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At least 127 records · Page 7

Ota City: Characterizing Output Variability from 553 Homes with Residential PV Systems on a Distribution Feeder

This report describes in-depth analysis of photovoltaic (PV) output variability in a high-penetration residential PV installation in the Pal Town neighborhood of Ota City, Japan. Pal Town is a unique test bed of high-penetration PV deployment. A total of 553 homes (approximately 80% of the neighborhood) have grid-connected PV totaling over 2 MW, and all are on a common distribution line. Power output at each house and irradiance at several locations were measured once per second in 2006 and 2007. Analysis of the Ota City data allowed for detailed characterization of distributed PV output variability and a better understanding of how variability scales spatially and temporally. For a highly variable test day, extreme power ramp rates (defined as the 99 th percentile) were found to initially decrease with an increase in the number of houses at all timescales, but the reduction became negligible after a certain number of houses. Wavelet analysis resolved the variability reduction due to geographic diversity at various timescales, and the effect of geographic smoothing was found to be much more significant at shorter timescales.

14 SOLAR ENERGY↗

LANL Institutional Computing Close-out Report for Project t22_ocean_time_step

This year, my team made a very productive use of LANL IC time. Four papers were published that used IC resources, and two more are under review. These publications fall into three categories: 1.) Improving tide modeling in the global ocean by adding self attraction and loading (Barton et. al. 2022), ice shelf cavities (Pal et al. 2023), and local time stepping (Lilly et al. 2023). 2.) A new sea ice numerical formulation (Capodaglio 2023). 3.) Performance comparisons, methods, and test cases for ocean model development, This includes a verification suite for ocean models (Bishnu, submitted) and a comparison between Julia and Fortran (Strauss, submitted). A new time-stepping method was introduced in Calandrini et al. (2022). These publications, and the use of LANL IC resources, go hand-in-hand with our mentoring efforts to train young scientists. Two of the lead authors are graduate students who are conducting their PhD research: Kristin Barton at the University of Michigan and Jeremy Lilly at Oregon State. These are both their first publications, and they both have DOE funding and DOE mentors. In addition, Bishnu is a post-doctoral researcher at LANL; Strauss conducted his research as a senior in high school; and Capodaglio, Calandrini and Pal are all early-career scientists who were converted to staff in 2021 or 2022. Here we highlight two publications on improvements in tidal modeling: Barton et al. 2022 and Lilly et al. 2023.

58 GEOSCIENCES↗

Summary of Pilot Project State Technical Assistance on Multi-Sector Analysis for Electric and Petroleum Fuels

The Oregon Energy Security Plan, (ODOE 2024) published in September 2024, builds a strong case for the state to give acute attention to the fuel supply chain. In December 2024, Pacific Northwest National Laboratory (PNNL) in partnership with Oregon Department of Energy (ODOE), announced a pilot project to conduct an analysis that synthesizes current and projected transportation fuel dynamics, supply chain risks, and risk comparators with relevant sectors, such as transportation electrification, sponsored by the Department of Energy’s (DOE) Office of Cybersecurity, Energy Security, and Emergency Response (CESER). The study, is intended to leverage existing modeling and frameworks from a recent 2024 sector coupling analysis supported by the DOEs Office of Electricity (OE) (B. Mitra, S. Pal, et al., Coupling of the Electricity and Transportation Sectors - Part I: Sector Overviews 2024) (B. Mitra, S. Pal and J. Reeve, et al. 2024). While the PNNL team set out to conduct a quantitative risk analysis driven by detailed data that synthesizes current and projected transportation fuel dynamics, supply chain risks, and risk comparators with relevant sectors. The intention was to provide an approach that could be extendable to other parts of the country. They encountered data limitations and adjusted their approach accordingly. This report summarizes PNNL's original plan for executing the study, including limitations for obtaining data requirements for fuel flows and interim products, as well as a risk matrix that can be used to identify supply chain risks.

02 PETROLEUM↗

Multi-sightline observation of narrow absorption lines in lensed quasar SDSS J1029+2623

We exploit the widely separated images of the lensed quasar SDSS J1029+2623 (z{sub em} = 2.197, θ = 22.″5) to observe its outflowing wind through two different sightlines. We present an analysis of three observations, including two with the Subaru telescope in 2010 February and 2014 April, separated by four years, and one with the Very Large Telescope, separated from the second Subaru observation by ∼2 months. We detect 66 narrow absorption lines (NALs), of which 24 are classified as intrinsic NALs that are physically associated with the quasar based on partial coverage analysis. The velocities of intrinsic NALs appear to cluster around values of v{sub ej} ∼ 59,000, 43,000, and 29,000 km s{sup −1}, which is reminiscent of filamentary structures obtained by numerical simulations. There are no common intrinsic NALs at the same redshift along the two sightlines, implying that the transverse size of the NAL absorbers should be smaller than the sightline distance between two lensed images. In addition to the NALs with large ejection velocities of v{sub ej} > 1000 km s{sup −1}, we also detect broader proximity absorption lines (PALs) at z{sub abs} ∼ z{sub em}. The PALs are likely to arise in outflowing gas at a distance of r ≤ 620 pc from the central black hole with an electron density of n {sub e} ≥8.7 × 10{sup 3} cm{sup −3}. These limits are based on the assumption that the variability of the lines is due to recombination. We discuss the implications of these results on the three-dimensional structure of the outflow.

79 ASTRONOMY AND ASTROPHYSICS↗

Oxidant abundances in rainwater and the evolution of atmospheric oxygen

H2O2 is probably the dominant oxidant in rainwater at O2 levels lower than 0.01-0.001 present atmospheric levels (PAL), and the magnitude of its dissolved flux is sensitive to the concentration of the trace gases NO, CO, and CH4 in the atmosphere, as well as to the partial pressure of atmospheric CO2. The earlier interpretation of the paleosol data in terms of the ratio of p-O2/p-CO2 in the atmosphere must be modified by taking into account the effects of photochemically produced oxidants and reactants at p-O2 of les than 0.01 PAL.

Kasting, J. F.↗

The origin and evolution of atmospheric oxygen

This paper discusses the chemical processes involved in the evolution of the earth's atmospheric oxygen and ozone, as well as the sources, sinks, and transfer rates of oxygen in the present atmosphere. Special attention is given the evolution of atmospheric O3 as a function of the buildup of O2, with the results of calculations presented as the vertical profiles of O3, in terms of the present atmospheric level (PAL) oxygen values. Calculations show that the total O3 column density that is approximately half of the present level was reached when atmospheric oxygen level reached 0.1 PAL. At this level of ozone, the biological shielding of the earth's surface from the UV radiation is believed to have been achieved.

Levine, Joel S.↗

Young globular clusters in the Milky Way Galaxy

Ruprecht 106 and Pal 12 are two known globular clusters in the Milky Way that are unequivocally younger than other clusters of similar metallicity. The Galactic coordinates of Ruprecht 106 place it near to the Magellanic Stream in projection, suggesting a tidal capture from the Magellanic Clouds. It is demonstrated that a family of orbits for both clusters can be constructed that are consistent with this capture hypothesis and that these then lead to a prediction of 3 milliarcseconds per year for the proper motions of both Ruprecht 106 and Pal 12.

Lin, D. N. C.↗

Linearization of an annular image by using a diffractive optic

The goal for this project is to develop the algorithms for fracturing the zones defined by the mapping transformation, and to actually produce the binary optic in an appropriate setup. In 1984 a side-viewing panoramic viewing system was patented, consisting of a single piece of glass with spherical surfaces which produces a 360 degree view of the region surrounding the lens which extends about 25 degrees in front of and 20 degrees behind the lens. The system not only produces images of good quality, it is also afocal, i.e., images stay in focus for objects located right next to the lens as well as those located far from the lens. The lens produced a panoramic view in an annular shaped image, and so the lens was called a PAL (panoramic annular lens). When applying traditional measurements to PAL images, it is found advantageous to linearize the annular image. This can easily be done with a computer and such a linearized image can be produced within about 40 seconds on current microcomputers. However, this process requires a frame-grabber and a computer, and is not real-time. Therefore, it was decided to try to perform this linearization optically by using a diffractive optic.

Matthys, Donald R.↗

Investigation of Polymer Liquid Crystals

The positron annihilation lifetime spectroscopy (PALS) using a low energy flux generator may provide a reasonably accurate technique for measuring molecular weights of linear polymers and characterization of thin polyimide films in terms of their dielectric constants and hydrophobity etc. Among the tested samples are glassy poly arylene Ether Ketone films, epoxy and other polyimide films. One of the proposed techniques relates the free volume cell size (V(sub f)) with sample molecular weight (M) in a manner remarkably similar to that obtained by Mark Houwink (M-H) between the inherent viscosity (eta) and molecular wieght of polymer solution. The PALS has also demonstrated that free-volume cell size in thermoset is a versatile, useful parameter that relates directly to the polymer segmental molecular weight, the cross-link density, and the coefficient of thermal expansion. Thus, a determination of free volume cell size provides a viable basis for complete microstructural characterization of thermoset polyimides and also gives direct information about the cross-link density and coefficient of expansion of the test samples. Seven areas of the research conducted are reported here.

Han, Kwang S.↗

Free Volume in Glassy Poly(arylene Ether Ketone)s

Amorphous polyarylene ether ketones were examined in the glassy state by positron annihilation lifetime spectroscopy ( PALS ) and in the melt by standard rheological techniques. Specimens were well-characterized fractions of two isomeric structures. PALS clearly shows that the polymer with meta linkages in its backbone contains larger voids (greater than 0.25 nm radius). Thus despite their similar bulk densities, the two materials must pack very differently on a local scale. On the other hand, the free volumes inferred from the WLF treatment of melt viscosity data are practically identical in both materials ca. 4% at T(sub g). The comparison between techniques sheds some light on the distribution of free volume.

Hinkley, J. A.↗

An in silico assessment of gene function and organization of the phenylpropanoid pathway metabolic networks in Arabidopsis thaliana and limitations thereof

The Arabidopsis genome sequencing in 2000 gave to science the first blueprint of a vascular plant. Its successful completion also prompted the US National Science Foundation to launch the Arabidopsis 2010 initiative, the goal of which is to identify the function of each gene by 2010. In this study, an exhaustive analysis of The Institute for Genomic Research (TIGR) and The Arabidopsis Information Resource (TAIR) databases, together with all currently compiled EST sequence data, was carried out in order to determine to what extent the various metabolic networks from phenylalanine ammonia lyase (PAL) to the monolignols were organized and/or could be predicted. In these databases, there are some 65 genes which have been annotated as encoding putative enzymatic steps in monolignol biosynthesis, although many of them have only very low homology to monolignol pathway genes of known function in other plant systems. Our detailed analysis revealed that presently only 13 genes (two PALs, a cinnamate-4-hydroxylase, a p-coumarate-3-hydroxylase, a ferulate-5-hydroxylase, three 4-coumarate-CoA ligases, a cinnamic acid O-methyl transferase, two cinnamoyl-CoA reductases) and two cinnamyl alcohol dehydrogenases can be classified as having a bona fide (definitive) function; the remaining 52 genes currently have undetermined physiological roles. The EST database entries for this particular set of genes also provided little new insight into how the monolignol pathway was organized in the different tissues and organs, this being perhaps a consequence of both limitations in how tissue samples were collected and in the incomplete nature of the EST collections. This analysis thus underscores the fact that even with genomic sequencing, presumed to provide the entire suite of putative genes in the monolignol-forming pathway, a very large effort needs to be conducted to establish actual catalytic roles (including enzyme versatility), as well as the physiological function(s) for each member of the (multi)gene families present and the metabolic networks that are operative. Additionally, one key to identifying physiological functions for many of these (and other) unknown genes, and their corresponding metabolic networks, awaits the development of technologies to comprehensively study molecular processes at the single cell level in particular tissues and organs, in order to establish the actual metabolic context.

NASA Program Fundamental Space Biology↗

Induced phenylpropanoid metabolism during suberization and lignification: a comparative analysis

Induction of the biosynthesis of phenylpropanoids was monitored at the enzyme level through measurement of the temporal change in the activity of two marker enzymes of phenylpropanoid metabolism, phenylalanine ammonia-lyase, (PAL, E.C. 4.1.3.5) and 4-coumaryl-CoA ligase (4-CL, E.C. 6.2.1.12) and two marker enzymes for hydroxycinnamyl alcohol biosynthesis, cinnamoyl-CoA:NADP+ oxidoreductase (CCR, E.C. 1.2.1.44) and cinnamyl alcohol dehydrogenase (CAD, E.C. 1.1.1.195) in both suberizing potato (Solanum tuberosum) tubers and lignifying loblolly pine (Pinus taeda) cell cultures. While measurable activities of PAL, 4-CL and CAD increased upon initiation of suberization in potato tubers, that of CCR did not. By contrast, all four enzymes were induced upon initiation of lignification in pine cell cultures. The lack of CCR induction in potato by wound treatment is consistent with the channelling of hydroxycinnamoyl-CoA derivatives away from monolignol formation and toward other hydroxycinnamoyl derivatives such as those that accumulate during suberization.

Non-NASA Center↗

Growth and lignification in seedlings exposed to eight days of microgravity

Four-day-old pine seedlings and mung bean and oat seeds were prepared for flight on the third Space Transport System Mission (STS-3). The seedlings and seeds were planted in six mini-growth chambers (two chambers per species) which were placed in a plant growth unit (PGU). Another set of seedlings and seeds was prepared and placed in another PGU as the 1 g control. The flight PGU was positioned in the orbiter mid-deck locker area about 11 h prior to launch. The pine seedlings and germinating mung bean and oat seeds were exposed to 194 h of microgravity. The PGU was received at a temporary laboratory about 75 min post-landing. Plants were observed, photographed and the atmospheric gases analyzed at the landing site. The plants were then brought to our Houston laboratory where they were measured and analyzed for lignin and protein content and for phenylalanine ammonia-lyase (PAL) and peroxidase activities. Flight seedlings were shorter than the controls in all three species. Twenty-five to 40 per cent of the mung bean and oat roots were growing upward, and the mung beans showed signs of disorientation. Flight mung beans showed a significant reduction in lignin content in comparison to the controls, and PAL and peroxidase activities were reduced in flight pine seedlings. The results generally support the postulate that lignin synthesis is reduced in near-weightlessness and show other interesting findings.

Flight Experiment↗

Shoot inversion inhibition of stem elongation in Pharbitis nil: a possible role for ethylene-induced glycoprotein and lignin

Inversion of the upper shoot of Pharbitis nil results in the inhibition of elongation in the inverted stem. The objective of the present study was to determine how shoot inversion-induced gravity stress inhibited elongation and to elucidate the possible role of ethylene-induced glycoprotein and lignin in this process. Determinations of hydroxyproline, peroxidase, phenylalanine ammonia-lyase (PAL), phenol, and lignin content/activity were carried out by appropriate spectrophotometric methods. It was found that inversion and Ethrel treatments of upright shoots caused significant increases in hydroxyproline content, peroxidase, and PAL activity in 12 hours and in phenol and lignin contents in 24 hours. All of these increases except for that of cytoplasmic peroxidase activity were partially reversed by AgNO3, the ethylene action inhibitor. It is concluded that possible cross-linking associated with the accumulation of the ethylene-induced hydroxyproline-rich glycoprotein and lignin may be responsible for the later stages of cessation of elongation in the inverted Pharbitis shoot.

NASA Program Space Biology↗

A paleoweathering profile from Griqualand West, South Africa: evidence for a dramatic rise in atmospheric oxygen between 2.2 and 1.9 bybp

A core drilled near Wolhaarkop in Griqualand West, South Africa, intersected highly oxidized Kuruman Iron Formation below red beds of the Gamagara Formation. The lateral equivalents of the Kuruman Iron Formation in this drill hole consist largely of siderite, ankerite, magnetite, greenalite, and quartz. The oxidation of the Kuruman Iron Formation in WOL 2 occurred almost certainly during weathering prior to the deposition of the Gamagara Formation. The date of this weathering episode is bracketed between about 2.2 and 1.9 bybp by the age of the Ongeluk lavas in the Transvaal sequence below the unconformity and by the age of the Hartley lavas in the Olifantshoek Group above the unconformity. The ratio of iron to SiO2 in the several facies of the weathered Kuruman Iron Formation in WOL 2 is nearly the same as that in their unweathered equivalents. Since SiO2 loss during weathering was almost certainly minor, the similarity of the Fe/SiO2 ratio in the weathered and unweathered BIF indicates that nearly all the "FeO" in the Kuruman Iron Formation was oxidized and retained as FeO3 during weathering. Such a high degree of iron retention is best explained by an O2 content of the atmosphere > or = 0.03 atm at the time of weathering. Such an O2 pressure is very much greater than that suggested by the composition of paleosols developed on basalt > or = 2.2 bybp but is consistent with the highly oxidized nature of the 1.85 by Flin Flon paleosol. The new data suggest that PO2 rose dramatically from about 1 percent PAL (present atmospheric level) to > or = 15 percent PAL between 2.2 and 1.9 bybp.

NASA Discipline Number 52-20↗

Mineral catalysis of a potentially prebiotic aldol condensation

Minerals may have played a significant role in chemical evolution. In the course of investigating the chemistry of phosphonoacetaldehyde (PAL), an analogue of glycolaldehyde phosphate, we have observed a striking case of catalysis by the layered hydroxide mineral hydrotalcite ([Mg2Al(OH)6][Cl.nH2O]). In neutral or moderately basic aqueous solutions, PAL is unreactive even at a concentration of 0.1 M. In the presence of a large excess of NaOH (2 M), the compound undergoes aldol condensation to produce a dimer containing a C3-C4 double-bond. In dilute neutral solutions and in the presence of the mineral, however, condensation takes place rapidly, to produce a dimer which is almost exclusively the C2-C3 unsaturated product.

Non-NASA Center↗

PBMA Pause and Learn Video Nuggets Transcript

This document is a transcript for a video about a practice practiced at Goddard Space Flight Center called Pause and Learn (PaL). The PaL process is intended to, first of all, help the team learn. So, the team that was involved in the activity, the group that actually did the work, that handled the review, or ran the tests, or developed the piece of equipment, they sit down and actually say, "What did we learn from this exercise?" The idea is to create a learning environment at various key milestones in the execution of a process, rather than wait until the end of the given process, be it a launch or a mission.

Rogers, Ed↗

Evolution of Combustion-Generated Particles at Tropospheric Conditions

This paper describes particle evolution measurements taken in the Particulate Aerosol Laboratory (PAL). The PAL consists of a burner capable of burning jet fuel that exhausts into an altitude chamber that can simulate temperature and pressure conditions up to 13,700 m. After presenting results from initial temperature distributions inside the chamber, particle count data measured in the altitude chamber are shown. Initial particle count data show that the sampling system can have a significant effect on the measured particle distribution: both the value of particle number concentration and the shape of the radial distribution of the particle number concentration depend on whether the measurement probe is heated or unheated.

Tacina, Kathleen M.↗