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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Effect of water vapor on the destruction of ozone in the stratosphere perturbed by ClX or NOx pollutants

Results are presented for a self-consistent one-dimensional coupled flow calculation for Ox, NOx, HOx, ClX, H2O, H2, CH4, H2O2, and N2O densities between 10 and 120 km. The results agree well with observations for the normal midlatitude atmosphere over this altitude range. ClX, NOx, and H2O are varied independently in the model considered. It is shown that the effect of depletion of ozone by ClX is to remove ozone preferentially above 30 km and to lower the altitude of maximum ozone density. This leads to enhanced solar heating of the lower stratosphere and tropopause and suggests the possibility of an increased flux of water into the stratosphere. Increasing water vapor in the stratosphere greatly enhances the rate of destruction of O3 by ClX and also causes an increase in the rate of destruction of O3 in the NOx-perturbed atmosphere.

Liu, S. C.↗
NASA NTRS1991

The Apollo lunar surface water vapor event revisited

On March 7, 1971, the first sunrise following the Apollo 14 mission, the Suprathermal Ion Detector Experiment (SIDE) deployed at the Apollo 14 site reported an intense flux of ions whose mass per charge was consistent with water vapor. The amount of water is examined, and the various acceleration processes, responsible for accelerating ions into the SIDE, are discussed. It is concluded that during most of the event the observed water vapor ions were accelerated by the negative lunar surface electric potential and, secondly, that this event was probably the result of mission associated water vapor, either from the LM ascent and descent stage rockets or from residual water in the descent stage tanks.

Freeman, J. W., Jr.↗
NASA NTRS1993

Surface Net Solar Radiation Estimated from Satellite Measurements: Comparisons with Tower Observations

A parameterization that relates the reflected solar flux at the top of the atmosphere to the net solar flux at the surface in terms of only the column water vapor amount and the solar zenith angle was tested against surface observations. Net surface fluxes deduced from coincidental collocated satellite-measured radiances and from measurements from towers in Boulder during summer and near Saskatoon in winter have mean differences of about 2 W/sq m, regardless of whether the sky is clear or cloudy. Furthermore, comparisons between the net fluxes deduced from the parameterization and from surface measurements showed equally good agreement when the data were partitioned into morning and afternoon observations. This is in contrast to results from an empirical clear-sky algorithm that is unable to account adequately for the effects of clouds and that shows, at Boulder, a distinct morning to afternoon variation, which is presumably due to the predominance of different cloud types throughout the day. It is also demonstrated that the parameterization may be applied to irradiances at the top of the atmosphere that have been temporally averaged by using the temporally averaged column water vapor amount and the temporally averaged cosine of the solar zenith angle. The good agreement between the results of the parameterization and surface measurements suggests that the algorithm is a useful tool for a variety of climate studies.

Li, Zhanqing↗
NASA NTRS1992

Comparison of the observed and calculated clear sky greenhouse effect - Implications for climate studies

The clear sky greenhouse effect is defined in terms of the outgoing longwave clear sky flux at the top of the atmosphere. Recently, interest in the magnitude of the clear sky greenhouse effect has increased due to the archiving of the clear sky flux quantity through the Earth Radiation Budget Experiment (ERBE). The present study investigates to what degree of accuracy this flux can be analyzed by using independent atmospheric and surface data in conjunction with a detailed longwave radiation model. The conclusion from this comparison is that for most regions over oceans the analyzed fluxes agree to within the accuracy of the ERBE-retrieved fluxes (+/- 5 W/sq m). However, in regions where deep convective activity occurs, the ERBE fluxes are significantly higher (10-15 W/sq m) than the calculated fluxes. This bias can arise from either cloud contamination problems or variability in water vapor amount. It is argued that the use of analyzed fluxes may provide a more consistent clear sky flux data set for general circulation modeling validation. Climate implications from the analyzed fluxes are explored. Finally, results for obtaining longwave surface fluxes over the oceans are presented.

Kiehl, J. T.↗
NASA NTRS2002

Cyclic Failure Mechanisms of Thermal and Environmental Barrier Coating Systems Under Thermal Gradient Test Conditions

Plasma-sprayed ZrO2-8wt%Y2O3 and mullite+BSAS/Si multilayer thermal and environmental barrier coating (TBC-EBC) systems on SiC/SiC ceramic matrix composite (CMC) substrates were thermally cyclic tested under high thermal gradients using a laser high-heat-flux rig in conjunction with furnace exposure in water-vapor environments. Coating sintering and interface damage were assessed by monitoring the real-time thermal conductivity changes during the laser heat-flux tests and by examining the microstructural changes after exposure. Sintering kinetics of the coating systems were also independently characterized using a dilatometer. It was found that the coating failure involved both the time-temperature dependent sintering and the cycle frequency dependent cyclic fatigue processes. The water vapor environments not only facilitated the initial coating conductivity increases due to enhanced sintering and interface reaction, but also promoted later conductivity reductions due to the accelerated coating cracking and delamination. The failure mechanisms of the coating systems are also discussed based on the cyclic test results and are correlated to the sintering and thermal stress behavior under the thermal gradient test conditions.

Zhu, Dongming↗
NASA NTRS1993

Surface net solar radiation estimated from satellite measurements - Comparisons with tower observations

A parameterization that relates the reflected solar flux at the top of the atmosphere to the net solar flux at the surface in terms of only the column water vapor amount and the solar zenith angle was tested against surface observations. Net surface fluxes deduced from coincidental collocated satellite-measured radiances and from measurements from towers in Boulder during summer and near Saskatoon in winter have mean differences of about 2 W/sq m, regardless of whether the sky is clear or cloudy. Furthermore, comparisons between the net fluxes deduced from the parameterization and from surface measurements showed equally good agreement when the data were partitioned into morning and afternoon observations. This is in contrast to results from an empirical clear-sky algorithm that is unable to account adequately for the effects of clouds and that shows, at Boulder, a distinct morning to afternoon variation. It is also demonstrated that the parameterization may be applied to irradiances at the top of the atmosphere that have been temporally averaged. The good agreement between the results of the parameterization and surface measurements suggests that the algorithm is a useful tool for a variety of climate studies.

Li, Zhanqing↗
NASA NTRS2017

NIR-Driven Moist Upper Atmospheres of Synchronously Rotating Temperate Terrestrial Exoplanets

H2O is a key molecule in characterizing atmospheres of temperate terrestrial planets, and observations of transmission spectra are expected to play a primary role in detecting its signatures in the near future. The detectability of H2O absorption features in transmission spectra depends on the abundance of water vapor in the upper part of the atmosphere. We study the three-dimensional distribution of atmospheric H2O for synchronously rotating Earth-sized aquaplanets using the general circulation model (GCM) ROCKE-3D, and examine the effects of total incident flux and stellar spectral type. We observe a more gentle increase of the water vapor mixing ratio in response to increased incident flux than one-dimensional models suggest, in qualitative agreement with the climate-stabilizing effect of clouds around the substellar point previously observed in GCMs applied to synchronously rotating planets. However, the water vapor mixing ratio in the upper atmosphere starts to increase while the surface temperature is still moderate. This is explained by the circulation in the upper atmosphere being driven by the radiative heating due to absorption by water vapor and cloud particles, causing efficient vertical transport of water vapor. Consistently, the water vapor mixing ratio is found to be well-correlated with the near-infrared portion of the incident flux. We also simulate transmission spectra based on the GCM outputs, and show that for the more highly irradiated planets, the H2O signatures may be strengthened by a factor of a few, loosening the observational demands for a H2O detection.

Fujii, Yuka↗
NASA NTRS2020

Influence of Sea-Ice Anomalies on Antarctic Precipitation Using Source Attribution in the Community Earth System Model

We conduct sensitivity experiments using a general circulation model that has an explicit water source tagging capability forced by prescribed composites of pre-industrial sea-ice concentrations (SICs) and corresponding sea surface temperatures (SSTs) to understand the impact of sea-ice anomalies on regional evaporation, moisture transport and source–receptor relationships for Antarctic precipitation in the absence of anthropogenic forcing. Surface sensible heat fluxes, evaporation and column-integrated water vapor are larger over Southern Ocean (SO) areas with lower SICs. Changes in Antarctic precipitation and its source attribution with SICs have a strong spatial variability. Among the tagged source regions, the Southern Ocean (south of 50∘ S) contributes the most (40 %) to the Antarctic total precipitation, followed by more northerly ocean basins, most notably the South Pacific Ocean (27%), southern Indian Ocean (16 %) and South Atlantic Ocean (11 %). Comparing two experiments prescribed with high and low pre-industrial SICs, respectively, the annual mean Antarctic precipitation is about 150 Gt yr−1 (or 6 %) more in the lower SIC case than in the higher SIC case. This difference is larger than the model-simulated interannual variability in Antarctic precipitation (99 Gt yr−1). The contrast in contribution from the Southern Ocean, 102 Gt yr−1, is even more significant compared to the interannual variability of 35 Gt yr−1 in Antarctic precipitation that originates from the Southern Ocean. The horizontal transport pathways from individual vapor source regions to Antarctica are largely determined by large-scale atmospheric circulation patterns. Vapor from lower-latitude source regions takes elevated pathways to Antarctica. In contrast, vapor from the Southern Ocean moves southward within the lower troposphere to the Antarctic continent along moist isentropes that are largely shaped by local ambient conditions and coastal topography. This study also highlights the importance of atmospheric dynamics in affecting the thermodynamic impact of sea-ice anomalies associated with natural variability on Antarctic precipitation. Our analyses of the seasonal contrast in changes of basin-scale evaporation, moisture flux and precipitation suggest that the impact of SIC anomalies on regional Antarctic precipitation depends on dynamic changes that arise from SIC–SST perturbations along with internal variability. The latter appears to have a more significant effect on the moisture transport in austral winter than in summer.

Wang, Hailong↗
DOE OSTI2026

ARM Data-Oriented Metrics and Diagnostics Package for Climate Model Evaluation

A Python-based metrics and diagnostics package is currently being developed by the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Infrastructure Team at Lawrence Livermore National Laboratory (LLNL) to facilitate the use of long-term, high-frequency measurements from the ARM Facility in evaluating the regional climate simulation of clouds, radiation, and precipitation. This metrics and diagnostics package computes climatological means of targeted climate model simulation and generates tables and plots for comparing the model simulation with ARM observational data. The Coupled Model Intercomparison Project (CMIP) model data sets are also included in the package to enable model intercomparison as demonstrated in Zhang et al. (2017). The mean of the CMIP model can serve as a reference for individual models. Basic performance metrics are computed to measure the accuracy of mean state and variability of climate models. The evaluated physical quantities include cloud fraction, temperature, relative humidity, cloud liquid water path, total column water vapor, precipitation, sensible and latent heat fluxes, and radiative fluxes, with plan to extend to more fields, such as aerosol and microphysics properties. Process-oriented diagnostics focusing on individual cloud- and precipitation-related phenomena are also being developed for the evaluation and development of specific model physical parameterizations. The version 1.0 package is designed based on data collected at ARM’s Southern Great Plains (SGP) Research Facility, with the plan to extend to other ARM sites. The metrics and diagnostics package is currently built upon standard Python libraries and additional Python packages developed by DOE (such as CDMS and CDAT). The ARM metrics and diagnostic package is available publicly with the hope that it can serve as an easy entry point for climate modelers to compare their models with ARM data. In this report, we first present the input data, which constitutes the core content of the metrics and diagnostics package in section 2, and a user's guide documenting the workflow/structure of the version 1.0 codes, and including step-by-step instruction for running the package in section 3.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1988

The profile of upwelling 11-micron radiance through the atmospheric boundary layer overlying the ocean

Measurements of the gradient of 11-micron radiance from the ocean surface were made with spaceborne AVHRR and with radiometers carried on research vessels in California and east Florida waters. The results obtained for the radiance gradient at a variety of atmospheric conditions are in good agreement with radiative transfer calculations, suggesting that there was no significant error in the water vapor absorption parameters used in the calculations. The results confirm earlier predictions that, for a typical viewing factor (i.e., zenith angle 60 deg) and for mid-latitude standard water vapor conditions, the 11-micron radiant flux measured by a spaceborne sensor will be dominated by the atmospheric contribution to the total outgoing radiation in this 'window' region.

Hagen, Denise E.↗
NASA NTRS1992

Air-sea interaction and remote sensing

The first part of the proposed research was a joint effort between our group and the Applied Physics Laboratory (APL), University of Washington. Our own research goal is to investigate the relation between the air-sea exchange processes and the sea state over the open ocean and to compare these findings with our previous results obtained over a small body of water namely, Lake Washington. The goals of the APL researchers are to study (1) the infrared sea surface temperature (SST) signature of breaking waves and surface slicks, and (2) microwave and acoustic scattering from water surface. The task of our group in this joint effort is to conduct measurements of surface fluxes (of momentum, sensible heat, and water vapor) and atmospheric radiation (longwave and shortwave) to achieve our research goal as well as to provide crucial complementary data for the APL studies. The progress of the project is summarized.

Katsaros, Kristina B.↗
NASA NTRS2001

Thermal Conductivity and Thermal Gradient Cyclic Behavior of Refractory Silicate Coatings on SiC/SiC Ceramic Matrix Composites

Plasma-sprayed mullite and BSAS coatings have been developed to protect SiC/SiC ceramic matrix composites from high temperature environmental attack. In this study, thermal conductivity and thermal barrier functions of these coating systems are evaluated using a laser high-heat-flux test rig. The effects of water vapor on coating thermal conductivity and durability are studied by using alternating furnace and laser thermal gradient cyclic tests. The influence of laser high thermal-gradient cycling on coating failure modes is also investigated.

Zhu, Dongming↗
NASA NTRS1992

Solar cycle variations in H(+) and D(+) densities in the Venus ionosphere - Implications for escape

The hydrogen ion concentrations recently observed on Venus, near solar minimum, by the Ion Mass Spectrometer on the Pioneer Venus Orbiter in the anti-solar sector of the ionosphere are more than an order of magnitude less than those previously observed at solar maximum. This strong solar cycle variation has a profound effect on the escape of hydrogen (and deuterium) from Venus; almost all escape occurs during solar maximum. After adjustment for solar cycle variation, a planet-averaged hydrogen escape flux of 0.6-1.4 x 10 exp 7/sq cm per sec is obtained along with a large deuterium fractionation factor of 0.1-0.14. These results suggest at least two plausible scenarios for the evolution of water on Venus: (1) water vapor on Venus may be approaching a steady state if the escape flux is balanced by endogenous sources of water or (2) the present day D/H ratio of 0.024 could be established by Rayleigh fractionation of an early low D/H water reservoir if the escape flux was sufficiently large in earlier times. An early water endowment at least 340 times today's abundance would be needed.

Donahue, Thomas M.↗
NASA NTRS1992

Satellite-derived surface latent heat fluxes in a rapidly intensifying marine cyclone

The aim of this article is to estimate surface latent heat fluxes in the vicinity of a rapidly deepening cyclone before and during its period of most rapid intensification. This is done with a bulk parameterization scheme and remotely sensed input data. A method for estimating the difference in specific humidity between the surface and a 10-m height is investigated using the Special Sensor Microwave/Imager-observed integrated water vapor field and a sea surface temperature analysis. The surface latent heat flux fields generally have estimated errors below 40 percent south of 40 deg N and outside the region of high integrated water vapor values associated with frontal bands. The method of estimating surface latent heat fluxes for the case study was found to be usable in most regions of the northwest Atlantic Ocean except for those locations directly adjacent to coastlines in instances of offshore flow and in the vicinity of surface fronts.

Miller, Douglas K.↗
DOE OSTI2025

Simulating Pyrocumulonimbus Clouds Using a Multiscale Wildfire Simulation Framework

Pyrocumulonimbus (pyroCb) clouds, driven by extreme fires under favorable meteorological conditions, can inject smoke into the stratosphere at magnitudes comparable to those of moderate volcanic eruptions, potentially altering the global radiative balance and atmospheric composition. However, simulating pyroCb is particularly challenging in Earth system models. Using the Energy Exascale Earth System Model (E3SM), we developed a novel global multiscale framework to model pyroCb events in California, which includes a high‐resolution fire radiative power time series, a one‐dimensional plume‐rise parameterization, a fire‐induced vertical water vapor transport scheme, and a surface wildfire sensible heat flux representation. Our simulation successfully reproduces many pyroCb features, including cloud height, spatiotemporal evolution, and convective intensity in comparison with satellite and ground‐based observations. Sensitivity experiments show that realistic pyroCb simulation depends on vertical water vapor transport. These advances provide a basis for future exploration of pyroCb impacts at regional and global scales within climate models.

E3SM↗
NASA NTRS1992

Satellite-derived surface latent heat fluxes in a rapidly intensifying marine cyclone

Surface latent heat fluxes are estimated in the vicinity of a rapidly deepening cyclone before and during its period of most rapid intensification. This was done with a bulk parameterization scheme and remotely sensed input data. A method is studied for estimating the difference in specific humidity between the surface and a ten meter height using the Special Sensor Microwave/Imager (SSM/I) observed integrated water vapor field and a sea surface temperature analysis. The surface latent heat flux fields generally have estimated errors below 40 pct. south of 40 deg. N and outside the region of high integrated water vapor values associated with frontal bands. The method of estimating surface latent heat fluxes for the case study was found to be usable in most regions of the Northwest Atlantic Ocean except for those locations directly adjacent to coastlines in instances of offshore flow and in the vicinity of surface fronts.

Miller, Douglas K.↗
NASA NTRS2001

The Role of Clear Sky Identification in the Study of Cloud Radiative Effects: Combine Analysis from ISCCP and the Scanner of Radiation Budget (ScaRaB)

Since the effect of clouds on the earth's radiation balance is often estimated as the difference of net radiative fluxes at the top of the atmosphere between all situations and monthly averaged clear sky situations of the same regions, a reliable identification of clear sky is important for the study of cloud radiative effects. The Scanner for Radiation Balance (ScaRaB) radiometer on board the Russian Meteor-3/7 satellite provided earth radiation budget observations from March 1994 to February 1995 with two ERBE-Re broad-band longwave and shortwave channels. Two narrow-band channels, in the infrared atmospheric window and in the visible band, have been added to the ScaRaB instrument to improve the cloud scene identification. The International Satellite Cloud Climatology Project (ISCCP) method for cloud detection and determination of cloud and surface properties uses the same narrow-band channels as ScaRaB, but is employed to a collection of measurements at a better spatial resolution of about 5 km. By applying the original ISCCP algorithms to the ScaRaB data, the clear sky frequency is about 5% lower than the one over quasi-simultaneous original ISCCP data, an indication that the ISCCP cloud detection is quite stable. However, one would expect an about 10 to 20% smaller clear sky occurrence over the larger ScaRaB pixels. Adapting the ISCCP algorithms to the reduced spatial resolution of 60 km and to the different time sampling of the ScaRaB data leads therefore to a reduction of a residual cloud contamination. A sensitivity study with time-space collocated ScaRaB and original ISCCP data at a spatial resolution of 1deg longitude x 1deg latitude shows that the effect of clear sky identification method plays a higher role on the clear sky frequency and therefore on the statistics than on the zonal mean values of the clear sky fluxes. Nevertheless, the zonal outgoing longwave fluxes corresponding to ERBE clear sky are in general about 2 to 10 W/sq m higher than those obtained from the ScaRaB adapted ISCCP clear sky identifications. The latter are close to (about 1 W/sq m higher) fluxes corresponding to clear sky regions from original ISCCP data, whereas ScaRaB clear sky LW fluxes obtained with the original ISCCP identification lie about 1 to 2 W/sq m below. Especially in the tropics where water vapor abundance is high, the ERBE clear sky LW fluxes seem to be systematically overestimated by about 4 W/sq m, and SW fluxes are lower by about 5 to 10 W/sq m. However, the uncertainty in the analysis of monthly mean zonal cloud radiative effects is also produced by the low frequency of clear sky occurrence, illustrated when averaging over pixels or even over regions of 4deg longitude x 5deg latitude, corresponding to the spatial resolution of General Circulation Models. The systematic bias in the clear sky fluxes is not reflected in the zonal cloud radiative effects, because the clear sky regions selected by the different algorithms can occur in different geographic regions with different cloud properties.

Rossow, W. B.↗
NASA NTRS1983

A radiative transfer model for surface radiation budget studies

A high resolution spectral radiative transfer model of the troposphere for computing downwelling radiance and flux density at the surface in the 5-200 micron region has been developed. The model is fast and accurate and takes into consideration all major and minor constituents active in this region, namely, water vapor, carbon dioxide, ozone, nitrous oxide, and methane. It uses the quasi-random band model of absorption for computing atmospheric transmittances due to various bands. Continuum absorption by water vapor in the 8-14 micron region has also been taken into account. The model has been used to examine the sensitivity of downwelling flux to variations of surface water vapor pressure (or surface relative humidity), water vapor scale-height and concentrations of other gaseous constituents of the atmosphere. In addition, sensitivity to changes in a number of cloud parameters, namely, fractional cloud cover, cloud height, and high-cloud emissivity, has also been examined. Results obtained with the present model compare well with those from the empirical and semi-empirical correlations. The present work demonstrates, for the first time, the feasibility of using a high-resolution narrow-band model for computing this flux for a meteorological application.

Gupta, S. K.↗