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NASA NTRS2015

Nanotubular Toughening Inclusions

Conventional toughening agents are typically rubbery materials or small molecular weight molecules, which mostly sacrifice the intrinsic properties of a matrix such as modulus, strength, and thermal stability as side effects. On the other hand, high modulus inclusions tend to reinforce elastic modulus very efficiently, but not the strength very well. For example, mechanical reinforcement with inorganic inclusions often degrades the composite toughness, encountering a frequent catastrophic brittle failure triggered by minute chips and cracks. Thus, toughening generally conflicts with mechanical reinforcement. Carbon nanotubes have been used as efficient reinforcing agents in various applications due to their combination of extraordinary mechanical, electrical, and thermal properties. Moreover, nanotubes can elongate more than 20% without yielding or breaking, and absorb significant amounts of energy during deformation, which enables them to also be an efficient toughening agent, as well as excellent reinforcing inclusion. Accordingly, an improved toughening method is provided by incorporating nanotubular inclusions into a host matrix, such as thermoset and thermoplastic polymers or ceramics without detrimental effects on the matrix's intrinsic physical properties.

Park, Cheol↗

NASA NTRS2017

Nanotubular Toughening Inclusions

Park, Cheol↗

DOE OSTI2021

Multicolor Variability of Young Stars in the Lagoon Nebula: Driving Causes and Intrinsic Timescales

Space observatories have provided unprecedented depictions of the many variability behaviors typical of low-mass, young stars. However, those studies have so far largely omitted more massive objects (~2 M {sub ⊙} to 4–5 M {sub ⊙}) and were limited by the absence of simultaneous, multiwavelength information. We present a new study of young star variability in the ~1–2 Myr old, massive Lagoon Nebula region. Our sample encompasses 278 young, late B to K-type stars, monitored with Kepler/K2. Auxiliary u, g, r, i, Hα time-series photometry, simultaneous with K2, was acquired at the Paranal Observatory. We employed this comprehensive data set and archival infrared photometry to determine individual stellar parameters, assess the presence of circumstellar disks, and tie the variability behaviors to inner disk dynamics. We found significant mass-dependent trends in variability properties, with B/A stars displaying substantially reduced levels of variability compared to G/K stars for any light-curve morphology. These properties suggest different magnetic field structures at the surface of early-type and later-type stars. We also detected a dearth of some disk-driven variability behaviors, particularly dippers, among stars earlier than G. This indicates that their higher surface temperatures and more chaotic magnetic fields prevent the formation and survival of inner disk dust structures corotating with the star. Finally, we examined the characteristic variability timescales within each light curve and determined that the day-to-week timescales are predominant over the K2 time series. These reflect distinct processes and locations in the inner disk environment, from intense accretion triggered by instabilities in the innermost disk regions to variable accretion efficiency in the outer magnetosphere.

47 OTHER INSTRUMENTATION↗

NASA NTRS2004

MARIE Dose and Flux Measurements in Mars Orbit

We present results from the Martian Radiation Environment Experiment (MARIE), aboard the 2001 Mars Odyssey spacecraft in orbit around Mars. MARIE operated successfully from March 2002 through October 2003. At the time of this writing, the instrument is off due to a loss of communications during an extremely intense Solar Particle Event. Efforts to revive MARIE are planned for Spring 2004, when Odyssey's role as a communications relay for the MER rovers is completed. During the period of successful operation, MARIE returned the first detailed energetic charged particle data from Mars. Due to limitations of the instrument, normalizing MARIE data to flux or dose is not straightforward - several large corrections are needed. Thus normalized results (like dose or flux) have large uncertainties and/or significant model-dependence. The problems in normalization are mainly due to inefficiency in detecting high-energy protons (signal-to-noise problems force the trigger threshold to be higher than optimal), to the excessively high gains employed in the signal processing electronics (many ions deposit energy sufficient to saturate the electronics, and dE/dx information is lost), and to artifacts associated with the two trigger detectors (incomplete registration of dE/dx). Despite these problems, MARIE is efficient for detecting helium ions with kinetic energies above about 30 MeV/nucleon, and for detecting high-energy ions (energies above about 400 MeV/nucleon) with charges from 5 to 10. Fluxes of these heavier ions can be compared to fluxes obtained from the ACE/CRIS instrument, providing at least one area of direct comparison between data obtained at Earth and at Mars; this analysis will be presented as a work in progress. We will also present dose-rate data, with a detailed explanation of the many sources of uncertainty in normalization. The results for both flux and dose will be compared to predictions of the HZETRN model of the GCR.

Zeitlin, C.↗

DOE OSTI2020

FPGA-based tracking for the CMS Level-1 trigger using the tracklet algorithm

The high instantaneous luminosities expected following the upgrade of the Large Hadron Collider (LHC) to the High-Luminosity LHC (HL-LHC) pose major experimental challenges for the CMS experiment. A central component to allow efficient operation under these conditions is the reconstruction of charged particle trajectories and their inclusion in the hardware based trigger system. There are many challenges involved in achieving this: a large input data rate of about 20–40 Tb/s; processing a new batch of input data every 25 ns, each consisting of about 15,000 precise position measurements and rough transverse momentum measurements of particles (“stubs”); performing the pattern recognition on these stubs to find the trajectories; and producing the list of trajectory parameters within 4 µs. Here, this paper describes a proposed solution to this problem, specifically, it presents a novel approach to pattern recognition and charged particle trajectory reconstruction using an all-FPGA solution. The results of an end-to-end demonstrator system, based on Xilinx Virtex-7 FPGAs, that meets timing and performance requirements are presented along with a further improved, optimized version of the algorithm together with its corresponding expected performance.

47 OTHER INSTRUMENTATION↗

DOE OSTI2025

Analysis of the linear and nonlinear stability of Alfven eigenmodes and fish-bones in JET DT discharges: mode identification and shear flows generation

The plasma in future nuclear fusion reactors will be heated by neutral beam injectors (NBIs) and high frequency electromagnetic waves as well as fusion born alpha particles. Energetic particles (EPs), with energies up to two orders of magnitude larger than the thermal plasma, can trigger EP driven modes and induce harmful EP losses, reducing the plasma heating efficiency and the economical viability of the reactor. The present study is dedicated to analyze the Alfven Eigenmode (AE) activity in JET D–T discharges, the closest experiment to reactor-like operation performed until now. There, EP driven modes are induced by the combined effect of tangential NBIs and ion cyclotron resonance heating (ICRH) driven EP. Linear and nonlinear simulations are performed with the gyro-fluid FAR3d code to analyze the AE activity observed in the discharge 99896. The linear simulations reproduce the unstable n = 3 to 5 toroidal AEs (TAE) at the inner plasma region observed in the experiment, triggered by highly energetic passing deuterium populations injected by the tangential NBIs, further accelerated by the effect of the ICRH up to 1 MeV. In addition, fish-bones triggered by energetic trapped hydrogen induced by the ICRH are also reproduced. On the other hand, the alpha particles density is too small to destabilize AEs in the experiment. Nonetheless, increasing artificially the alpha density by one order of magnitude, an n = 1 beta induced AE can be destabilized in the inner plasma region. Nonlinear simulations indicate the generation of zonal structures during the AE/fish-bone saturation phase. TAE and fish-bones causes a rather weak increase of the passing D and trapped H EP (around 2%), respectively. Shear flows and zonal currents are generated during the saturation of TAE and fish-bones. Nonlinear simulations performed for D–T and pure deuterium thermal plasma indicate AE/fish-bone activity is weaker and shear flows are less intense in the pure deuterium case, trends consistent with the experimental observations that also indicates a deterioration of the thermal plasma confinement. Therefore, both numerical studies and experimental evidence indicate the generation of shear flows by AE/fish-bones could be connected with an improvement of the thermal plasma confinement.

AE↗

DOE OSTI2023

Interfacial Connections between Organic Perovskite/n + Silicon/Catalyst that Allow Integration of Solar Cell and Catalyst for Hydrogen Evolution from Water

Abstract The rapidly increasing solar conversion efficiency (PCE) of hybrid organic–inorganic perovskite (HOIP) thin‐film semiconductors has triggered interest in their use for direct solar‐driven water splitting to produce hydrogen. However, application of these low‐cost, electronic‐structure‐tunable HOIP tandem photoabsorbers has been hindered by the instability of the photovoltaic‐catalyst‐electrolyte (PV+E) interfaces. Here, photolytic water splitting is demonstrated using an integrated configuration consisting of an HOIP/n + silicon single junction photoabsorber and a platinum (Pt) thin film catalyst. An extended electrochemical (EC) lifetime in alkaline media is achieved using titanium nitride on both sides of the Si support to eliminate formation of insulating silicon oxide, and as an effective diffusion barrier to allow high‐temperature annealing of the catalyst/TiO 2 ‐protected‐n + silicon interface necessary to retard electrolytic corrosion. Halide composition is examined in the (FA 1‐x Cs x )PbI 3 system with a bandgap suitable for tandem operation. A fill factor of 72.5% is achieved using a Spiro‐OMeTAD‐hole‐transport‐layer (HTL)‐based HOIP/n + Si solar cell, and a high photocurrent density of −15.9 mA cm −2 (at 0 V vs reversible hydrogen electrode) is attained for the HOIP/n + Si/Pt photocathode in 1 m NaOH under simulated 1‐sun illumination. While this thin‐film design creates stable interfaces, the intrinsic photo‐ and electro‐degradation of the HOIP photoabsorber remains the main obstacle for future HOIP/Si tandem PEC devices.

08 HYDROGEN↗

NASA NTRS1989

Measuring Fracture Times Of Ceramics

Electrical measurements complement or replace fast cinematography. Electronic system measures microsecond time intervals between impacts of projectiles on ceramic tiles and fracture tiles. Used in research on ceramics and ceramic-based composite materials such as armor. Hardness and low density of ceramics enable them to disintegrate projectiles more efficiently than metals. Projectile approaches ceramic tile specimen. Penetrating foil squares of triggering device activate display and recording instruments. As ceramic and resistive film break oscilloscope plots increase in electrical resistance of film.

Shlichta, Paul J.↗

NASA NTRS2001

Performance Assessment of the Optical Transient Detector and Lightning Imaging Sensor: Predicted Diurnal Variability - 1

Laboratory calibration and observed background radiance data are used to determine the effective sensitivities of the Optical Transient Detector and Lightning Imaging Sensor, as functions of local hour and pixel location within the instrument arrays. The effective LIS thresholds, expressed as radiances emitted normal to cloud top, are 4.0 plus or minus 0.7 and 7.6 plus or minus 3.3 micro J/ster/m (sup 2) for night and local noon; the OTD thresholds am 11.7 plus or minus 2.2 and 16.8 plus or minus 4.6 microJ/ster/m (sup 2). LIS and OTD minimum signal to noise ratios occur from 0800 to 1600 local time, and attain values of 10 plus or minus 2 and 20 plus or minus 3, respectively. False alarm rate due to instrument noise yields approximately 5 false triggers per month for LIS, and is negligible for OTD. Flash detection efficiency, based on prior optical pulse sensor measurements, is predicted to be 93 plus or minus 4% and 73 plus or minus 11% for LIS night and noon; 56 plus or minus 7% and 44 plus or minus 9% for OTD night and noon, corresponding to a 12 - 20% diurnal variability and LIS:OTD ratio of 1.7. Use of the weighted daily mean detection efficiency (i.e., not controlling for local hour) corresponds to a sigma = 8 - 9% uncertainty. These are likely overestimates of actual flash detection efficiency due to differences in pixel ground field-of-view across the instrument arrays, which are not accounted for in the validation optical pulse sensor data.

Boccippio, Dennis J.↗

DOE OSTI2025

Hexagonal Boron Nitride: Physical Properties, Hydride Vapor‐Phase Epitaxy Growth of Large‐Diameter Quasi‐Bulk Wafers and Applications

Hexagonal boron nitride ( h ‐BN), with its ultrawide bandgap and 2D structure, holds an immense promise for advanced semiconductor applications. Scaling bulk crystals to large‐diameter wafers, crucial for complex device fabrication, remains a challenge with high temperature, high pressure, and metal flux solution methods. To address this, recent efforts have focused on hydride vapor‐phase epitaxy (HVPE) for producing large diameter thick h ‐BN quasi‐bulk wafers, reaching hundreds of micrometers. These HVPE‐grown quasi‐bulk crystals exhibit excellent c ‐axis long‐range order. Notably, the in‐plane mobility‐lifetime products for both electrons and holes surpass 10 −4 cm 2 V −1 , which are two orders of magnitude greater than the out‐of‐plane (vertical) values, highlighting the potential for high‐performance devices leveraging superior lateral transport. Lateral detectors fabricated from 100 μm thick B‐10 enriched h‐ BN wafers have achieved a record 60% thermal neutron detection efficiency. Based on its physical properties, h‐ BN appears to be an outstanding material of choice for light‐triggered electronic power switches capable of supporting high ‐ voltage and high ‐ power operations. These recent advancements in large‐diameter h ‐BN quasi‐bulk crystal growth, enabled by HVPE, pave the way for applications spanning deep UV photonics, high‐power electronics, high‐efficiency neutron detection, and quantum information technologies, establishing h ‐BN as both a versatile active semiconductor and an ideal substrate.

Jiang, Hongxing [Department of Electrical and Comp↗

NASA NTRS1972

Arc driver operation for either efficient energy transfer or high-current generator

An investigation is made to establish predictable electric arcs along triggered paths for research purposes, the intended application being the heating of the driver gas of a 1 MJ electrically driven shock tube. Trigger conductors consisting of wires, open tubes, and tubes pressurized with different gases were investigated either on the axis of the arc chamber or spiraled along the chamber walls. Design criteria are presented for successful arc initiation with reproducible voltage-current characteristics. Results are compared with other facilities and several application areas are discussed.

Dannenberg, R. E.↗

DOE OSTI2024

Nonadiabatic dynamics with classical trajectories: The problem of an initial coherent superposition of electronic states

Advances in coherent light sources and development of pump–probe techniques in recent decades have opened the way to study electronic motion in its natural time scale. When an ultrashort laser pulse interacts with a molecular target, a coherent superposition of electronic states is created and the triggered electron dynamics is coupled to the nuclear motion. A natural and computationally efficient choice to simulate this correlated dynamics is a trajectory-based method where the quantum-mechanical electronic evolution is coupled to a classical-like nuclear dynamics. These methods must approximate the initial correlated electron–nuclear state by associating an initial electronic wavefunction to each classical trajectory in the ensemble. Different possibilities exist that reproduce the initial populations of the exact molecular wavefunction when represented in a basis. We show that different choices yield different dynamics and explore the effect of this choice in Ehrenfest, surface hopping, and exact-factorization-based coupled-trajectory schemes in a one-dimensional two-electronic-state model system that can be solved numerically exactly. Furthermore, this work aims to clarify the problems that standard trajectory-based techniques might have when a coherent superposition of electronic states is created to initialize the dynamics, to discuss what properties and observables are affected by different choices of electronic initial conditions and to point out the importance of quantum-momentum-induced electronic transitions in coupled-trajectory schemes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2013

Minimal Power Latch for Single-Slope ADCs

Column-parallel analog-to-digital converters (ADCs) for imagers involve simultaneous operation of many ADCs. Single-slope ADCs are well adapted to this use because of their simplicity. Each ADC contains a comparator, comparing its input signal level to an increasing reference signal (ramp). When the ramp is equal to the input, the comparator triggers a latch that captures an encoded counter value (code). Knowing the captured code, the ramp value and hence the input signal are determined. In a column-parallel ADC, each column contains only the comparator and the latches; the ramp and code generation are shared. In conventional latch or flip-flop circuits, there is an input stage that tracks the input signal, and this stage consumes switching current every time the input changes. With many columns, many bits, and high code rates, this switching current can be substantial. It will also generate noise that may corrupt the analog signals. A latch was designed that does not track the input, and consumes power only at the instant of latching the data value. The circuit consists of two S-R (set-reset) latches, gated by the comparator. One is set by high data values and the other by low data values. The latches are cross-coupled so that the first one to set blocks the other. In order that the input data not need an inversion, which would consume power, the two latches are made in complementary polarity. This requires complementary gates from the comparator, instead of complementary data values, but the comparator only triggers once per conversion, and usually has complementary outputs to begin with. An efficient CMOS (complementary metal oxide semiconductor) implementation of this circuit is shown in the figure, where C is the comparator output, D is the data (code), and Q0 and Q1 are the outputs indicating the capture of a zero or one value. The latch for Q0 has a negative-true set signal and output, and is implemented using OR-AND-INVERT logic, while the latch for Q1 uses positive- true signals and is implemented using AND-OR-INVERT logic. In this implementation, both latches are cleared when the comparator is reset. Two redundant transistors are removed from the reset side of each latch, making for a compact layout. CMOS imagers with column-parallel ADCs have demonstrated high performance for remote sensing applications. With this latch circuit, the power consumption and noise can be further reduced. This innovation can be used in CMOS imagers and very-low-power electronics

Hancock, Bruce R.↗

DOE OSTI2026

Towards a self-driving trigger at the LHC: adaptive response in real time

Real-time data filtering and selection—or trigger—systems at high-throughput scientific facilities such as the experiments at the Large Hadron Collider must process extremely high-rate data streams under stringent bandwidth, latency, and storage constraints. Yet these systems are typically designed as static, hand-tuned menus of selection criteria grounded in prior knowledge and simulation. In this work, we further explore the concept of a self-driving trigger, an autonomous data-filtering framework that reallocates resources and adjusts thresholds dynamically in real-time to optimize signal efficiency, rate stability, and computational cost as instrumentation and environmental conditions evolve. We introduce a benchmark ecosystem to emulate realistic collider scenarios and demonstrate real-time optimization of a menu including canonical energy sum triggers as well as modern anomaly-detection algorithms that target non-standard event topologies using machine learning. Using simulated data streams and publicly available collision data from the Compact Muon Solenoid experiment, we demonstrate the capability to dynamically and automatically optimize trigger performance under specific cost objectives without manual retuning. Our adaptive strategy shifts trigger design from static menus with heuristic tuning to intelligent, automated, data-driven control, unlocking greater flexibility and discovery potential in future high-energy physics analyses.

Emami, Shaghayegh [Michigan U.] (ORCID:00090007589↗

DOE OSTI2023

CHEETAH: Compact High Efficiency Electrically Tunable Amplifier (Final Report)

The goal of this project was to develop a new type of optically triggered, high speed and high power switch for radiofrequency applications with potential to exceed current state-of-the-art power and bandwidth. This device operates under a new operation principle, where discrete packets of charge carriers are generated with defined size. These are then swept out of the device at high enough fields to prevent diffusion and expansion of these packets. Individual pulse widths are determined by the spatial extent of these packets and their drift velocity, which would enable control over both amplitude and frequency by control of the initial packet size, illumination intensity, and applied voltage. This effort demonstrated this new mode of operation, while uncovering a new regime of pulse compression using negative differential mobility (NDM) semiconductors such as GaAs, where the output electrical pulse is substantially shorter than the input optical pulse.

42 ENGINEERING↗

DOE OSTI2025

Optoelectronic polymer memristors with dynamic control for power-efficient in-sensor edge computing

Abstract As the demand for edge platforms in artificial intelligence increases, including mobile devices and security applications, the surge in data influx into edge devices often triggers interference and suboptimal decision-making. There is a pressing need for solutions emphasizing low power consumption and cost-effectiveness. In-sensor computing systems employing memristors face challenges in optimizing energy efficiency and streamlining manufacturing due to the necessity for multiple physical processing components. Here, we introduce low-power organic optoelectronic memristors with synergistic optical and mV-level electrical tunable operation for a dynamic “control-on-demand” architecture. Integrating signal sensing, featuring, and processing within the same memristors enables the realization of each in-sensor analogue reservoir computing module, and minimizes circuit integration complexity. The system achieves 97.15% fingerprint recognition accuracy while maintaining a minimal reservoir size and ultra-low energy consumption. Furthermore, we leverage wafer-scale solution techniques and flexible substrates for optimal memristor fabrication. By centralizing core functionalities on the same in-sensor platform, we propose a resilient and adaptable framework for energy-efficient and economical edge computing.

Optics↗

DOE OSTI2023

GEM detectors for the CMS endcap muon system: status of three new detector stations

The High-Luminosity LHC (HL-LHC, or Phase-2 LHC) will deliver proton-proton collisions at 5–7.5 times the nominal LHC luminosity, with an expected number of 140–200 pp-interactions per bunch crossing (Pile-up or PU). To maintain the performance of muon triggering and reconstruction under high background, the forward part of the Muon Spectrometer of the CMS experiment will be upgraded with Gas Electron Multipliers (GEM) and improved Resistive Plate Chambers (iRPC) detectors. A first GEM station (GE1/1) was installed during Long Shutdown 2 (LS2, 2019–2021), a 2 nd station (GE2/1) of Triple-GEM detectors will be installed in winter 2023–24 and 2024–25, while a new 6-layer station (ME0) will be installed in the third Long Shutdown (LS3, 2026–2028). GE11 is considered an early Phase-2 upgrade as it will reduce the p T threshold by combining GEM and Cathode Strip Chamber (CSC) hits in the forward muon system at twice the LHC design luminosity ($\mathcal{L}$ = 2 · 10 34 cm -2 s -1 , 50 PU). After a successful start of Run-3 in 2022, with almost 40 fb -1 collected, the commissioning of the GE1/1 detector is nearly complete. Most chambers are operated stably with an efficiency in excess of 95%, next being the demonstration of the combined CSC-GEM trigger in 2023. The lessons learnt with the first large-area GEM station have lead to improvements in detector and electronics design for the Phase 2 detectors GE2/1 and ME0. This proceeding will discuss the progress made since last MPGD Conference (MPGD 2019), discussing the commissioning and early performance of GE1/1; the design improvements and start of construction of GE2/1; and the R&D currently ongoing for ME0.

47 OTHER INSTRUMENTATION↗

DOE OSTI2026

Investigating the Role of Polymer Architecture in Poly(methyl methacrylate) Depolymerization

Advanced architectures in polymers have garnered traction within the last two decades due to their distinct and tunable properties compared to linear analogs. However, the effects of architecture on nascent polymethacrylate depolymerization strategies remain underexplored. Herein, we investigate the depolymerization behavior of poly(methacrylate)-based star copolymers synthesized via a core-first approach. By incorporating either labile chain-end or pendent-group triggers, we demonstrate the first direct comparison of bulk depolymerization behaviors in star versus linear methacrylate copolymers under matched conditions. While pendent-triggered systems required higher loadings of N-(methacryloxy)phthalimide methacrylate (PhthMA) to achieve similar mass loss compared to linear copolymers, chain-end-initiated depolymerization showed enhanced efficiency of monomer liberation in the star topology. Furthermore, these findings highlight the importance of considering macromolecular architecture in designing sustainable polymers and provide actionable guidelines for installing depolymerization triggers based on polymer topology.

Copolymers↗