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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Stream water sourcing from high-elevation snowpack inferred from stable isotopes of water: a novel application of d-excess values

About 80 % of the precipitation at the Colorado River's headwaters is snow, and the resulting snowmelt-driven hydrograph is a crucial water source for about 40 million people. Snowmelt from alpine and subalpine snowpack contributes substantially to groundwater recharge and river flow. However, the dynamics of snowmelt progression are not well understood because observations of the high-elevation snowpack are difficult due to challenging access in complex mountainous terrain as well as the cost and labor intensity of currently available methods. We present a novel approach to infer the processes and dynamics of high-elevation snowmelt contributions predicated upon stable hydrogen and oxygen isotope ratios observed in streamflow. We show that deuterium-excess (d-excess) values of stream water could serve as a comparatively cost-effective proxy for a catchment-integrated signal of high-elevation snowmelt contributions to catchment runoff. We sampled stable hydrogen and oxygen isotope ratios of the precipitation, snowpack, and stream water in the East River, a headwater catchment of the Colorado River, and the stream water of larger catchments at sites on the Gunnison River and Colorado River. The d-excess of snowpack increased with elevation; the upper subalpine and alpine snowpack (> 3200 m) had substantially higher d-excess compared to lower elevations (< 3200 m) in the study area. The d-excess values of stream water reflected this because d-excess values increased as the higher-elevation snowpack contributed more to stream water generation later in the snowmelt/runoff season. End-member mixing analyses based on the d-excess data showed that the share of high-elevation snowmelt contributions within the snowmelt hydrograph was on average 44 % and generally increased during melt period progression, up to 70 %. The observed pattern was consistent during 6 years for the East River, and a similar relation was found for the larger catchments on the Gunnison and Colorado rivers. High-elevation snowpack contributions were found to be higher for years with lower snowpack and warmer spring temperatures. Thus, we conclude that the d-excess of stream water is a viable proxy to observe changes in high-elevation snowmelt contributions in catchments at various scales. Inter-catchment comparisons and temporal trends of the d-excess of stream water could therefore serve as a catchment-integrated measure to monitor if mountain systems rely on high-elevation water inputs more during snow drought compared to years of average snowpack depths.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1993

Temporal changes in endmember abundances, liquid water and water vapor over vegetation at Jasper Ridge

Imaging spectrometry offers a new way of deriving ecological information about vegetation communities from remote sensing. Applications include derivation of canopy chemistry, measurement of column atmospheric water vapor and liquid water, improved detectability of materials, more accurate estimation of green vegetation cover and discrimination of spectrally distinct green leaf, non-photosynthetic vegetation (NPV: litter, wood, bark, etc.) and shade spectra associated with different vegetation communities. Much of our emphasis has been on interpreting Airborne Visible/Infrared Imaging Spectrometry (AVIRIS) data spectral mixtures. Two approaches have been used, simple models, where the data are treated as a mixture of 3 to 4 laboratory/field measured spectra, known as reference endmembers (EM's), applied uniformly to the whole image, to more complex models where both the number of EM's and the types of EM's vary on a per-pixel basis. Where simple models are applied, materials, such as NPV, which are spectrally similar to soils, can be discriminated on the basis of residual spectra. One key aspect is that the data are calibrated to reflectance and modeled as mixtures of reference EM's, permitting temporal comparison of EM fractions, independent of scene location or data type. In previous studies the calibration was performed using a modified-empirical line calibration, assuming a uniform atmosphere across the scene. In this study, a Modtran-based calibration approach was used to map liquid water and atmospheric water vapor and retrieve surface reflectance from three AVIRIS scenes acquired in 1992 over the Jasper Ridge Biological Preserve. The data were acquired on June 2nd, September 4th and October 6th. Reflectance images were analyzed as spectral mixtures of reference EM's using a simple 4 EM model. Atmospheric water vapor derived from Modtran was compared to elevation, and community type. Liquid water was compare to the abundance of NPV, Shade and Green Vegetation (VG) for select sites to determine whether a relationship existed, and under what conditions the relationship broke down. Temporal trends in endmember fractions, liquid water and atmospheric water vapor were investigated also. The combination of spectral mixture analysis and the Modtran based atmospheric/liquid water models was used to develop a unique vegetation community description.

Roberts, Dar A.↗
NASA NTRS2015

The Mars Dust and Water Cycles: Investigating the Influence of Clouds on the Vertical Distribution and Meridional Transport of Dust and Water.

The dust and water cycles are critical to the current Martian climate, and they interact with each other through cloud formation. Dust modulates the thermal structure of the atmosphere and thus greatly influences atmospheric circulation. Clouds provide radiative forcing and control the net hemispheric transport of water through the alteration of the vertical distributions of water and dust. Recent advancements in the quality and sophistication of both climate models and observations enable an increased understanding of how the coupling between the dust and water cycles (through cloud formation) impacts the dust and water cycles. We focus here on the effects of clouds on the vertical distributions of dust and water and how those vertical distributions control the net meridional transport of water. We utilize observations of temperature, dust and water ice from the Mars Climate Sounder (MCS) on the Mars Reconnaissance Orbiter (MRO) and the NASA ARC Mars Global Climate Model (MGCM) to show that the magnitude and nature of the hemispheric exchange of water during NH summer is sensitive to the vertical structure of the simulated aphelion cloud belt. Further, we investigate how clouds influence atmospheric temperatures and thus the vertical structure of the cloud belt. Our goal is to isolate and understand the importance of radiative/dynamic feedbacks due to the physical processes involved with cloud formation and evolution on the current climate of Mars.

NASA ARC Mars Global Climate Model (MGCM)↗
NASA NTRS2019

Updated MISR Over-Water Research Aerosol Retrieval Algorithm - Part 2: A Multi-Angle Aerosol Retrieval Algorithm for Shallow, Turbid, Oligotrophic, and Eutrophic Waters

Coastal waters serve as transport pathways to the ocean for all agricultural and other runoff from terrestrial sources, and many are the sites for upwelling of nutrient rich, deep water; they are also some of the most biologically productive on Earth. Estimating the impact coastal waters have on the global carbon budget requires relating satellite-based remote-sensing retrievals of biological productivity (e.g., chlorophyll alpha concentration) to in situ measurements taken in near-surface waters. The Multi-angle Imaging SpectroRadiometer (MISR) can uniquely constrain the "atmospheric correction" needed to derive ocean color from remote-sensing imagers. Here, we retrieve aerosol amount and type from MISR over all types of water. The primary limitation is an upper bound on aerosol optical depth (AOD), as the algorithm must be able to distinguish the surface. This updated MISR research aerosol retrieval algorithm (RA) also assumes that light reflection by the underlying ocean surface is Lambertian. The RA computes the ocean surface reflectance (R (sub rs)) analytically for a given AOD, aerosol optical model, and wind speed. We provide retrieval examples over shallow, turbid, and eutrophic waters and introduce a productivity and turbidity index (PTI), calculated from retrieved spectral R (sub rs), that distinguished water types (similar to the the normalized difference vegetation index, NDVI, over land). We also validate the new algorithm by comparing spectral AOD and Angstrom exponent (ANG) results with 2419 collocated AErosol RObotic NETwork (AERONET) observations. For AERONET 558 nanometer-interpolated AOD less than 1.0, the root-mean square error (RMSE) is 0.04 and linear correlation coefficient is 0.95. For the 502 cloud-free MISR and AERONET collocations with an AERONET AOD greater than 0.20, the ANG RMSE is 0.25 and r is 0.89. Although MISR RA AOD retrieval quality does not appear to be substantially impacted by the presence of turbid water, the MISR-RA-retrieved Angstrom exponent seems to suffer from increased uncertainty under such conditions. MISR supplements current ocean color sources in regions where sunglint precludes retrievals from single-view-angle instruments. MISR atmospheric correction should also be more robust than that derived from single-view instruments such as the Moderate Resolution Imaging Spectroradiometer (MODIS). This is especially true in regions of shallow, turbid, and eutrophic waters, locations where biological productivity can be high, and single-view-angle retrieval algorithms struggle to separate atmospheric from oceanic features.

Satellite Remote Sensing↗
NASA NTRS2018

Remote Sensing Applications for Water Resources Management, Including Droughts, Floods, and Associated Water Cycle Extremes II

Water resources management can benefit from applications of remote sensing and hydrologic models. These tools can be especially valuable during extreme events and in data-sparse regions. Observational platforms include the GPM, SMAP, Terra, Aqua, Landsat, GRACE, and Sentinel satellites, and other satellite and airborne platforms. They can support the operational water resources management community in responding to climate change, increases in climate variability and the frequency of extreme events. This session will highlight advances in the use of satellite, airborne and ground-based sensor networks to: measure the quantity/quality of hydrologic resources in the U.S. and internationally; provide information to water managers to improve water resources management; and support risk-based decision making. Topics of interest include (1) extreme events such as floods and droughts; (2) water supply and snow water resource monitoring and forecasting; (3) evapotranspiration, soil moisture, groundwater, and agricultural water management; (4) water quality and (5) global water sustainability.

Bolten, John D.↗
NASA NTRS2019

Water-Saving Agriculture Can Deliver Deep Water Cuts for China

China is working hard to reconcile growing demands for freshwater with already oversubscribed renewable water resources. However, the knowledge essential for setting and achieving the intended water consumption cuts remains limited. Here we show that on-farm water management interventions such as improved irrigation and soil management practices for maize cultivation can lead to substantial water consumption reductions, by a simulated total of 28-46% (7-14 billion m3/year) nationally, with or without the impacts of climate change. The water consumption cut is equivalent to 16-31% of the ultimate capacity of the South-North Water Transfer Project. Much of the reduction is achievable at the populous and water-stressed North China Plain and Northeast China. Meanwhile, the interventions can increase maize production by an estimated 7-15%, meeting 22-28% of demand increase projected for 2050. The water management and food production improvements obtained are crucial for achieving multiple Sustainable Development Goals (SDGs) related to water, land, and food in China and far beyond.

Guorui Huang↗
DOE OSTI2022

In Hot Water! The Challenges and Barriers of Decarbonizing Water Heating in Multifamily Buildings: Preprint

Domestic hot water heating is responsible for 32% of the total energy consumption in multifamily buildings and offers a significant decarbonization opportunity. An extensive market assessment was conducted to understand and document key technical and economic barriers to electrification of domestic water heating in multifamily buildings throughout the U.S. Through the program, 77 interviews were conducted to understand key market drivers and technical challenges associated with electrification of water heating systems in both retrofit and new construction scenarios. Interviewees encompassed a wide range of stakeholders in the ecosystem surrounding water heating systems, including suppliers, manufacturers, designers, owners, utilities, and developers. This paper documents key interview takeaways, including an extensive list of market barriers, technical challenges, and sought-after technology attributes that can inform pertinent design criteria for electric water heating research, development, and deployment efforts. Among economics and energy efficiency features, interviewees overwhelmingly alluded to space constraints, cold air exhaust, and lack of clear guidance regarding distributed versus centralized design selections as key challenges associated with mass adoption of electric water heating. Owners and developers seek systems with minimal footprint, which maximize rentable space and profits. Moreover, distributed heat pump solutions should balance ducting costs that mitigate cold exhaust entrainment into conditioned zones. Lastly, the market needs clear guidance regarding the selection of distributed versus central electric hot water systems.

challenges of water heating electrification↗
DOE OSTI2022

Water limiting current measurements in anion exchange membrane fuel cells (AEMFCs); part 1: Water limiting current method development

We report water management is critical in optimizing anion exchange membrane fuel cell (AEMFCs) performance and durability. The role of membranes on determining cell water balance in AEMFCs has received limited study. A more thorough understanding of membrane water transport parameters is necessary for thorough cell optimization. In this study, a novel method for probing limiting current based on water flux across an AEMFC is presented for the first time. The water limiting current has been investigated as a function of relative humidity of anode and cathode streams, cathode backpressure and cell operating temperature. From these studies, it is clearly shown that water diffusion through the membrane from the anode is the most critical mechanism for achieving high current density performance and durability. The developed method can act as a novel screening technique that focuses on the impacts of water transport parameters and helps identify promising membrane materials based on their water transport properties. A critical but underappreciated facet of AEMFC performance and durability.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2025

Field-scale mapping of California crop water productivity to inform water management in critically overdrafted groundwater basins

Crop water productivity (CWP) metrics can reveal how the dynamics of crop production and water use change across space and time. We use field-scale satellite inputs from 2016–2021 to estimate potential water savings for four crops (almonds, grapes, walnuts, and citrus—which collectively account for approximately one-third of California’s cropland area), within critically overdrafted groundwater sub-basins of California’s San Joaquin Valley. These annual estimates of field-level water savings potential are based on locally achievable CWP values for each crop type. Our findings show considerable spatial variation in CWP and potential water savings within each sub-basin. We find that increasing CWP to peak efficiency (defined as improving fields to the 95th percentile of observed CWP) for four crops could meet up to 36% of the estimated annual overdraft in San Joaquin Valley. For comparison, fallowing 5% of the four crop type fields in the same study area could potentially reduce annual overdraft by 11%. By delivering results at the field scale, our work can inform targeted interventions by irrigation district managers and more efficient allocation of state incentives for improved water management. For example, we estimate that state grant funding for water efficiency upgrades could have amplified potential water savings threefold by targeting investments to the least efficient fields.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2012

Correction Technique for Raman Water Vapor Lidar Signal-Dependent Bias and Suitability for Water Wapor Trend Monitoring in the Upper Troposphere

The MOHAVE-2009 campaign brought together diverse instrumentation for measuring atmospheric water vapor. We report on the participation of the ALVICE (Atmospheric Laboratory for Validation, Interagency Collaboration and Education) mobile laboratory in the MOHAVE-2009 campaign. In appendices we also report on the performance of the corrected Vaisala RS92 radiosonde measurements during the campaign, on a new radiosonde based calibration algorithm that reduces the influence of atmospheric variability on the derived calibration constant, and on other results of the ALVICE deployment. The MOHAVE-2009 campaign permitted the Raman lidar systems participating to discover and address measurement biases in the upper troposphere and lower stratosphere. The ALVICE lidar system was found to possess a wet bias which was attributed to fluorescence of insect material that was deposited on the telescope early in the mission. Other sources of wet biases are discussed and data from other Raman lidar systems are investigated, revealing that wet biases in upper tropospheric (UT) and lower stratospheric (LS) water vapor measurements appear to be quite common in Raman lidar systems. Lower stratospheric climatology of water vapor is investigated both as a means to check for the existence of these wet biases in Raman lidar data and as a source of correction for the bias. A correction technique is derived and applied to the ALVICE lidar water vapor profiles. Good agreement is found between corrected ALVICE lidar measurments and those of RS92, frost point hygrometer and total column water. The correction is offered as a general method to both quality control Raman water vapor lidar data and to correct those data that have signal-dependent bias. The influence of the correction is shown to be small at regions in the upper troposphere where recent work indicates detection of trends in atmospheric water vapor may be most robust. The correction shown here holds promise for permitting useful upper tropospheric water vapor profiles to be consistently measured by Raman lidar within NDACC (Network for the Detection of Atmospheric Composition Change) and elsewhere, despite the prevalence of instrumental and atmospheric effects that can contaminate the very low signal to noise measurements in the UT.

MOHAVE-2009↗
DOE OSTI2020

Small molecule crystals with 1D water wires modulate electronic properties of surface water networks

This work evaluates the effect of water vapor pressure on the surface conductivity of a hydrated small molecule crystal under dry and wet conditions. The crystal contains a discrete metal complex with waters of hydration in structural positions and in 1D water wires. Under dry conditions, the surface of the hydrated crystal behaves as a near ideal capacitor. Under wet conditions, the waters of hydration serve as a template to assemble surface water networks by organization of water from the environment. The surface water provides pathways for charge transfer attributed to proton mobility that increases conductivity by > 3 orders in magnitude. Modulation between wet and dry conditions tunes the conductivity of the crystal surface via a two-step process, which has been evaluated kinetically as a function of the water vapor pressure.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Quantifying the anomalous water absorption behavior of cement mortar in view of its physical sensitivity to water

The one-dimensional water absorption into cement-based materials, possibly the simplest case of unsaturated water flow playing a fundamental role in predicting mass transport and durability, is still far from being completely understood due to several puzzling anomalies. Considering the water sensitivity of C-S-H gels (swell upon wetting and contract upon drying), a modified Richards equation (MRE) is proposed to quantify the anomalous water absorption into cement-based materials of changing porosity. Consistent experimental tests on a cement mortar and calculations indicate that the MRE with time-decaying water permeability can quantitatively capture the long-term absorption with two linear stages and a nonlinear transition stage between them. The water sensitivity is validated to be responsible for the anomalous deviation of water absorption from the classical square root of time law. It also partially contributes to the anomalous dependence of sorptivity on the temperature-dependent surface tension and viscosity of water and many organic liquids.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Peak Reduction Using Mode Adjustment of Heat Pump Water Heaters in a Residential Neighborhood

Building electrification is putting pressure on distribution grid worldwide. Peak reduction is an important concern that can help reduce the growing stress and allow to defer investments in new capacity. Water heaters represent a convenient way of reducing peak because they are less dependent on weather, and their storage volume allows for asynchronous water heating and hot water use. Previous empirical studies investigated the ability of water heaters to reduce peak through the adjustment of the temperature setpoint. However, not all equipment vendors offer this option. This study aims at understanding the feasibility of peak reduction with an alternative configuration available in the market - by adjusting the device mode rather than temperature setpoint. The peak reduction methodology is tested in an occupied 46-townhome neighborhood located in Atlanta, GA. We find that peak shifting is possible with the adjustable mode approach, with the change in the peak load by 30-60%.

demand response↗
DOE OSTI2022

METSiCloPs in Cooling Tower Water, Final Presentation: Water Treatment at FSI [Slides]

Motivation: According to current projections, FSI could require anywhere from 83-288 MGY of water. Reducing excessive dependence on external water supply by making operations as water-lean as possible in the face of water availability fluctuations seasonally. The amount of Silica occurring naturally in New Mexico is several multiples higher than most of the country, with average values of 90 ppm, but reaching as high as 113 ppm. Since its saturation concentration at ambient temperatures is about 150 ppm, this corresponds to cycles of concentration as low as 1-2 for untreated water in cooling towers (i.e., the water is circulated through the towers only once or twice before they are dumped into the outfall), thereby making operations highly water intensive. There is, therefore, there is a strong need and internal motivation to remove Silica from the water that is circulated in the cooling towers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Irrigation Infrastructure and Modernization – Setting a Baseline: Estimates of Irrigation Water Conveyance Infrastructure Extents and Composition and the Potential Water, Energy, and Economic Benefits of Modernization in the Western U.S.

In the Western United States (U.S.), water delivery for irrigation is still largely managed using century-old equipment and designs. Modernization of this vital water conveyance infrastructure, such as piping of earthen canals, is known to improve water availability and water quality for farmers, while saving energy and enabling new hydropower. However, there is sparse information about the extent of irrigation water delivery infrastructure, which makes it challenging to estimate the cost of upgrades at scale and the potential benefits of accelerating modernization work. This report estimates a variety of previously unquantified data points related to irrigation water delivery infrastructure in the Western U.S. to support stakeholders interested in nationwide modernization planning. The findings should be considered approximations, useful for understanding the scale, range, or variability of these indicators. Taken together, the findings of this report illustrate some of the challenges and opportunities involved in modernizing the agricultural water delivery infrastructure in the Western U.S. Accelerating the pace of modernization could strengthen the long-term resilience of U.S. food systems while providing significant economic, energy, water, and environmental benefits.

13 HYDRO ENERGY↗
DOE OSTI2026

Single‐Step Recovery of Water from Stable Crude Oil‐Water Emulsion Using Surface Engineered Hybrid Inorganic‐Polymer Membranes

ABSTRACT Separating crude oil from water remains one of the most stubborn challenges in environmental remediation, especially for surfactant‐stabilized emulsions that resist conventional demulsification methods. Here, we report a scalable strategy for achieving near‐zero‐discharge separation of crude oil emulsions using a single superhydrophilic membrane. By applying low‐temperature atomic layer deposition (ALD) of various metal oxides onto activated polyvinylidene fluoride (PVDF) membranes, we create atomically precise surface‐engineered (SE) membranes that maintain an exceptionally strong hydration layer at the membrane‐feed interface, even at high oil loadings. Among the various metal oxides, TiO 2 ‐modified SE membranes exhibit superior interfacial water stability, enabling sustained dewatering of complex crude oil‐water emulsions with >98% separation efficiency and >97% water recovery, compared to only 24.6% water recovery for the pristine membrane. This separation performance surpasses conventional hydrophilic membranes and is comparable to complex Janus channel membrane systems, demonstrating near‐complete emulsion separation using a single membrane. This low‐temperature membrane surface engineering process with atomic‐level precision and potential for scalability via roll‐to‐roll fabrication is promising for industrial‐scale, energy‐efficient water treatment and oil spill remediation applications.

Sengupta, Bratin [Applied Materials Division Argon↗
DOE OSTI2023

An investigation on the structural stability of $\mathrm{ZIF}$-8 in water versus water-derived oxidative species in aqueous environment

We report the zeolitic-imidazolate-framework-8 (ZIF-8) is one of the extensively studied metal-organic frameworks (MOF) materials because of its unique structure. For its potential applicability in numerous fields, it becomes crucial to have detailed studies on the structural stability of ZIF-8, especially in aqueous environments. A number of studies have been conducted to investigate the breakdown process of the ZIF-8 structure in water; which is known as the hydrolysis of ZIF-8. However, those studies reported different opposing experimental observations on the role of water on the structural stability of ZIF-8, which created obscurity in understanding this phenomenon. This study explored the effects of different water-derived species on the structural stability of ZIF-8; specifically, examined the effects of only water and water with different oxidative species that may be generated by water molecules' dissociation under external energy or catalyst presence. To this effort, we experimentally probed the physical and chemical structural changes of ZIF-8 in DI water and three different solutions of hydrogen peroxides (H 2 O 2 ); taking H 2 O 2 as the source of oxidative species. To assess the changes in elemental compositions, chemical bonds, functional groups, crystal structure, and morphology, all the samples were analyzed by X-ray photoelectron spectroscopy (XPS), energy-dispersive x-ray (EDX) spectroscopy, Fourier Transform Infrared (FTIR) spectroscope, X-ray diffractometer (XRD), and scanning electron microscope (SEM). Significant structural changes in ZIF-8 occurred mainly in the presence of oxidative species in water. Notably, oxidative species' concentration exceeding 1 M heightened the deformation of the ZIF-8 structure.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Sequence Modulates Polypeptoid Hydration Water Structure and Dynamics

We use molecular dynamics simulations to investigate the effect of polypeptoid sequence on the structure and dynamics of its hydration waters. Polypeptoids provide an excellent platform to study small-molecule hydration in disordered polymers, as they can be precisely synthesized with a variety of sidechain chemistries. We examine water behavior near a set of peptoid oligomers in which the number and placement of nonpolar versus polar sidechains are systematically varied. To do this, we leverage a new computational workflow enabling accurate sampling of polypeptoid conformations. We find that the hydration waters are less dense, are more tetrahedral, and have slower dynamics compared to bulk water. The magnitude of these shifts increases with the number of nonpolar groups. Here, we also find that shifts in the water structure and dynamics are strongly correlated, suggesting that experimental insight into the dynamics of hydration water obtained by Overhauser dynamic nuclear polarization (ODNP) also contains information about water structural properties. We then demonstrate the ability of ODNP to probe site-specific dynamics of hydration water near these model peptoid systems.

36 MATERIALS SCIENCE↗