observed universally in comets establish H-atom addition as an important and likely ubiquitous process, and comparing C2H6/C2H2 among comets can provide information on its efficiency. The IR is uniquely capable since symmetric hydrocarbons (e.g., C2H2, CH4, C2H6) have no electric dipole moment and thus no allowed pure rotational transitions. CO should also be hydrogenated on grain surfaces. Irradiation experiments on interstellar ice analogs show this to require very low temperatures, the resulting yields of H2CO and CH30H being highly dependent on temperature in the range approx 10 - 25 K. The relative abundances of these chemically-related molecules in comets provide one measure of the efficiency of H-atom addition to CO Oxidation of CO is also important on grain mantles, as evidenced by the widespread presence of C02 ice towards interstellar sources observed with ISO and in a survey of 17 comets observed with AKARI. H-atom addition to C2H2 produces the vinyl radical, and through subsequent oxidation1reduction reactions can lead to vinyl alcohol, acetaldehyde, and ethanol This may have implications for interpreting observed abundance ratios CO/C2H2. We will discuss possible implications regarding formation conditions in the context of measured primary volatile compositions, emphasizing recently observed comets and published results. These are continually providing new insights regarding our taxonomic scheme and also delivery of pre-biological material to the young Earth.

DiSanti, M. A.↗
NASA NTRS2016

Abundant Solar Nebula Solids in Comets

Comets have been proposed to consist of unprocessed interstellar materials together with a variable amount of thermally annealed interstellar grains. Recent studies of cometary solids in the laboratory have shown that comets instead consist of a wide range of materials from across the protoplanetary disk, in addition to a minor complement of interstellar materials. These advances were made possible by the return of direct samples of comet 81P/Wild 2 coma dust by the NASA Stardust mission and recent advances in microscale analytical techniques. Isotopic studies of 'cometary' chondritic porous interplanetary dust particles (CP-IDPs) and comet 81P/Wild 2 Stardust samples show that preserved interstellar materials are more abundant in comets than in any class of meteorite. Identified interstellar materials include sub-micron-sized presolar silicates, oxides, and SiC dust grains and some fraction of the organic material that binds the samples together. Presolar grain abundances reach 1 weight percentage in the most stardust-rich CP-IDPs, 50 times greater than in meteorites. Yet, order of magnitude variations in presolar grain abundances among CP-IDPs suggest cometary solids experienced significant variations in the degree of processing in the solar nebula. Comets contain a surprisingly high abundance of nebular solids formed or altered at high temperatures. Comet 81P/Wild 2 samples include 10-40 micron-sized, refractory Ca- Al-rich inclusion (CAI)-, chondrule-, and ameboid olivine aggregate (AOA)-like materials. The O isotopic compositions of these refractory materials are remarkably similar to their meteoritic counterparts, ranging from 5 percent enrichments in (sup 16) O to near-terrestrial values. Comet 81P/Wild 2 and CP-IDPs also contain abundant Mg-Fe crystalline and amorphous silicates whose O isotopic compositions are also consistent with Solar System origins. Unlike meteorites, that are dominated by locally-produced materials, comets appear to be composed of materials that were formed across a wide swath of the early protoplanetary disk.

Messenger, S.↗
NASA NTRS2017

Deriving Global OH Abundance and Atmospheric Lifetimes for Long-Lived Gases: A Search for CH3CCl3 Alternatives

An accurate estimate of global hydroxyl radical (OH) abundance is important for projections of air quality, climate, and stratospheric ozone recovery. As the atmospheric mixing ratios of methyl chloroform (CH3CCl3) (MCF), the commonly used OH reference gas, approaches zero, it is important to find alternative approaches to infer atmospheric OH abundance and variability. The lack of global bottom-up emission inventories is the primary obstacle in choosing a MCF alternative. We illustrate that global emissions of long-lived trace gases can be inferred from their observed mixing ratio differences between the Northern Hemisphere (NH) and Southern Hemisphere (SH), given realistic estimates of their NH-SH exchange time, the emission partitioning between the two hemispheres, and the NH versus SH OH abundance ratio. Using the observed long-term trend and emissions derived from the measured hemispheric gradient, the combination of HFC-32 (CH2F2), HFC-134a (CH2FCF3, HFC-152a (CH3CHF2), and HCFC-22 (CHClF2), instead of a single gas, will be useful as a MCF alternative to infer global and hemispheric OH abundance and trace gas lifetimes. The primary assumption on which this multispecies approach relies is that the OH lifetimes can be estimated by scaling the thermal reaction rates of a reference gas at 272 K on global and hemispheric scales. Thus, the derived hemispheric and global OH estimates are forced to reconcile the observed trends and gradient for all four compounds simultaneously. However, currently, observations of these gases from the surface networks do not provide more accurate OH abundance estimate than that from MCF.

Lifetime↗
NASA NTRS2017

VIII. New Zr IV-VII, Xe IV-V, and Xe VII Oscillator Strengths and the Al, Zr, and Xe Abundances in the Hot White Dwarfs G191-B2B and RE0503-289

Context: For the spectral analysis of high-resolution and high-signal-to-noise spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims: To search for zirconium and xenon lines in the ultraviolet (UV) spectra of G191−B2B and RE 0503−289, new Zr iv-vii, Xe iv-v, and Xe vii oscillator strengths were calculated. This allows, for the first time, determination of the Zr abundance in white dwarf (WD) stars and improvement of the Xe abundance determinations.Methods: We calculated Zr iv-vii, Xe iv-v, and Xe vii oscillator strengths to consider radiative and collisional bound-bound transitions of Zr and Xe in our NLTE stellar-atmosphere models for the analysis of their lines exhibited in UV observations of the hot WDs G191−B2B and RE 0503−289. Results: We identified one new Zr iv, 14 new Zr v, and ten new Zr vi lines in the spectrum of RE 0503−289. Zr was detected for the first time in a WD. We measured a Zr abundance of −3.5 +/- 0.2 (logarithmic mass fraction, approx. 11 500 times solar). We identified five new Xe vi lines and determined a Xe abundance of −3.9 +/- 0.2 (approx. 7500 times solar). We determined a preliminary photospheric Al abundance of −4.3 +/- 0.2 (solar) in RE 0503−289. In the spectra of G191−B2B, no Zr line was identified. The strongest Zr iv line (1598.948 Å) in our model gave an upper limit of −5.6 +/- 0.3 (approx. 100 times solar). No Xe line was identified in the UV spectrum of G191−B2B and we confirmed the previously determined upper limit of −6.8 +/- 0.3 (ten times solar). Conclusions: Precise measurements and calculations of atomic data are a prerequisite for advanced NLTE stellar-atmosphere modeling. Observed Zr iv-vi and Xe vi-vii line profiles in the UV spectrum of RE 0503−289 were simultaneously well reproduced with our newly calculated oscillator strengths.

Rauch, T.↗
NASA NTRS2022

The Abundances of F, Cl, and H2O in 4Vesta from Eucrites

The abundance and distribution of magmatic volatiles (i.e., H, C, N, F, S, and Cl) within the silicate portion of a differentiated planetary body has important consequences on its thermochemical evolution. However, the abundances of magmatic volatiles within differentiated bodies are difficult to quantify, and they are often depleted by varying degrees relative to CI chondrites. The mechanisms of depletion are not well constrained and could relate to intrinsic volatile depletion of the building blocks that formed the bodies, high temperature processes that result from accretion, post-accretion loss through parent body geological processes and large-scale impacts, and/or redistribution within a parent body through processes like core formation [1–4]. In the present study, we aim to constrain the abundances of F, Cl, and H2O in eucrites to better understand the magnitude of volatile depletion on 4Vesta. To accomplish this objective, we report electron microprobe analyses of apatite from seven unbrecciated, non-cumulate eucrites (i.e., CMS 04049,GRA 98098, LEW 88010, MAC 02522, MAC 041169,QUE 94484, and QUE 97053) and two monomict, non-cumulate eucrites (i.e., Berthoud and Stannern). In combination with previously published data on eucrite-hosted apatite, we determine Cl/F and H2O/F ratios in bulk rock eucrites through the application of apatite-based melt hygrometry and chlorometry [e.g., 5–7].Additionally, we estimate the bulk rock abundances of F in six non-cumulate eucrites (i.e., GRA 98098, MAC041169, PCA 91078, QUE 97053, Stannern, and Berthoud), which we combine with previously published bulk rock F data on non-cumulate eucrites[8] to constrain the abundances of F, Cl, and H2O in 4Vesta using appropriately paired volatile/refractory element ratios for F, followed by Cl/F and H2O/F ratios for Cl and H2O, respectively.

F M McCubbin↗
NASA NTRS2022

Rock Abundance on the Lunar Mare on Surfaces of Different Age: Implications for Regolith Evolution and Thickness

The growth of lunar regolith over time affects surface rock abundance, because larger, less frequent impacts are needed to penetrate thicker regolith developed on older surfaces and excavate rocks. On younger surfaces with thinner regolith, smaller, more frequent impacts are sufficient to excavate rocks. We quantify the correlation between observed rock abundances and age on the lunar surface by comparing Diviner rock abundance data to the surface ages of inter-crater parts on the maria. Our observations show the expected negative correlation between age and rock abundance. The commonality of non-zero rock abundance values on ancient surfaces, combined with a simple Monte Carlo model of the rock excavation process, suggest that rocks re-excavated from the regolith volume contribute to the presently observed rock population on the lunar surface. The half-life of meter-scale surface rocks most consistent with our observations is 80±20 Myr.

Sashank Vanga↗
NASA NTRS2022

New Constraints on Titan's Stratospheric n-Butane Abundance

Curiously, n-butane has yet to be detected at Titan, though it is predicted to be present in a wide range of abundances that span over 2.5 orders of magnitude. We have searched infrared spectroscopic observations of Titan for signals from n-butane (n-C4H10) in Titan's stratosphere. Three sets of Cassini Composite Infrared Spectrometer Focal Plane 4 (1050–1500 cm−1) observations were selected for modeling, having been collected from different flybys and pointing latitudes. We modeled the observations with the Nonlinear Optimal Estimator for MultivariatE Spectral AnalySIS radiative transfer tool. Temperature profiles were retrieved for each of the data sets by modeling the ν4 emission from methane near 1305 cm−1. Then, incorporating the temperature profiles, we retrieved abundances of all of Titan's known trace gases that are active in this spectral region, reliably reproducing the observations. We then systematically tested a set of models with varying abundances of n-butane, investigating how the addition of this gas affected the fits. We did this for several different photochemically predicted abundance profiles from the literature, as well as for a constant-with-altitude profile. Ultimately, though we did not produce any firm detection of n-butane, we derived new upper limits on its abundance specific to the use of each profile and to multiple different ranges of stratospheric altitudes. These results will tightly constrain the C4 chemistry of future photochemical modeling of Titan's atmosphere and also motivate the continued search for n-butane and its isomer, isobutane.

Brendan L. Steffens↗
NASA NTRSDate not supplied

Elemental Abundances of nearby M Dwarfs Based on High-resolution Near-infrared Spectra Obtained by the Subaru/IRD Survey: Proof of Concept

Detailed chemical analyses of M dwarfs are scarce but necessary to constrain the formation environment and internal structure of planets being found around them. We present elemental abundances of 13 M dwarfs (2900 < T eff < 3500 K) observed in the Subaru/IRD planet search project. They are mid- to late-M dwarfs whose abundance of individual elements has not been well studied. We use the high-resolution (∼70,000) near-infrared (970–1750 nm) spectra to measure the abundances of Na, Mg, Si, K, Ca, Ti, V, Cr, Mn, Fe, and Sr by the line-by-line analysis based on model atmospheres, with typical errors ranging from 0.2 dex for [Fe/H] to 0.3–0.4 dex for other [X/H]. We measure radial velocities from the spectra and combine them with Gaia astrometry to calculate the Galactocentric space velocities UVW . The resulting [Fe/H] values agree with previous estimates based on medium-resolution K-band spectroscopy, showing a wide distribution of metallicity (−0.6 < [Fe/H] < +0.4). The abundance ratios of individual elements [X/Fe] are generally aligned with the solar values in all targets. While the [X/Fe] distributions are comparable to those of nearby FGK stars, most of which belong to the thin-disk population, the most metal-poor object, GJ 699, could be a thick-disk star. The UVW velocities also support this. The results raise the prospect that near-infrared spectra of M dwarfs obtained in the planet search projects can be used to grasp the trend of elemental abundances and the Galactic stellar population of nearby M dwarfs.

Hiroyuki Tako Ishikawa↗
NASA NTRS2022

Global Hydrogen Abundances on the Lunar Surface

A global map of bulk hydrogen abundances on the Moon is presented. This map was generated using data from the Lunar Prospector Neutron Spectrometer. This map required corrections for variations due to rare-earth elements, and was calibrated to Apollo sample hydrogen abundances. Since neutron-derived measurements sample hydrogen content to a depth of tens of cm, these results provide complementary insights to those provided by studies using spectral reflectance data, which sample depths of order μm. Comparison of these abundances to Apollo sample values suggest that the samples reflect actual hydrogen content on the lunar surface, not dominantly from non-lunar contamination. The average lunar hydrogen abundance is 47 ppm with a systematic uncertainty of ∼10 ppm. This is consistent with bulk hydrogen from solar wind emplacement. A bulk hydrogen enhancement (50–68 ppm) has been identified at the Moon's largest pyroclastic deposit (Aristarchus Plateau), which corroborates prior observations that hydrogen and/or water plays a role in lunar magmatic events. Global data show a correlation between hydrogen and evolved materials rich in incompatible trace elements (i.e., KREEP type rocks), with a hydrogen excess of 14–36 ppm in these materials. Based on this hydrogen enhancement, we estimate a lower-limit water abundance within urKREEP materials (i.e., the final ∼2% of the lunar magma ocean) of 320–820 ppm H2O. This observation implies that water played a role in the original magma-ocean formation and solidification with a lower-limit water content in the original lunar magma ocean of 7–16 ppm or higher.

David J. Lawrence↗
NASA NTRS2022

The First Gradual Solar Energetic Particle Event With an Enhanced He-3 Abundance on Solar Orbiter

The origin of 3 He abundance enhancements in gradual solar energetic particle (SEP) events remains largely unexplained. Two mechanisms have been suggested: the reacceleration of remnant flare material by coronal mass ejection (CME)-driven shocks in interplanetary space, and concomitant activity in the corona. We explore the first gradual SEP event with enhanced 3 He abundance that was observed by Solar Orbiter. The event started on 2020 November 24 and was associated with a relatively fast halo CME. During the event, the spacecraft was at 0.9 au from the Sun. The event-averaged 3 He/ 4 He abundance ratio is 24 times higher than the coronal or solar wind value, and the timing of the 3He intensity was similar to that of other species. We inspected available imaging, radio observations, and the spacecraft magnetic connection to the CME source. The most probable cause of the enhanced 3He abundance apparently are residual 3He ions remaining from a preceding long period of 3 He-rich SEPs on 2020 November 17–23.

Solar particle emission↗
NASA NTRS1972

Helium abundance variations

Using observations of the solar wind by Explorers 34 and 43, the relationship is confirmed between the relative abundance of helium n sub alpha/n sub p and the bulk speed U of the wind, recently described by Hirschberg, Asbridge and Robbins. Use of this relationship n sub alpha/n sub p = a(t)+bU allows the dependence of the relative abundance of helium upon solar activity to be separated from its bulk speed dependence. The proportion of helium in the solar wind at a given bulk speed is found to increase with increasing sunspot number, averaged over the period of observation. It is shown that the relationship between average relative abundance and temperature, deduced using the bulk speed - temperature relation, is consistent with the data. The relative abundance of helium is not found to increase with increasing solar wind flux. This confirms the result of Hirschberg et al, and contradicts the theoretical prediction of Geiss.

Ogilvie, K. W.↗
NASA NTRS1972

Bulk and rare earth abundances in the Luna 16 soil levels A and D.

Determination of the abundances of major, minor, and trace elements by means of sequential INAA (instrumental neutron activation analysis) in two Luna 16 soils, at levels A (about 7 cm depth) and D (about 30 cm depth). Abundances of the bulk elements in Luna 16 soils generally agree with the values reported by Vinogradov (1971). Elemental abundances of both bulk and trace elements are nearly the same for the two A and D soil levels. Overall, the chemical compositions of the two Luna 16 soils are more closely related to Apollo 11 soil 10084 than to Apollo 12 and 14 soils, with the exception of TiO2 abundances.-

Gillum, D. E.↗
NASA NTRS1972

Elemental abundances in stone meteorites.

Measurement of abundances of Na, Al, Sc, Cr, Mn, Fe, Co, and Cu by instrumental neutron activation analyses of 103 chondrites and 17 achondrites. Various sources of error in the method, including sampling errors, are discussed in detail. Examination of the patterns of coherence of the elements determined suggests the presence of effects of fractionation during condensation from the solar nebula of matter parental to chondrites. Such effects seem to be exhibited both in the abundances of lithophilic elements, perhaps being related to varied temperatures of accretion and in the abundances of those elements which would be affected by metal-silicate fractionation in the solar nebula. Atomic abundances relative to Si vary little in carbonaceous chondrites, suggesting that efficient mixing processes operated on these meteorites prior to or during their formation. It is suggested that, at present, no single class of carbonaceous chondrites is clearly more primitive than another. Carbonaceous and unequilibrated ordinary chondrites may represent aggregates of material accreted from the solar nebula at relatively low temperatures. The present data support a model of equilibration and minor mobilization of nonvolatile elements within small domains of chondrites after accretion. Such a model would be consistent with the petrologic types of Van Schmus and Wood (1967).

Schmitt, R. A.↗
NASA NTRS1972

Helium abundance variations.

Use of observations of the solar wind by Explorers 34 and 43 to confirm the existence of a linear relationship between the relative abundance of helium and the bulk speed of the wind, recently described by Hirshberg et al. (1972). Use of this relationship allows the dependence of the relative abundance of helium on solar activity to be separated from its dependence on bulk speed. The proportion of helium in the solar wind at a given bulk speed is found to increase with increasing sunspot number, averaged over the period of observation. It is shown that the relationship between average relative abundance and temperature, deduced by using the bulk speed/temperature relation, is consistent with the data. The relative abundance of helium is not found to increase with increasing solar-wind flux. This confirms the result of Hirshberg et al.

Ogilvie, K. W.↗
NASA NTRS1972

Abundances of the elements.

An elemental abundance table along the lines used by Suess and Urey (1956) is presented. Since this early work, other studies have been made, and improvement in the abundance tables has been made as more reliable data have become available. Some changes in the original tables have been made, but the original abundances and their variations with mass numbers remain remarkably similar. The solar abundance of iron for many years appeared to be very much less relative to silicon than would be indicated by the data from the meteorites.

Urey, H. C.↗
NASA NTRS1973

Luna 20 soil - Abundance and composition of phases in the 45-125 micron fraction.

Glass compositions in the Luna 20 soil indicate a minor contribution of mare rocks and a major contribution of highly feldspathic highland material. Glasses with the composition of highland basalt (anorthositic gabbro or norite) predominate in a range of highly aluminous glasses. The analyses of minerals in the soil show that the highland rocks have a unique assemblage of minerals that can readily be distinguished from the mineral assemblages of either mare or KREEP basalts. The soils are characterized by abundant anorthitic, low-Fe plagioclase. Highly magnesian orthopyroxenes, pigeonites, and augites are the most prominent pyroxenes. Unlike mare basalt pyroxenes, clinopyroxenes with intermediate Ca values are not abundant, but extreme iron enrichment toward pyroxferroite does occur. Olivines are more abundant than at other sites and are Mg-rich, low in Ca and Cr. Spinels with compositions approaching MgAl2O4 predominate over pleonastes and chromites. Ilmenite and metal are present but not abundant. The mineral compositions are consistent with derivation from a suite of highly feldspathic rocks in which highland basalt compositions predominate.

Reid, A. M.↗