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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1970

Photoionization mass spectrometer

Photoionization source with a vacuum UV monochromator is used in ion reaction kinetics. Monochromator passes only the photon energies near the threshold of the selected ionization process. Absence of electron impact alleviates creation of different type ions that result in ion fragmentation.

Warneck, P.↗
NASA NTRS1972

Photoionization measurement study

An analysis was conducted of a gas window photoionization device for studying cosmic X-rays in the region 20 eV to 1 keV. The detecting element is an argon proportional counter whose window is a two-dimensional supersonic gas jet. Spectroscopic features of the incoming radiation can be determined by the choice of gas forming the jet (as well by the fluid dynamic parameters of the flow). The choice of gas can be made from pure substances and/or compounds with Z between 1 and 10. The counter walls can be prepared for selective analysis of the extreme ultraviolet radiation.

Sandri, G.↗
NASA NTRS1971

Photoionization and absorption spectrum of formaldehyde in the vacuum ultraviolet.

The measurements have been conducted in the spectral range from 600 to 2000 A. Integrated oscillator strengths were determined for a number of strong Rydberg transitions above 1200 A. From the photoionization curve the first adiabatic ionization potential was found to be 10.87 plus or minus 0.01 eV. As an aid in interpreting the absorption spectrum, theoretical calculations were made using a single-configuration self-consistent field procedure for the Rydberg states and a model which included mixing between the Rydberg and valence states.

Mentall, J. E.↗
NASA NTRS1972

Photoionization and the emission-line spectra of quasi-stellar objects.

Detailed photoionization calculations are used to examine the information conveyed by relative emission-line intensities in QSO spectra. It is found that the elemental abundances cannot be estimated with any assurance; but if ?conventional' values are assumed, then certain restrictions may be placed on the ionizing spectra and gas densities. In particular, the ratio between radiation density and gas density is determined. Narrow filaments or sheets of ionized gas seem to be indicated; these may be compressed regions behind shock fronts.

Davidson, K.↗
NASA NTRS1972

Effect of core polarizability on photoionization cross-section calculations.

Demonstration of the importance of core polarizability in a case where cancellation is only moderate, with suggestion of an improvement to the scaled Thomas-Fermi (STF) wave functions of Stewart and Rotenberg (1965). The inclusion of dipole polarizability of the core for argon is shown to substantially improve the agreement between the theoretical and experimental photoionization cross sections for the ground-state configuration.

Kirkpatrick, R. C.↗
NASA NTRS1971

Photoionization of methanol and formaldehyde

Photoions produced in methanol and formaldehyde by radiation in the spectral region 450-1150 A were analyzed mass spectrometrically, and their relative yields were determined as a function of wavelength. First ionization potentials were determined, and the ion yield curves were interpreted in terms of ionization processes in conjunction with other data. Fragment ions were detected on mass numbers of 31, 30, 29, 15, and 14 for methanol, and 29, 2, and 1 for formaldehyde. The associated appearance potentials were determined and were used to calculate heats of formation of the ions CH2OH(+) and HCO(+), and the radicals CH3, CH2, and HCO.

Warneck, P.↗