Effect of Gas Composition on the Ablation Behavior of a Charring Material
Ablation behavior of charring material in high velocity streams of arc heated air, nitrogen, and argon
GAS STREAM↗
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Tangle-Free Mesh Motion for Ablation Simulations
Problems involving mesh motion-which should not be mistakenly associated with moving mesh methods, a class of adaptive mesh redistribution techniques-are of critical importance in numerical simulations of the thermal response of melting and ablative materials. Ablation is the process by which material vaporizes or otherwise erodes due to strong heating. Accurate modeling of such materials is of the utmost importance in design of passive thermal protection systems ("heatshields") for spacecraft, the layer of the vehicle that ensures survival of crew and craft during re-entry. In an explicit mesh motion approach, a complete thermal solve is first performed. Afterwards, the thermal response is used to determine surface recession rates. These values are then used to generate boundary conditions for an a posteriori correction designed to update the location of the mesh nodes. Most often, linear elastic or biharmonic equations are used to model this material response, traditionally in a finite element framework so that complex geometries can be simulated. A simple scheme for moving the boundary nodes involves receding along the surface normals. However, for all but the simplest problem geometries, evolution in time following such a scheme will eventually bring the mesh to intersect and "tangle" with itself, inducing failure. This presentation demonstrates a comprehensive and sophisticated scheme that analyzes the local geometry of each node with help from user-provided clues to eliminate the tangle and enable simulations on a wide-class of difficult problem geometries. The method developed is demonstrated for linear elastic equations but is general enough that it may be adapted to other modeling equations. The presentation will explicate the inner workings of the tangle-free mesh motion algorithm for both two and three-dimensional meshes. It will show abstract examples of the method's success, including a verification problem that demonstrates its accuracy and correctness. The focus of the presentation will be on the algorithm; specifics on how the techniques may be used in spacecraft design will be not discussed.
Droba, Justin↗
Thermal Insulating Coating for Spacecrafts
To protect spacecraft and their contents from excessive heat thermal protection system are essential. For such thermal protection, metal coatings, ceramic materials, ablative materials, and various matrix materials have all been tried, but none have been found entirely satisfactory. The basis for this thermal protection system is the fact that the heat required to melt a substance is 80 to 100 times larger than the heat required to raise its temperature one degree. This led to the use herein of solid-liquid phase change materials. Unlike conventional heat storage materials, when phase change materials reach the temperature at which they change phase they absorb large amounts of heat without getting hotter. By this invention, then, a coating composition is provided for application to substrates subjected to temperatures above 100 F. The coating composition includes a phase change material.
Kaul, Raj K.↗
Thermal insulating coating for spacecrafts
To protect spacecraft and their contents from excessive heat thermal protection systems are essential. For such thermal protection, metal coatings, ceramic materials, ablative materials, and various matrix materials have all been tried, but none have been found entirely satisfactory. The basis for this thermal protection system is the fact that the heat required to melt a substance is 80 to 100 times larger than the heat required to raise its temperature one degree. This led to the use herein of solid-liquid phase change materials. Unlike conventional heat storage materials, when phase change materials reach the temperature at which they change phase they absorb large amounts of heat without getting hotter. By this invention, then, a coating composition is provided for application to substrates subjected to temperatures above 100? F. The coating composition includes a phase change material.
Kaul, Raj K.↗
Apatites in Gale Crater
ChemCam is an active remote sensing instrument suite that has operated successfully on MSL since landing Aug. 6th, 2012. It uses laser pulses to remove dust and to analyze rocks up to 7 m away. Laser-induced breakdown spectroscopy (LIBS) obtains emission spectra of materials ablated from the samples in electronically excited states. The intensities of the emission lines scale with the abundances of the related element. ChemCam is sensitive to most major rock-forming elements as well as to a set of minor and trace elements such as F, Cl, Li, P, Sr, Ba, and Rb. The measured chemical composition can then be used to infer the mineralogical composition of the ablated material. Here, we report a summary of inferred apatite detections along the MSL traverse at Gale Crater. We present the geologic settings of these findings and derive some interpretations about the formation conditions of apatite in time and space.
Forni, O.↗
Ablative Thermal Protection: An Overview
Contents include the following: Why ablative thermal protections - TPS. Ablative TPS chronology: strategic reentry systems, solid rocket motor nozzles, space (manned missions and planetary entry probes). Ablation mechanisms. Ablation material testing. Ablative material testing.
Laub, Bernie↗
Laser Ablation of Materials for Propulsion of Spacecraft
A report describes experiments performed as part of a continuing investigation of the feasibility of laser ablation of materials as a means of propulsion for small spacecraft. In each experiment, a specimen of ablative material was mounted on a torsion pendulum and irradiated with a laser pulse having an energy of 5 J. The amplitude of the resulting rotation of the torsion pendulum was taken to be an indication of the momentum transferred from the laser beam. Of the ablative materials tested, aluminum foils yielded the smallest rotation amplitudes of the order of 10 degrees. Black coating materials yielded rotation amplitudes of the order of 90 degrees. Samples of silver coated with a fluorinated ethylene propylene (FEP) copolymer yielded the largest rotation amplitudes 6 to 8 full revolutions. The report presents a theory involving heating of a confined plasma followed by escape of the plasma to explain the superior momentum transfer performance of the FEP specimens. It briefly discusses some concepts for optimizing designs of spacecraft engines to maximize the thrust obtainable by exploiting the physical mechanisms of the theory. Also discussed is the use of laser-ablation engines with other types of spacecraft engines.
Edwards, David L.↗
Hemispherical spectral emittance of ablation chars, carbon, and zirconia to 6,000 deg f.
Optical techniques for high temperature emittance and reflectance studies of ablation material char
SPECTRAL EMISSION↗
Thermochemical ablation.
Thermochemical interaction between ablation material and environment during manned reentry, using mainly graphite and composite materials
REENTRY EFFECT↗
Reentry thermal protection from Pioneer F RTG insulation material
Ablation tests were performed on the insulation material used in the Pioneer F radioisotope thermoelectric generator (RTG) in the Ames Arc-Heated Planetary-Gas Wind Tunnel. Test results indicate that the material, trade name Min-K 1301, should experience little ablation for heat transfer rates below 40 BTU/sq ft-sec. If the current design were to be changed so that the various pieces of Min-K were fastened or interlocked together the total amount of heat delivered to the RTG heat source during an earth orbital decay reentry would be reduced by at least 22.7%.
Vorreiter, J. W.↗
Assessment of tbe Performance of Ablative Insulators Under Realistic Solid Rocket Motor Operating Conditions (a Doctoral Dissertation)
Ablative insulators are used in the interior surfaces of solid rocket motors to prevent the mechanical structure of the rocket from failing due to intense heating by the high-temperature solid-propellant combustion products. The complexity of the ablation process underscores the need for ablative material response data procured from a realistic solid rocket motor environment, where all of the potential contributions to material degradation are present and in their appropriate proportions. For this purpose, the present study examines ablative material behavior in a laboratory-scale solid rocket motor. The test apparatus includes a planar, two-dimensional flow channel in which flat ablative material samples are installed downstream of an aluminized solid propellant grain and imaged via real-time X-ray radiography. In this way, the in-situ transient thermal response of an ablator to all of the thermal, chemical, and mechanical erosion mechanisms present in a solid rocket environment can be observed and recorded. The ablative material is instrumented with multiple micro-thermocouples, so that in-depth temperature histories are known. Both total heat flux and thermal radiation flux gauges have been designed, fabricated, and tested to characterize the thermal environment to which the ablative material samples are exposed. These tests not only allow different ablative materials to be compared in a realistic solid rocket motor environment but also improve the understanding of the mechanisms that influence the erosion behavior of a given ablative material.
Martin, Heath Thomas↗
Development of moldable carbonaceous materials for ablative rocket nozzles.
Description of a materials system developed for use as low-cost ablative nozzles for NASA's 260-in. solid rocket motor. Petroleum coke and carbon black fillers were employed; high density was achieved by controlling particle size distribution. An alumina catalyzed furfuryl ester resin which produced high carbon residues after pyrolysis was employed as the binder. Staple carbon fibers improved the strength and crack resistance of molded bodies. In static firing tests of two subscale nozzles, this material compared favorably in erosion rate with several other ablative systems.
Lockhart, R. J.↗
Analytical comparisons of ablative nozzle materials final report, jun. 20, 1963 - nov. 20, 1964
Reaction kinetics ablation program to predict ablation performance of rocket nozzle heat protection materials
ROCKET NOZZLE↗
Exploring in aerospace rocketry. 5 - Materials
Refractory and ablative materials for use in space propulsion systems
Klopp, W. D.↗
Development of Thermal Protection Materials for Future Mars Entry, Descent and Landing Systems
Entry Systems will play a crucial role as NASA develops the technologies required for Human Mars Exploration. The Exploration Technology Development Program Office established the Entry, Descent and Landing (EDL) Technology Development Project to develop Thermal Protection System (TPS) materials for insertion into future Mars Entry Systems. An assessment of current entry system technologies identified significant opportunity to improve the current state of the art in thermal protection materials in order to enable landing of heavy mass (40 mT) payloads. To accomplish this goal, the EDL Project has outlined a framework to define, develop and model the thermal protection system material concepts required to allow for the human exploration of Mars via aerocapture followed by entry. Two primary classes of ablative materials are being developed: rigid and flexible. The rigid ablatives will be applied to the acreage of a 10x30 m rigid mid L/D Aeroshell to endure the dual pulse heating (peak approx.500 W/sq cm). Likewise, flexible ablative materials are being developed for 20-30 m diameter deployable aerodynamic decelerator entry systems that could endure dual pulse heating (peak aprrox.120 W/sq cm). A technology Roadmap is presented that will be used for facilitating the maturation of both the rigid and flexible ablative materials through application of decision metrics (requirements, key performance parameters, TRL definitions, and evaluation criteria) used to assess and advance the various candidate TPS material technologies.
Cassell, Alan M.↗
Retro Rocket Motor Self-Penetrating Scheme for Heat Shield Exhaust Ports
A preliminary scheme was developed for base-mounted solid-propellant retro rocket motors to self-penetrate the Orion Crew Module heat shield for configurations with the heat shield retained during landings on Earth. In this system the motors propel impactors into structural push plates, which in turn push through the heat shield ablator material. The push plates are sized such that the remaining port in the ablator material is large enough to provide adequate flow area for the motor exhaust plume. The push plate thickness is sized to assure structural integrity behind the ablative thermal protection material. The concept feasibility was demonstrated and the performance was characterized using a gas gun to launch representative impactors into heat shield targets with push plates. The tests were conducted using targets equipped with Fiberform(R) and PICA as the heat shield ablator material layer. The PICA penetration event times were estimated to be under 30 ms from the start of motor ignition. The mass of the system (not including motors) was estimated to be less than 2.3 kg (5 lbs) per motor. The configuration and demonstrations are discussed.
landing system↗
TPSAS-NF1676L-21180-DND
Ablative materials are used as the Thermal Protection System (TPS) for space vehicles that enter a planetary atmosphere. During the entry phase, the vehicle experiences high rates of aerodynamic heating. These ablative materials, acting as a heat shield, protect the vehicle from the harsh environment and ensure a safe entry. Ablative materials reduce the incoming heat flux through various phenomena such as near-surface oxidation, pyrolysis chemical reaction, vaporization, and other erosive processes, collectively known as ablation. Spallation is one such ablative process, in which solid particles are ejected from the material into the flow field. The many conditions leading to spallation, however, are not well understood and cannot be described accurately by simple phenomenological models. However, the spallation phenomenon might impact the aerodynamic heating rates of re-entry vehicles using ablative heat shields. For example, the solid particles ejected from the surface can modify the near surface chemical processes and flow field. To investigate spallation effects, a code was developed to compute the dynamics of spalled particles. The code uses a finite-rate chemistry model to study the chemical interactions of the particles with the flow field. The spallation code is dynamically coupled to a CFD solver that models the time accurate hypersonic flow field around an ablative sample. An experimental investigation was also performed at the NASA Langley HYMETS facility. HYMETS is a 400 kW arcjet that can simulate hypersonic flight and Earth or Martian entry conditions. Using high speed cameras, an IR camera, NIR and UV-VIS spectrometers, and other diagnostic instruments, test data on various graphite, LI-900, FiberForm, and PICA test samples were obtained, using target heat flux conditions of 100, 200, and 400 W/cm 2 . From the test campaign, measurements of particle velocity, acceleration and trajectory are obtained.
A Martin↗
An experimental investigation of the damping contribution of an elastomeric ablator on aluminum beams
Damping results are presented for an elastometric ablation material bonded to an aluminum alloy substrate. Tests were conducted on aluminum beams 0.159, 0.318, and 0.476 cm thick, and with and without an ablator. Ablation-material thickness varied from 0.159 to 0.953 cm. Comparative damping data were obtained by using variations of the free-free beam technique with strain gages and piezoelectric transducers. Of the two test arrangements employed, the technique using strain gages produced results that indicated less restraint of the beams. Ablation material, in thicknesses less than 1 cm, substantially increased the damping parameter of the aluminum beams.
Howell, W. E.↗