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At least 127 records · Page 7

An Estimate of the Size and Shape of Sunspot Cycle 24 Based on its Early Cycle Behavior using the Hathaway-Wilson-Reichmann Shape-Fitting Function

On the basis of 12-month moving averages (12-mma) of monthly mean sunspot number (R), sunspot cycle 24 had its minimum amplitude (Rm = 1.7) in December 2008. At 12 mo past minimum, R measured 8.3, and at 18 mo past minimum, it measured 16.4. Thus far, the maximum month-to-month rate of rise in 12-mma values of monthly mean sunspot number (AR(t) max) has been 1.7, having occurred at elapsed times past minimum amplitude (t) of 14 and 15 mo. Compared to other sunspot cycles of the modern era, cycle 24?s Rm and AR(t) max (as observed so far) are the smallest on record, suggesting that it likely will be a slow-rising, long-period sunspot cycle of below average maximum amplitude (RM). Supporting this view is the now observed relative strength of cycle 24?s geomagnetic minimum amplitude as measured using the 12-mma value of the aa-geomagnetic index (aam = 8.4), which also is the smallest on record, having occurred at t equals 8 and 9 mo. From the method of Ohl (the inferred preferential association between RM and aam), one predicts RM = 55 +/- 17 (the ?1 se prediction interval) for cycle 24. Furthermore, from the Waldmeier effect (the inferred preferential association between the ascent duration (ASC) and RM) one predicts an ASC longer than 48 mo for cycle 24; hence, maximum amplitude occurrence should be after December 2012. Application of the Hathaway-Wilson-Reichmann shape-fitting function, using an RM = 70 and ASC = 56 mo, is found to adequately fit the early sunspot number growth of cycle 24.

Wilson, Robert M.↗

Ruggedness Evaluation of ASTM International Standard Test Methods for Shape Memory Materials: E3097 Standard Test Method for Mechanical Uniaxial Constant Force Thermal Cycling of Shape Memory Alloys

This paper evaluates the ruggedness testing of the newly released ASTM International E3097 Standard Test Method for Mechanical Uniaxial Constant Force Thermal Cycling of Shape Memory Alloys. The ruggedness experiment was designed with eight runs in two replicates, consisting of seven factors of strain rate (ė), heating and cooling rates (T(sub heat) and T(sub cool), respectively), upper and lower cycle temperatures (UCT and LCT, respectively), hold time (t(sub hold)), and minimum load (F(sub min)) imparted on the samples. The results indicate that the hold time factor had no effect on any result variable. The minimum load factor, alternatively, had the greatest effect on several result variables, with the greatest influence on the strains at martensite start and finish (strain variation ~0.1 percent), and the strains at the upper and lower cycle temperatures (strain variation of 0.14 percent). The UCT was found to have a large effect on the austenite and martensite finish tangent line and data intersect, denoted by A(sub f(sup *)) and M(sub f(sup*)), by ~17 and 4 °C, respectively. The testing methodology, analysis techniques, and resulting conclusions on the ruggedness of the test methods are presented.

Benafan, Othmane↗

Alloys for shaped charge liners method for making alloys for shaped charge liners

One embodiment of the invention provides an alloy with a density greater than 10 g/cm3, the alloy comprising a single phase solution of tungsten, nickel, and iron. Also provided is a cone liner for use in shaped charges, the liner comprised of a tungsten, nickel, iron alloy having a single phase microstructure. Substantially no precipitates or second phases exist in the alloy. One embodiment of the invention further provides a method for producing a single phase alloy, the method comprising establishing a melt of iron and nickel; dissolving tungsten in the melt to form a solution; wherein the atomic percents of the nickel, tungsten and iron range from between approximately Ni-7%W-0%Fe, Ni-18%W-0%Fe, and Ni-8%W-24%Fe, wherein Ni is the remainder, maintaining the solution at a first temperature sufficient to create a homogeneous mixture; allowing the homogeneous mixture to solidify; and thermochemically treating the solidified mixture for a time to dissolve any second phases or microstructure within the mixture.

36 MATERIALS SCIENCE↗

Magnetic and magneto-transport studies of substrate effect on the martensitic transformation in a NiMnIn shape memory alloy

The effect of substrates on the magnetic and transport properties of Ni{sub 2}Mn{sub 1.5}In{sub 0.5} ultra-thin films were studied theoretically and experimentally. High quality 8-nm films were grown by laser-assisted molecular beam epitaxy deposition. Magneto-transport measurements revealed that the films undergo electronic structure transformation similar to those of bulk materials at the martensitic transformation. The temperature of the transformation depends strongly on lattice parameters of the substrate. To explain this behavior, we performed DFT calculations on the system and found that different substrates change the relative stability of the ferromagnetic (FM) austenite and ferrimagnetic (FiM) martensite states. We conclude that the energy difference between the FM austenite and FiM martensite states in Ni{sub 2}Mn{sub 1.5}In{sub 0.5} films grown on MgO (001) substrates is ΔE = 0.20 eV per NiMnIn f.u, somewhat lower compared to ΔE = 0.24 eV in the bulk material with the same lattice parameters. When the lattice parameters of Ni{sub 2}Mn{sub 1.5}In{sub 0.5} film have values close to those of the MgO substrate, the energy difference becomes ΔE = 0.08 eV per NiMnIn f.u. These results suggest the possibility to control the martensitic transition in thin films through substrate engineering.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Shape-Controlled CO 2 Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra

Electrochemical CO 2 reduction reaction (CO 2 RR) provides a potential pathway to mitigate challenges related to CO 2 emissions. Pd nanoparticles have shown interesting properties as CO 2 RR electrocatalysts, while how different facets of Pd affect its performance in CO 2 reduction to synthesis gas with controlled H 2 to CO ratios has not been studied. Herein, we synthesized nano-sized Pd cubes and octahedra particles dominated by Pd(100) and Pd(111) facets, respectively. Here, the Pd octahedra particles show higher CO selectivity (up to 95%) and better activity than Pd cubes and commercial particles. For both Pd octahedra and cubes, the ratio of H 2 /CO products was tunable between 1 and 2, a desirable ratio for methanol production and the Fischer-Tropsch processes. Further studies of Pd octahedra in a 25-cm 2 flow cell showed a total CO current of 5.47 A was achieved at a potential of 3.4 V, corresponding to a CO partial current density of 220 mA/cm -2 . In situ X-ray absorption spectroscopy studies showed that regardless of facet Pd transformed into Pd hydride (PdH) under reaction conditions. DFT calculations show that the reduced binding energies of CO and HOCO intermediates on PdH(111) are key parameters to the high current density and Faradaic efficiency in CO 2 to CO conversion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗