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At least 127 records · Page 7

EVs@Scale NextGen Profiles: EVSE Characterization 2024

As part of the U.S. Department of Energy's EVs@Scale consortium, the Next-Generation Profiles (NextGen Profiles) project presents analysis and results from the characterization of high-power conductive and wireless charging infrastructure. High power charging equipment is capable of recharging electric vehicle traction batteries at power levels of 200KW and above. EVSE characterization was conducted over a wide range of DC output current and DC voltage charging for nominal and off-nominal test conditions. Test plans and procedures were developed and refined to define the test configurations and requirements, measurement parameters, and test procedures used throughout NextGen Profiles testing.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Aging of Concrete for the Evaluation of Repair Materials to Protect the Walls of the HCAEX Tunnel at Savannah River - 20301

H-Canyon, located in the Savannah River site, is a unique facility for chemical reprocessing of plutonium, highly-enriched uranium, and other radioactive materials. The exhaust gases of the H-Canyon are sent through the H-Canyon Exhaust (HCAEX) tunnel for contamination removal. Robotic inspections of the tunnel revealed significant degradation of the reinforced concrete structure that was associated with acid attack, and could compromise the structural stability of the tunnel. Thus, the identification and evaluation of potential repair materials that could be applied on the degraded walls to mitigate and prevent further degradation is of significant interest to the Department of Energy and the Savannah River representatives. This research effort has been divided into two phases: 1) Development and evaluation of aged concrete under accelerated aging conditions (which is the focus of this paper) and 2) Evaluation of potential repair materials applied on aged and non-aged concrete under simulated aggressive conditions. In order to develop and evaluate concrete samples exposed to accelerated aging conditions in simulated aggressive environments, a literature review of the HCAEX tunnel was conducted that included 1) characterization and extent of the concrete damage, 2) environmental conditions inside the tunnel and 3) primary deterioration mechanisms. In addition, potential coatings and/or repair materials for degraded concrete surfaces exposed to aggressive environments (primarily acidic) were selected from the literature review and the most common testing and measurements for evaluating acid attack phenomena, erosion, etc. were reviewed. From the literature review findings, a preliminary bench-scale test plan for the concrete aging was developed, including accelerated aging tests with aggressive conditions (acid fumes, humidity, etc.). Concrete samples were exposed to the aging accelerated conditions (e.g. immersion in acid solutions) and visual inspection, mass loss and pH change (acid solution) were recorded over time. Correlations between the visual inspection, mass loss and pH changes results and the aging time or the aging conditions were developed. Specimens submitted to the highest acid concentration showed the fastest and most intense degradation. The type of coarse aggregate (limestone) used for the concrete seemed to be the cause of the fastest aging observed, compared to the cement paste. The research findings created the foundation for the ongoing investigation, in which new concrete samples with a mix design similar to the HCAEX tunnel will be tested and will serve as the substrate for testing the selected coatings and /or repair materials. In this paper, the literature review and preliminary results from the aging tests are provided. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

MARVEL Utilization Plan

This report provides a high-level overview of the operational plan for the MARVEL microreactor. The main focus is on discussing testing and application demonstration opportunities that leverage the reactor. With the reactor rapidly progressing towards demonstration, along with the short operational window (2 years), it was deemed critical to start establishing a basis for how stakeholders can engage with the program and leverage the reactor as a testbed. The report discusses potential opportunities for using MARVEL leveraging from data/design access, novel controls testing, novel nuclear-electric applications, to novel nuclear-heat applications. It also provides guidance for interested stakeholders on potential funding opportunities that can be pursued to support tests during the operational lifetime of the reactor. The report also discusses the recommended strategy for outreach and the organization structure to review and down select project. It is important to emphasize that this is intended to be a living document with revisions issued as the MARVEL demonstration timeline evolves. Similarly, the framework for engagement is subject to change as the project nears construction. As such, this first revision to the original test plan highlights the new Microreactor Program-sponsored pathway for engaging with stakeholders via an Expression of Interest and Notice of Opportunity.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Iodine Capture Studies of Silver Mordenite and Novel Alternative Metal Sorbents

Radioiodine is one of the radionuclides of concern when considering reprocessing of used nuclear fuel (UNF). It is expected to be released primarily in the dissolver off-gas (DOG) stream. Sorbents that target I 2 removal from a UNF processing off gas must perform efficiently under elevated temperatures in the presence of water vapor and nitrogen oxide gasses (NOx). Many studies have been conducted that examine the adsorption of iodine species in the presence of NOx gases through reduced silver-exchanged mordenite (Ag 0 Z), a zeolite mineral. This study characterizes the effects of iodine, water vapor, and nitrogen dioxide on the adsorption of I 2 by Ag 0 Z at lower temperatures suitable for comparison with novel Cu- and Bi- bearing sorbents which offer a non-RCRA alternative. When exposed to ‘harsh’ conditions such as I 2 , H 2 O, and NO 2 vapors carried by air, Cu 2 S-polyacrylonitrile (PAN) is more efficient than Ag 0 Z and all other novel sorbents, providing with 11% I capture efficiency. However, under ‘ideal’ conditions in which I 2 is carried by dry air), Ag 0 Z is more efficient than Cu 2 S-PAN and other novel sorbents, providing 74% I capture efficiency. To investigate this result and the overall performance of all sorbents tested, several characterization techniques were employed, including thermal gravimetric analysis, scanning electron microscopy – electron dispersion X-Ray spectroscopy, powder X-ray diffraction, and X-ray photoelectron spectroscopy. These techniques are discussed within this report. This document also includes a design and test plan update from Idaho National Laboratory as the next step in testing the high performing sorbents from thin-bed tests carried out by Oak Ridge National Laboratory.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NREL Validation of S3.2 and S3.3 (CRADA Final Report)

The scope of work for S3.2 and S3.3 validation includes cooperative planning, execution, and analysis of all recommended and agreed-upon test protocols to determine the suitability of the product for long-term deployment of the photovoltaic modules to a broad range of climates. The test plan will be established within two months of project initiation, and NREL will write monthly reports for the duration of the work.

14 SOLAR ENERGY↗

Integrated Mechanical System Pods (CRADA Final Report)

LBNL provided input to setting the requirements related to indoor air quality and contributed to the development of metrics and test plans to evaluate prototypes of the mechanical pods, which were developed by other members of the project team. The testing of prototypes was conducted by and at Syracuse University, another project partner. LBNL also collaborated with RMI to develop a basic plan for data collection when the pods are deployed for field testing in Phase 2.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Status Update for the Canister Deposition Field Demonstration

This report updates the high-level test plan for evaluating surface deposition on three commercial 32PTH2 spent nuclear fuel (SNF) canisters inside NUTECH Horizontal Modular Storage (NUHOMS) Advanced Horizontal Storage Modules (AHSM) from Orano (formerly Transnuclear Inc.) and provides a description of the surface characterization activities that have been conducted to date. The details contained in this report represent the best designs and approaches explored for testing as of this publication. Given the rapidly developing nature of this test program, some of these plans may change to accommodate new objectives or requirements. The goal of the testing is to collect highly defensible and detailed surface deposition measurements from the surface of dry storage canisters in a marine coastal environment to guide chloride-induced stress corrosion crack (CISCC) research. To facilitate surface sampling, the otherwise highly prototypic dry storage systems will not contain SNF but rather will be electrically heated to mimic the thermal-hydraulic-environment. Instrumentation throughout the canister, storage module, and environment will provide an extensive amount of information for the use of model validation. Manual sampling over a comprehensive portion of the canister surface at regular time intervals will offer a high-fidelity quantification of the conditions experienced in a harsh yet realistic environment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Status Update for the Canister Deposition Field Demonstration

This report updates the high-level test plan for evaluating surface deposition on three commercial 32PTH2 spent nuclear fuel (SNF) canisters inside NUTECH Horizontal Modular Storage (NUHOMS) Advanced Horizontal Storage Modules (AHSMs) from Orano (formerly Transnuclear Inc.) and provides a description of the surface characterization activities that have been conducted to date. The details contained in this report represent the best designs and approaches explored for testing as of this publication. Given the rapidly developing nature of this test program, some of these plans may change to accommodate new objectives or requirements. The goal of the testing is to collect highly defensible and detailed dust deposition measurements from the surface of dry storage canisters in a marine coastal environment to guide chloride-induced stress corrosion crack (CISCC) research. To facilitate surface sampling, the otherwise highly prototypic dry storage systems will not contain SNF but rather will be electrically heated to mimic the decay heat and thermal hydraulic environment. Test and heater design is supported by detailed computational fluid dynamics modeling. Instrumentation throughout the canister, storage module, and environment will provide extensive information about thermal-hydraulic behavior. Manual sampling over a comprehensive portion of the canister surface at regular time intervals will offer a high-fidelity quantification of the conditions experienced in a harsh yet realistic environment. Functional testing of the finalized heater assemblies and test apparatus is set to begin in December 2022. The proposed delivery of the canisters to the host test site is June/July 2023, which is well ahead of when the AHSM installations would be completed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Safe Response to Renewable Energy Hazards

The International Association of Fire Fighters (IAFF) and Underwriters Laboratories, LLC (UL) in conjunction with UL Solutions initiated a joint project in 2022 under an agreement with the United States Department of Energy-Office of Energy Efficiency and Renewable Energy (DOE-EERE). This project focused on two separate and important initiatives related to energy efficiency in residential buildings. Initiative 1: Fire Performance on Energy Efficient Exterior Walls. Initiative 2: Firefighting Tactics in Residential Properties with Building Energy Storage Systems (BESS). The project’s first initiative addresses concerns surrounding new technologies with enhanced, energy-efficient exterior walls installed on residential properties. The concerns of fire rapidly traveling vertically up the exterior of these walls were examined. This addressed a growing concern from the first responder community that many times, the fires on the exterior of residential buildings have already evolved into an attic fire by the time of arrival – making it problematic to address the fire scenario. The test plan for Initiative 1 incorporated a modified version of an American Society for Testing and Materials (ASTM) test method, ASTM E2707, Standard Test Method for Determining Fire Penetration of Exterior Wall Assemblies Using a Direct Flame Impingement Exposure, as the foundation of the research. The test method involved a wall structure intended to represent retrofit construction to evaluate how fire would spread vertically or laterally. The second aspect of the UL-IAFF Project focuses on the fire service response to Residential Battery Energy Storage System (RBESS) incidents. These simulation tests were constructed in the large-scale fire test facility at UL Solutions’ Northbrook, IL campus. A baseline test was conducted that involved a test structure with no batteries—shelving units populated with standardized commodities, representing a typical garage with cellulosic and plastic contents. Three additional tests have been conducted to generate data with the contribution of energy storage system (ESS) batteries to compare fire and explosion hazards against the baseline test. Through this work, fire service tactical considerations can be explored. From the data, the team can determine 1) the visual indicators of a residential fire that has involved an RBESS (or, potentially, other large batteries) and 2) the impact of fire service-initiated ventilation of the structure on the fire conditions and explosion risks.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

In-Cell Thermal Creep Frame Capability: Out-of-Cell Construction and Subsized Sample Testing

This report describes the activities related to the construction of an in-cell thermal creep test facility for small-scale specimens in the irradiation-assisted stress-corrosion cracking (IASCC) hotcell located at the Fuels and Applied Science Building (FASB) at INL. The whole project includes three stages: (i) conceptual design; (ii) out-of-cell demonstration tests; and (iii) in-cell demonstration testing. During the current fiscal year (FY)-2022, materials and equipment required to construct the conceptual design outlined in a previous report were procured. Frames for conducting out-of-cell testing have been constructed, and testing plans have been developed to assess the operation of the newly constructed frames. Preliminary testing of flat subsized tensile specimens on ASTM creep frames has also been completed for two sample thicknesses: 0.75 mm and 1.0 mm.

36 MATERIALS SCIENCE↗

Transient Testing of Nuclear Fuels Performed in the Original Operation of TREAT (2nd ed.)

This report provides summary information on experiments performed in the Transient Reactor Test Facility (TREAT) during its original operation from 1959-1994, and more specifically, before the TREAT core was upgraded at the end of the 1980s. The tests performed since about 1970 are summarized in considerable detail. Earlier tests are noted by their designated series and by some parameters that help to identify and distinguish each series from the others. The detailed summary descriptions are intended to help inform future researchers regarding the large, historical, empirical data base generated from that 35-year span during which hundreds of TREAT experiments were performed to investigate and demonstrate the transient behavior of a wide variety of nuclear fuels during severe off-normal and accident conditions -- using direct nuclear heating of the test samples. That empirical basis is foundational and valuable for guiding future qualification and safety evaluation of improved fuel designs and for future transient test planning and performance in TREAT. Since Edition 1 of this report, descriptions of the following test series have been added: D, E, EOS, F, H, J, R, RX, and S.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

2023 SRNL Aging and Lifetimes Report: Tritium Aging of Welded and Additively Manufactured Austenitic Stainless Steels

This report documents work performed in fiscal year 2023 at Savannah River National Laboratory (SRNL) collaborating with Sandia National Laboratories in support of the Aging and Lifetimes program. This work supports Gas Transfer Systems (GTS) design by measuring the mechanical behavior of structural materials used in GTS. Data on properties in relevant conditions are crucial for GTS lifetime assessments and predictions. To simulate relevant conditions, SRNL, in concert with the Savannah River Site, thermally pre-charges test specimens with tritium and stores them at -80°C to allow the tritium decay product, helium-3, to build up while limiting tritium diffusion. According to test plans based on how much helium-3 has accumulated, specimens are removed from storage and tested. Results from mechanical testing provide an empirical basis for GTS design as well as insight to how these structural materials degrade in a tritium environment.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Iodine Removal in the DFLAW Flow-Sheet

In support of the WTP project, off-gas system and regulatory testing has been conducted previously on the DM1200 pilot melter equipped with a prototypical off-gas system installed at The Catholic University of America’s Vitreous State Laboratory (VSL). During the regulatory tests, an AC-S test bed filled with Kombisorb BAT 37 was included in the prototypical off-gas system and evaluated for response to HLW and LAW exhaust streams. Offline testing and small-scale testing of that media were also conducted. Testing demonstrated that a temperature rise occurred in the activated carbon media when water vapor was first introduced to virgin Kombisorb BAT 37, in response to high nitrogen oxide concentrations, and in response to the presence of organic compounds. Conditioning of the test bed by gradually increasing the NOx concentration prior to the introduction of organics was found to be an important operational strategy for preventing larger temperature excursions. However, no mercury was present in the exhaust stream during DM1200 testing and therefore comparable test data for mercury removal efficiency or temperature response of the carbon media in the presence of mercury were not collected in the DM1200 tests. In view of the need for data on mercury removal performance, BNI contracted with Atkins and the VSL to install and operate a suitable test system at VSL to collect the required data. That testing was designed to assess the performance of Kombisorb BAT-37 and the guard bed material, Sofnolime RG, for simulated melter exhaust streams that contain the highest concentrations of mercury, nitrogen oxides, acid gases, and organic compounds expected in WTP LAW melter exhaust. During shakedown testing with the new system, however, it became evident that a number of issues with Sofnolime RG as the guard bed material would render it unsuitable for this application. BNI subsequently determined that the guard bed was redundant for removal of acid gases since they could be adequately removed by the SBS and WESP. However, since the guard bed material was also credited with significant iodine removal , there was a need for a replacement material that would adequately perform that role. BNI identified several candidate media but performance data in gas compositions that are representative of the WTP LAW off-gas were not available. Accordingly, there was a need to test and evaluate the performance of these candidate media prior to performing the originally-planned tests. To that end, small scale tests were conducted to assess the performance of various adsorbents in simulated melter exhaust streams that contain mercury, iodine, nitrogen oxides, acid gases, and acetonitrile, which are expected to be present in WTP LAW melter exhaust.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Full Submersion Water Testing of SAVY-4000 Nuclear Material Storage Containers

SAVY-4000 (SAVY) containers are the primary container used at Technical Area (TA) TA-55 plutonium facility for the prevention of water ingress to mitigate against a criticality event. The basis for water resistance of these containers has long been attributed to the Polytetrafluoroethylene (PTFE) membrane that is assembled on the outermost surface of the filter assembly. On August 22nd a test of a container used inside of a glovebox was performed that brought into question this long-standing-basis. This test was performed by inverting a SAVY-lid onto a specialized piece of equipment for evaluating the integrity of the PTFE membrane. During the test water was observed passing through the filter indicating that the filter membrane was no longer preventing the ingress of water through the filter. The assumption after making this observation was that alpha-particles were rapidly degrading the membrane creating a leak path through the underlying aluminosilicate media (Fiberfrax®). The apparatus used was designed to only test the lid rather than the entire SAVY assembly. A test plan, PA-PLAN-01921, was developed to investigate whether a fully assembled container with a fully degraded PTFE membrane would be capable of meeting the criteria defined in PA-RD-1009 of not allowing more than 200 ml of water to enter the container with a water column of 6-inches applied over a 2-hour period. This report provides the results of the testing performed against PA-PLAN-01921.

36 MATERIALS SCIENCE↗

Williston Basin Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Program

The U.S. Department of Energy’s Office of Fossil Energy awarded 13 CORE-CM programs as part of the CORE-CM Initiative, designed to develop the technology and upstream and midstream supply chains to extract rare-earth elements (REEs) and critical minerals (CMs) from the nation’s coal supplies. The intent is to catalyze regional economic growth and job creation while strengthening the use of domestic resources. The Williston Basin CORE-CM Program aims to drive the expansion and transformation of coal and coal-based resource usage within the Williston Basin to produce REEs, CMs, and nonfuel carbon-based products (CBPs). The work constitutes Phase 1 of a long-term program. The objectives of Phase 1 are to identify the existing knowledge base and gaps and to develop a series of assessments/plans, including an initial basinal assessment; a characterization and data acquisition plan; a waste stream reuse plan; a basinal strategies assessment for infrastructure, industries, and business; a technology assessment, development, and field testing plan; a technology innovation center plan(s); and a stakeholder outreach and education plan. The goal of this project is to initiate the development of a new industry in the resource-rich Williston Basin that will catalyze economic growth and job creation through a coalition team of private industry, university, and state, local, and federal government entities. A coalition team of nearly 30 private industry, university, and state, local, and federal government partners was formed for this program. Partners include the University of North Dakota Energy & Environmental Research Center, Institute for Energy Studies, and Nistler College; North Dakota State University; Montana Tech University; Pacific Northwest National Laboratory; Critical Materials Institute; North Dakota Geological Survey; South Dakota Geological Survey; U.S. Geological Survey; North American Coal Corporation; BNI Energy; Basin Electric Power Cooperative; Minnkota Power Cooperative; and many more.

Kay, John P.↗

Transient Testing of Nuclear Fuels Performed in the Original Operation of TREAT, Third Edition

TREAT core was upgraded at the end of the 1980s. The tests performed since about 1970 are summarized in considerable detail. Earlier tests are noted by their designated series and by some parameters that help to identify and distinguish each series from the others. The detailed summary descriptions are intended to help inform future researchers regarding the large, historical, empirical data base generated from that 35-year span during which hundreds of TREAT experiments were performed to investigate and demonstrate the transient behavior of a wide variety of nuclear fuels during severe off-normal and accident conditions -- using direct nuclear heating of the test samples. That empirical basis is foundational and valuable for guiding future qualification and safety evaluation of improved fuel designs and for future transient test planning and performance in TREAT. The second edition of this report added descriptions of the following test series: D, E, EOS, F, H, J, R, RX, and S. This third edition includes descriptions of an additional four test series: the HUT, HOP (& HUC), ORNL-TR, and PNL.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Finite Element Modeling of Spent Nuclear Fuel in Dry Storage under Seismic Excitation

Spent nuclear fuel (SNF) is currently stored at independent spent fuel storage installations (ISFSIs) at nuclear power plant sites across the US. The US Department of Energy (DOE) Spent Fuel and Waste Science and Technology (SFWST) program is currently working to understand the response of SNF during a seismic event. This investigation is part of a long-term effort by DOE to quantify the external mechanical loads on SNF. The SFWST program has recently completed campaigns evaluating SNF behavior during normal conditions of transport and in 30 cm package drop scenarios; both campaigns included a combination of testing and modeling. Likewise, the investigation into seismic response of SNF will include full-size shake table tests of a vertical storage overpack containing instrumented surrogate fuel assemblies, as well as pre- and post-test finite element modeling. This work focuses on the development of finite element models simulating the planned test configuration. The seismic response is calculated at two scales: at the package level, and at the fuel level. The package level model evaluates the behavior of the storage overpack and its contents in response to the ground motions of a representative earthquake. The motion of the package is input to the fuel level model, which consists of a detailed finite element model of a 17x17 or 16x16 pressurized water reactor (PWR) fuel assembly or of a 10x10 boiling water reactor (BWR) fuel assembly. The stress and strain on individual components such as fuel rods and guide tubes are extracted from this model. This work details the SNF response to various input ground motions, considering representative earthquakes in the Central and Eastern US under various site conditions. Also discussed is the development of a “reduced scope” finite element model of the SNF, which consists of a single fuel rod while retaining the dynamic response of the entire fuel assembly. This reduced scope model addresses the significant computational expense of modeling the SNF under long-duration input ground motions and facilitates simulating additional parameter variations of the model beyond the as-tested configuration. The modeling results provide important insight that will help to inform future testing and modeling efforts by the SFWST program to close the knowledge gap related to external loads on SNF.

Kadooka, Kevin↗

Williston Basin Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Program

The U.S. Department of Energy’s (DOE’s) Office of Fossil Energy awarded 13 Carbon Ore, Rare-Earth and Critical Minerals (CORE-CM) programs as part of the CORE-CM Initiative, designed to develop the technology and upstream and midstream supply chains to extract rare-earth elements (REEs) and CMs from the nation’s coal supplies. The intent is to catalyze regional economic growth and job creation while strengthening the use of domestic resources. The Williston Basin CORE-CM Program aims to drive the expansion and transformation of coal and coal-based resource usage within the Williston Basin to produce REEs, CMs, and nonfuel carbon-based products (CBPs). The work constitutes Phase 1 of a long-term program. The objectives of Phase 1 are to identify the existing knowledge base and gaps and to develop a series of assessments/plans, including an initial basinal assessment; a characterization and data acquisition plan; a waste stream reuse plan; a basinal strategies assessment for infrastructure, industries, and business; a technology assessment, development, and field-testing plan; a technology innovation center plan(s); and a stakeholder outreach and education plan. Originally, the CORE-CM programs were to do little if any sample collection as part of the Phase 1 program. As part of the ongoing interactions with DOE regarding the progress of the 13 CORE-CM programs, DOE has decided to extend Phase 1 with additional funding to allow all of the Phase 1 CORE-CM programs to collect and characterize more samples that have potential to be sources of REEs and CMs. The goal of this project is to initiate the development of a new industry in the resource-rich Williston Basin that will generate economic growth and job creation through a coalition team of private industry; university; and state, local, and federal government entities. A coalition team of nearly 30 private industry; university; and state, local, and federal government partners was formed for this program. Partners include the University of North Dakota Energy & Environmental Research Center, Institute for Energy Studies, and Nistler College; North Dakota State University; Montana Tech University; Pacific Northwest National Laboratory; Critical Materials Institute; North Dakota Geological Survey; South Dakota Geological Survey; U.S. Geological Survey; North American Coal Corporation; BNI Energy; Basin Electric Power Cooperative; Minnkota Power Cooperative; and many more.

Kay, John P.↗