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At least 127 records · Page 7

Wave packet dynamics and control in excited states of molecular nitrogen

Wave packet interferometry with vacuum ultraviolet light has been used to probe a complex region of the electronic spectrum of molecular nitrogen, N 2 . Wave packets of Rydberg and valence states were excited by using double pulses of vacuum ultraviolet (VUV), free-electron-laser (FEL) light. These wave packets were composed of contributions from multiple electronic states with a moderate principal quantum number (n ~ 4-9) and a range of vibrational and rotational quantum numbers. The phase relationship of the two FEL pulses varied in time, but as demonstrated previously, a shot-by-shot analysis allows the spectra to be sorted according to the phase between the two pulses. The wave packets were probed by angle-resolved photoionization using an infrared pulse with a variable delay after the pair of excitation pulses. The photoelectron branching fractions and angular distributions display oscillations that depend on both the time delays and the relative phases of the VUV pulses. The combination of frequency, time delay, and phase selection provides significant control over the ionization process and ultimately improves the ability to analyze and assign complex molecular spectra.

74 ATOMIC AND MOLECULAR PHYSICS↗

Sensor detects hydrocarbon oil contaminants in fluid lines

Sensor with ultraviolet light monitors and detects hydrocarbon oil contaminants present in fluid lines. The light causes the oil particles to fluoresce. This light emitted by the oil particle is detected by a photocell which is relatively insensitive to ultraviolet radiation.

Roth, B.↗

Short-term FUV flux variability and phase-dependent winds in Be stars

FUV (Far Ultraviolet) light curves and the behavior of the C IV wind line versus phase are discussed for four Be stars. The IUE (International Ultraviolet Explorer) data acquired during three multiwavelength campaigns aimed at determining the cause for short term optical light variability in Be stars and whether it is linked with the mass loss mechanism is presented. The observations confirm that it is a modulation in the star's photospheric temperature that causes the flux variability. A phase dependent variation is seen in the equivalent width and profile in the C IV wind line. The wind absorption tends to be strongest at maximum light and in a Be shell star the absolute flux of its C IV emission component appears to be anticorrelated with the absorption strength and the level of the FUV flux. The observations suggest that nonradial pulsations are responsible for the photometric variability and the generic model of a star pulsating in a sectorial mode.

Peters, G. J.↗

Imaging Thermal He(+)in Geospace from the Lunar Surface

By mass, thermal plasma dominates near-earth space and strongly influences the transport of energy and mass into the earth's atmosphere. It is proposed to play an important role in modifying the strength of space weather storms by its presence in regions of magnetic reconnection in the dayside magnetopause and in the near to mid-magnetotail. Ionospheric-origin thermal plasma also represents the most significant potential loss of atmospheric mass from our planet over geological time. Knowledge of the loss of convected thermal plasma into the solar wind versus its recirculation across high latitudes and through the magnetospheric flanks into the magnetospheric tail will enable determination of the mass balance for this mass-dominant component of the Geospace system and of its influence on global magnetospheric processes that are critical to space weather prediction and hence to the impact of space processes on human technology in space and on Earth. Our proposed concept addresses this basic issue of Geospace dynamics by imaging thermal He(+) ions in extreme ultraviolet light with an instrument on the lunar surface. The concept is derived from the highly successful Extreme Ultraviolet imager (EUV) flown on the Imager for Magnetopause-to-Aurora Global Exploration (IMAGE) spacecraft. From the lunar surface an advanced EUV imager is anticipated to have much higher sensitivity, lower background noise, and higher communication bandwidth back to Earth. From the near-magnetic equatorial location on the lunar surface, such an imager would be ideally located to follow thermal He(+) ions to high latitudes, into the magnetospheric flanks, and into the magnetotail.

Gallagher, D. L.↗

Mosaic-Detector-Based Fluorescence Spectral Imager

A battery-powered, pen-sized, portable instrument for measuring molecular fluorescence spectra of chemical and biological samples in the field has been proposed. Molecular fluorescence spectroscopy is among the techniques used most frequently in laboratories to analyze compositions of chemical and biological samples. Heretofore, it has been possible to measure fluorescence spectra of molecular species at relative concentrations as low as parts per billion (ppb), with a few nm spectral resolution. The proposed instrument would include a planar array (mosaic) of detectors, onto which a fluorescence spectrum would be spatially mapped. Unlike in the larger laboratory-type molecular fluorescence spectrometers, mapping of wavelengths to spatial positions would be accomplished without use of relatively bulky optical parts. The proposed instrument is expected to be sensitive enough to enable measurement of spectra of chemical species at relative concentrations <1 ppb, with spectral resolution that could be tailored by design to be comparable to a laboratory molecular fluorescence spectrometer. The proposed instrument (see figure) would include a button-cell battery and a laser diode, which would generate the monochromatic ultraviolet light needed to excite fluorescence in a sample. The sample would be held in a cell bounded by far-ultraviolet-transparent quartz or optical glass. The detector array would be, more specifically, a complementary metal oxide/ semiconductor or charge-coupled- device imaging photodetector array, the photodetectors of which would be tailored to respond to light in the wavelength range of the fluorescence spectrum to be measured. The light-input face of the photodetector array would be covered with a matching checkerboard array of multilayer thin film interference filters, such that each pixel in the array would be sensitive only to light in a spectral band narrow enough so as not to overlap significantly with the band of an adjacent pixel. The wavelength interval between adjacent pixels (and, thus, the spectral resolution) would typically be chosen by design to be approximately equal to the width of the total fluorescence wavelength range of interest divided by the number of pixels. The unitary structure comprising the photodetector array overlaid with the matching filter array would be denoted a hyperspectral mosaic detector (HMD) array.

Son, Kyung-Ah↗

Water additives improve the efficiency of violet perovskite light-emitting diodes

High external quantum efficiencies (EQEs) have been achieved for blue, green, red, and near-infrared perovskite light-emitting diodes (PeLEDs), and their energy efficiencies are approaching the efficiencies of III-V-based LEDs. Beyond the visible regime, ultraviolet light offers great promise for many applications such as disinfection. However, PeLEDs demonstrate poor performance in the violet/ultraviolet region, with reports of violet PeLED performance hindered by poor thin-film quality. In this work, we improve the uniformity of perovskite films by adding water into the precursor solution to engineer the crystallization process of spin-coated 2D perovskites. The resulting improved film uniformity, coupled with the reduction in nanoplate size, reduces leakage current and promotes faster recombination rates. The fabricated PeLEDs deliver bright violet emission at 408 nm with a maximum external quantum efficiency of 0.41%, a 5-fold increase over control devices. Furthermore, this work demonstrates viable steps toward cost-effective, efficient ultraviolet PeLEDs.

36 MATERIALS SCIENCE↗

Effects of levitated dust on astronomical observations from the lunar surface

It is believed that a substantial population of levitated dust is present in the terminator region of the moon. Stray light scattered by this dust layer may contaminate astronomical observations made from the lunar surface using infrared, visible, and ultraviolet light. The evidence for dust levitation stems from: Surveyor vidicon images of horizon glow; anomalous brightness in photographs of the solar corona taken by Apollo astronauts while the spacecraft was just inside the moon's shadow; and observations by Apollo astronauts of streamers just prior to lunar orbital sunrise or just after lunar orbital sunset. It has been proposed that the differential charging of the lunar surface in the terminator region due to photoemission and the consequent strong local electric fields comprise the mechanism responsible for this levitation. Although quantitative data on the levitated lunar dust distribution are meager, it is possible to estimate column densities and sizes. In this paper we summarize the estimates of particulate sizes and number densities of previous authors, and construct a nominal terminator dust distribution, as a function of particulate radius and altitude above the lunar surface. Using the model we estimate the brightness of scattered sunshine for three wavelength bands. For the results in the visible wavelengths, we compare the estimated brightness with the known brightness of selected astronomical objects and discuss the implications for lunar-based astronomy.

Murphy, D. L.↗

Effects of solar ultraviolet radiations on Bacillus subtilis spores and T-7 bacteriophage

Spores of Bacillus subtilis HA 101 and the DNA polymerase I-defective mutant HA 101 (59)F were exposed to selected wavelengths of solar ultraviolet light and space vacuum during the return of Apollo 16. In addition, coliphage T-7 suspensions were exposed to solar ultraviolet radiation as part of the Microbial Response to Space Environment Experiment. Optical filters were employed to provide different energy levels at wavelengths 254 nm and 280 nm. Dose-response curves for lethal and mutagenic effects were compared with ground-based data. A close parallel was observed between the results of solar radiation and ground tests with spores of the two strains. However, significantly greater inactivation of T-7 bacteriophage was observed after exposure to solar ultraviolet radiation.

Spizizen, J.↗

Physics of the Cosmos: Program Annual Technology Report

From ancient times, humans have looked up at the night sky and wondered: Are we alone? How did the universe come to be? How does the universe work? PCOS focuses on that last question. Scientists investigating this broad theme use the universe itself as their laboratory, investigating its fundamental laws and properties. They test Einstein's General Theory of Relativity to see if our current understanding of space-time is borne out by observations. They examine the behavior of the most extreme environments - supermassive black holes, active galactic nuclei, and others - and the farthest reaches of the universe, to expand our understanding. With instruments sensitive across the spectrum, from radio, through infrared (IR), visible light, ultraviolet (UV), to X rays and gamma rays, as well as gravitational waves (GWs), they peer across billions of light-years, observing echoes of events that occurred instants after the Big Bang. The Laser Interferometer Gravitational-Wave Observatory (LIGO) recently recorded the first direct measurement of long-theorized GWs. Another surprising recent discovery is that the universe is expanding at an ever-accelerating rate, the first hint of so-called "dark energy," estimated to account for 75% of mass-energy in the universe. Dark matter, so called because we can only observe its effects on regular matter, accounts for another 20%, leaving only 5% for regular matter and energy. Scientists now also search for special polarization in the cosmic microwave background to support the notion that in the split-second after the Big Bang, the universe inflated faster than the speed of light! The most exciting aspect of this grand enterprise today is that we can finally develop the tools needed for such discoveries.

COR↗

Program Annual Technology Report: Physics of the Cosmos Program Office

From ancient times, humans have looked up at the night sky and wondered: Are we alone? How did the universe come to be? How does the universe work? PCOS focuses on that last question. Scientists investigating this broad theme use the universe as their laboratory, investigating its fundamental laws and properties. They test Einstein’s General Theory of Relativity to see if our current understanding of space-time is borne out by observations. They examine the behavior of the most extreme environments – supermassive black holes, active galactic nuclei, and others – and the farthest reaches of the universe, to expand our understanding. With instruments sensitive across the spectrum, from radio, through infrared (IR), visible light, ultraviolet (UV), to X rays and gamma rays, as well as gravitational waves (GWs), they peer across billions of light-years, observing echoes of events that occurred instants after the Big Bang. Last year, the LISA Pathfinder (LPF) mission exceeded expectations in proving the maturity of technologies needed for the Laser Interferometer Space Antenna (LISA) mission, and the Laser Interferometer Gravitational-Wave Observatory (LIGO) recorded the first direct measurements of long-theorized GWs. Another surprising recent discovery is that the universe is expanding at an ever-accelerating rate, the first hint of so-called “dark energy,” estimated to account for 75% of mass-energy in the universe. Dark matter, so called because we can only observe its effects on regular matter, is thought to account for another20%, leaving only 5% for regular matter and energy. Scientists now also search for special polarization in the cosmic microwave background to support the notion that in the split-second after the Big Bang, the universe inflated faster than the speed of light! The most exciting aspect of this grand enterprise today is the extraordinary rate at which we can harness technologies to enable these key discoveries.

COR↗

Shuttle contamination effects on ultraviolet coronagraphic observations

The ultraviolet light coronagraph being developed for Shuttle by the Harvard-Smithsonian Center for Astrophysics is described. Effects of Shuttle contaminants on ultraviolet coronagraphic observations are discussed and column densities for acceptable attenuation are provided which are generally applicable to high spectral resolution measurements in the 600 A - 1700 A spectral range.

Kohl, J. L.↗

Growth Of Delta-Doped Layer On Silicon CCD

Response to ultraviolet light enhanced. Back-side-illuminated silicon charge-coupled device fabricated exhibiting nearly 100 percent internal quantum efficiency in near ultraviolet, by using molecular beam epitaxy to grow thin crystalline-silicon layer containing high concentration of boron (p-type dopant). By confining dopant atoms to one or few atomic layers in silicon lattice, concentration-vs.-depth profile made to resemble Dirac delta function, and resulting silicon layer said to be "delta-doped."

Hoenk, Michael E.↗

Water Purification Systems

A water purification/recycling system developed by Photo-Catalytics, Inc. (PCI) for NASA is commercially available. The system cleanses and recycles water, using a "photo-catalysis" process in which light or radiant energy sparks a chemical reaction. Chemically stable semiconductor powders are added to organically polluted water. The powder absorbs ultraviolet light, and pollutants are oxidized and converted to carbon dioxide. Potential markets for the system include research and pharmaceutical manufacturing applications, as well as microchip manufacture and wastewater cleansing.

Source record↗

Ultraviolet Lidar Would Measure Wind Velocity

Incoherent Doppler-shifted scattering from aerosols reveals important weather data. Remote-sensing system in early stage of development makes global measurements of wind velocities along probing beam of ultraviolet light. In aviation system promotes safety through detection of wind shears and clear-air turbulence. System includes range-gated ultraviolet-excimer laser operating at 308 or 353 nm.

Mcdermid, Iain Stuart↗

The early spectral evolution of Nova Cassiopeiae 1993

In this paper we describe the evolution of Nova Cas 1993 over the first two months of its outburst. We present an ultraviolet light curve that covers the period from announcement to just after dust began forming in the ejecta (1994 Feb. 15) and International Ultraviolet Explorer (IUE) spacecraft constraints forced us to halt our observations. We have used spherical, expanding, Non-local Thermodynamic Equilibrium (NLTE) stellar atmospheres to compute synthetic spectra and have compared the results to combined ultraviolet (low-resolution 1200-3400 A and high-resolution 2400-3300 A) spectra. Our fits show that the effective temperature of the ejecta increased from approx. 8000 to about approx. 16 000 K between 1993 Dec. 12 and 1993 Dec. 26. The temperature then increased more slowly to approx. 24 000 on 1994 Jan. 28. A preliminary abundance analysis shows evidence for hydrogen depletion, as we also found for Nova V1974 Cygni; however we find a larger enhancement of carbon, nitrogen, and oxygen. We also show that the principal mechanism for mass ejection in this nova is a radiation pressure driven wind and that mechanical driving is not necessary.

Hauschildt, Peter H.↗

Microorganisms in the Stratosphere (MIST): In-flight Sterilization with UVC Leds

The stratosphere (10 km to 50 km above sea level) is a unique place on Earth for astrobiological studies of microbes in extreme environments due to the combination of harsh conditions (high ultraviolet radiation, low pressure, desiccation, and low temperatures). Microorganisms in the Stratosphere (MIST) will attempt to characterize the diversity of microbes at these altitudes using a balloon collection device on a meteorological weather balloon. A major challenge of such an aerobiology study is the potential for ground contamination that makes it difficult to distinguish between collected microbes and contaminants. One solution is to use germicidal ultraviolet light emitting diodes (UV LEDs) to sterilize the collection strip. To use this solution, an optimal spatial arrangement of the lights had to be determined to ensure the greatest chance of complete sterilization within the 30 to 60 minute time of balloon ascent. A novel, 3D-printed test stand was developed to experimentally determine viable Bacillus pumilus SAFR-032 spore reduction after exposure to ultraviolet radiation at various times, angles, and distances. Taken together, the experimental simulations suggested that the UV LEDs on the MIST flight hardware should be active for at least 15 minutes and mounted within 4 cm of the illuminated surface at any angle to achieve optimal sterilization. These findings will aid in the production of the balloon collection device to ensure pristine stratospheric microbial samples are collected. Flight hardware capable of in-flight self-sterilization will enable future life detection missions to minimize both forward contamination and false positives.

Exobiology↗

The Spacelab Lyman alpha and white light coronagraphs program

The Harvard-Smithsonian Center for Astrophysics and the High Altitude Observatory have defined a joint coronagraphs experiment for a future Spacelab mission. The instrumentation package would include an ultraviolet light coronagraph to measure the intensity and profiles of spectral lines formed between 1.2 and 8 solar radii from sun center and a white light coronagraph to measure the intensity and polarization of visible light. The overall goals of the joint program are to use new coronal plasma diagnostic techniques to understand the physical processes and mechanisms operating in the solar corona, to understand the acceleration of high-speed and low-speed solar wind streams and to extrapolate this knowledge to other stars in order to help understand the physics of stellar coronae and stellar mass loss.

Kohl, J. L.↗

The intracellular responses of frog eggs to novel orientations to gravity

It is found that multiple short doses of ultraviolet light are as effective as a single large dose in producing neural defects. In addition, 180 deg rotation (inversion) of irradiated eggs reduces the ultraviolet effect. Since yolk platelets may be the gravity sensing mechanism, their size, density, and distribution in normal and inverted eggs are investigated. Large platelets are denser and for the most part are in a distinct zone in the vegetal hemisphere, whereas small platelets are less dense and occur in the animal hemisphere. When inverted, the large platelets flow into the animal hemisphere as a coherent mass and partially displace the small platelets. Inversion is thought to rearrange cytoplasmic components necessary for later neural development into an appropriate configuration.

Radice, G. P.↗