Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Oxide Particles”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7

Structure of a Swirl-stabilized, Combusting Spray

Measurements of the structure of a swirl-stabilized, reacting spray are presented. The configuration consisted of a research air-assist atomizer located in the center surrounded by a coflowing air stream. Both the air assist and coflow streams had swirl imparted to them in the same direction with 45 degree angle swirlers. The fuel and air entered the combustor at ambient temperature and the combustor was operated in an unconfined environment. The gas phase was seeded with aluminum oxide particles in order to obtain velocity measurements. Velocity measurements for the gas phase are reported for both an isothermal, single-phase case without drops and a reacting spray case at axial distances from 2.5 to 350 mm downstream of the nozzle. Both mean and fluctuating values are reported. Heptane fuel was used for all the experiments. Drop size and velocity, and drop number flux are also reported for five axial distances downstream. Both mean and fluctuating values are reported for the drops. The measurements were performed using a two-component phase/Doppler particle analyzer. Profiles across the entire flowfield where velocities were significant are presented. Mean gas phase temperatures were also measured intrusively using a single pt/pt-13 percent rh thermocouple and are reported at axial distances from 2.5 to 200 mm downstream of the nozzle.

Bulzan, Daniel L.↗

Secondary ion mass spectrometry (SIMS) analysis of hypervelocity microparticle impact sites on LDEF surfaces

Two dimensional elemental ion maps have been recorded for hundreds of microparticle impact sites and contamination features on LDEF surfaces. Since the majority of the analyzed surfaces were metal-oxide-silicon (MOS) impact detectors from the Interplanetary Dust Experiment, a series of 'standard' and 'blank' analyses of these surfaces are included. Hypervelocity impacts of forsterite olivine microparticles on activated flight sensors served as standards while stylus and pulsed laser simulated 'impacts' served as analytical blanks. Results showed that despite serious contamination issues, impactor residues can be identified in greater than 1/3 of the impact sites. While aluminum oxide particles could not be detected on aluminum surfaces, they were detected on germanium surfaces from row 12. Remnants of manmade debris impactors consisting of paint chips and bits of metal were identified on surfaces from LDEF Rows 3 (west or trailing side), 6 (south), 9 (ram or leading side), 12 (north) and the space end. Higher than expected ratios of manmade microparticle impacts to total microparticle impacts were found on the space end and the trailing side. These results were consistent with time-tagged and time-segregated microparticle impact data from the IDE and other LDEF experiments. A myriad of contamination interferences were identified and their effects on impactor debris identification mitigated during the course of this study. These interferences include pre-, post and inflight deposited surface contaminants as well as indigenous heterogeneous material contaminants. Non-flight contaminations traced to human origins, including spittle and skin oils, contributed significant levels of alkali-rich carbonaceous interferences. A ubiquitous layer of in-flight deposited silicaceous contamination varied in thickness with location on LDEF, even on a micro scale. In-flight deposited (low velocity) contaminants include urine droplets and bits of metal film from eroded thermal blankets.

Simon, C. G.↗

Structure of a swirl-stabilized combusting spray

Measurements of the structure of a swirl-stabilized, reacting spray are presented. The configuration consisted of a research air-assist atomizer located in the center surrounded by a co-flowing airstream. Both the air-assist and co-flowing streams had swirl imparted to them in the same direction with 45-deg angle swirlers. The fuel and air entered the combustor at ambient temperature and the combustor was operated in an unconfined environment. The gas phase was seeded with aluminum-oxide particles in order to obtain velocity measurements. Mean velocity measurements for the gas phase are reported for both an isothermal, single-phase case without drops and a reacting spray case at axial distances from 2.5 to 50 mm downstream of the nozzle. Heptane fuel was used for all the experiments. Drop size and mean velocity and drop number flux are also reported for five axial distances downstream. The measurements were performed using a two-component phase/Doppler particle analyzer. Profiles across the entire flowfield where velocities were significant are presented. Mean gas-phase temperatures were also measured intrusively using a single pt/pt-13%rh thermocouple and are also reported at axial distances from 2.5 to 50 "im downstream of the nozzle.

Bulzan, Daniel L.↗

An Experimental Study of Characteristic Combustion-Driven Flow for CFD Validation

A series of uni-element rocket injector studies were completed to provide benchmark quality data needed to validate computational fluid dynamic models. A shear coaxial injector geometry was selected as the primary injector for study using gaseous hydrogen/oxygen and gaseous hydrogen/liquid oxygen propellants. Emphasis was placed on the use of nonintrusive diagnostic techniques to characterize the flowfields inside an optically-accessible rocket chamber. Measurements of the velocity and species fields were obtained using laser velocimetry and Raman spectroscopy, respectively. Qualitative flame shape information was also obtained using laser-induced fluorescence excited from OH radicals and laser light scattering studies of aluminum oxide particle seeded combusting flows. The gaseous hydrogen/liquid oxygen propellant studies for the shear coaxial injector focused on breakup mechanisms associated with the liquid oxygen jet under subcritical pressure conditions. Laser sheet illumination techniques were used to visualize the core region of the jet and a Phase Doppler Particle Analyzer was utilized for drop velocity, size and size distribution characterization. The results of these studies indicated that the shear coaxial geometry configuration was a relatively poor injector in terms of mixing. The oxygen core was observed to extend well downstream of the injector and a significant fraction of the mixing occurred in the near nozzle region where measurements were not possible to obtain. Detailed velocity and species measurements were obtained to allow CFD model validation and this set of benchmark data represents the most comprehensive data set available to date. As an extension of the investigation, a series of gas/gas injector studies were conducted in support of the X-33 Reusable Launch Vehicle program. A Gas/Gas Injector Technology team was formed consisting of the Marshall Space Flight Center, the NASA Lewis Research Center, Rocketdyne and Penn State. Injector geometries studied under this task included shear and swirl coaxial configurations as well as an impinging jet injector.

Santoro, Robert J.↗

An Experimental Study of Characteristic Combustion-Driven Flow for CFD Validation

A series of uni-element rocket injector studies were completed to provide benchmark quality data needed to validate computational fluid dynamic models. A shear coaxial injector geometry was selected as the primary injector for study using gaseous hydrogen/oxygen and gaseous hydrogen/liquid oxygen propellants. Emphasis was placed on the use of non-intrusive diagnostic techniques to characterize the flowfields inside an optically-accessible rocket chamber. Measurements of the velocity and species fields were obtained using laser velocimetry and Raman spectroscopy, respectively Qualitative flame shape information was also obtained using laser-induced fluorescence excited from OH radicals and laser light scattering studies of aluminum oxide particle seeded combusting flows. The gaseous hydrogen/liquid oxygen propellant studies for the shear coaxial injector focused on breakup mechanisms associated with the liquid oxygen jet under sub-critical pressure conditions. Laser sheet illumination techniques were used to visualize the core region of the jet and a Phase Doppler Particle Analyzer was utilized for drop velocity, size and size distribution characterization. The results of these studies indicated that the shear coaxial geometry configuration was a relatively poor injector in terms of mixing. The oxygen core was observed to extend well downstream of the injector and a significant fraction of the mixing occurred in the near nozzle region where measurements were not possible to obtain Detailed velocity and species measurements were obtained to allow CFD model validation and this set of benchmark data represents the most comprehensive data set available to date As an extension of the investigation, a series of gas/gas injector studies were conducted in support of the X-33 Reusable Launch Vehicle program. A Gas/Gas Injector Technology team was formed consisting of the Marshall Space Flight Center, the NASA Lewis Research Center, Rocketdyne and Penn State. Injector geometries studied under this task included shear and swirl coaxial configurations as well as an impinging jet injector.

Santoro, Robert J.↗

Virtual and Experimental Visualization of Flows in Packed Beds of Spheres Simulating Porous Media Flows

A videotape presentation of flow in a packed bed of spheres is provided. The flow experiment consisted of three principal elements: (1) an oil tunnel 76.2 mm by 76.2 mm in cross section, (2) a packed bed of spheres in regular and irregular arrays, and (3) a flow characterization methodology, either (a) full flow field tracking (FFFT) or (b) computational fluid dynamic (CFD) simulation. The refraction indices of the oil and the test array of spheres were closely matched, and the flow was seeded with aluminum oxide particles. Planar laser light provided a two-dimensional projection of the flow field, and a traverse simulated a three-dimensional image of the entire flow field. Light focusing and reflection rendered the spheres black, permitting visualization of the planar circular interfaces in both the axial and transverse directions. Flows were observed near the wall-sphere interface and within the set of spheres. The CFD model required that a representative section of a packed bed be formed and gridded, enclosing and cutting six spheres so that symmetry conditions could be imposed at all cross-boundaries. Simulations had to be made with the flow direction at right angles to that used in the experiments, however, to take advantage of flow symmetry. Careful attention to detail was required for proper gridding. The flow field was three-dimensional and complex to describe, yet the most prominent finding was flow threads, as computed in the representative 'cube' of spheres with face symmetry and conclusively demonstrated experimentally herein. Random packing and bed voids tended to disrupt the laminar flow, creating vortices.

Hendricks, R. C.↗

Predicting Slag Generation in Sub-Scale Test Motors Using a Neural Network

Generation of slag (aluminum oxide) is an important issue for the Reusable Solid Rocket Motor (RSRM). Thiokol performed testing to quantify the relationship between raw material variations and slag generation in solid propellants by testing sub-scale motors cast with propellant containing various combinations of aluminum fuel and ammonium perchlorate (AP) oxidizer particle sizes. The test data were analyzed using statistical methods and an artificial neural network. This paper primarily addresses the neural network results with some comparisons to the statistical results. The neural network showed that the particle sizes of both the aluminum and unground AP have a measurable effect on slag generation. The neural network analysis showed that aluminum particle size is the dominant driver in slag generation, about 40% more influential than AP. The network predictions of the amount of slag produced during firing of sub-scale motors were 16% better than the predictions of a statistically derived empirical equation. Another neural network successfully characterized the slag generated during full-scale motor tests. The success is attributable to the ability of neural networks to characterize multiple complex factors including interactions that affect slag generation.

Wiesenberg, Brent↗

Visualization of Flows in Packed Beds of Twisted Tapes

A videotape presentation of the flow field in a packed bed of 48 twisted tapes which can be simulated by very thin virtual cylinders has been assembled. The indices of refraction of the oil and the Lucite twisted tapes were closely matched, and the flow was seeded with magnesium oxide particles. Planar laser light projected the flow field in two dimensions both along and transverse to the flow axis. The flow field was three dimensional and complex to describe, yet the most prominent finding was flow threads. It appeared that axial flow spiraled along either within the confines of a virtual cylindrical boundary or within the exterior region, between the tangency points, of the virtual cylinders. Random packing and bed voids created vortices and disrupted the laminar flow but minimized the entrance effects. The flow-pressure drops in the packed bed fell below the Ergun model for porous-media flows. Single-twisted-tape results of Smithberg and Landis (1964) were used to guide the analysis. In appendix A the results of several investigators are scaled to the Ergun model. Further investigations including different geometric configurations, computational fluid dynamic (CFD) gridding, and analysis are required.

Hendricks, R. C.↗

Palagonitic (Not Andesitic) Mars: Evidence from Thermal Emission and VNIR Spectra of Palgonitic Alteration Rinds on Basaltic Rock

Visible and near-IR (VNIR) spectra of both Martian bright and dark regions are characterized by a ferric absorption edge extending from approx. 400 to 750 nm, with bright regions having about twice the reflectivity at 750 nm as dark regions. Between 750 nm to beyond 2000 nm, bright and dark regions have nearly constant and slightly negative spectral slopes, respectively. Depending on location, bright regions have shallow reflectivity minima in the range 850-910 nm that are attributed to ferric oxides. Similarly, dark regions have shallow reflectivity minima near approx. 950 and 1700-2000 nm that are attributed to ferrous silicate minerals (pyroxene). Among terrestrial geologic materials, the best spectral analogues for Martian bright regions are certain palagonitic tephras from Mauna Kea Volcano (Hawaii). By definition, palagonite is a "yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass". The ferric pigment in palagonite is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles is not known, but the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates.

R V Morris↗

Palagonitic Mars from Rock Rinds to Dust: Evidence from Visible, Near-IR, and Thermal Emission Spectra of Poorly Crystalline Materials

Visible and near-IR (VNIR) spectral data for Martian bright regions are characterized by a general shape consisting of a ferric absorption edge extending from about 400 to 750 nm and relatively constant reflectivity extending from about 750 nm to beyond 2000 nm . Among terrestrial geologic materials, the best spectral analogues are certain palagonic tephras from Mauna Kea Volcano (Hawaii). By definition, palagonite is a yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass. The ferric pigment in palagonite is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles is not known, and the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates. We show here that laboratory VNIR and TES spectra of palagonitic alteration rinds developed on basaltic rocks are spectral endmembers that provide a consistent explanation for both VNIR and TES data of Martian dark regions.

Morris, R. V.↗

Hydrothermal Alteration on Basaltic Mauna Kea Volcano as a Template for Identification of Hydrothermal Alteration on Basaltic Mars

Certain samples of palagonitic tephra from Mauna Kea Volcano (Hawaii) are spectral analogues for bright martian surface materials at visible and near-IR wavelengths because both are characterized by a ferric absorption edge extending from about 400 to 750 nm and relatively constant reflectivity extending from about 750 nm to beyond 2000 nm. Palagonite is a yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass. For Mars-analogue palagonite, the pigment is nanometersized ferric oxide particles (np-Ox) dispersed throughout an allophane-like hydrated basaltic glass matrix. Crystalline phyllosilicates are not generally detected, and the hydration state of the is not known. The poorly crystalline nature of glass alteration products implies relatively low temperature formation pathways. We report here x-ray diffraction, major element, Mossbauer, and VNIR data for 9 basaltic tephras. Thermal emission spectra are reported in a separate abstract. Our multidisciplinary approach both tightly constrains mineralogical interpretations and maximizes overlap with datasets available for the martian surface available now and in the future.

Morris, R. V.↗

Cell sorting apparatus

Polymeric functional microspheres containing metal or metal compounds are formed by addition polymerization of a covalently bondable olefinic monomer such as hydroxyethylmethacrylate in the presence of finely divided metal or metal oxide particles, such as iron, gold, platinum or magnetite, which are embedded in the resulting microspheres. The microspheres can be covalently bonded to chemotherapeutic agents, antibodies, or other proteins providing a means for labeling or separating labeled cells. Labeled cells or microspheres can be concentrated at a specific body location such as in the vicinity of a malignant tumor by applying a magnetic field to the location and then introducing the magnetically attractable microspheres or cells into the circulatory system of the subject. Labeled cells can be separated from a cell mixture by applying a predetermined magnetic field to a tube in which the mixture is flowing. After collection of the labeled cells, the magnetic field is discontinued and the labeled sub-cell population recovered.

Yen, Shiao-Ping S.↗

Method for producing a biological reagent

Polymeric functional microspheres containing metal or metal compounds are formed by addition polymerization of a covalently bondable olefinic monomer such as hydroxyethylmethacrylate in the presence of finely divided metal or metal oxide particles, such as iron, gold, platinum or magnetite, which are embedded in the resulting microspheres. The microspheres can be covalently bonded to chemotherapeutic agents, antibodies, or other proteins providing a means for labeling or separating labeled cells. Labeled cells or microspheres can be concentrated at a specific body location such as in the vicinity of a malignant tumor by applying a magnetic field to the location and then introducing the magnetically attractable microspheres or cells into the circulatory system of the subject. Labeled cells can be separated from a cell mixture by applying a predetermined magnetic field to a tube in which the mixture is flowing. After collection of the labeled cells, the magnetic field is discontinued and the labeled sub-cell population recovered.

Yen, Shiao-Ping S.↗

Metal containing polymeric functional microspheres

Polymeric functional microspheres containing metal or metal compounds are formed by addition polymerization of a covalently bondable olefinic monomer such as hydroxyethylmethacrylate in the presence of finely divided metal or metal oxide particles, such as iron, gold, platinum or magnetite, which are embedded in the resulting microspheres. The microspheres can be covalently bonded to chemotherapeutic agents, antibodies, or other proteins providing a means for labeling or separating labeled cells. Labeled cells or microspheres can be concentrated at a specific body location such as in the vicinity of a malignant tumor by applying a magnetic field to the location and then introducing the magnetically attractable microspheres or cells into the circulatory system of the subject. Labeled cells can be separated from a cell mixture by applying a predetermined magnetic field to a tube in which the mixture is flowing. After collection of the labeled cells, the magnetic field is discontinued and the labeled sub-cell population recovered.

Yen, Shiao-Ping S.↗

Glass Frit Filters for Collecting Metal Oxide Nanoparticles

Filter disks made of glass frit have been found to be effective as means of high-throughput collection of metal oxide particles, ranging in size from a few to a few hundred nanometers, produced in gas-phase condensation reactors. In a typical application, a filter is placed downstream of the reactor and a valve is used to regulate the flow of reactor exhaust through the filter. The exhaust stream includes a carrier gas, particles, byproducts, and unreacted particle-precursor gas. The filter selectively traps the particles while allowing the carrier gas, the byproducts, and, in some cases, the unreacted precursor, to flow through unaffected. Although the pores in the filters are much larger than the particles, the particles are nevertheless trapped to a high degree: Anecdotal information from an experiment indicates that 6-nm-diameter particles of MnO2 were trapped with greater than 99-percent effectiveness by a filtering device comprising a glass-frit disk having pores 70 to 100 micrometer wide immobilized in an 8-cm-diameter glass tube equipped with a simple twist valve at its downstream end.

Ackerman, John↗

Pad A Main Flame Deflector Sensor Data and Evaluation

Space shuttle launch pads use flame deflectors beneath the vehicle to channel hot gases away from the vehicle. Pad 39 A at the Kennedy Space Center uses a steel structure coated with refractory concrete. The solid rocket booster plume is comprised of gas and molten alumina oxide particles that erodes the refractory concrete. During the beginning of the shuttle program the loads for this system were never validated with a high level of confidence. This paper presents a representation of the instrumentation data collected and follow on materials science evaluation of the materials exposed to the SRB plume. Data collected during STS-133 and STS-134 will be presented that support the evaluation of the components exposed to the SRB plume.

Parlier, Christopher R.↗

Highly porous ceramic oxide aerogels having improved flexibility

Ceramic oxide aerogels incorporating periodically dispersed flexible linkages are provided. The flexible linkages impart greater flexibility than the native aerogels without those linkages, and have been shown to reduce or eliminate the need for supercritical CO.sub.2-mediated drying of the corresponding wet gels. The gels may also be polymer cross-linked via organic polymer chains that are attached to and extend from surface-bound functional groups provided or present over the internal surfaces of a mesoporous ceramic oxide particle network via appropriate chemical reactions.

Meador, Mary Ann B.↗

Flow Visualizations in a Packed Bed of Twisted Tapes

A videotape presentation of the flow field in a packed bed of 48 twisted tapes which can be simulated by very thin virtual cylinders has been assembled. The indices of refraction of the oil and the Lucite twisted tapes were closely matched, and the flow was seeded with magnesium oxide particles. Planar laser light projected the flow field in two dimensions both along and transverse to the flow axis. The flow field was three dimensional and complex to describe, yet the most prominent finding was flow threads. It appeared that axial flow spiraled along either within the confines of a virtual cylindrical boundary or within the exterior region, between the tangency points, of the virtual cylinders. Random packing and bed voids created vortices and disrupted the laminar flow but minimized the entrance effects. The flow-pressure drops in the packed bed fell below the Ergun model for porous-media flows. Single-twisted-tape results of Smithberg and Landis (1964) were used to guide the analysis. In appendix A the results of several investigators are scaled to the Ergun model. Further investigations including different geometric configurations, computational fluid dynamic (CFD) gridding, and analysis are required.

Hendricks, R. C.↗