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At least 127 records · Page 7

Chemical Characterization and Thermal Stressing Studies of Perfluorohexane Fluids for Space-Based Applications

Perfluorohexane (PFH), C6F14, is a perfluorocarbon fluid. Several PFH fluids with different isomer concentrations were evaluated for use in an upcoming NASA space experiment. Samples tested included two commercially obtained high-purity n-perfluorohexane (n-PFH) fluids and a technical grade mixture of C6F14 branched and linear isomers (FC-72(TradeMark)). These fluids were evaluated for exact chemical composition, impurity purity and high temperature degradation behavior (pyrolysis). Our investigation involved simulated thermal stressing studies of PFH fluids under conditions likely to occur in the event of an atmospheric breach within the International Space Station (ISS) and subsequent exposure of the vapors to the high temperature and catalyst present in its Trace Contaminant Control Subsystem (TCCS). Exposure to temperatures in the temperature range of 200-450 C in an inert or oxidizing atmosphere, with and without the presence of catalyst was investigated. The most aggressive conditions studied were exposure of PFH vapors to 450 C in air and in the presence of TCCS (palladium) catalyst. Gas chromatography-mass spectrometry (GC-MS) and gas chromatography (GC) analyses were conducted on the perfluorohexane samples before and after pyrolysis. The FC-72 and n-PFH samples showed no significant degradation following pyrolysis even under the most aggressive study conditions. Some trace level impurities associated with the PFH samples such as linear perfluorocarbon monohydrides or monoiodides were destroyed by pyrolysis at the upper limit. Other trace level impurities such as olefinic or cycloolefinic perfluorocarbons were converted into oxidation products by pyrolysis. The purity of PFH following pyrolysis actually increased slightly as a consequence since these trace contaminants were effectively scrubbed from the samples. However, since the initial concentrations of the thermally-impacted impurities were so low, the net effect was trivial. A potential byproduct of exposure of perfluorohexane fluids to high temperatures is the production of perfluoroisobutene (PFiB), which is extremely toxic. An ultra-high sensitivity PFiB-specific analysis based on GC-MS with negative ion chemical ionization (NICI) detection was used to evaluate the samples following thermal stressing. The perfluorohexanes examined here under conditions reflective of the ISS TCCS environment showed no signs of PFiB production with an analytical detection limit of 10 part per billion (ppb v/v).

Arnold, William A.↗

A biharmonic relaxation method for calculating thermal stress in cooled irregular cylinders

A numerical method was developed for calculating thermal stresses in irregular cylinders cooled by one or more internal passages. The use of relaxation methods and elementary methods of finite differences was found to give approximations to the correct values when compared with previously known solutions for concentric circular cylinders possessing symmetrical and asymmetrical temperature distributions.

Holms, Arthur G↗

Direct solution for thermal stresses in a nose cap under an arbitrary axisymmetric temperature distribution

The design of a nose cap for a hypersonic vehicle is an iterative process requiring a rapid, easy to use and accurate stress analysis. The objective of this paper is to develop such a stress analysis technique from a direct solution of the thermal stress equations for a spherical shell. The nose cap structure is treated as a thin spherical shell with an axisymmetric temperature distribution. The governing differential equations are solved by expressing the stress solution to the thermoelastic equations in terms of a series of derivatives of the Legendre polynomials. The process of finding the coefficients for the series solution in terms of the temperature distribution is generalized by expressing the temperature along the shell and through the thickness as a polynomial in the spherical angle coordinate. Under this generalization the orthogonality property of the Legendre polynomials leads to a sequence of integrals involving powers of the spherical shell coordinate times the derivative of the Legendre polynomials. The coefficients of the temperature polynomial appear outside of these integrals. Thus, the integrals are evaluated only once and their values tabulated for use with any arbitrary polynomial temperature distribution.

Davis, Randall C.↗

Metallic coating reduces thermal stress

Addition of metallic outer layer deposited by standard plating method, having high thermal conductivity, substantially reduces thermal stress in high-temperature/high-strength materials, preventing structural overloads.

Morgan, R. D.↗

Analysis of thermal stresses and metal movement during welding

Finite element computer programs were developed to determine thermal stresses and metal movement during butt welding of flat plates and bead-on-plate welding along the girth of a cylindrical shell. Circular cylindrical shells of 6061 aluminum alloy were used for the tests. Measurements were made of changes in temperature and thermal strains during the welding process.

Muraki, T.↗

Direct and Inverse Problems of Thermomechanics Concerning the Optimization and Identification of the Thermal Stressed State of Deformed Solids

We describe the main stages of the development of investigations originated by Prof. Vihak in the fields of the theory and methods of optimal control over the thermal processes and thermal stressed state of deformed solids, theory of inverse problems of heat conduction and thermomechanics, and the mathematical methods in the mechanics of deformable solids. We indicate the existence of close relationship between the obtained theoretical results and the applied problems of thermal power engineering motivating investigations of this kind. We describe a significant contribution made by the researchers of the Pidstryhach Institute for Applied Problems in Mechanics and Mathematics of the Ukrainian National Academy of Sciences to the development of investigations in these fields. The prospects of further development of these studies are analyzed and some facts from the life and creative activity of Prof. V. М. Vihak are presented.

42 ENGINEERING↗

Thermal stress analysis of a silicon carbide/aluminum composite

Thermal deformations and stresses were studied in a silicon-carbide/aluminum filamentary composite at temperatures up to 370 C (700 F). Longitudinal and transverse thermal strains were measured with strain gages and a dilatometer. An elastoplastic micromechanical analysis based on a one-dimensional rule-of-mixtures model and an axisymmetric two-material composite cylinder model was performed. It was established that beyond a critical temperature thermal strains become nonlinear with decreasing longitudinal and increasing transverse thermal-expansion coefficients. This behavior was attributed to the plastic stresses in the aluminum matrix above the critical temperature. An elastoplastic analysis of both micromechanical models was performed to determine the stress distributions and thermal deformation in the fiber and matrix of the composite. While only axial stresses can be determined by the rule-of-mixtures model, the complete triaxial state of stress is established by the composite cylinder model. Theoretical predictions for the two thermal-expansion coefficients were in satisfactory agreement with experimental results.

Gdoutos, E. E.↗

Thermal stresses, differential subsidence, and flexure at oceanic fracture zones

Geosat geoid undulations over four Pacific fracture zones have been analyzed. After correcting for the isostatic thermal edge effect, the amplitudes of the residuals are shown to be proportional to the age offset. The shape of the residuals seems to broaden with increasing age. Both geoid anomalies and available ship bathymetry data suggest that slip must sometimes occur on the main fracture zone or secondary faults. Existing models for flexure at fracture zones cannot explain the observed anomalies. A combination model accounting for slip and including flexure from thermal stresses and differential subsidence is presented. This model accounts for lateral variations in flexural rigidity from brittle and ductile yielding due to both thermal and flexural stresses and explains both the amplitudes and the shape of the anomalies along each fracture zone. The best fitting models have mechanical plate thicknesses that are described by the depth to the 600-700 C isotherms.

Wessel, Pal↗

Temperature, Thermal Stress, And Creep In A Structure

Report presents comparison of predicted and measured temperatures, thermal stresses, and residual creep stresses in heated and loaded titanium structure. Study part of continuing effort to develop design capability to predict and reduce deleterious effects of creep, which include excessive deformations, residual stresses, and failure.

Jenkins, Jerald M.↗

Thermal Stress Analysis of RCG-Tempered TUFI Tile TPS for Hypersonic Vehicles

This paper presents detailed results from linear and nonlinear finite-element thermal stress analyses of a new tile, Thermal Protection Systems (TPS) concept. A very thin coating of Reaction Cured Glass (RCG) is used to "temper" the surface of Toughened Uni-Piece Fibrous Insulation (TUFI) tiles to improve resistance to thermal shock and thermal cycling effects. The coating also serves to reduce catalytic heating and may improve waterproofing. Calculations include trajectory-based aerothermal heating environments for X-34 wing leading edge TPS designs and arc jet environments for TPS test articles. The nonlinear analyses include the high temperature plasticity of RCG to demonstrate the reuseability of the material.

Milos, Frank S.↗

A finite element for thermal stress analysis of shells of revolution

A new finite element is described for performing detailed thermal stress analysis of thin orthotropic shells of revolution. The element provides for temperature loadings which may vary over the surface of the shell as well as through the thickness. In a number of sample calculations, results from the present method are compared with analytical solutions as well as with independent numerical analyses. Such calculations are carried out for two cylinders, a conical frustum, a truncated hemisphere, and an annular plate. Generally, the agreement between the present solution and the other solutions is excellent.

Adelman, H. M.↗

Adaptive unstructured meshing for thermal stress analysis of built-up structures

An adaptive unstructured meshing technique for mechanical and thermal stress analysis of built-up structures has been developed. A triangular membrane finite element and a new plate bending element are evaluated on a panel with a circular cutout and a frame stiffened panel. The adaptive unstructured meshing technique, without a priori knowledge of the solution to the problem, generates clustered elements only where needed. An improved solution accuracy is obtained at a reduced problem size and analysis computational time as compared to the results produced by the standard finite element procedure.

Dechaumphai, Pramote↗

Adaptive unstructured meshing for thermal stress analysis of built-up structures

An adaptive unstructured meshing technique for mechanical and thermal stress analysis of built-up structures has been developed. A triangular membrane finite element and a new plate bending element are evaluated on a panel with a circular cutout and a frame stiffened panel. The adaptive unstructured meshing technique, without a priori knowledge of the solution to the problem, generates clustered elements only where needed. An improved solution accuracy is obtained at a reduced problem size and analysis computational time as compared to the results produced by the standard finite element procedure.

Dechaumphai, Pramote↗