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At least 127 records · Page 7

Evaluation of Bosch-Based Systems Using Non-Traditional Catalysts at Reduced Temperatures

Oxygen and water resupply make open loop atmosphere revitalization (AR) systems unfavorable for long-term missions beyond low Earth orbit. Crucial to closing the AR loop are carbon dioxide reduction systems with low mass and volume, minimal power requirements, and minimal consumables. For this purpose, NASA is exploring using Bosch-based systems. The Bosch process is favorable over state-of-the-art Sabatier-based processes due to complete loop closure. However, traditional operation of the Bosch required high reaction temperatures, high recycle rates, and significant consumables in the form of catalyst resupply due to carbon fouling. A number of configurations have been proposed for next-generation Bosch systems. First, alternative catalysts (catalysts other than steel wool) can be used in a traditional single-stage Bosch reactor to improve reaction kinetics and increase carbon packing density. Second, the Bosch reactor may be split into separate stages wherein the first reactor stage is dedicated to carbon monoxide and water formation via the reverse water-gas shift reaction and the second reactor stage is dedicated to carbon formation. A series system will enable maximum efficiency of both steps of the Bosch reaction, resulting in optimized operation and maximum carbon formation rate. This paper details the results of testing of both single-stage and two-stage Bosch systems with alternative catalysts at reduced temperatures. These results are compared to a traditional Bosch system operated with a steel wool catalyst.

Abney, Morgan B.↗

Space shuttle abort separation pressure investigation. Volume 1, Part A: Booster data at Mach 5

Pressure data obtained from a joint Langley Research Center (LaRC)/Marshall Space Flight Center (MSFC) Space Shuttle about stage separation wind tunnel test are presented. The .00556 scale models of the McDonnell-Douglas orbiter and booster configurations were tested in proximity in Tunnel A of the Von Karman Facility (VKF), Arnold Engineering Development Center (AEDC). Mach numbers were 5.0, 3.0, and 2.0 and nominal Reynolds numbers were 1.09, 1.60, and 1.74 million per foot, respectively. Pressure data were obtained for the booster upper surface and orbiter lower surface at angles of attack of -10 deg, -5, 0, 5, and 10 deg for zero degrees sideslip. The models were tested at incidence angles of 0 and 5 deg for several separation distances and power conditions. Plug nozzles utilizing air were used to simulate booster and orbiter plumes at various altitudes along a nominal ascent trajectory. Powered conditions were 100, 50, and 0 percent of full power for the orbiter and 100, 50 and 0 percent of full power for the booster. Data were also obtained with the booster canard off in close proximity.

Trimmer, L. L.↗

Greatly Increasing Trapped Ion Populations for Mobility Separations Using Traveling Waves in Structures for Lossless Ion Manipulations

The initial use of traveling waves (TW) for ion mobility (IM) separations using a structures for lossless ion manipulations (SLIM) employed an ion funnel trap (IFT) to accumulate ions from a continuous electrospray ionization source, and limited to injected ion populations of ~106 charges due to the onset of space charge effects in the trapping region. Additional limitations arise due to the loss of resolution for the injection of ions over longer periods (e.g. in extended pulses). In this work a new SLIM ‘flat funnel’ (FF) module has been developed and demonstrated to enable the accumulation of much larger ion populations and their injection for IM separations. Ion current measurements indicate a capacity of ~3.2×108 charges for the extended trapping volume, over an order of magnitude greater than the IFT. The orthogonal ion injection into a funnel shaped separation region can greatly reduce space charge effects during the initial IM separation stage, and the gradually reduced width of the path allows the ion packet to be increasingly compressed in the lateral dimension as the separation progresses, allowing e.g. efficient transmission through conductance limits or compatibility with subsequent ion manipulations. This work examined the TW, RF, and DC confining field SLIM parameters involved in ion accumulation, injection, transmission and separation in the FF IM module using both direct ion current and MS measurements. Wide m/z range ion transmission is demonstrated, along with significant increases in signal to noise (S/N) ratios due to the larger ion populations injected. Additionally, we observed a reduction in the chemical background, which was attributed to more efficient desolvation of solvent related clusters over the extended ion accumulation periods. The TW SLIM FF IM module is anticipated to be especially effective as a front end for long path SLIM IM separation modules.

Environmental Molecular Sciences Laboratory↗

High performance techniques for micro channel plate computations in photo multipliers

Monte Carlo - MC methods, requiring heavy computations of large data volume, can be used to predict the amplitude distribution and variance of outputted electron charge in Micro Channel Plates - MCPs, which are fed with primary emitted electrons in their inputs. The concept of parallel and serial combination of separate stages of such stochastic processes, which can be applied in MCP systems and simulated using MC computations, has recently proposed and shown interesting theorems and results. Separating the electron multiplication procedures, occurring in the channels of MCP systems, into sub-procedures, which are similar in nature and occur either in parallel or in consecutive manners, is equivalent to splitting the relevant stochastic system calculations into smaller ones, which can be performed concurrently and/or sequentially. In this way, calculations similar in nature, can be executed only once, thus, eliminating a great percentage of heavy computations. However, when designing and implementing the calculation inferences of the derived theorems using High Performance Computation - HPC techniques, the overall computation cost can further and significantly be reduced. In this paper, the hardware mappings of the relevant theorem inferences onto parallel computing architectures, resulting in circuits of computing blocks for calculation purposes of MCP system stochastic processes, are investigated. Each of the designed and implemented computing circuits corresponds to a theorem inference or to a combination of inferences. The parallelism of the proposed circuits consists of both the concurrent functioning of all the system blocks and of the simultaneous operation of each block, which is processing pieces of data, for many parts of the whole circuit in which it belongs. All the circuits are designed and tested using Altera Quartus II environment and can be implemented as chips, which can be incorporated in computing devices to assist Monte Carlo computations for the estimation of different MCP electron multiplication system performances.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Technoeconomic Analysis of the Electrochemically Mediated Amine Regeneration CO 2 Capture Process

The electrochemically mediated amine regeneration (EMAR) process presents an alternative route to the conventional thermal amine regeneration for carbon capture from a flue gas source. In this study, we conducted an economic analysis on the EMAR system for postcombustion CO2 capture from a 550 MWe power plant capturing 3.1 MtCO2 annually and from a mini steel mill with annual capture close to 170 ktCO2. We followed the recommendation of the National Energy Technology Laboratory (NETL) 2010 report to estimate the cost of CO2 avoided ([$/tCO2]). Detailed cost modeling of the electrochemical separation stage was conducted. This is integrated with the entire process flowsheet (e.g., including absorber, compressor, pumps, and other auxiliary equipment). Here, we identified the membrane cost as the dominant capital cost for the electrochemical separation train. At a membrane unit price of less than 10/m2, the CO2 capture cost can be reduced to below 50/tCO2 with optimized process conditions (e.g., desorption pressure and utilization of waste heat). Improvements in process design, cell construction, and solvent formulation may lead to additional reductions in the CO2 capture cost.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Understanding the performance of membrane for direct air capture of CO 2

Abstract Direct air capture (DAC) of CO 2 is becoming increasingly important for reducing greenhouse gas concentrations in the atmosphere. However, the cost and energy requirements associated with DAC make it less economically feasible than carbon capture from flue gases. While various methods like solid sorbents and gas–liquid absorption have been explored for DAC, membrane processes have only recently been investigated. The objective of this study is to examine the separation performance of a membrane unit for capturing CO 2 from ambient air. The performance of a membrane depends on several factors, including the composition of the feed gas, pressure ratio, material selectivity, and membrane area. The single‐stage separation process with the co‐current flow and constant permeability flux model is evaluated using a commercial module integrated with a process simulator to separate a binary mixture of carbon dioxide and nitrogen to assess the sensitivity of selectivity on purity and recovery of CO 2 in permeate, and power requirement. Additionally, three levels of CO 2 reduction from the feed stream to the retentate stream (25%, 50%, and 75%) are studied. A trade‐off between purity and recovery factor is observed, and achieving high purity in permeate requires high concentration in the retentate.

Panja, Palash↗

Sequential separation of battery electrode materials and metal foils in aqueous media

To recycle high-value lithium-ion battery components, it is imperative to efficiently separate electrode materials from current collector foils and to separate cathodes from anodes. This study investigates the delamination behaviors of cathodes and anodes from their respective current collectors in aqueous media. Whereas anode films can easily detach from copper foils in water, the delamination of cathode films does not exhibit the same behavior in water; instead, the cation exchange reaction results in lithium leaching and aluminum corrosion in the presence of water. Here, a buffer solution with surfactant additives has been designed to prevent aluminum corrosion and to improve solution wetting behavior, thereby facilitating cathode delamination. The delamination difference enables the sequential recovery of electrode materials and metal foils at different separation stages, simplifying the traditionally intricate processes within a one-pot recovery system. The recovered materials retain their crystal structure and morphology, and there are no signs of aluminum corrosion or residues on the metal foils. The sequential separation technique achieves nearly 100% separation efficiency for electrode materials from metal foils and over 98% separation efficiency for cathode and anode materials.

25 ENERGY STORAGE↗

Demonstration of a Pyrotechnic Bolt-Retractor System

A paper describes a demonstration of the X-38 bolt-retractor system (BRS) on a spacecraft-simulating apparatus, called the Large Mobility Base, in NASA's Flight Robotics Laboratory (FRL). The BRS design was proven safe by testing in NASA's Pyrotechnic Shock Facility (PSF) before being demonstrated in the FRL. The paper describes the BRS, FRL, PSF, and interface hardware. Information on the bolt-retraction time and spacecraft-simulator acceleration, and an analysis of forces, are presented. The purpose of the demonstration was to show the capability of the FRL for testing of the use of pyrotechnics to separate stages of a spacecraft. Although a formal test was not performed because of schedule and budget constraints, the data in the report show that the BRS is a successful design concept and the FRL is suitable for future separation tests.

Johnston, Nick↗

Simulation and Analyses of Staging Maneuvers of Next Generation Reusable Launch Vehicles

NASA has initiated a comprehensive stage separation tool development activity to address the technology needed for successful development and operation of next generation reusable launch vehicles. As a part of this activity, ConSep simulation tool is being developed. This paper discusses the application of this tool to the staging maneuvers of two-stage-to-orbit (TSTO) vehicles. Simulation and analyses are performed for two bimese TSTO concepts, one staging at Mach 3 and the other at Mach 6. The TSTO bimese vehicles used in this study are sized for international space station class payload. The proximity and isolated aerodynamic databases used in the simulation were generated using the data from wind tunnel tests conducted at NASA Langley Research Center. ConSep is a MATLAB-based front end to the commercially available ADAMS solver, an industry standard package for solving multi-body dynamic problems.

Pamadi, Bandu N.↗

Ares I-X: First Step in a New Era of Exploration

Since 2005, NASA's Constellation Program has been designing, building, and testing the next generation of launch and space vehicles to carry humans beyond low-Earth orbit (LEO). On October 28, 2009, the Ares Projects successfully launched the first suborbital development flight test of the Ares I crew launch vehicle, Ares I-X, from Kennedy Space Center (KSC). Although the final Constellation Program architecture is under review, data and lessons obtained from Ares I-X can be applied to any launch vehicle. This presentation will discuss the mission background and future impacts of the flight. Ares I is designed to carry up to four astronauts to the International Space Station (ISS). It also can be used with the Ares V cargo launch vehicle for a variety of missions beyond LEO. The Ares I-X development flight test was conceived in 2006 to acquire early engineering, operations, and environment data during liftoff, ascent, and first stage recovery. Engineers are using the test flight data to improve the Ares I design before its critical design review the final review before manufacturing of the flight vehicle begins. The Ares I-X flight test vehicle incorporated a mix of flight and mockup hardware, reflecting a similar length and mass to the operational vehicle. It was powered by a four-segment SRB from the Space Shuttle inventory, and was modified to include a fifth, spacer segment that made the booster approximately the same size as the five-segment SRB. The Ares I-X flight closely approximated flight conditions the Ares I will experience through Mach 4.5, performing a first stage separation at an altitude of 125,000 feet and reaching a maximum dynamic pressure ("Max Q") of approximately 850 pounds per square foot. The Ares I-X Mission Management Office (MMO) was organized functionally to address all the major test elements, including: first stage, avionics, and roll control (Marshall Space Flight Center); upper stage simulator (Glenn Research Center); crew module/launch abort system simulator (Langley Research Center); and ground systems and operations (KSC). Interfaces between vehicle elements and vehicle-ground elements, as well as environment analyses were performed by a systems engineering and integration team at Langley. Experience and lessons learned from these integrated product teams area are already being integrated into the Ares Projects to support the next generation of exploration launch vehicles.

Davis, Stephan R.↗

Multitemperature Cryogenic Radiative Cooler

Multiple radiator stages separated by V-groove shields protect main cooler from parasitic heat radiation and offer usable cooling themselves. Proposed cryogenic radiative cooler achieves lower temperatures previously possible with passive radiators in space. Provides useful cooling power at several temperatures instead of one. Cold-radiator stage protected by multiple shield assemblies intercepting radiation heat leaks from warmer supporting structure and redirects it out to space. Each shield assembly has effective cooling capacity enabling it to cool optical filter.

Bard, Steven↗

Flight and Integrated Vehicle Testing: Laying the Groundwork for the Next Generation of Space Exploration Launch Vehicles

Integrated vehicle testing will be critical to ensuring proper vehicle integration of the Ares I crew launch vehicle and Ares V cargo launch vehicle. The Ares Projects, based at Marshall Space Flight Center in Alabama, created the Flight and Integrated Test Office (FITO) as a separate team to ensure that testing is an integral part of the vehicle development process. As its name indicates, FITO is responsible for managing flight testing for the Ares vehicles. FITO personnel are well on the way toward assembling and flying the first flight test vehicle of Ares I, th Ares I-X. This suborbital development flight will evaluate the performance of Ares I from liftoff to first stage separation, testing flight control algorithms, vehicle roll control, separation and recovery systems, and ground operations. Ares I-X is now scheduled to fly in summer 2009. The follow-on flight, Ares I-Y, will test a full five-segment first stage booster and will include cryogenic propellants in the upper stage, an upper stage engine simulator, and an active launch abort system. The following flight, Orion 1, will be the first flight of an active upper stage and upper stage engine, as well as the first uncrewed flight of an Orion spacecraft into orbit. The Ares Projects are using an incremental buildup of flight capabilities prior to the first operational crewed flight of Ares I and the Orion crew exploration vehicle in 2015. In addition to flight testing, the FITO team will be responsible for conducting hardware, software, and ground vibration tests of the integrated launch vehicle. These efforts will include verifying hardware, software, and grou handling interfaces. Through flight and integrated testing, the Ares Projects will identify and mitigate risks early the United States prepares to take its next giant leaps to the Moon and beyond.

Taylor, Jim↗

Flight and Integrated Vehicle Testing: Laying the Groundwork for the Next Generation of Space Exploration Launch Vehicles

Integrated vehicle testing will be critical to ensuring proper vehicle integration of the Ares I crew launch vehicle and Ares V cargo launch vehicle. The Ares Projects, based at Marshall Space Flight Center in Alabama, created the Flight and Integrated Test Office (FITO) as a separate team to ensure that testing is an integral part of the vehicle development process. As its name indicates, FITO is responsible for managing flight testing for the Ares vehicles. FITO personnel are well on the way toward assembling and flying the first flight test vehicle of Ares I, the Ares I-X. This suborbital development flight will evaluate the performance of Ares I from liftoff to first stage separation, testing flight control algorithms, vehicle roll control, separation and recovery systems, and ground operations. Ares I-X is now scheduled to fly in summer 2009. The follow-on flight, Ares I-Y, will test a full five-segment first stage booster and will include cryogenic propellants in the upper stage, an upper stage engine simulator, and an active launch abort system. The following flight, Orion 1, will be the first flight of an active upper stage and upper stage engine, as well as the first uncrewed flight of an Orion spacecraft into orbit. The Ares Projects are using an incremental buildup of flight capabilities prior to the first operational crewed flight of Ares I and the Orion crew exploration vehicle in 2015. In addition to flight testing, the FITO team will be responsible for conducting hardware, software, and ground vibration tests of the integrated launch vehicle. These efforts will include verifying hardware, software, and ground handling interfaces. Through flight and integrated testing, the Ares Projects will identify and mitigate risks early as the United States prepares to take its next giant leaps to the Moon and beyond.

Taylor, J. L.↗

Sticking-Free Reduction of Titanomagnetite Ironsand in a Fluidized Bed Reactor

Fluidized bed reduction of iron ore fines is typically inhibited by the onset of “sticking” at temperatures above 973 K, which leads to particle agglomeration and defluidization of the bed. Here, we report the sticking-free fluidized bed reduction of titanomagnetite (TTM) ironsand at 1223 K in Ar-H{sub 2} gas mixtures. We show that sticking is prevented by the formation of a protective titanium-rich oxide shell around each particle during the initial reduction stage. This protective shell prevents iron-iron contact between particles throughout the reduction process, enabling metallization degrees of 93 pct to be attained without sticking occurring. Phase evolution during the reaction has also been analyzed using q-X-ray diffraction and scanning electron microscope/energy dispersed spectroscopy. We find that the reduction proceeds through four separate stages. During the initial stage, approximately half of the initial TTM phase is converted to wüstite, forming a network of sub-micron wüstite channels which interlace the TTM matrix. During this stage, Ti and Al are enriched within the TTM matrix, due to the low solubility of both species in wüstite. This enrichment stabilizes the remaining TTM, meaning that wüstite is then preferentially reduced to metallic iron in stage 2 of the reduction. In stage 3, the remaining Ti-enriched TTM is reduced directly to metallic iron and ilmenite. The final stage of reduction involves the conversion of ilmenite into rutile and pseudobrookite. Our findings clarify the important role played by titanium species during the reduction of TTM and suggest that New Zealand ironsand can offer significant advantages over conventional hematite ores when used as a feedstock for fluidized bed direct-reduced iron processes.

36 MATERIALS SCIENCE↗

A provisional regulatory gene network for specification of endomesoderm in the sea urchin embryo

We present the current form of a provisional DNA sequence-based regulatory gene network that explains in outline how endomesodermal specification in the sea urchin embryo is controlled. The model of the network is in a continuous process of revision and growth as new genes are added and new experimental results become available; see http://www.its.caltech.edu/~mirsky/endomeso.htm (End-mes Gene Network Update) for the latest version. The network contains over 40 genes at present, many newly uncovered in the course of this work, and most encoding DNA-binding transcriptional regulatory factors. The architecture of the network was approached initially by construction of a logic model that integrated the extensive experimental evidence now available on endomesoderm specification. The internal linkages between genes in the network have been determined functionally, by measurement of the effects of regulatory perturbations on the expression of all relevant genes in the network. Five kinds of perturbation have been applied: (1) use of morpholino antisense oligonucleotides targeted to many of the key regulatory genes in the network; (2) transformation of other regulatory factors into dominant repressors by construction of Engrailed repressor domain fusions; (3) ectopic expression of given regulatory factors, from genetic expression constructs and from injected mRNAs; (4) blockade of the beta-catenin/Tcf pathway by introduction of mRNA encoding the intracellular domain of cadherin; and (5) blockade of the Notch signaling pathway by introduction of mRNA encoding the extracellular domain of the Notch receptor. The network model predicts the cis-regulatory inputs that link each gene into the network. Therefore, its architecture is testable by cis-regulatory analysis. Strongylocentrotus purpuratus and Lytechinus variegatus genomic BAC recombinants that include a large number of the genes in the network have been sequenced and annotated. Tests of the cis-regulatory predictions of the model are greatly facilitated by interspecific computational sequence comparison, which affords a rapid identification of likely cis-regulatory elements in advance of experimental analysis. The network specifies genomically encoded regulatory processes between early cleavage and gastrula stages. These control the specification of the micromere lineage and of the initial veg(2) endomesodermal domain; the blastula-stage separation of the central veg(2) mesodermal domain (i.e., the secondary mesenchyme progenitor field) from the peripheral veg(2) endodermal domain; the stabilization of specification state within these domains; and activation of some downstream differentiation genes. Each of the temporal-spatial phases of specification is represented in a subelement of the network model, that treats regulatory events within the relevant embryonic nuclei at particular stages. (c) 2002 Elsevier Science (USA).

Non-NASA Center↗

A superstructure-based framework for bio-separation network synthesis

Modern biotechnologies enable the production of chemicals using engineered microorganisms. However, the cost of downstream recovery and purification steps is high, which means that the feasibility of bio-based chemicals production depends heavily on the synthesis of cost-effective separation networks. To this end, we develop a superstructure-based framework for bio-separation network synthesis. Based on general separation principles and insights obtained from industrial processes for specific products, we first identify four separation stages: cell treatment, product phase isolation, concentration and purification, and refinement. For each stage, we systematically implement a set of connectivity rules to develop stage-superstructures, all of which are then integrated to generate a general superstructure that accounts for all types of chemicals that can be produced using microorganisms. Here we further develop a superstructure reduction method to solve specific instances, based on product attributes, technology availability, case-specific considerations, and final product stream specifications. A general optimization model, including short-cut models for all technologies, is formulated. The proposed framework enables preliminary synthesis and analysis of bio-separation networks, and thus estimation of separation costs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Interdependence in active mobility adoption: Joint modeling and motivational spillover in walking, cycling and bike-sharing

Active mobility offers an array of physical, emotional, and social well-being benefits. However, with the proliferation of the sharing economy, new nonmotorized means of transport are entering the fold, complementing some existing mobility options while competing with others. The purpose of this research study is to investigate the adoption of three active travel modes—namely walking, cycling, and bikesharing—in a joint modeling framework. Here, the analysis is based on an adaptation of the stages of change framework, which originates from the health behavior sciences. Multivariate ordered probit modeling drawing on U.S. survey data provides well-needed insights into individuals’ preparedness to adopt multiple active modes as a function of personal, neighborhood, and psychosocial factors. The research suggests three important findings. (1) The joint model structure confirms interdependence among different active mobility choices. The strongest complementarity is found for walking and cycling adoption. (2) Each mode has a distinctive adoption path with either three or four separate stages. We discuss the implications of derived stage-thresholds and plot adoption contours for selected scenarios. (3) Psychological and neighborhood variables generate more coupling among active modes than individual and household factors. Specifically, identifying strongly with active mobility aspirations, experiences with multimodal travel, possessing better navigational skills, along with supportive local community norms are the factors that appear to drive the joint adoption decisions. This study contributes to the understanding of how decisions within the same functional domain are related and help to design policies that promote active mobility by identifying positive spillovers and joint determinants.

42 ENGINEERING↗

Artemis Innovative Assembly and Integration Operations of the Launch Abort Systemat KSC

This paper describes the Artemis program assembly and integration approach that enables affordable and low risk processing operations for the Launch Abort System at KSC. NASA is currently developing the Artemis 1 spacecraft to meet the test objectives of an uncrewed orbital mission to the moon and return to earth in 2021. The Artemis Orion spacecraft consists of a Crew Module (CM), a Service Module (SM), and a Launch Abort System (LAS) to safely transport a crew of 4 to the moon and return to earth. The LAS enables the CM to have an abort capability for the crew during the launch phase of the mission from the launch pad throughout the ascent phase. The LAS includes motor elements for abort, attitude control, and stage separation is assembled at the Launch Abort System Facility (LASF) adjacent to the CM/SM (CSM) assembly operations in the Neil Armstrong Operations and Checkout Building (O&C) at KSC. The LAS integration to the CSM is completed in the LASF and the completed Artemis spacecraft is integrated to the Space Launch System (SLS) in the Vehicle Assembly Building (VAB) at KSC. A significant LAS development flight test milestone was recently completed in 2019 for the Ascent Abort (AA-2) flight test at Cape Canaveral Air Force Station where a high-altitude abort test was successfully achieved using a Peacekeeper booster stage exercising all of the LAS systems including propulsion, avionics, and pyrotechnics demonstrating he LAS readiness for crewed flight. The first operational flight of the LAS will be for the Artemis 2 mission which is the first crewed mission for the Orion program planned in 2023.

William J Koenig↗