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Tm(AsO)2 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tm(AsO)2 clusters. Tm3+ is bonded in a linear geometry to two equivalent O2- atoms. Both Tm–O bond lengths are 2.10 Å. As+0.50+ is bonded in a single-bond geometry to one O2- atom. The As–O bond length is 1.76 Å. O2- is bonded in a bent 150 degrees geometry to one Tm3+ and one As+0.50+ atom.
TmFe4Ge2 crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Tm is bonded to six equivalent Ge atoms to form a mixture of distorted edge and corner-sharing TmGe6 octahedra. The corner-sharing octahedral tilt angles are 41°. There are two shorter (2.91 Å) and four longer (2.94 Å) Tm–Ge bond lengths. Fe is bonded in a 3-coordinate geometry to three equivalent Ge atoms. There are one shorter (2.43 Å) and two longer (2.44 Å) Fe–Ge bond lengths. Ge is bonded in a 9-coordinate geometry to three equivalent Tm and six equivalent Fe atoms.
Remote Area Modular Monitoring (RAMM) for canister surface temperature measurement (TM), or RAMM-TM, is a novel remote monitoring device for detection of gas leakage based on surface temperature measurements of canisters containing spent nuclear fuel. Here we describe the development of RAMM-TM, as is the demonstration of its performance in detecting canister gas leakage from a small, simulated chloride-induced stress corrosion crack in experiments using a 1/4.5-scale model cask. Both helium and air gas leakage from a canister were detected within hours after the start of the leakage. The change in surface temperatures at the top and bottom of the canister (ΔTBT) during gas leakage (depressurization) triggered automatic alarms, providing a sound basis for early detection of gas leakage from the canister. This methodology would allow consequence management through the implementation of mitigatory actions to continue effective aging management and to reduce risks to public safety, health, and the environment.
We report here our discovery of crystallographic and interstitial sites and onsite electron correlation propelled intrinsic and derived permanent magnetic properties of critical elements lean RE(TM) 5 (RE = La, Ce and TM = Fe, Co) magnet materials. A full potential linearized augmented plane wave (FP-LAPW) method within the local density approximation (LDA) is used to investigate and analyze the electronic structure and magnetism of these RE(TM) 5 type structures. To better correlate the experimental results, the effective Coulomb (U) and exchange (J) interactions (Hubbard parameters) are crucial at the transition metal sites. Results show that the main propeller of magnetic anisotropy in these compounds is the cobalt atoms at the 2c sites not the 3g sites. This site-specific property and site preference energetics are used to replace 3g sites with non-critical elements such as iron that exhibits a larger magnetic moment. Based on this strategic replacement, we predict two new compounds that have a larger hardness parameter with a relatively large energy product due to the atomic dilution caused by interstitial addition of nitrogen in the compounds: CeCo 2 Fe 3 N 2 and LaCo 2 Fe 3 N 2 .
Nonsolvent-induced phase separation (NIPS) is widely used to prepare asymmetric gas separation membranes. Most industrial NIPS casting solution formulations are limited to a small group of glassy polymers and, importantly, require toxic polar aprotic solvents such as N,N-dimethylacetamide (DMAc), N,N-dimethylformamide (DMF), or N-methyl-2-pyrrolidone (NMP). Growing restrictions on the use of such solvents are spurring the search for more benign casting solution formulations that do not compromise membrane performance. Herein this study reports high-flux, defect-free asymmetric polysulfone (PSf) gas separation membranes prepared using dihydrolevoglucosenone (Cyrene TM ), a polar aprotic solvent that is believed to be safer than DMAc, DMF, and NMP, as the majority casting solution component. Optimized formulations and casting conditions produce membranes with hydrogen permeances exceeding 100 gas permeance units (GPU) and selectivities at or above those of dense PSf films. Dry/wet NIPS membrane performance improved with shorter dry step times and increased Cyrene TM loadings relative to the volatile solvent, tetrahydrofuran (THF), in the casting solution. The high water-Cyrene TM Flory-Huggins interaction parameter, $\mathcal{X}12$ , and high casting solution viscosities help suppress the formation of skin layer defects and sublayer macrovoids. In some cases, membrane selectivities were influenced by substructure resistance, providing insight into the relationship between sublayer morphology and membrane performance.
In this work, a novel method for producing ultrafine tantalum and hafnium carbide fibers using the Forcespinning TM technique via a nonhalide‐based sol‐gel process was investigated. An optimal solution viscosity range was systematically determined via rheological studies of neat PAN/DMF as a function of fiber formation. Subsequently, Forcespinning TM parameters were also systemically studied to determine the optimal rotational velocity and spinneret‐to‐collecting rod distance required for ideal fiber formation. TaC and HfC fibers were synthesized via Forcespinning TM utilizing a mixture of PAN and refractory transition metal alkoxides (i.e., tantalum (V) ethoxide and hafnium (IV) tert‐butoxide) in DMF solution based on optimal conditions determined from the neat PAN/DMF. In all instances after calcination, powder X‐ray diffraction (PXRD) and energy dispersive spectroscopy (EDS) indicated that TaC and HfC fibers were produced. TGA/DSC confirmed the chemical stability of the resulting fibers.
High-energy short-pulse laser systems demonstrated to date have been limited to low repetition rates due to significant thermal management challenges associated with scaling these systems to high average power, including the need to understand the thermal fracture limits of laser gain media. In this paper, we demonstrate the thermal fracture limits of two high-average-power gain media in a realistic diode-pumped amplifier geometry: a 5 mm thick Nd:APG-1 slab and a 2 mm thick Tm:YLF slab, both cooled by room-temperature helium gas. Finite element analysis revealed maximum tensile stress at fracture of 25 ± 3 MPa for Nd:APG-1 and 30 ± 3 MPa for Tm:YLF. These stress levels correspond to average volumetric heat loads of 13 ± 1 W/cm 3 in Nd:APG-1 and 247 ± 12 W/cm 3 in Tm:YLF. Additional simulations show geometric scaling: thinner slabs tolerate higher heat loads before fracture, while larger pump spots reach the fracture stress at lower heat loads.
The effects of the earth's atmosphere on the Thematic Mapper (TM) measurements are studied with two radiative transfer models. A doubling model is used to compute the effective reflectance of the earth-atmosphere system, as measured by the TM for the reflective bands. An emission-transmission model is used to compute the satellite-received radiance for the thermal band. The influences of the aerosol loading, the amount of water vapor, and the solar illumination angle on the effective reflectance are investigated. The effect of varying atmospheric water vapor on the measurements of the thermal band is studied. The scattering and absorption effects on TM bands are compared with those on Multispectral Scanner System (MSS) bands. While the changes in the aerosol loading introduce comparable variation of the effective reflectance for both sensors, the changes in the water vapor amount give less impact on TM4 than MSS7.
Software was constructed to reformat data to band interlevel format and analysis software was developed in an effort to quantify the increased information content (statistical variability within a data set) of thematic mapper data as compared to that from the LANDSAT 4 multispectral band scanner. Computer runs were carried out for several subareas from a data set acquired simultaneously by TM and MSS over a test area in northeast Arkansas, one of the most agriculturally diverse sea areas in the country. The 6 visible-near IR channels of the TM provide more information than the 4 channels of the MSS. A rough estimate of 20 bits per pixel for TM, and 10 bits per pixel for the MSS was computed for these subareas. These numbers are to be revised downward when allowance is made for noise in the data.
Key spectral, radiometric, and geometric characteristics of the TM sensor are examined. Spectrally, band 5 is slightly wider than specified and its upper edge at 50% of miximum of 1784 nm includes some unintended overlap with water absorption bands. Thermal band 6 is half the expected width. Radiometrically, the TM has extreme linearity and stability in comparison with previous MSS photomultiplier systems. Forward and reverse scans on TM show some unexplained radiometric differences of up to four digital levels. Primary focal plane bands show a monotomic decrease in gain of about 5% in the five months since launch. The relative internal gains of bands 5 and 7 varied with a period of about 60 days and an amplitude of about 6%. Radiometric calibration must be applied before histogram equalization algorithms to preserve radiometric accuracy. Geometrically, channel 4 in band 2 has a smaller modulation transfer function than desired. There is apparent misregistration of .75 pixels along scan and 0.2 pixels across scan.
Radiometrically and geometrically corrected TM data from three different geographic locations were examined. Histograms were inspected for each band to determine the dynamic range of the data, the shape of the distributions, and to verify whether empty bins were introduced by the radiometric correction process. The effect of geometric correction on the radiometry of the resampled pixels was determined. The information content between TM and MSS data sets were compared and the TM data were used to map the thermal effluent discharge into a river ecosystem from a nuclear thermal power plant, and application only possible previously only possible through the acquisition of thermal infrared scanner data from aircraft altitudes.
The structure, format, and quality of the LANDSAT-4 TM and MSS photographic and digital products for one scene covering the Black Hills area of South Dakota were assessed and the extent to which major resource categories can be detected and identified on various photographic products generated from a subset of TM spectral bands and from all bands of the MSS was determined. The overall spectral, spatial, and radiometric quality of the TM data was found to be excellent. Agricultural fields of variable shape, size, and orientation were detected with relative ease. The addition of the short-wave infrared band (TM5) has significantly improved the ability to detect and identify crop types on single date imagery.
A detailed description of the thematic mapper (TM) instrument is presented in chart form. A comparison is made between TM and MSS capabilities. Applications for TM data are also included.
The European program of the European Space Agency received a mandate to upgrade the two existing LANDSAT stations operating in Europe, Kiruna in Sweden and Fucino in Italy, to acquire and process TM data. The salient features of the TM systems are summarized, and the preliminary results of the acceptance tests being carried out using the TM passes acquired in Fucino are reviewed before the X band downlink anomaly of LANDSAT-4.
Systematic analysis of both image and numeric data shows that the overall spectral, spatial, and radiometric quality of the TM data are excellent. Spectral variations in fallow fields are due to the vaiability in soil moisture and surface roughness resulting from the various stages of field preparation for small grains production. Spectrally, the addition of the first TM short wave infrared band (Band 5) significantly enhanced ability to discriminate different crop types. Bands 1, 5, and 6 contain saturated pixels due to high albedo effects, low moisture conditions, and high radiant temperatures of granite and dry, bare soil on south facing slopes, respectively. Spatially, the two fold decrease in interpixel distance and four fold decrease in area per pixel between the TM and MSS allow for improved discrimination of small fields, boundary conditions, road and stream networks in rough terrain, and small forest clearings resulting from various forest management practices.
A fixed factor analysis-of-variance (ANOVA) approach was used to quantify the impact of each TM sensor characteristic (spectral, spatial, and radiometric resolutions) on classification accuracy. All assessments were made relative to MSS sensor characteristics, and the impact of each characteristic was assessed individually, and in all possible combinations. Thematic Mapper data acquired over the Washington, D.C. area on November 2, 1982 were utilized to conduct the experiment. The following results were obtained: the reduction of quantization level from eight bits to six bits caused a decrease in overall accuracy (7%); the use of only three bands (TM 2, 3 and 4) covering the isible and near infrared portion of the spectrum caused a decrease in overall accuracy (7%); and the decrease in spatial resolution resulted in an increase in overall accuracy (4%). Results indicate that the increased radiometric and spectral resolution of the TM instrument do provide increased information content. The result of the spatial resolution degradation is somewhat misleading, in that the result is more a function of spatial resolution.
A comparison was made between ground data collected from Lake Chicot, Arkansas, and Thematic Mapper (TM) data collected on September 23, 1982. A preliminary analysis of limited data indicate tht Thematic Mapper data may be useful in monitoring suspended sediment and chlorophyll in a lake with high suspended sediment loads. Total suspended loads ranged from 168 to 508 mg/l. TM Band 3 appears to be most useful with Bands 1, 2 and 4 also containing useful information relative to suspended sediments. Considering water data only, Bands 1, 2 and 3 appear to provide similar information. Bands 3 and 4 are also significantly related. Bands 5 and 7 appear to have independent information content relative to the presence or absence of water. Insufficient range of water temperature ground truth data made an evaluation of TM Band 6 difficult.
Thematic mapper data acquired over Mississippi County, Arkansas, were examined for utility in separating soil associations within generally level alluvium deposited by the Mississippi River. The 0.76 to 0.90 micron (Band 4) and the 1.55 to 1.75 micron (Band 5) were found to separate the different soil associations fairly well when compared to the USDA-SCS general soil map. The thermal channel also appeared to provide information at this level. A detailed soil survey was available at the field level along with ground observations of crop type, plant height, percent cover and growth stage. Soils within the fields ranged from uniform to soils that occur as patches of sand that stand out strongly against the intermingled areas of dark soil. Examination of the digital values of individual TM bands at the field level indicates that the influence of the soil is greater in TM than it was in MSS bands. The TM appears to provide greater detail of within field variability caused by soils than MSS and thus should provide improved information relating to crop and soil properties. However, this soil influence may cause crop identification classification procedures to have to account for the soil in their algorithms.