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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Conversion and Extraction of Insoluble Organic Materials in Meteorites

We endeavor to develop and implement methods in our laboratory to convert and extract insoluble organic materials (IOM) from low car-bon bearing meteorites (such as ordinary chondrites) and Precambrian terrestrial rocks for the purpose of determining IOM structure and prebiotic chemistries preserved in these types of samples. The general scheme of converting and extracting IOM in samples is summarized in Figure 1. First, powdered samples are solvent extracted in a micro-Soxhlet apparatus multiple times using solvents ranging from non-polar to polar (hexane - non-polar, dichloromethane - non-polar to polar, methanol - polar protic, and acetonitrile - polar aprotic). Second, solid residue from solvent extractions is processed using strong acids, hydrochloric and hydrofluoric, to dissolve minerals and isolate IOM. Third, the isolated IOM is subjected to both thermal (pyrolysis) and chemical (oxidation) degradation to release compounds from the macromolecular material. Finally, products from oxidation and pyrolysis are analyzed by gas chromatography - mass spectrometry (GCMS). We are working toward an integrated method and analysis scheme that will allow us to determine prebiotic chemistries in ordinary chondrites and Precambrian terrestrial rocks. Powerful techniques that we are including are stepwise, flash, and gradual pyrolysis and ruthenium tetroxide oxidation. More details of the integrated scheme will be presented.

Locke, Darren R.↗
NASA NTRSDate not supplied

High Performance Access to Archival Data Stored in HDF4 and HDF5 on Cloud Object Stores Without Reformatting the Files

Cloud computing offers numerous advantages for users of extensive Earth science data collections. These benefits encompass direct online access to data files and granules from any location, scalable access supporting parallel computing workflows, and flexible computing tools enabling innovative experimentation with processing techniques. However, older archival file formats designed for distinct computing systems hinder efficient access to decade-long time-series data when compared to data stored in modern cloud-optimized formats like Web Object Stores (WOS), exemplified by Amazon Web Services’ Simple Storage Service (S3). We describe DMR++ (Dataset Metadata Response plus plus), a technology facilitating efficient access to HDF5 (Hierarchical Data Format, version 5) and HDF4 files stored on WOS systems without requiring data reformatting. DMR++ achieves performance comparable to technologies like Zarr while preserving the original file structure, a substantial benefit considering the vast quantity of archival files held by organizations such as NASA. Moreover, DMR++ typically outperforms cloud-optimized versions of HDF5. Essentially an XML (Extensible Markup Language) document usually stored alongside the described data, DMR++ can also be generated on-the-fly but is generally created during data staging to the WOS. Archival files that use HDF4/5 often store large arrays of numerical data. The data in these files is often compressed, typically reducing their size by a factor of four or more. To achieve efficient access to portions of those arrays, they are 'chunked' into smaller sub-arrays, each individually compressed. The chunk size is a compromise, where spinning disks can efficiently access data in smaller chunks while S3 favors larger chunks. A simple optimization of aggregating smaller chunks that are stored adjacently, transferring them in a single access and then individually decompressing them will improve performance. NASA data pose an additional challenge: special Application Programmer Interface (API) libraries are often needed to compute some variables. These libraries are incompatible with WOS environments. Our solution involves storing computed values in the DMR++ document or a companion file, making them accessible like other variables and eliminating the need for specialized APIs. We outline specific optimizations for both satellite grid and swath data stored in HDF4-EOS2 (Earth Observing System).

James Gallagher↗
NASA NTRS1986

Community living long before man: fossil and living microbial mats and early life

Microbial mats are layered communities of bacteria that form cohesive structures, some of which are preserved in sedimentary rocks as stromatolites. Certain rocks, approximately three and a half thousand million years old and representing the oldest known fossils, are interpreted to derive from microbial mats and to contain fossils of microorganisms. Modern microbial mats (such as the one described here from Matanzas, Cuba) and their fossil counterparts are of great interest in the interpretation of early life on Earth. Since examination of microbial mats and stromatolites increases our understanding of long-term stability and change, within the global environment, such structures should be protected wherever possible as natural science preserves. Furthermore, since they have existed virtually from the time of life's origin, microbial mats have developed exemplary mechanisms of local community persistence and may even play roles in the larger global environment that we do not understand.

NASA Discipline Exobiology↗
NASA NTRS1984

The impact cratering rate in recent time

The terrestrial data base for crater structures with diameters over 20 km on the North American and European cratons has been investigated for variations in the rate with time. The variation in the degree of preservation of highly eroded complex structures on the two cratons suggests that, if no contrasts exist between near-surface and uplifted lithologies, a 20 km-sized crater may be rendered virtually unrecognizable in 34 to 300 m.y. If lithological contrasts are present, it may be still recognizable as an anomalous structure for 79 to 630 m.y. It is unlikely that a significant number of craters with diameters greater than 20 km and ages in the range 0-117 m.y. are unrecognizable because of erosion. The relatively slower rate of increase in the number of craters with time for the 180-360 m.y. population may reflect a recognition problem.

Grieve, R. A.↗
NASA NTRS1977

Impact cratering phenomenon for the Ries multiring structure based on constraints of geological, geophysical, and petrological studies and the nature of the impacting body

In the present paper, an attempt is made to delineate, on the basis of field and laboratory data, the phenomenon of formation of the Ries multiring basin - the best preserved very large terrestrial impact structure. The model proposed conforms to constraints imposed by geological, geophysical, and petrological studies and by the nature of the postulated impacting body. It is also based on the impact features of a stony meteorite measuring 3 km in diameter at an impact velocity of 15 km/sec. The schematic reconstruction shows that critical to the production of a shallow crater is shallow impact penetration (shallow depth of burst). This and the nonballistic ejection of excavated material appear to be genetically related, i.e., if extensive nonballistic transport is recognized, then the associated crater must be a shallow structure and vice versa. This also means the shallow configuration of a crater may not have anything to do with postcratering readjustment.

Chao, E. C. T.↗
NASA NTRS1998

Biomarkers as tracers for life on early earth and Mars

Biomarkers in geological samples are products derived from biochemical (natural product) precursors by reductive and oxidative processes (e.g., cholestanes from cholesterol). Generally, lipids, pigments and biomembranes are preserved best over longer geological times and labile compounds such as amino acids, sugars, etc. are useful biomarkers for recent times. Thus, the detailed characterization of biomarker compositions permits the assessment of the major contributing species of extinct and/or extant life. In the case of the early Earth, work has progressed to elucidate molecular structure and carbon isotropic signals preserved in ancient sedimentary rocks. In addition, the combination of bacterial biochemistry with the organic geochemistry of contemporary and ancient hydrothermal ecosystems permits the modeling of the nature, behavior and preservation potential of primitive microbial communities. This approach uses combined molecular and isotopic analyses to characterize lipids produced by cultured bacteria (representative of ancient strains) and to test a variety of culture conditions which affect their biosynthesis. On considering Mars, the biomarkers from lipids and biopolymers would be expected to be preserved best if life flourished there during its early history (3.5-4 x 10(9) yr ago). Both oxidized and reduced products would be expected. This is based on the inferred occurrence of hydrothermal activity during that time with the concomitant preservation of biochemically-derived organic matter. Both known biomarkers (i.e., as elucidated for early terrestrial samples and for primitive terrestrial microbiota) and novel, potentially unknown compounds should be characterized.

Non-NASA Center↗
NASA NTRS2007

NanoSIMS opens a New Window for Deciphering Organic Matter in Terrestrial and Extraterrestrial Samples

Recognition of the earliest morphological or chemical evidence of terrestrial life has proved to be challenging, as organic matter in ancient rocks is commonly fragmentary and difficult to distinguish from abiotically-produced materials (Schopf, 1993; Van Zuilen et al., 2002; Altermann & Kazmierczak, 2003; Cady et al., 2003; Brasier et al., 2002, 2004, 2005; Hofmann, 2004; Skrzypczak et al., 2004, 2005). Yet, the ability to identify remnants of earliest life is critical to our understanding of the timing of life's origin on earth, the nature of earliest terrestrial life, and recognition of potential remnants of microbial life that might occur in extraterrestrial materials. The search for earliest life on Earth now extends to early Archean organic remains; these tend to be very poorly preserved and considerably more difficult to interpret than the delicately permineralized microfossils known from many Proterozoic deposits. Thus, recent efforts have been directed toward finding biosignatures that can help distinguish fragmentary remnants of ancient microbes from either pseudofossils or abiotic organic materials that may have formed hydrothermally or in extraterrestrial processes (House et al., 2000; Boyce et al., 2001; Kudryavtsev et al., 2001; Schopf, 2002; Schopf et al., 2002, 2005a,b; Cady et al., 2003; Garc a-Ruiz et al., 2003; Hofmann, 2004; Brasier et al., 2005; Rushdi and Simoneit, 2005; Skrzypczak et al., 2005). An exciting area of biosignature research involves the developing technology of NanoSIMS. NanoSIMS is secondary ion mass spectrometry (SIMS) for ultrafine feature, elemental and isotopic analysis. Its resolution approaches 0.05 micrometers for element mapping, which is 10-50 times finer than that attainable with conventional SIMS or electron microprobes. Consequently, NanoSIMS has the potential to reveal previously unknown, chemical and structural characteristics of organic matter preserved in geologic materials. Robert et al. (2005) were the first to combine NanoSIMS element maps with optical microscopic imagery in an effort to develop a new method for assessing biogenicity. They showed that the ability to simultaneously map the distribution of organic elements [such as carbon (C), nitrogen (N), and sulfur (S)] and compare those element distributions with optically recognizable, cellularly preserved fossils could provide significant new insights into the origin of organic materials in ancient sediments. This chapter details a recent NanoSIMS study which was designed to acquire new data relevant to establishing critical biosignatures (Oehler et al., 2006a-c). In this study, NanoSIMS was used to characterize element distributions of spheroidal and filamentous microfossils and associated organic laminae in chert from the approx. 0.85 billion year old (Ga) Bitter Springs Formation of Australia. Previous work established preservation of a diverse microbiota in the Bitter Springs Formation (Schopf, 1968; Schopf and Blacic, 1971), and there is no dispute within the scientific community regarding the biogenicity of any of the Bitter Springs structures evaluated in this new study. Thus, the NanoSIMS results described below provide new insight into - and can be used as a guide for assessing - the origin of less well understood organic materials that may occur in early Archean samples and in meteorites or other extraterrestrial samples.

Oehler, Dorothy ZS.↗
NASA NTRS1989

Microbial trace fossils in Antarctica and the search for evidence of early life on Mars

It is possible to hypothesize that, if microbial life evolved on early Mars, fossil remnants of these organisms may be preserved on the surface. However, the cooling and drying of Mars probably resembled a cold desert and such an environment is not suitable for the process of fossilization. The frigid Ross Desert of Antarctica is probably the closest terrestrial analog to conditions that may have prevailed on the surface of the cooling and drying Mars. In this desert, cryptoendolithic microbial communities live in the airspaces of porous rocks, the last habitable niche in a hostile outside environment. The organisms produce characteristic chemical and physical changes in the rock substrate. Environmental changes (deterioration of conditions) may result in the death of the community. Although no cellular structures are fossilized, the conspicuous changes in the rock substrate are preserved as trace fossils. Likewise, microbial trace fossils (without cellular structures) may also be preserved on Mars: Discontinuities in structure or chemistry of the rock that are independent of physical or chemical gradients may be of biological origin. Ross Desert trace fossils can be used as a model for planning search strategies and for instrument design to find evidence of past Martian life.

Friedmann, E. Imre↗
NASA NTRS1996

Lipid biomarkers for bacterial ecosystems: studies of cultured organisms, hydrothermal environments and ancient sediments

This paper forms part of our long-term goal of using molecular structure and carbon isotopic signals preserved as hydrocarbons in ancient sediments to improve understanding of the early evolution of Earth's surface environment. We are particularly concerned with biomarkers which are informative about aerobiosis. Here, we combine bacterial biochemistry with the organic geochemistry of contemporary and ancient hydrothermal ecosystems to construct models for the nature, behaviour and preservation potential of primitive microbial communities. We use a combined molecular and isotopic approach to characterize lipids produced by cultured bacteria and test a variety of culture conditions which affect their biosynthesis. This information is then compared with lipid mixtures isolated from contemporary hot springs and evaluated for the kinds of chemical change that would accompany burial and incorporation into the sedimentary record. In this study we have shown that growth temperature does not appear to alter isotopic fractionation within the lipid classes produced by a methanotropic bacterium. We also found that cultured cyanobacteria biosynthesize diagnostic methylalkanes and dimethylalkanes with the latter only made when growing under low pCO2. In an examination of a microbial mat sample from Octopus Spring, Yellowstone National Park (USA), we could readily identify chemical structures with 13C contents which were diagnostic for the phototrophic organisms such as cyanobacteria and Chloroflexus. We could not, however, find molecular evidence for operation of a methane cycle in the particular mat samples we studied.

NASA Discipline Exobiology↗
NASA NTRS1982

Adhesive-Bonded Tab Attaches Thermocouples to Titanium

Mechanical strength of titanium-alloy structures that support thermocouples is preserved by first spotwelding thermocouples to titanium tabs and then attaching tabs to titanium with a thermosetting adhesive. In contrast to spot welding, a technique previously used for thermocouples, fatigue strength of the titanium is unaffected by adhesive bonding. Technique is also gentler than soldering or attaching thermocouples with a tap screw.

Cook, C. F.↗
NASA NTRS1985

Microbial mats and modern stromatolites in Shark Bay, Western Australia

Distribution, external morphology, texture, and microbial composition of microbial mats in Hamelin Pool, Shark Bay, Western Australia, have been studied and reviewed along a composite representative profile starting from the permanently submerged zone, across the zones of periodic flooding, toward permanently emerged land and coastal dunes. The following nine types of algal mats have been recognized: colloform, gelatinous, smooth, pincushion, tufted, mamillate, film, reticulate, and blister. Solar ponds represent a particular environment. The mat types represent microbial communities that are characterized by one or more dominant microorganisms. The colonization and stabilization of loose sediment is carried out by a microbial assemblage of generalists that prepare the ground for later replacement and succession by specialized microflora. Lithification of microbial mats takes place periodically, mainly during the austral summer. This process is destructive for the microbial community but increases the preservation potential of the stromatolitic structures.

Golubic, S.↗
NASA NTRS1988

Origin and evolution of Gneiss-Charnockite rocks of Dharmapuri District, Tamil Nadu, India

A low- to high-grade transition area in Dharmapuri district was investigated petrologically and geochemically. The investigation confirmed the presence of a continuous section through a former lower crust, with felsic charnockites predominating the lower part and felsic gneisses the upper part. The structure of original gneisses is preserved in charnockites and the latter show petrographic evidence for prograde metamorphism. The prograde metamorphism is of isochemical nature as revealed by the similarity of compositions of tonalitic gneisses and tonalitic charnockites. However, the depletion of LIL elements particularly Rb, caused variation in K/Rb ratios from low values (345) in the gneisses in upper part to higher values (1775) in the charnockites in the lower crust. This variation in K/Rb ratio in a north to south traverse is related to the progressive break-down of hydrous minerals under decreasing H2O and increasing CO2 fluid conditions. Metasomatism and partial melting has also taken place to a limited extent along shear planes and weak zones. During cooling the H2O circulation affected substantial auto-regression in the transition zone resulting in the formation of second generation biotite.

Rao, D. Rameshwar↗
NASA NTRS1988

On conjugate gradient type methods and polynomial preconditioners for a class of complex non-Hermitian matrices

Conjugate gradient type methods are considered for the solution of large linear systems Ax = b with complex coefficient matrices of the type A = T + i(sigma)I where T is Hermitian and sigma, a real scalar. Three different conjugate gradient type approaches with iterates defined by a minimal residual property, a Galerkin type condition, and an Euclidian error minimization, respectively, are investigated. In particular, numerically stable implementations based on the ideas behind Paige and Saunder's SYMMLQ and MINRES for real symmetric matrices are proposed. Error bounds for all three methods are derived. It is shown how the special shift structure of A can be preserved by using polynomial preconditioning. Results on the optimal choice of the polynomial preconditioner are given. Also, some numerical experiments for matrices arising from finite difference approximations to the complex Helmholtz equation are reported.

Freund, Roland↗
NASA NTRS1993

Parabolic features and the erosion rate on Venus

The impact cratering record on Venus consists of 919 craters covering 98 percent of the surface. These craters are remarkably well preserved, and most show pristine structures including fresh ejecta blankets. Only 35 craters (3.8 percent) have had their ejecta blankets embayed by lava and most of these occur in the Atla-Beta Regio region; an area thought to be recently active. parabolic features are associated with 66 of the 919 craters. These craters range in size from 6 to 105 km diameter. The parabolic features are thought to be the result of the deposition of fine-grained ejecta by winds in the dense venusian atmosphere. The deposits cover about 9 percent of the surface and none appear to be embayed by younger volcanic materials. However, there appears to be a paucity of these deposits in the Atla-Beta Regio region, and this may be due to the more recent volcanism in this area of Venus. Since parabolic features are probably fine-grain, wind-deposited ejecta, then all impact craters on Venus probably had these deposits at some time in the past. The older deposits have probably been either eroded or buried by eolian processes. Therefore, the present population of these features is probably associated with the most recent impact craters on the planet. Furthermore, the size/frequency distribution of craters with parabolic features is virtually identical to that of the total crater population. This suggests that there has been little loss of small parabolic features compared to large ones, otherwise there should be a significant and systematic paucity of craters with parabolic features with decreasing size compared to the total crater population. Whatever is erasing the parabolic features apparently does so uniformly regardless of the areal extent of the deposit. The lifetime of parabolic features and the eolian erosion rate on Venus can be estimated from the average age of the surface and the present population of parabolic features.

Strom, Robert G.↗
NASA NTRS2000

The Role of Endolithic Cyanobacteria in the Formation of Lithified Laminae in Bahamian Stromatolites

The microboring activity of endolithic cyanobacteria plays a major role in the formation of lithified laminae in modern marine stromatolites in the Exuma Cays, Bahamas. These stromatolites are composed primarily of fine grained carbonate sand that is trapped and bound by the filamentous cyanobacteria Schizothrix sp. Periodic introduction of coccoid endolithic cyanobacteria, Solentia sp., results in formation of lithified horizons, 200 to 1000 micron thick. We used SEM and petrographic analyses to examine both naturally occurring lithified layers dominated by endoliths and fused oolitic crusts generated in the laboratory by activity of endolithic cyanobacteria (Solentia sp.). Fused grain crusts consist of micritized grains that are welded together at point contacts. Micritization results from extensive microboring and rapid (days to weeks) carbonate precipitation within the bore holes. This precipitation appears to occur concurrently with further endolithic activity within the grain, Infilling of bore holes that cross from one grain to another at point contacts results in grain welding, Thus, while microboring destroys original grain textures, at the same time the endolith activity plays a constructional role in stromatolite growth by forming lithified layers of welded grains. These framework structures help to stabilize and preserve the stromatolite deposits.

Prufert-Bebout, L.↗
NASA NTRS1997

On the Use of Vortex-Fitting in the Numerical Simulation of Blade-Vortex Interaction

The usefulness of vortex-fitting in the computational fluid dynamics (CFD) methods to preserve the vortex strength and structure while convecting in a uniform free stream is demonstrated through the numerical simulations of two- and three-dimensional blade-vortex interactions. The fundamental premise of the formulation is the velocity and pressure field of the interacting vortex are unaltered either in the presence of an airfoil or a rotor blade or by the resulting nonlinear interactional flowfield. Although, the governing Euler and Navier-Stokes equations are nonlinear and independent solutions cannot be superposed, the interactional flowfield can be accurately captured by adding and subtracting the flowfield of the convecting vortex at each instant. The aerodynamics and aeroacoustics of two- and three-dimensional blade-vortex interactions have been calculated in Refs. 1-6 using this concept. Some of the results from these publications and similar other published material will be summarized in this paper.

Srinivasan, G. R.↗
NASA NTRS1999

Pressure-Sensitive Paint Applied to Ice Accretions

Aircraft icing occurs when a plane flies through a cloud of supercooled water droplets. When the droplets impinge on aircraft components, ice starts to form and accumulate. This accumulation of ice severely increases the drag and lift of the aircraft, and can ultimately lead to catastrophic failures and even loss of life. Knowledge of the air pressures on the surfaces of ice and models in wind tunnels allows researchers to better predict the effects that different icing conditions will have on the performance of real aircraft. The use of pressure-sensitive paint (PSP) has provided valuable information on similar problems in conventional wind tunnel testing. In NASA Lewis Research Center Icing Research Tunnel, Lewis researchers recently demonstrated the world s first application of PSP on actual ice formed on a wind tunnel model. This proof-of-concept test showed that a new paint formulation developed under a grant by the University of Washington adheres to both the ice shapes and cold aluminum models, provides a uniform coating that preserves the detailed ice shape structure, and responds to simulated pressure changes.

Bencic, Timothy J.↗