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At least 127 records · Page 7

Understanding Cirrus Ice Crystal Number Variability for Different Heterogeneous Ice Nucleation Spectra

Along with minimizing parameter uncertainty, understanding the cause of temporal and spatial variability of the nucleated ice crystal number, Ni, is key to improving the representation of cirrus clouds in climate models. To this end, sensitivities of Ni to input variables like aerosol number and diameter provide valuable information about nucleation regime and efficiency for a given model formulation. Here we use the adjoint model of the adjoint of a cirrus formation parameterization (Barahona and Nenes, 2009b) to understand Ni variability for various ice-nucleating particle (INP) spectra. Inputs are generated with the Community Atmosphere Model version 5, and simulations are done with a theoretically derived spectrum, an empirical lab-based spectrum and two field-based empirical spectra that differ in the nucleation threshold for black carbon particles and in the active site density for dust. The magnitude and sign of Ni sensitivity to insoluble aerosol number can be directly linked to nucleation regime and efficiency of various INP. The lab-based spectrum calculates much higher INP efficiencies than field-based ones, which reveals a disparity in aerosol surface properties. Ni sensitivity to temperature tends to be low, due to the compensating effects of temperature on INP spectrum parameters; this low temperature sensitivity regime has been experimentally reported before but never deconstructed as done here.

Cirrus↗

2021 Site Environmental Report (SER) for the Ernest Orlando Lawrence Berkeley National Laboratory (LBNL)

Lawrence Berkeley National Laboratory (LBNL, Berkeley Lab) is a multiprogram scientific facility operated by the University of California (UC) for the U.S. Department of Energy (DOE). Berkeley Lab’s research is focused on the physical, biological, environmental, and computational sciences, with the objective of delivering scientific knowledge and discoveries pertinent to DOE’s mission. This annual report describes environmental protection activities and potential impacts resulting from operations conducted in calendar year 2021, unless otherwise indicated. The format and content of this report satisfy the requirements of both DOE Order 231.1B, Administrative Change 1 (Environment, Safety, and Health Reporting) (DOE, 2012) and the operating contract between UC and DOE (DOE Contract No. DE-AC02-05CH11231, also known as Contract 31).

54 ENVIRONMENTAL SCIENCES↗

Continuous sensor suite measurements of weather, energy, soil and flux at four PumpHouse sites at the East River, Colorado

The purpose of this package is to monitor energy and water fluxes using a comprehensive set of sensors integrated on a tripod set up at 4 locations at the East River watershed in Colorado in the Upper Colorado River Basin as part of the Scientific Focus Area (SFA) research led by the Lawrence Berkeley National Lab (LBNL). This is a continuous sensor suite measurements of weather, energy, soil and flux at four East River pumphouse sites (ER-PHS1, ER-PHS2, ER-PHS3 and ER-PHS4) include: (1) soil CO2 concentration, CO2 flux and heat flux from soil surface; (2) photosynthetic active radiation flux at 1 m; (3) incoming/outcoming short and long wave radiation at 1 m, and user calculated net short and long wave radiation; (4) oxygen concentration and surface infrared temperature; (5) soil volumetric water content, temperature, and electrical conductivity at 10, 30, 60, 115 cm depth 115 cm depth; (6) soil matric potential and temperature at 30 cm depth; (7) incoming short wave radiation at 3 m height; (8) rainfall precipitation; (9) lightning strikes and strike distances; (10) wind direction and speed, maximum wind gust at 3 m; (11) air temperature, vapor pressure and barometric pressure at 3 m; (12) X _axis_level and Y_axis_level_(degree), tilt of the ATMOS 41 sensor; (13) maximum rainfall rate; (14) relative humidity sensor temperature at 3 m; (15) internally calculated vapor pressure deficit at 3 m with vapor pressure, relative humidity and sensor temperature measurements; (16) user calculated vapor pressure.These datasets contain data from Oct 11 2019 to March 20, 2020, and new datasets will be updated on annual basis. Files uploaded in Excel and Word, with copies in csv and pdf format.

54 ENVIRONMENTAL SCIENCES↗

Impacts of PV Module Connector Failures on Cost and Performance of Utility Scale Photovoltaic Systems

The reliability, cost and performance of electrical connectors are a concern in all types of electrical systems, and demands on connectors used on photovoltaic (PV) systems include that connectors maintain electrical conductivity and physical strength, endure ultraviolet sunlight and high ambient temperature, and resist moisture and chemical intrusion over a very long (>25 year) performance period. Connector failures increase operation and maintenance (O&M) costs and reduce plant production, but connector failure can also cause safety and liability problems, which are of greater concern. This work results from a three-year collaboration between Sandia National Laboratories (SNL), the Electric Power Research Institute (EPRI), and the National Renewable Energy Laboratory (NREL) and funded by the U.S. Department of Energy (DOE) Solar Energy Technology Office (SETO) under Agreements #39035 and #38531 "Connector Reliability Across the US Solar Sector." a multi-pronged investigation of PV connector health across the US (see https://energy.sandia.gov/pvconnectors/). This report presents derivation of a Techno-Economic Analysis (TEA) that models failure modes and frequencies (how often failure occurs), estimates O&M costs and lost production associated with connector failures, and then calculates the effect that PV module connectors can have on Levelized Cost of Energy (LCOE). The model is informed with initial data from quantitative assessment of failure rates, root causes and mechanisms, in-situ diagnostics and data collection, lab-based forensics, and interviews with PV connector manufacturers and plant operators. SNL conducted site inspections at multiple utility-scale sites in different climates and subjected field samples of new, used, and degraded connectors to visual and electrical characterization. EPRI conducted metallurgical analysis of the pin and sleeve conductors to study failure-induced morphological and compositional changes. There is in general a shortage of statistically valid data, but data from PVROM database maintained by SNL was sufficient to ascertain failure rates and lost production as well as provide qualitative insight in its curated maintenance records. This report details the structure of the mathematical model but the sources of data to inform the model will continue to evolve. Analysis of a 100 MW PV plant is provided as an example of the use of the model, with results indicating that connectors are responsible for Annualized O&M Costs of $\$$71,933/year; Annualized Unit O&M Costs of $\$$0.72/kW/year; that a Reserve Account of $\$$187,220 should be available to fund repairs related to connectors; that connectors add $\$$1,494,004 to the Net Present Value of the O&M Costs (project life); and that O&M related to connectors adds about $\$$0.00088/kWh to the Levelized Cost of Energy. The impact of this model is to provide a tool to make the US solar sector more robust by quantifying and monetizing the reliability risks to utility-scale PV systems posed by poorly installed, mismatched and/or poorly designed and manufactured connectors. The TEA provides a model incorporating failure statistics, O&M cost data, and lost production into a single figure of merit, informing decisions and enabling practitioners to optimize cost and performance trade-offs. Stakeholders include connector manufacturers, system designers and equipment specifiers, standards bodies, installers and O&M providers, investors and insurance underwriters. This report supports continued growth of PV predicated on assurances that properly installed and maintained PV system connectors are safe and reliable. The project team is proposing future work including accelerated testing of connectors and expanding the approach taken here to other PV system components, such as TEA for rapid shut-down devices.

14 SOLAR ENERGY↗

The TRANSCEND University Consortium: Theme 2 - Site Decommissioning, Deconstruction and Remediation - 20329

This paper will discuss the aims, objectives and progress to-date under Theme 2 of the TRANSCEND consortium project: Site decommissioning, deconstruction and remediation. Decommissioning nuclear sites involves waste retrieval, decontamination, deconstruction and, where necessary, containment and/or remediation of the remaining structure and surrounding land. Critical to management of these processes is limiting radiation exposure for the workforce, restricting the spread of radionuclides in groundwater, surface water and airborne particulates, and minimising the volume of contaminated waste for disposal. The aim of Theme 2 research is to develop new technologies for monitoring, remediation and containment that serve to minimise the volume of radioactively contaminated waste for disposal, for application prior to, during and after retrieval, deconstruction and decontamination operations. Prior research, conducted under the previous DISTINCTIVE project, demonstrated that colloidal silica grout can penetrate low permeability materials (including cement) for hydraulic barrier formation, and improved sorption capacity. The silica grout can be injected at surface using extremely small (potentially gravity-driven) fluid pressures, without the need for borehole drilling. Current work is investigating the erodibility of silica-grouted soils for inhibition of airborne and water-borne particulates as well as enhancing the grout's sorption capacity by addition of other materials to provide a chemical, as well as hydraulic, barrier to subsurface migration. EK remediation uses low voltage DC current to control migration of contaminants in porous media as well as to remove or degrade them. Researchers in the consortium have already demonstrated that low-energy ex-situ EK techniques can be used to provide remediation and volume minimisation for AWE legacy wastes in the UK. Under the current project researchers are building EK test cells containing simulated site materials at laboratory and intermediate(m)-scales to: remove, focus or degrade contaminants (remediation or waste minimisation); and direct subsurface water, chemical and colloid flow (fencing/containment or forced migration). This lab-based research is being informed by numerical models of EK processes that can subsequently be used to design full-scale on-site applications by nuclear site holders. Research under theme 2 of TRANSCEND will ultimately combine novel non-invasive detection technologies with EK techniques and colloidal silica grout barriers, to optimise the containment of radionuclide contamination in soils. Thus, allowing us to detect in-situ contamination, mobilise it to a selected location and grout it in-situ, prior to the initiation of decommissioning and deconstruction operations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The role of sample–window coupling in shock temperature experiments

Radiometric studies of opaque materials under shock compression probe a sample–window interface that may be very different than the bulk state. Subtle experimental details, particularly an initial sample–window gap vs an adhesively bonded stack, have tremendous influence on measured temperature. This work experimentally tests gapped vs bonded targets and theoretically investigates observed differences in the measured temperature. The results indicate that perturbations created by a thin adhesive are smaller than those suggested by a previous work, whereas sample–window gaps alter the measured state more significantly than that previously realized.

Adhesives↗

Leaf C and N content by leaf age, Feb2017, PA-SLZ: Panama

This dataset contains carbon, hydrogen and nitrogen content measurements of sunlit canopy leaves of Apeiba membranacea (APEIME), Guatteria dumetorum (GUATDU), Miconia borealis (MICOBO), Terminalia amazonia (TERMAM), Virola multiflora (VIROSP) and Vochysia ferruginea (VOCHFE) species. Data was collected from the NGEE-Tropics Bosque Protector San Lorenzo (PA-SLZ) site in Panama in February of 2017 as part of the 2017 Brookhaven National Lab–Smithsonian Tropical Research Institute leaf traits by age campaign. A PDF with full sapling protocol is included in this dataset, along with metadata files in Excel file format. Data is in both CSV (Panama2017_CHN.csv) and Excel file formats. See related datasets for further sample details, leaf spectra, sap flow, leaf water potential, leaf mass per area (LMA), and gas exchange measurements.

54 ENVIRONMENTAL SCIENCES↗

CIO Cloud Strategy

The purpose of the Sandia CIO Cloud Strategy is to establish the strategic direction for the adoption of cloud services and technologies as the prevailing IT solution for Sandia National Laboratories. Sandia’s Chief Information Officer (CIO) will champion unified, site-wide adoption of cloud and will amplify business and mission impacts across the Labs. Sandia’s CIO Cloud Strategy aligns to the Federal Cloud Computing Strategy1 (Cloud Smart) and the Sandia Management and Operating Contract (Prime Contract).

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

IDB Database Tables

The International Database of Reference Gamma-Ray Spectra of Various Nuclear Matter is designed to hold curated gamma spectral data is hosted by the International Atomic Energy Agency on its public facing web site. The database used to hold the spectral data was designed by Sandia National Labs under the auspices of the State Department’s Support Program. This document describes the tables and entity relationships that make up the database.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

BOREAS TE-2 NSA Soil Lab Data

This data set contains the major soil properties of soil samples collected in 1994 at the tower flux sites in the Northern Study Area (NSA). The soil samples were collected by Hugo Veldhuis and his staff from the University of Manitoba. The mineral soil samples were largely analyzed by Barry Goetz, under the supervision of Dr. Harold Rostad at the University of Saskatchewan. The organic soil samples were largely analyzed by Peter Haluschak, under the supervision of Hugo Veldhuis at the Centre for Land and Biological Resources Research in Winnipeg, Manitoba. During the course of field investigation and mapping, selected surface and subsurface soil samples were collected for laboratory analysis. These samples were used as benchmark references for specific soil attributes in general soil characterization. Detailed soil sampling, description, and laboratory analysis were performed on selected modal soils to provide examples of common soil physical and chemical characteristics in the study area. The soil properties that were determined include soil horizon; dry soil color; pH; bulk density; total, organic, and inorganic carbon; electric conductivity; cation exchange capacity; exchangeable sodium, potassium, calcium, magnesium, and hydrogen; water content at 0.01, 0.033, and 1.5 MPascals; nitrogen; phosphorus: particle size distribution; texture; pH of the mineral soil and of the organic soil; extractable acid; and sulfur. These data are stored in ASCII text files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Veldhuis, Hugo↗

Nanofluidic size exclusion chromatograph for in site macrometer analyses

We are developing a nanofluidic size exclusion chromatograph system that can be incorporated into a miniature lab-on-a-chip devices which will provide detailed information on the geochemical and biological history of soil, ice, and water samples by identifying and qualifying a broad range of macromolecular polar and nonpolar organic compounds.

size exclusion chromatograph↗

Scale dependence in functional equivalence and difference in the soil microbiome

Climatic history can shape the functioning of soil microbial communities and thus rates of ecosystem processes such as organic matter decomposition. For example, broad spatial scale differences in climatic history, such as contrasting precipitation regimes, have been shown to generate unique microbial functional responses to contemporary moisture conditions. Yet it is an open question as to whether local differences in soil microclimate similarly influence the functional potential of decomposer communities. Here, we use a multi-scale approach within and among two temperate forest field sites to investigate this question. Soils from fifty-four microsites, that vary in their soil moisture climate-regimes, were used as inocula for a common leaf litter (Quercus rubra L.) in a controlled, laboratory microcosm study. Microcosms were placed under dry, mesic and wet lab-moisture conditions and the rate of carbon (C) mineralization of the litter was measured over 202 days. Our results reveal differences in decomposition rates under controlled conditions that highlight broad-scale functional differences between the soil communities at each site. Specifically, we found that C mineralization differed by as much as two-fold for soil communities when compared between the sites. Our results also show that functional differences of soil communities are observable within one site but not the other. In the site where local-scale functional legacies were apparent, the historical soil moisture microclimate-regimes generated as much as an 89% change in C mineralization rates of the leaf litter under the same contemporary, lab-imposed moisture conditions. Here, a similar pattern was not observable in the other site; instead, laboratory moisture conditions explained almost all variation in C mineralization. Notably, for the site with pronounced local-scale functional legacies, there was much greater within-site variation in field-soil microsite moisture than at the site which did not exhibit functional legacies, suggesting that the extent of local-scale variation in microclimate may act as control on whether local-scale functional legacies are observed. Regardless of whether this mechanism does explain our findings, our observations do confirm those from prior studies where regional-scale moisture-regime differences shape microbial function, and extend this prior work by providing evidence that pronounced local-scale differences in soil moisture microclimate-regimes are associated with microbial functional legacies.

54 ENVIRONMENTAL SCIENCES↗

Results from Laboratory and Field Study of Thin Triple Pane Windows

Heat transfer through windows accounts for a significant percentage of a building’s energy use and adds substantially to the peak cooling load of a home. In recent years, improvements in glass manufacturing have enabled the use of a very thin central pane of glass similar to a cell phone screen to produce a thin triple-pane window, for finished insulated glass units (IGUs) with an overall thickness similar to standard double-pane windows. Because this highly insulating “thin triple” glass product can be incorporated into almost any existing window frame and can be fabricated at a modest added cost, the U.S. Department of Energy sponsored laboratory and field demonstration testing of thin triple-pane windows to validate thermal performance and installation requirements in real-life field settings. Thin triple pane windows were evaluated at the PNNL Lab Homes, a matched pair of manufactured houses located on PNNL’s campus in Richland, Washington and also at 16 different field study sites around the country. The experimental results include a comparison of heating, ventilation, and air-conditioning (HVAC) energy usage, condensation potential, occupant comfort, sound infiltration, and thermal performance. Field study data will be gathered through June of 2022; preliminary results are being shared in this paper. The lab houses are identical except that the reference house had standard double pane windows with assembly U-0.66 and the test house had thin triple pane windows with assembly U-0.19. Across the experimental test days, the daily HVAC savings ranged from 0.2 to 18.7 kWh (3%–18%) for the heating season and from 2.5 to 8.0 kWh (23%–41%) for the cooling season. The higher thermal performance of the thin triple-pane windows also reduced the condensation potential on the interior surface during winter months and provided more even distribution of temperatures throughout the home in comparison to the baseline. In addition to the added thermal performance, the thin triple-pane windows demonstrated significant acoustic benefits, reducing sound infiltration by 8 dB to 10 dB. For the field test portion of the project thin triple pane insulated glass units were produced by two different manufacturers, and then installed without modification into the ½” IGU pockets of the standard double pane frames of four other manufacturers. Field tests performed on existing homes in Washington, Montana, Colorado, and New York compared thin triple pane retrofits to original window conditions (before and after). Field tests at new construction sites in Minnesota, Michigan, and New York compared thin triple pane windows to commercially available solutions such as double pane or traditional triple pane (with a standard-thickness center pane). Field test work is ongoing, but preliminary results appear to follow the sound, surface temperature, and energy improvement results from the Lab Homes comparison. Additionally, reports from builders and installers indicate that thin triples require almost no added time or effort to install and look nearly identical to other windows, indicating the possibility of offering next-level performance with a product that requires very little modification to current production or installation practices, long considered a major barrier to technology uptake in the construction market.

energy efficiency, home retrofit, Windows, window ↗

Porewater chemistry in Typha-dominated brackish tidal marsh, PIE LTER, Plum Island Sound, MA, July 2022–September 2024

This dataset contains profile measurements of porewater constituents taken on 3-4 days across the growing seasons in 2022, 2023, and 2024 in a tidal brackish marsh within the Plum Island Ecosystems Long Term Ecological Research site (PIE LTER), located in the Plum Island Sound, Massachusetts (MA). Measurements were taken to monitor changes in porewater chemistry induced by seasonal saltwater intrusion at the site. Samples were taken in two locations: one was close to the creek bank and the other in the marsh interior. Water was sampled from 2-5 depths between the surface to 50cm using a sipper consisting of a hollow stainless steel rod with an opening at the end similar to that described in (Berg & McGlathery, 2001). The rod was pushed into the sediment to the desired depth, typically every 10cm, and water samples were taken by syringe. Water was not obtained at all depths. Samples were preserved and analyzed in the lab. Metadata files Typha_porewater_sipper_dd.csv and Typha_porewater_sipper_flmd.csv contain detailed information on data variables, sampling and QA/QC methods, and site location.

54 ENVIRONMENTAL SCIENCES↗

PV Variability at the DeSoto Next Generation Solar Energy Center (Cooperative Research and Development Final Report, CRADA Number CRD-11-425)

In order to support the continued integration of utility-scale solar photovoltaic sites into the Florida transmission system and to further enhance our understanding of the effects of cloud-induced output variability on the site and transmission operations, participant elects to enter a Cooperative Research and Development Agreement (CRADA) with the National Renewable Energy Lab (NREL). Under this agreement, NREL will work with participant to instrument their PV plant in DeSoto county FL and obtain solar radiation and power output data. The Florida Power & Light's (FPL) DeSoto Next Generation Energy Center is the largest installed PV plant in the country (25 MW). Our goal is that this site be instrumented and used for research into PV variability and forecasting.

14 SOLAR ENERGY↗

Status of SNS Proton Power Upgrade SRF Cavities Production Qualification

The Pro­ton Power Up­grade pro­ject at Oak Ridge Na­tional Lab’s Spal­la­tion Neu­tron Source (SNS PPU) cur­rently being con­structed will dou­ble the pro­ton beam power from 1.4 to 2.8 MW by adding 7 ad­di­tional cry­omod­ules, each con­tains four six-cell high beta (\beta = 0.81) su­per­con­duct­ing radio fre­quency cav­i­ties. The cav­i­ties were built by Re­search In­stru­ments, Ger­many, with all the cav­ity pro­cess­ing done at the ven­dor site, in­clud­ing elec­trop­o­l­ish­ing as the final ac­tive chem­istry step. All 28 cav­i­ties needed for 7 cry­omod­ules were de­liv­ered to Jef­fer­son Lab, ready to be tested. The cryo­genic RF qual­i­fi­ca­tions and he­lium ves­sel weld­ing were done at Jef­fer­son Lab. The per­for­mance largely ex­ceed the re­quire­ments, and greatly ex­ceeded the per­for­mance of the orig­i­nal SNS cav­ity pro­duc­tion se­ries. Here, we pre­sent the sum­mary of RF test on pro­duc­tion cav­i­ties to this date.

Dhakal, P.↗

Status of SNS Proton Power Upgrade SRF Cavities Production Qualification

The Pro­ton Power Up­grade pro­ject at Oak Ridge Na­tional Lab’s Spal­la­tion Neu­tron Source (SNS PPU) cur­rently being con­structed will dou­ble the pro­ton beam power from 1.4 to 2.8 MW by adding 7 ad­di­tional cry­omod­ules, each con­tains four six-cell high beta (\beta = 0.81) su­per­con­duct­ing radio fre­quency cav­i­ties. The cav­i­ties were built by Re­search In­stru­ments, Ger­many, with all the cav­ity pro­cess­ing done at the ven­dor site, in­clud­ing elec­trop­o­l­ish­ing as the final ac­tive chem­istry step. All 28 cav­i­ties needed for 7 cry­omod­ules were de­liv­ered to Jef­fer­son Lab, ready to be tested. The cryo­genic RF qual­i­fi­ca­tions and he­lium ves­sel weld­ing were done at Jef­fer­son Lab. The per­for­mance largely ex­ceed the re­quire­ments, and greatly ex­ceeded the per­for­mance of the orig­i­nal SNS cav­ity pro­duc­tion se­ries. Here, we pre­sent the sum­mary of RF test on pro­duc­tion cav­i­ties to this date.

Dhakal, P.↗

LANL Workforce Reporting Tool

The LANL Workforce Reporting Tool compiles and analyzes workforce demographics and attributes as presented in the annual Stockpile and Stewardship Management Plan (SSMP) over FY15-21 using MicroStrategy, a data analytics and visualization software. There are three major employee populations included in the tool: 1) LANL’s regular (permanent) employees; 2) LANL’s entire workforce (regular, craft, contractors, students, post doctorate students, limited term employees, and lab associates); 3) The Nuclear Security Enterprise’s (NSE) permanent career employees (combined and site-by-site).

97 MATHEMATICS AND COMPUTING↗