Ka-Band ARM Zenith RADAR (KAZR): moderate sensitivity mode, spectrally-decomposed
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radar↗
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Results for “SPECTRAL BANDS”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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A New Method for Deriving Composition of S-type Asteroids from Noisy and Incomplete Near-infrared Spectra
The surface composition of S-type asteroids can be determined using band parameters extracted from their near-infrared (NIR) spectra (0.7–2.50 μm) along with spectral calibrations derived from laboratory samples. In the past, these empirical equations have been obtained by combining NIR spectra of meteorite samples with information about their composition and mineral abundance. For these equations to give accurate results, the characteristics of the laboratory spectra they are derived from should be similar to those of asteroid spectral data (i.e., similar signal-to-noise ratio (S/N) and wavelength range). Here we present new spectral calibrations that can be used to determine the mineral composition of ordinary chondrite-like S-type asteroids. Contrary to previous work, the S/N of the ordinary chondrite spectra used in this study has been decreased to recreate the S/N typically observed among asteroid spectra, allowing us to obtain more realistic results. In addition, the new equations have been derived for five wavelength ranges encompassed between 0.7 and 2.50 μm, making it possible to determine the composition of asteroids with incomplete data. The new spectral calibrations were tested using band parameters measured from the NIR spectrum of asteroid (25143) Itokawa, and comparing the results with laboratory measurements of the returned samples. We found that the spectrally derived olivine and pyroxene chemistry, which are given by the molar contents of fayalite (Fa) and ferrosilite (Fs), are in excellent agreement with the mean values measured from the samples (Fa{sub 28.6±1.1} and Fs{sub 23.1±2.2}), with a maximum difference of 0.6 mol% for Fa and 1.4 mol% for Fs.
79 ASTRONOMY AND ASTROPHYSICS↗
Earth as an Exoplanet. I. Time Variable Thermal Emission Using Spatially Resolved Moderate Imaging Spectroradiometer Data
Among the more than 4000 exoplanets known today, some terrestrial planets have been detected in the so-called habitable zone of their host stars and their number is expected to increase in the near future, energizing a drive to understand and interpret the eagerly awaited wealth of data to identify signs of life beyond our solar system. So far, Earth remains the best and only example of a habitable (and inhabited) world. Although, it seems extremely unlikely that any other exoplanets will be true Earth twins, it is important to explore and understand the full range of spectral signatures and variability of Earth in order to inform the design of future instruments and missions, and understand their diagnostic power as well as potential limitations. In this work we use Earth observation data collected by the MODIS instrument aboard the Aqua satellite. The complete data set comprises 15 years of thermal emission observations in the 3.66–14.40 μm range for five different locations on Earth (Amazon Rainforest, Antarctica, Arctic, Indian Ocean, and the Sahara Desert). We then determine flux levels and variations as a function of wavelength and surface type (i.e., climate zone and surface thermal properties) and investigate whether periodic signals indicating Earth’s tilted rotation axis can be detected. Our findings suggest that (1) viewing geometry plays an important role when thermal emission data is analyzed as Earth’s spectrum varies by a factor of three and more depending on the dominant surface type underneath; (2) typically strong absorption bands from CO 2 (15 μm) and O 3 (9.65 μm) are significantly less pronounced and partially absent in data from the polar regions implying that estimating correct abundance levels for these molecules might be challenging in these cases; and (3) the time-resolved thermal emission spectrum encodes information about seasons/planetary obliquity, but the significance depends on the viewing geometry and spectral band considered.
79 ASTRONOMY AND ASTROPHYSICS↗
Spectrally separable photon-pair generation in dispersion engineered thin-film lithium niobate
Existing nonlinear-optic implementations of pure, unfiltered heralded single-photon sources do not offer the scalability required for densely integrated quantum networks. Additionally, lithium niobate has hitherto been unsuitable for such use due to its material dispersion. We engineer the dispersion and the quasi-phasematching conditions of a waveguide in the rapidly emerging thin-film lithium niobate platform to generate spectrally separable photon pairs in the telecommunications band. Such photon pairs can be used as spectrally pure heralded single-photon sources in quantum networks. We estimate a heralded-state spectral purity of >94% based on joint spectral intensity measurements. Further, a joint spectral phase-sensitive measurement of the unheralded time-integrated second-order correlation function yields a heralded-state purity of (86 ± 5)%.
36 MATERIALS SCIENCE↗
W-Band ARM Scanning Cloud Radar (WSACR) 2nd Generation CF-Radial Spectral Data, Vertically-Pointing Scan, Cross Mode (a1)
ARM's scanning cloud radars are fully coherent dual-frequency, dual-polarization Doppler radars mounted on a common scanning pedestal. Each pedestal includes a Ka-band radar (2kW peak power) and the deployment location determines whether the second radar is a W-band (WSACR; 1.7 kW peak power) or X-band (XSACR; 20 kW peak power). Beamwidths at Ka and W bands are roughly matched at 0.3 degrees. Due to the narrow antenna beamwidth, ARM’s scanning cloud radars use scanning strategies that are unlike typical weather radars. Rather than focusing on plan position indicator, or PPI, scans, the Ka-SACR uses range height indicator, or RHI, scans at numerous azimuths to obtain cloud volume data. Measurements collected with the W-SACR are copolar and cross-polar radar reflectivity, Doppler velocity, spectra width and spectra when not scanning, and linear depolarization ration.
54 ENVIRONMENTAL SCIENCES↗
Spin-orbit-proximitized ferromagnetic metal by monolayer transition metal dichalcogenide: Atlas of spectral functions, spin textures, and spin-orbit torques in Co/MoSe 2 , Co/WSe 2 and Co/TaSe 2 heterostructures
In this work, the heterostructures composed of an ultrathin ferromagnetic metal (FM) and a material hosting strong spin-orbit (SO) coupling are the principal resource for SO torque and spin-to-charge conversion nonequilibrium effects in spintronics. The key quantity in theoretical description of these effects is nonequilibrium spin density, which can appear on any monolayer of the heterostructure through which the current is flowing as long as the monolayer bands are affected by the native or proximity induced SO coupling. Here we demonstrate how hybridization of wave functions of Co layer and a monolayer of transition metal dichalcogenides (TMDs)—such as semiconducting MoSe 2 and WSe 2 or metallic TaSe 2 —can lead to dramatic transmutation of electronic and spin structure of Co within some distance away from its interface with TMD, when compared to the bulk of Co or its surface in contact with a vacuum. This is due to proximity induced SO splitting of Co bands encoded in the spectral functions and spin textures on its monolayers, which we obtain using noncollinear density functional theory (ncDFT) combined with equilibrium Green function (GF) calculations. In fact, SO splitting is present due to structural inversion asymmetry of the bilayer—i.e., just the presence of the interface—even if SO coupling within TMD monolayer is artificially switched off in ncDFT calculations. However, switching it on makes the effects associated with proximity SO coupling within Co layer about five times larger. Injecting spin-unpolarized charge current through SO-proximitized monolayers of Co generates nonequilibrium spin density over them, so that its cross product with the magnetization of Co determines SO torque. The SO torque computed via first-principles quantum transport methodology, which combines ncDFT with nonequilibrium GF calculations, can be used as the screening parameter to identify optimal combination of materials and their interfaces for applications in spintronics. In particular, we identify heterostructure two-monolayer-Co/monolayer-WSe 2 as the most optimal one, at least in the clean limit.
2-dimensional systems↗
Source Characterization of the Declared North Korean Nuclear Tests From Regional Distance Coda Wave Spectral Ratios
Abstract Seismic observations of underground nuclear explosions provide crucial data on source yield and depth that cannot easily be estimated from other geophysical methods. However, it is difficult to obtain reliable yield estimates for test sites for which we do not have direct seismic calibration experiments. To obtain source information from uncalibrated sites and paths, local and regional seismic records of six, proximal, declared underground nuclear explosions in North Korea are used to compute spectral ratios of narrow‐band waveform envelopes of body‐wave coda that remove path and site effects to reveal precise, relative source moment. The yields of these explosions are obtained from the observed source ratios by simultaneously fitting the classical source model of Mueller and Murphy (1971), https://doi.org/10.1785/bssa0610061675 to all event pairs. The source model provides an impressive fit to the observations considering that the P phase coda derived source spectral ratios did not require a prior knowledge of the source or regionally calibrated corrections to be applied to the data. However, the observed corner frequencies from S wave coda spectral ratios are lower than the source model predictions, but are well fit by models calculated using the corner frequency consistent with the Fisk conjecture. The results presented here provide novel constraints on the spectral distributions of the energy radiated by the sources of the DPRK test series, and allows for an independent evaluation of existing estimated source model parameters.
58 GEOSCIENCES↗
W-Band ARM Scanning Cloud Radar (WSACR) 2nd Generation CF-Radial Spectral Data, Vertically-Pointing Scan, Co-Polarization Mode (a1)
ARM's scanning cloud radars are fully coherent dual-frequency, dual-polarization Doppler radars mounted on a common scanning pedestal. Each pedestal includes a Ka-band radar (2kW peak power) and the deployment location determines whether the second radar is a W-band (WSACR; 1.7 kW peak power) or X-band (XSACR; 20 kW peak power). Beamwidths at Ka and W bands are roughly matched at 0.3 degrees. Due to the narrow antenna beamwidth, ARM’s scanning cloud radars use scanning strategies that are unlike typical weather radars. Rather than focusing on plan position indicator, or PPI, scans, the Ka-SACR uses range height indicator, or RHI, scans at numerous azimuths to obtain cloud volume data. Measurements collected with the W-SACR are copolar and cross-polar radar reflectivity, Doppler velocity, spectra width and spectra when not scanning, and linear depolarization ration.
54 ENVIRONMENTAL SCIENCES↗
W-Band ARM Scanning Cloud Radar (WSACR) 2nd Generation CF-Radial Spectral Data, Vertically-Pointing Scan, Cross-Polarization Model (a1)
ARM's scanning cloud radars are fully coherent dual-frequency, dual-polarization Doppler radars mounted on a common scanning pedestal. Each pedestal includes a Ka-band radar (2kW peak power) and the deployment location determines whether the second radar is a W-band (WSACR; 1.7 kW peak power) or X-band (XSACR; 20 kW peak power). Beamwidths at Ka and W bands are roughly matched at 0.3 degrees. Due to the narrow antenna beamwidth, ARM’s scanning cloud radars use scanning strategies that are unlike typical weather radars. Rather than focusing on plan position indicator, or PPI, scans, the Ka-SACR uses range height indicator, or RHI, scans at numerous azimuths to obtain cloud volume data. Measurements collected with the W-SACR are copolar and cross-polar radar reflectivity, Doppler velocity, spectra width and spectra when not scanning, and linear depolarization ration.
54 ENVIRONMENTAL SCIENCES↗
Electronic structure of van der Waals ferromagnet CrI 3 from self-consistent vertex corrected GW approaches
Electronic structure of the layered van der Waals ferromagnet CrI 3 is studied with self consistent diagrammatic approaches beyond the GW approximation. Considerable improvement in the calculated band gap as compared to the non-self-consistent G0W0 results has been found. Certain spectral features in the valence bands discovered recently by the angle resolved photoemission spectroscopy, are reproduced better when we use full frequency dependent self energy. Density functional theory and the quasiparticle self-consistent GW method which are based on the frequency-independent self energy are unable to resolve these features. The non-locality effects in the diagrams beyond the GW approximation are large for both polarizability and self energy. This finding can potentially have an impact on the development of methods like the GW+DMFT (dynamical mean field theory).
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Enhanced Coherence in Superconducting Circuits via Band Engineering
In superconducting circuits interrupted by Josephson junctions, the dependence of the energy spectrum on offset charges on different islands is 2e periodic through the Aharonov-Casher effect and resembles a crystal band structure that reflects the symmetries of the Josephson potential. We show that higher-harmonic Josephson elements described by a cos(2φ) energy-phase relation provide an increased freedom to tailor the shape of the Josephson potential and design spectra featuring multiplets of flat bands and Dirac points in the charge Brillouin zone. Flat bands provide noise-insensitive energy levels, and consequently, engineering band pairs with flat spectral gaps can help improve the coherence of the system. We discuss a modified version of a flux qubit that achieves, in principle, no decoherence from charge noise and introduce a flux qutrit that shows a spin-1 Dirac spectrum and is simultaneously quite robust to both charge and flux noise.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Spectrally-dependent positive and negative photo-plastic effects in CdZnTe and CdZnTeSe
We studied the Vickers microhardness HV0.025 of CdZnTe and CdZnTeSe samples upon illumination with quasi-monochromatic light with wavelengths ranging between 750 and 1540 nm. We observed that light with a wavelength close to or above the bandgap of the samples results in a positive photo-plastic effect (hardening), and light in the spectral range well below the band gap can lead both to positive or negative effects depending on the parameters of deep levels in the bandgap. We performed measurements of spectrally dependent photoconductivity and compared them with HV0.025. Based on the analysis, we propose a complex qualitative model explaining the spectral dependence of HV0.025 by the charging and neutralization of deep levels by optical transitions between the valence and conduction bands and between the bands and deep levels in the band gap. Tuning of parameters of deep levels could be used to control the sign and magnitude of the photo-plastic effect.
36 MATERIALS SCIENCE↗
Filtered Multi-Tone Spread Spectrum With Overlapping Subbands
A new form of the filter bank multi-carrier spread spectrum (FBMC-SS) waveform is presented. This new waveform modifies the filtered multi-tone spread spectrum (FMT-SS) system, and is intended to whiten the power spectral density (PSD) of the transmit signal. In the conventional FMT-SS, subcarrier bands are non-overlapping, leaving a spectral null between the adjacent subcarrier bands. To make FMT-SS more appealing for a broader set of applications than those studied in the past, we propose adding additional subcarriers centered at these nulls and thoroughly explore the impact of the added subcarriers on the system performance. This modified form of FMT-SS is referred to as overlapped FMT-SS (OFMT-SS). We explore the conditions required for maximally flattening the PSD of the synthesized OFMT-SS signal and for cancelling the interference caused by overlapping subbands. We also explore the choices of spreading gains that result in a low peak-to-average power ratio (PAPR) for a number of different scenarios. Further reduction of the PAPR of the synthesized signal through clipping methods is also explored. Additionally, we propose methods of multi-coding for increasing the data rate of the OFMT-SS waveform, while minimally impacting its PAPR.
42 - ENGINEERING↗
Controlling Interfacial Charge Separation Energetics and Kinetics
The overall goal is to probe electron transfer kinetics of the Marcus inverted region at interfaces. This project specifically uses a dye‐semiconductor interface with a reversible electron transfer reagent in solution where the semiconductor conduction band and electron transfer reagent ideally have a potential energy difference firmly within the Marcus inverted region. The goals of this project are: (Goal 1) Identify dye design elements that give dyes with low energy ground‐state oxidation potentials while retaining desirable electron transfer kinetics at the semiconductor interface. (Goal 2) Identify dye designs with excited‐state oxidation potentials set to fixed energies through molecular design while the dye ground‐state oxidation potentials are varied to allow for the evaluation of varied electron transfer reagents/redox shuttles (RS) with different free energies for electron transfer. (Goal 3) Within the context of the functionality identified in goals 1 and 2, goal 3 seeks to design dyes with features maximizing charge carrier lifetimes by minimizing recombination losses at metal oxide interfaces with high voltage systems. (Goal 4) Probe electron transfer kinetics in a high voltage‐dye sensitized solar cell with both the oxidized dye and RS firmly within the Marcus inverted region with regard to the TiO2 CB. (Goal 5) Identify tailored sensitizer/redox shuttle pairs with desirable electron transfer kinetics in defined spectral regions capable of “banding off” incident solar irradiation to give high voltage multijunction systems capable of exceeding the Shockley‐Queisser limit and powering catalytic processes.
14 SOLAR ENERGY↗
Design and simulation of multilayer coatings for a multi-channel Wolter-like x-ray imager with large field of view and high resolution
X-ray diagnostics are key instruments for understanding the physics behind inertial confinement fusion experiments. We report on the multilayer design optimization for the Toroidal X-ray Imager (TXI), a hard x-rays microscope instrument designed by Commissariat à l’énergie atomique (CEA) and Laboratoire Charles Fabry (LCF) to be installed on the National Ignition Facility. TXI includes six channels designed for three different energy bands centered on 8.7, 13, and 17.5 keV. Each channel is made up of two toroidal mirrors arranged in a Wolter-like configuration. The required field of view is 800 × 400 µm2, and the resolution should be better than 5 µm. In addition, we seek to estimate the spatial distribution of the temperature, which requires no spectral overlap of the different energy bands and a good spectral homogeneity of the image produced. The development of the multilayer coatings was performed in a two-step method. First, the coatings were optimized to obtain proper energy bands. Then, an x-ray tracing code was used to calculate the integrated optical response of each channel and adjust the response of the mirror to fulfill the requirements. To fulfill all the specifications, we propose an original design using a combination of two aperiodic coatings, one with a narrow bandwidth and the other one with a larger bandwidth.
hard x-rays↗
Assessing Uncertainties and Approximations in Solar Heating of the Climate System
In calculating solar radiation, climate models make many simplifications, in part to reduce computational cost and enable climate modeling, and in part from lack of understanding of critical atmospheric information. Whether known errors or unknown errors, the community's concern is how these could impact the modeled climate. The simplifications are well known and most have published studies evaluating them, but with individual studies it is difficult to compare. Here, we collect a wide range of such simplifications in either radiative transfer modeling or atmospheric conditions and assess potential errors within a consistent framework on climate-relevant scales. We build benchmarking capability around a solar heating code (Solar-J) that doubles as a photolysis code for chemistry and can be readily adapted to consider other errors and uncertainties. The broad classes here include: use of broad wavelength bands to integrate over spectral features; scattering approximations that alter phase function and optical depths for clouds and gases; uncertainty in ice-cloud optics; treatment of fractional cloud cover including overlap; and variability of ocean surface albedo. We geographically map the errors in W m -2 using a full climate re-creation for January 2015 from a weather forecasting model. For many approximations assessed here, mean errors are ~2 W m -2 with greater latitudinal biases and are likely to affect a model’s ability to match the current climate state. Combining this work with previous studies, we make priority recommendations for fixing these simplifications based on both the magnitude of error and the ease or computational cost of the fix.
58 GEOSCIENCES↗
Order-disorder phase transition driven by interlayer sliding in lead iodides
A variety of phase transitions have been found in two-dimensional layered materials, but some of their atomic-scale mechanisms are hard to clearly understand. Here, we report the discovery of a phase transition whose mechanism is identified as interlayer sliding in lead iodides, a layered material widely used to synthesize lead halide perovskites. The low-temperature crystal structure of lead iodides is found not 2H polytype as known before, but non-centrosymmetric 4H polytype. This undergoes the order-disorder phase transition characterized by the abrupt spectral broadening of valence bands, taken by angle-resolved photoemission, at the critical temperature of 120 K. It is accompanied by drastic changes in simultaneously taken photocurrent and photoluminescence. The transmission electron microscopy is used to reveal that lead iodide layers stacked in the form of 4H polytype at low temperatures irregularly slide over each other above 120 K, which can be explained by the low energy barrier of only 10.6 meV/atom estimated by first principles calculations. Our findings suggest that interlayer sliding is a key mechanism of the phase transitions in layered materials, which can significantly affect optoelectronic and optical characteristics.
36 MATERIALS SCIENCE↗
Partial dynamical symmetry versus quasi dynamical symmetry examination within a quantum chaos analyses of spectral data for even–even nuclei
Statistical analyses of the spectral distributions of rotational bands in 51 deformed prolate even–even nuclei in the 152 ≤ A ≤ 250 mass region $R_{{4_{1}^{ + } /2_{1}^{ + } }} \ge 3.00$ are examined in terms of nearest neighbor spacing distributions. Specifically, the focus is on data for 0 + , 2 + , and 4 + energy levels of the ground, gamma, and beta bands. The chaotic behavior of the gamma band, especially the position of the $2_{\gamma }^{ + }$ band-head compared to other levels and bands, is clear. The levels are analyzed within the framework of two models, namely, a SU(3)-partial dynamical symmetry Hamiltonian and a SU(3) two-coupled quasi-dynamical symmetry Hamiltonian, with results that are further analyzed using random matrix theory. The partial and quasi dynamics both yield outcomes that are in reasonable agreement with the known experimental results. However, due to the degeneracy of the beta and gamma bands within the simplest SU(3) picture, the theory cannot be used to describe the fluctuation properties of excited bands. By changing relative weights of the different terms in the partial and quasi dynamical Hamiltonians, results are obtained that show more GOE-like statistics in the partial dynamical formalism as the strength of the pairing term is increased. Also, in the quasi-dynamical symmetry limit, more correlations are found because of the stronger couplings.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗