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At least 127 records · Page 7

Nondestructive evaluation of ceramic and metal matrix composites for NASA's HITEMP and enabling propulsion materials programs

In a preliminary study, ultrasonic, x-ray opaque, and fluorescent dye penetrants techniques were used to evaluate and characterize ceramic and metal matrix composites. Techniques are highlighted for identifying porosity, fiber alignment, fiber uniformity, matrix cracks, fiber fractures, unbonds or disbonds between laminae, and fiber-to-matrix bond variations. The nondestructive evaluations (NDE) were performed during processing and after thermomechanical testing. Specific examples are given for Si3N4/SiC (SCS-6 fiber), FeCrAlY/Al2O3 fibers, Ti-15-3/SiC (SCS-6 fiber) materials, and Si3N4/SiC (SCS-6 fiber) actively cooled panel components. Results of this study indicate that the choice of the NDE tools to be used can be optimized to yield a faithful and accurate evaluation of advanced composites.

Generazio, Edward R.↗

Advanced reinforcement systems for intermetallic applications

A 2-D axisymmetric model was employed to determine the magnitude of the radial, axial, and hoop stresses caused by the thermal expansion difference between fiber and matrix and which result from the fabrication temperature cycle. Finite element analysis was conducted for single fiber model systems based on SCS-6/Ti3Al+Nb and Al2O3/NiAl. The stress distribution due to the imposition of a graded intermediate layer for each system was determined and included variables of layer thickness and gradation in interlayer chemistry in order to vary the expansion gradient between fiber and matrix. Thermal cycling tests were conducted on sputter coated SCS-6 fibers selectively coated with Ti3Al+Nb, with and without an intermediate layer. Cracking of the Ti3Al+Nb layers was prevented by an interlayer based on Ti-TiN-Ti. The interlayer thickness appeared critical to its efficiency. Similarly, for the case of Al2O3/NiAl, an intermediate layer consisting of a Ni bond coat on the sapphire fiber followed by a graded Al2O3-NiAl layer did not crack when given a thermal excursion to 1100 C and then cooled to room temperature. Acoustic emission tests on single fiber specimens were unsuccessful in detecting load drops associated with the successive fracture of the fiber. For the SCS-6/Ti3Al system this was the result of several factors which included the matrix/fiber ratio and poor bonding of the matrix and fiber. In the case of the Al2O3/NiAl system brittle failure of the NiAl matrix precluded fiber breakdown during tensile loading.

Merrick, Howard F.↗

Simulated Bladed MMC Disk LCF Validation

The goal of this program was to evaluate the low cycle fatigue behavior of an SCS-6/Ti-6Al-4V sub-component under bi-axial loading conditions at 316 C(600 F). A simulated bladed TMC disk was designed having thirty four blades representing the number that would be used in Allied Signal's JTAGG II impeller. The outer diameter of the bladed ring was 254 mm (10.0 inch) and the inner diameter 114.3 mm (4.50 inch). The outer and inner diameter of the composite zone was 177.8 mm (7.00 inch) and 127.O mm(5.00 inch) respectively. Stress analysis showed that the fatigue life of the bladed composite ring would be about 12000 cycles for the test conditions applied. A modal analysis was conducted which showed that the blades would have sufficient life margin from dynamic excitation. The arbor design was the same as that employed in the spin-to burst test of NAS3-27027. A systematic stress analysis of each part making up the arbor was undertaken to assure the design would meet the low cycle fatigue requirements of the program. The Textron Systems grooved foil-fiber process was chosen to make the SCS-6/Ti-6Al-4V core ring based on the success they had in contract NAS3-27027. Fiber buckling, however, was observed at several locations in the first ring made which rendered it unsuitable for spin testing. The fiber buckling was attributed to cracking of the graphite tooling during the consolidation process. On this basis a second ring was made but it too contained fiber buckling defects. Analysis by Textron indicated that the fiber buckling was most likely due to poor placement of the SCS-6 fiber in the etched grooves of the Ti-6Al-4V foil. This was also a contributor to the defects in the first ring. Since there was little indication of control in the process to manufacture a quality ring a third attempt at making a ring was not undertaken.

Merrick, H. F.↗

Structure and Evolution of an Oceanic Squall Line During South China Sea Monsoon Experiment

The South China Sea Monsoon Experiment (SCSMEX) was conducted in South China Sea (SCS) and surrounding areas during May - June 1998. The primary goal of the experiment is to provide a better understanding of the key physical processes for the onset, maintenance and variability of the monsoon over the Southeast Asia and southern China leading to improved monsoon predictions. As the first comprehensive field experiment aiming on the SCS summer monsoon, the goals of the mesoscale program associated with the primary objective are: (1) to define the initiation, structure, evolution and dynamics of precipitation processes associated with the onset and mature phase of the SCS monsoon, and (2) to obtain quantitative rainfall estimates, vertical air motion and inferences on microphysical structure over a tropical oceanic site.

Wang, Jian-Jian↗

iLIDS Simulations and Videos for Docking TIM

The video shows various aspects of the International Low Impact Docking System, including team members, some production, configuration, mated androgynous iLIDS, SCS Lockdown system, thermal analysis, electrical engineering aspects, the iLIDS control box and emulator, radiation testing at BNL, component environmental testing, component vibration testing, 3G processor board delivery system, GTA vibe test, EMA testbed, hook and hook disassembly, flex shaftdrive assembly, GSE cradle MISSE-6 Columbus, MISSE 6 and 7 seal experiments, actuated full scale seal test rig, LIDS on Hubble, dynamics test prep, EDU 54 mass emulation and SCS, load ring characterization, 6DOF proof test, SCS at 6DOF, machining EEMS and inner ring assembly, APAS assembly, inner ring fitting, rotation stand assembly, EEMS mating, and EEMS proof of concept demonstration.

Lewis, James L.↗

Autonomous Control of Space Nuclear Reactors

Nuclear reactors to support future robotic and manned missions impose new and innovative technological requirements for their control and protection instrumentation. Long-duration surface missions necessitate reliable autonomous operation, and manned missions impose added requirements for failsafe reactor protection. There is a need for an advanced instrumentation and control system for space-nuclear reactors that addresses both aspects of autonomous operation and safety. The Reactor Instrumentation and Control System (RICS) consists of two functionally independent systems: the Reactor Protection System (RPS) and the Supervision and Control System (SCS). Through these two systems, the RICS both supervises and controls a nuclear reactor during normal operational states, as well as monitors the operation of the reactor and, upon sensing a system anomaly, automatically takes the appropriate actions to prevent an unsafe or potentially unsafe condition from occurring. The RPS encompasses all electrical and mechanical devices and circuitry, from sensors to actuation device output terminals. The SCS contains a comprehensive data acquisition system to measure continuously different groups of variables consisting of primary measurement elements, transmitters, or conditioning modules. These reactor control variables can be categorized into two groups: those directly related to the behavior of the core (known as nuclear variables) and those related to secondary systems (known as process variables). Reliable closed-loop reactor control is achieved by processing the acquired variables and actuating the appropriate device drivers to maintain the reactor in a safe operating state. The SCS must prevent a deviation from the reactor nominal conditions by managing limitation functions in order to avoid RPS actions. The RICS has four identical redundancies that comply with physical separation, electrical isolation, and functional independence. This architecture complies with the safety requirements of a nuclear reactor and provides high availability to the host system. The RICS is intended to interface with a host computer (the computer of the spacecraft where the reactor is mounted). The RICS leverages the safety features inherent in Earth-based reactors and also integrates the wide range neutron detector (WRND). A neutron detector provides the input that allows the RICS to do its job. The RICS is based on proven technology currently in use at a nuclear research facility. In its most basic form, the RICS is a ruggedized, compact data-acquisition and control system that could be adapted to support a wide variety of harsh environments. As such, the RICS could be a useful instrument outside the scope of a nuclear reactor, including military applications where failsafe data acquisition and control is required with stringent size, weight, and power constraints.

Merk, John↗

Can Asian Dust Trigger Phytoplankton Blooms in the Oligotrophic Northern South China Sea?

Satellite data estimate a high dust deposition flux (approximately 18 g m(exp-2 a(exp-1) into the northern South China Sea (SCS). However, observational evidence concerning any biological response to dust fertilization is sparse. In this study, we combined long-term aerosol and chlorophyll-a (Chl-a) measurements from satellite sensors (MODIS and SeaWiFS) with a 16-year record of dust events from surface PM10 observations to investigate dust transport, flux, and the changes in Chl-a concentration over the northern SCS. Our result revealed that readily identifiable strong dust events over this region, although relatively rare (6 cases since 1994) and accounting for only a small proportion of the total dust deposition (approximately 0.28 g m(exp-2 a(exp-1), do occur and could significantly enhance phytoplankton blooms. Following such events, the Chl-a concentration increased up to 4-fold, and generally doubled the springtime background value (0.15 mg m(exp-3). We suggest these heavy dust events contain readily bioavailable iron and enhance the phytoplankton growth in the oligotrophic northern SCS.

northern South China sea↗

Adaptive Load Control of Flexible Aircraft Wings Using Fiber Optic Sensing

Over the past century aircraft wing design has transformed from the morphing wing used on the Wright Flyer to rigid wings with little to no shape-tailoring abilities. Modern day wings are designed to fly at a single trim condition and optimized to have a maximum aerodynamic efficiency at only this condition. Shape morphing wings on the other hand have the potential to undergo geometric changes allowing them to adapt to their mission profiles. Several flight demonstrations have been conducted over the decades using morphing-wing technologies. Active wing-twist control was demonstrated on the X-53 Active Aeroelastic Wing (AAW) research project by utilizing multiple leading- and trailing-edge control surfaces. Passive morphing technology has been demonstrated on the Rockwell RPRV-870 Highly Maneuverable Aircraft Technology (HiMAT) aircraft. In the current study, the wings of a small unmanned aerial system (sUAS) were modified to have segmented control surfaces (SCS). The modifications include segmenting the original wing control surfaces (one flap and one aileron per wing) into 44 individual sections, each section having its own independent servo control motor. The wings were also instrumented with a network of over 1800 fiber-optic strain sensors (on four sensing fibers distributed over the top and bottom surfaces of the wing) monitoring the strain response of the wing to aerodynamic loading. The SCS positions were manipulated in real time to modify the spanwise lift distribution of the wings on the sUAS. The change in the structural response of the wings caused by load redistribution was quantified by measuring the bending strains on the upper and lower wing surfaces using an on-board compact fiber-optic strain sensing (cFOSS) system. A feedback controller was developed to control the SCS positions using strain-based shape estimations from the Displacement Transfer Function (DTF). Post-processing of the strain data allowed for the transverse displacement distributions and load distributions to be compared for the conventional and segmented control surface cases using displacements and loads algorithms developed by Richards and Ko at AFRC (refs. 5-10). While the current study focused on the shifting of the spanwise aerodynamic loads as quantified by displacements, future applications for loads or displacement control might include active gust alleviation and flutter suppression.

Pena, Francisco↗

Terrestrial Single-Station Analog for Constraining the Martian Core and Deep Interior: Implications for InSight

We used a terrestrial single-station seismometer to quantify the uncertainty of InSight (INterior explorations using Seismic Investigations, Geodesy and Heat Transport) data for determining Martian core size. To mimic Martian seismicity, we formed a catalog using 917 terrestrial earthquakes, from which we randomly selected events. We stacked ScS amplitudes on modeled arrival times and searched for where ScS produced coherent seismic amplitudes. A core detection was defined by a coherent peak with small offset between predicted and user-selected arrival times. Iterating the detection algorithm with varying signal-to-noise (SNR) ranges and quantity of events determined the selection frequency of each model and quantified core depth uncertainty. Increasing the quantity of events reduced core depth uncertainty while increasing the recovery rate, while increasing event SNR had little effect. Including ScS2 multiples increased the recovery rate and reduced core depth uncertainty when we used low quantities of events. The most-frequent core depths varied by back azimuth, suggesting our method is sensitive to the presence of mantle heterogeneities. When we added 1° in source distance errors, core depth uncertainty increased by up to 11 km and recovery rates decreased by <5%. Altering epicentral distances by 25% added ~35 km of uncertainty and reduced recovery rates to <50% in some cases. From these experiments, we estimate that if InSight can detect five events with high location precision (<10% epicentral distance errors), that there is at least an 88% chance of core depth recovery using ScS alone with uncertainty in core depth approaching 18 km and decreasing as more events are located.

Marusiak, Angela G.↗

Terrestrial Single-Station Analog for Constraining the Martian Core and Deep Interior: Implications for InSight

We used a terrestrial single-station seismometer to quantify the uncertainty of InSight (INterior explorations using Seismic Investigations, Geodesy and Heat Transport) data for determining Martian core size. To mimic Martian seismicity, we formed a catalog using 917 terrestrial earthquakes, from which we randomly selected events. We stacked ScS amplitudes on modeled arrival times and searched for where ScS produced coherent seismic amplitudes. A core detection was defined by a coherent peak with small offset between predicted and user-selected arrival times. Iterating the detection algorithm with varying signal-to-noise (SNR) ranges and quantity of events determined the selection frequency of each model and quantified core depth uncertainty. Increasing the quantity of events reduced core depth uncertainty while increasing the recovery rate, while increasing event SNR had little effect. Including ScS2 multiples increased the recovery rate and reduced core depth uncertainty when we used low quantities of events. The most-frequent core depths varied by back azimuth, suggesting our method is sensitive to the presence of mantle heterogeneities. When we added 1° in source distance errors, core depth uncertainty increased by up to 11 km and recovery rates decreased by <5%. Altering epicentral distances by 25% added ~35 km of uncertainty and reduced recovery rates to <50% in some cases. From these experiments, we estimate that if InSight can detect five events with high location precision (< 10% epicentral distance errors), that there is at least an 88% chance of core depth recovery using ScS alone with uncertainty in core depth approaching 18 km and decreasing as more events are located.

Angela G Marusiak↗

166 GHZ Ice Scattering Signal in Snowfall Events Over Ocean

Snowfall retrieval algorithms for spaceborne passive microwave (PMW) sensors have been developed and refined in recent years, but many complicating issues still affect their accuracy and reliability. Previous work showed that the Global Precipitation Measurement (GPM) mission Goddard PROFiling (GPROF) algorithm snowfall retrieval performance strongly depends on the snowfall type. In particular, PMW-based detection of shallow cumuliform snowfall (SCS), which accounts for 36%-70% of global snowfall frequency, can be very challenging. The snowfall scattering signal can be contaminated by the background surface or supercooled cloud liquid water emission. A scattering index (SI) approach that exploits the GPM Microwave Imager (GMI) dual-polarization 166 GHz channels is developed to analyze its behavior in presence of SCS over ocean. Case studies show that, compared to the SI at 89 GHz, it can isolate the SCS snowfall scattering signal in extremely dry conditions. Some issues are still observed in presence of supercooled liquid water.

Lisa Milani↗

Docking the Mars 2020 Perseverance Robotic Arm

The Mars 2020 Perseverance Rover includes an innovative Sample Caching Subsystem (SCS). Two key features of SCS are the ability to collect and process rock and regolith samples for possible future return to Earth and the ability to switch between different types of drill bits for coring rocks, abrading rocks, and collecting regolith. These capabilities are enabled by a Corer mounted on the end of a Robotic Arm and a Bit Carousel mounted on the front of the rover body. Beneath the Bit Carousel, a smaller Sample Handling Arm can insert and remove sample tubes from sampling bits in the carousel. For the Corer to interface with the Bit Carousel so that it can exchange drill bits and hand off rock samples, the Robotic Arm must maneuver the Corer to dock with the Bit Carousel. Docking serves two primary purposes: it precisely aligns the Corer with the hardware inside the Bit Carousel, and it applies enough preload between the Corer and the Bit Carousel to make them stay aligned through the process of bit exchange.The docking assembly consists of four concave alignment cones mounted on a large rotating ring, through the center of which the drill can exchange bits and samples with the Bit Carousel. The coring drill includes four alignment posts which mate with the four cones on the dock. Docking uses an algorithm we call “Force-Corrected Docking”, which means it iteratively reads the force/moments reported by the FTS, performs a small motion to reduce sideload and moments while increasing preload, and repeats until reaching a deadband around the target preload. Because docking is a critical function for SCS, the dock hardware and algorithm have been tested thousands of times over 7 years in various stages of development. The culmination of this work is a reliable docking system which has been demonstrated and used in flight.

Warner, Antonia↗

Microwave-assisted pyrolysis of hydrocarbons using iron-based alumina catalysts obtained via solution combustion synthesis

The demand for hydrogen is growing which makes the development of clean and efficient H2 synthesis technologies imperative. Microwave-assisted, thermocatalytic, dehydrogenation of hydrocarbons has demonstrated the ability to generate H2 with high yield and selectivity, leaving behind valuable solid carbon byproducts. However, this microwave-assisted process is unoptimized which prevents it from being utilized in industry. A critical component of optimization is the development of a catalyst that is catalytically active, a good microwave absorber, and can be regenerated for repeated dehydrogenation cycles. Previous studies that focused on plastic waste decomposition have used iron-based alumina (FeAlxOy) made via solution combustion synthesis (SCS). Unexplored is the effect of tuning SCS parameters on dehydrogenation performance, the use of these materials in hydrocarbon decomposition to H2, and the regeneration of these catalysts. This dissertation has three objectives: (1) characterize the relationship between SCS parameters and the material properties of FeAlxOy, (2) determine how differences in the material properties of FeAlxOy influence their performance as catalysts during microwave-assisted pyrolysis of fossil fuels, and (3) investigate the Boudouard reaction to regenerate the FeAlxOy post-dehydrogenation.

Chanoi, Zachary Aidan↗

Multi-purpose quantum laboratories from superconducting circuits

Superconducting circuits (SCs) are the cornerstone of modern quantum technology, enabling scalable computing through coherent control of macroscopic quantum states. Through a legacy that predates modern quantum computing, SCs have emerged as high-precision instruments for discovery. In this review, we highlight the role of SCs as general-purpose quantum laboratories, outlining the emerging landscape of correlated matter-circuit science. We review and unify the capabilities of superconducting quantum hardware across condensed matter, high energy and quantum information sciences. We trace the technical evolution of these architectures, illustrating how their foundational development has culminated in a toolkit for resolving the complexities of macroscopic quantum states.

Arora, Arpit [UCLA, Los Angeles (main); UCLA; Haim↗

Region-Specific Merchant Hydrogen Market Assessment and Techno-Economic Assessment of Electrolytic Hydrogen Generation: Cooperative Research and Development Final Report, CRADA Number CRD-18-00751

Utilities need to recover value from baseload and some renewable assets even when the electricity is curtailed. The declining cost of renewables (particularly solar), the persistently low-cost of natural gas, and the declining electricity demand, have all worked to lower the price of electricity. Furthermore, the baseload assets have a high turndown cost, which is not reflected in the low market electricity prices. One option for utilizing the curtailed electricity is hydrogen generation. One important aspect of this project will be to provide a “go/no-go” recommendation on the economic feasibility of pursuing hydrogen generation vs. other markets that could offtake curtailed electricity or nuclear steam. This project will specifically assess the opportunities for hydrogen production and use in the service territories of Southern Company Services (SCS), Exelon SBC, and Xcel Energy. Each utility partner represents a different mix of generation fleets: Exelon has significant nuclear assets, Xcel is primarily renewables (wind) with some nuclear, and SCS represents both a renewables fleet and a heavily baseload fleet, which includes significant nuclear. The Contractors will conduct the study of hydrogen market opportunities by first considering the approximate electricity demand and price profiles for the year, and power generation capacity that can be used to produce hydrogen. Therefore, a profile for hydrogen generation will also be developed to better understand the quantity and timing of hydrogen production. Once the hydrogen production schedule is estimated, hydrogen storage requirements can be determined. This effort will provide sufficient information to make a go/no-go decision on moving ahead with a detailed regional case study for hydrogen production in any of the three utility areas.

08 HYDROGEN↗

4D Printing of Stretchable Supercapacitors via Hybrid Composite Materials

Stretchable supercapacitors (SCs) have attracted significant attention in developing power-independent stretchable electronic systems due to their intrinsic energy storage function and unique mechanical properties. Most current SCs are generally limited by their low stretchability, complicated fabrication process, and insufficient performance and robustness. This study presents a facile method to fabricate arbitrary-shaped stretchable electrodes via 4D printing of conductive composite from reduced graphene oxide, carbon nanotube, and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate. The electrode patterns of an arbitrary shape can be deposited onto prestretched substrates by aerosol-jet printing, then self-organized origami (ridge) patterns are generated after releasing the substrates from holding stretchers due to the mismatched strains. The stretchable electrodes demonstrate superior mechanical robustness and stretchability without sacrificing its outstanding electrochemical performance. The symmetric SC prototype possesses a gravimetric capacitance of ≈21.7 F g -1 at a current density of 0.5 A g -1 and a capacitance retention of ≈85.8% from 0.5 to 5 A g -1 . A SC array with arbitrary-shaped electrodes is also fabricated and connected in series to power light-emitting diode patterns for large-scale applications. Finally, the proposed method paves avenues for scalable manufacturing of future energy-storage devices with controlled extensibility and high electrochemical performance.

36 MATERIALS SCIENCE↗

ADAM: A web platform for graph-based modeling and optimization of supply chains

Modeling and optimization are essential tasks that arise in the analysis and design of supply chains (SCs). SC models are essential for understanding emergent behavior such as transactions between participants, inherent value of products exchanged, as well as impact of externalities (e.g., policy and climate) and of constraints. Unfortunately, most users of SC models have limited expertise in mathematical optimization, and this hinders the adoption of advanced decision-making tools. Here, in this work, we present ADAM, a web platform that enables the modeling and optimization of SCs. ADAM facilitates modeling by leveraging intuitive and compact graph-based abstractions that allow the user to express dependencies between locations, products, and participants. ADAM model objects serve as repositories of experimental, technology, and socio-economic data; moreover, the graph abstractions facilitate the organization and exchange of models and provides a natural framework for education and outreach. Here, we discuss the graph abstractions and software design principles behind ADAM, its key functional features and workflows, and application examples.

97 MATHEMATICS AND COMPUTING↗

Inhibition of enzyme hydrolysis of cellulose by phenols from hydrothermally pretreated sugarcane straw

Relatively few studies have addressed the characterization of sugarcane straw (SCS) for production of fermentable sugars through enzyme hydrolysis. Straw is a major co-product of the sugarcane harvest in Brazil that has potential to sustainably increase cellulosic feedstocks in Brazil by 50%. Pretreatment of 10% w/v straw with liquid hot water (LHW) at 180°C for 50 min (severity, S of 4.05), solubilizes hemicellulose, preserves glucan, and generates 4.49 g/L soluble phenolic compounds in the resulting liquid. Extracts from washing pretreated solids with excess hot water followed by acetone resulted in 1.10 and 0.83 g/L phenolics, respectively. Here, acetone-derived extracts were more inhibitory and decreased glucose yield for enzyme hydrolysis of Solka Floc (a lignin-free cellulose) by 42%. In comparison, pretreated straw washed with hot water or acetone was readily hydrolyzed to 92% and 97% by cellulase enzyme. Hydrothermally treated SCS has the potential to provide a valuable and added source of fermentable sugars suitable for bioprocessing into biofuels and bioproducts when cellulase enzyme inhibitors are removed after pretreatment.

Deactivation↗