Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Photoionization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

The photoionization cross section of magnesium near threshold.

Description of a method for calculating the photoionization cross section of magnesium, using the technique of configuration reaction in the continuum. The two series of levels which give rise to autoionization near the threshold are explicitly included in the calculation. The described method is a logical extension of the basic technique developed by Atlick and Moore (1966) for similar calculations in application to helium.

Bates, G. N.↗
NASA NTRS1973

Photoionization branching ratios and vibrational intensity distribution for N2, CO; and CO2 between 53 and 75 nm

The probability of radiation producing ions in specific electronic and vibrational levels was documented. For example, when a narrow band-pass of solar ionizing photons is incident on an atmospheric species it is now possible to describe, accurately, how the radiant energy is shared among the various electronic states of the ions produced. The molecules studied were N2, CO, and CO2. These molecules were photoionized by radiation between 53 and 75 nm. The effects of autoionization are discussed and continuum vibrational intensities are tabulated and compared with theoretical Franck-Condon factors where available. The branching ratios and partial cross sections for ionization into various electronic states are tabulated.

Samson, J. A. R.↗
NASA NTRS1974

Vibrational intensity distributions for continuum photoionization of oxygen

The paper reports on experimental vibrational intensity distributions for continuum photoionization of oxygen using both 584 and 304 A helium lines. A cylindrical mirror energy analyzer with known transmission properties was used to record photoelectron spectra at a resolution of 45 meV with dispersed He radiation. At each wavelength the vibrational intensity distribution were corrected for the transmission of the analyzer and normalized to 100 at the strongest level. A table lists the results with calculated Franck-Condon factors.

Gardner, J. L.↗
NASA NTRS1975

Many-body-theory study of lithium photoionization

A detailed theoretical calculation is carried out for the photoionization of lithium at low energies within the framework of Brueckner-Goldstone perturbational approach. In this calculation extensive use is made of the recently developed multiple-basis-set technique. Through this technique all second-order perturbation terms, plus a number of important classes of terms to infinite order, have been taken into account. Analysis of the results enables one to resolve the discrepancies between two previous works on this subject. The detailed calculation also serves as a test on the convergence of the many-body perturbation-expansion approach.

Chang, T. N.↗
NASA NTRS1975

Photoionization cross sections for atomic chlorine using an open-shell random phase approximation

The use of the Random Phase Approximation with Exchange (RPAE) for calculating partial and total photoionization cross sections and photoelectron angular distributions for open shell atoms is examined for atomic chlorine. Whereas the RPAE corrections in argon (Z=18) are large, it is found that those in chlorine (Z=17) are much smaller due to geometric factors. Hartree-Fock calculations with and without core relaxation are also presented. Sizable deviations from the close coupling results of Conneely are also found.

Starace, A. F.↗
NASA NTRS1975

Photoionization of lithium

The photoionization of lithium from threshold to 50 eV above threshold is calculated using the method of polarized orbitals. The method is applied in as orthodox a manner as possible; this means that total wave functions are constructed as by Temkin and Lamkin (1961) using only the static dipole part of the perturbation of core electrons by the outer part of the external electron. According to other previously given prescriptions, both initial (bound) and final (continuum) wave functions are so polarized, only the length form of the matrix is calculated, and bilinear terms from the polarization contributions are retained (although their effect in this calculation is small). The results themselves are essentially identical to those of a recent diagrammatic calculation of Chang and Poe (1975) (in the region below 5 eV where thay have calculated), and as such they differ in certain significant components from exchange-adiabatic and extended-polarization results of Matese and LaBahn (1969) (although their overall result is similar). The s- and p-wave e-Li(+) phase shifts, which are derived as by-products of this calculation, are also presented and compared with other phase-shift calculations.

Bhatia, A. K.↗
NASA NTRS1975

The photoionization spectrum of neutral aluminium, Al I

The absorption spectrum of Al I has been studied for the wavelength range 1160 to 2000 A by the flash pyrolysis technique. Wavelengths and derived energy levels are reported for 70 new lines converging on the 3s3p(3)P(0) limits of Al II. The autoionization parameters of the 3p(2)P(0)-3p(2)(2)S doublet have been measured. Good agreement is obtained with the experiment of Kohl and Parkinson and the recent calculation of Le Dourneuf et al. The relative photoionization cross section has been measured in the wavelength region 1200 A to 2000 A.

Roig, R. A.↗
NASA NTRS1976

Photoionization and ion cyclotron resonance studies of the ion chemistry of ethylene oxide

The formation of the ethylene oxide molecular ion and its subsequent ion-molecule reactions leading to the products C2H5O(+) and C3H5O(+) have been studied using time-resolved photoionization mass spectroscopy, ion cyclotron resonance spectroscopy, and photoelectron spectroscopy. An examination of the effects of internal energy on reactivity shows that the ratio of C3H5O(+) to C2H5O(+) increases by an order of magnitude with a single quantum of vibrational energy. The formation of (C2H4O/+/)-asterisk in a collision-induced isomerization is found which yields a ring-opened structure by C-C bond cleavage. The relaxed ring-opened C2H4O(+) ion reacts with neutral ethylene oxide by CH2(+) transfer to yield an intermediate product ion C3H6O(+) which gives C3H5O(+) by loss of H.

Corderman, R. R.↗
NASA NTRS1976

A photoionization study of the charge transfer reactions - Xe/+/ + O2 yields O2/+/ + Xe and O2/+/ + Xe yields Xe/+/ + O2

The charge transfer reactions: Xe(+) + O2 yields O2(+) + Xe and O2(+) + Xe yields Xe(+) + O2 were studied using photoionization mass spectroscopy. It is shown that the reaction of Xe(+)(2P-3/2) ions with O2 molecules is much more efficient than the reaction of Xe(+)(2P-1/2) ions with O2 molecules. The charge transfer reaction of O2(+) ions with Xe atoms was detected for O2(+) ions in the a 4Pi-u state.

Ajello, J. M.↗
NASA NTRS1978

Stratospheric nitric oxide and ozone measurements using photoionization mass spectrometry and UV absorption

Nitric oxide has been measured in situ between 38.4 and 29.8 km by a new technique, photoionization mass spectrometry. Data indicate a peak mixing ratio of 5.7 plus or minus 0.35 ppbv at 37.5 km and only 0.2 plus or minus 0.2 ppbv at 32.8 km with a sharp gradient in concentration between 33 and 34 km. Simultaneous in-situ measurements of the ozone concentration show no significant feature at that altitude. The rapid decrease in mixing ratio is not predicted by current theory.

Maier, E. J.↗
NASA NTRS1978

Vibrational intensity distributions for the various electronic states of O2/+/, N2/+/ and CO/+/ produced by photoionization

Vibrational intensity distributions obtained with many discrete emission lines are presented for all major electronic states of O2(+), N2(+) and CO(+) subjected to photoionization. The vibrational distributions are reported as a function of wavelength between 745 and 304 A. The data, provided by photoelectron spectroscopy with an electron energy analyzer of known luminosity, appear to be consistent with calculated Franck-Condon Factors. Evidence for autoionization in the data is also discussed.

Gardner, J. L.↗
NASA NTRS1978

Absolute cross section for photoionization of atomic oxygen

The absolute cross section for photoionization of atomic oxygen from the 2p4 3P ground state of O(0) to the 2p3 4S ground state of O(+) has been measured at five narrow wavelength intervals between 89.8 and 76.2 nm. The cross section near the 2p3 4S threshold is 4.5 Mb + or - 7%. Recent calculations by Taylor and Burke (1976) and by Pradhan and Saraph (1977) are in reasonable agreement with this work. The dipole-length results of Taylor and Burke (4.1 Mb) are in better agreement with the experiment than their dipole-velocity results (3.2 Mb).

Kohl, J. L.↗
NASA NTRS1979

Quantitative energy extraction measurements in a photoionization-stabilized self-sustained XeF laser

Detailed time-correlated gain, fluorescence, and laser energy measurements were used to obtain quantitative data on energy extraction efficiencies for a photoionization-stabilized self-sustained XeF laser. A current pulse of 25 ns full width at half-maximum produced an 80-cu-cm XeF plasma in NF3:Xe:He gas mixtures with a maximum output energy of 80 mJ. The results show that the maximum small-signal gain and the maximum specific output energy is proportional to the NF3 content of the gas mixture. This suggests that there is an optimum fractional utilization of the NF3 molecules in the discharge. Under high-gain conditions, 30-40% of the energy stored in XeF(asterisk) can be extracted in a gain-switched pulse. The output energy represents less than 1% of the input energy.

Lee, C. M.↗
NASA NTRS1980

K-shell photoionization of multielectron atomic systems

A simplified procedure is proposed for calculating the cross section for photoionization from the K-shell for a general atomic system that contains an arbitrary number of outer-shell electrons. The procedure retains the formalism of the one-electron atom case (pure Coulomb-field problem) by determining the effective nuclear charge reduced from Z by 'screening parameters' associated with the other K-shell electron and the outer-bound electrons. The parameters are determined essentially by fitting the atom's radial electric field to Coulomb form at the distance from the nucleus where the integrand of the dipole radial integral is peaked.

Gould, R. J.↗
NASA NTRS1980

Cold dense photoionized universes

This investigation employs a computer code, initially constructed for modeling the evolution of a hot dense intergalactic medium (IGM), to study some properties of a cold dense IGM photoionized by QSOs. Within the observational constraints set by flux measurements in the far-ultraviolet, night sky brightness, and hard X-ray region, and the optical depth limits on various QSO spectra, it determines some allowable scenarios for a range of QSO spectral indices (alpha) and cutoff energies. With H(0) = 50 km/s-Mpc, closure density of an IGM (composed of H and He in their cosmic ratio) is possible only if alpha is greater than or equal to 0.1, a circumstance not likely to prevail; the most probable value, alpha = -0.7, implies an upper limit density about 0.35 of closure, which is somewhat larger than previous estimates. These estimates are substantially independent of whether or not QSOs produce the observed diffuse extragalactic X-ray background; such QSO spectral details are critical, however, in determining the ionization of heavy elements that are expected to contaminate a pure primeval plasma.

Sherman, R. D.↗
NASA NTRS1981

The production rate of C/+/ from the photoionization of CO and CO2

The dissociative photoionization cross sections for the production of C(+) ions are presented for the spectral region from the dissociative ionization threshold to 90 A. The cross sections are considerably larger than previously published data and should therefore influence the calculations of the C(+) concentrations in the Mars and Venus ionospheres. It is suggested that the released energy in the C(+) fragment ion could reduce the loss rate of the ions in collisional processes, thereby accounting for the apparent discrepancies between the observed and calculated C(+) ion density in the Venus ionosphere.

Samson, J. A. R.↗