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Results for “Optical Spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1980

Electron impact spectroscopy

The concepts of electron impact spectroscopy are discussed, comparing the electron spectroscopy techniques with those of the optical spectroscopy. The main advantage of the electron spectroscopy is to be found in the elimination of optical selection rules in excitation processes and the ability to scan the spectrum from the infrared to the X-ray region. The range of the method is indicated through a review of several examples, including electron impact excitation of Ba and rotational excitation of H2. The sensitivity of the method is demonstrated by vibrational excitation spectrum of N2. It is shown that the application of the method to the inner-shell excitation allows to obtain information about molecular species which are not commonly available, while spectroscopy of negative ions yields information about their energy and symmetry properties. However, the techniques are still under development and more data are expected to become available in the coming years.

Trajmar, S.↗

NASA NTRS1989

The optical counterpart of the X-ray source H0253+193 - A distant, high-luminosity RS Canum Venaticorum system

Optical and near-infrared photometry in the VRIJHK and CO (2.35 microns) bands and optical spectroscopy and polarimetry reveal that the optical counterpart of the X-ray source H0253+193 is most likely a RS CVn binary system. The results show a visual extinction of 11.3 mag to the star, with an IR excess possibly due a cooler binary companion or circumstellar material. It is suggested that the I-band polarization of 8.1 + or - 1.8 may be induced in the starlight by passage through the molecular cloud. The lack of strong H-alpha emission in the optical spectrum argues against the possibility of a classical T Tauri star, and the IR excess argues against a naked T Tauri star. The wide energy spectrum found in the dereddened optical and near-infrared photometry supports the binary star model.

Clemens, Dan P.↗

NASA NTRS1991

Engine throat/nozzle optics for plume spectroscopy

The Task 2.0 Engine Throat/Nozzle Optics for Plume Spectroscopy, effort was performed under the NASA LeRC Development of Life Prediction Capabilities for Liquid Propellant Rocket Engines program. This Task produced the engineering design of an optical probe to enable spectroscopic measurements within the SSME main chamber. The probe mounts on the SSME nozzle aft manifold and collects light emitted from the throat plane and chamber. Light collected by the probe is transferred to a spectrometer through a fiber optic cable. The design analyses indicate that the probe will function throughout the engine operating cycle and is suitable for both test stand and flight operations. By detecting metallic emissions that are indicative of component degradation or incipient failure, engine shutdown can be initiated before catastrophic failure. This capability will protect valuable test stand hardware and provide enhanced mission safety.

Bickford, R. L.↗

DOE OSTI2026

Design of a Molten Salt Flow Cell for Combined Absorbance and Laser-Induced Breakdown Spectroscopy for Online Measurements

A novel flow cell allowing for multiple optical spectroscopy measurements on flowing molten salts was designed, and demonstrative calibrations of impurities in aqueous samples were performed. Online compositional measurements of molten salts are of high interest to monitor the state of relevant solar and nuclear systems. Here, the Spectroscopic Configuration for Optical Real-Time Characterization of High-Temperature (SCORCH) fluids cell was designed to meet this need by providing optical access to a high-temperature molten salt sample stream without physical contact between the sample and window materials. Laser-induced breakdown spectroscopy (LIBS) was utilized to quantify Li, Cr, Fe, Ni, Sr, and Pr at concentrations ranging nominally from 0 to 315 mmol L −1 . Laser power, frequency, and plasma position were optimized to mitigate challenges associated with sample splashing. Univariate calibration models were built with R 2 > 0.98, percent root mean square error of cross-validation (%RMSECV) as low as 2.7%, and limits of quantification (LOQs) down to 4.1 mmol L −1 . Simultaneously, absorbance calibrations were developed for the applicable analytes (Cr, Ni, and Pr) using Beer’s law with a pathlength of 4.41 ± 0.10 mm. These models provide excellent quantification performance with R 2 > 0.999, %RMSECV as low as 0.6%, and LODs down to 0.08 mmol L −1 . Although these calibrations were performed for each spectroscopic technique separately, the two methods may be combined in the future through multivariate modeling and sensor fusion to provide more robust models with the benefits of both techniques (e.g., absorbance: oxidation state concentrations, LIBS: elemental concentration). Additionally, optimized spectrometers may be deployed to enhance sensitivity.

absorbance spectroscopy↗

DOE OSTI2025

Computational toolkit for predicting thickness of 2D materials using machine learning and autogenerated dataset by large language model

The thickness of 2D materials not only plays a crucial role in determining the performance of nanoelectronic and optoelectronic devices but also introduces complexities in predicting volume-dependent properties, such as energy storage capacity, due to the intrinsic vacuum within these materials. Although a plethora of experimental techniques, including but not limited to optical contrast, Raman spectroscopy, nonlinear optical spectroscopy, near-field optical imaging, and hyperspectral imaging, facilitate the measurement of 2D material thickness, comprehensive data for many materials remain elusive. Over the past decade, the exponential proliferation of 2D materials and their heterostructures has outstripped the capabilities of conventional experimental and computational approaches. In this evolving landscape, machine learning (ML) has emerged as an indispensable tool, offering a scalable approach to augment these traditional methodologies. Addressing the critical gap, we introduce THICK2D—Thickness Hierarchy Inference and Calculation Kit for 2D Materials. This Python-based computational framework harnesses an autogenerated thickness database, developed using large language models, and advanced ML algorithms to facilitate the rapid and scalable estimation of material thickness, relying solely on crystallographic data. To demonstrate the utility and robustness of THICK2D, we successfully used the toolkit to predict the thickness of more than 8000 2D-based materials, sourced from two extensive 2D materials databases. THICK2D is disseminated as an open-source utility, accessible on GitHub at https://github.com/gmp007/THICK2D, and archived on Zenodo at https://10.5281/zenodo.11216648.

Ekuma, Chinedu E. (ORCID:0000000258527556)↗

NASA NTRS1993

Mineralogy of three slightly palagonitized basaltic tephra samples from the summit of Mauna Kea, Hawaii

The paper characterizes the mineralogy and spectral properties of three slightly palagonitized basaltic tephra samples collected near the summit of Mauna Kea in order to contribute to the basis for inferring mineralogy and processes for Martian surface materials. The mineralogy of size fractions of these samples is examined by diffuse reflectance and FIR spectroscopy, optical microscopy, X-ray diffraction, Moessbauer spectroscopy, magnetic analysis, EMPA, TEM, and SEM. For the 20-1000 micron size fraction, sample HWMK11 (red) is essentially completely oxidized and has a hematite (Ti-hematite) pigment dispersed throughout the silicate matrix. Sample HWMK12 (black) has the lowest proportion of ferric-bearing phases and is thus least weathered. For HWMK11, the amount of hematite is essentially constant, and mica is present only in the coarse clay-sized fraction; smectites are low in structural Fe.

Golden, D. C.↗

NASA NTRS1976

The revised 3C catalog of radio sources - A review of optical identifications and spectroscopy

We present a catalog of the important optical data for the radio sources in the Revised Third Cambridge Catalog. Optical positions, redshifts, magnitudes, and identifications have been included, as well as radio flux densities and spectral indices for the sample of 297 extragalactic 3CR sources. A bibliography of optical identifications, spectroscopy, and radio position/structure is also given. In addition to the literature compilation, we present new spectroscopic observations of 27 3CR radio galaxies, 25 of which do not have previously published redshifts.

Smith, H. E.↗

DOE OSTI2024

Evolution and persistence of SiO emission in nanosecond laser ablation plumes

Analyzing laser-produced plasmas in a controlled oxygen-containing environment provides insight into the formation and evolution of molecular species through gas-phase oxidation. This study explores the role of ambient pressure and oxygen availability in forming SiO molecular species in laser ablation plumes. The self-emission emanating during the reactive ablation of Si targets was characterized by optical emission spectroscopy and optical time-of-flight techniques. Our results showed that the SiO species formation was greatly influenced by both the ambient pressure and oxygen availability. The intensity and the persistence of SiO emission bands are lower at higher oxygen concentrations, indicating they are depopulated by the formation of more complex silicon oxides. The oxygen partial pressure effects on plume chemistry showed that SiO formation is favored even with a minimal oxygen concentration in the environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1983

Optical detectors for spectroscopy

The modes of operation of photoconductive and photoemissive array detectors are described, and their performance characteristics compared and contrasted, with emphasis on their suitability for use as detectors for optical spectroscopy. The prospects for future developments of the array detectors are discussed.

Timothy, J. G.↗

DOE OSTI2024

Moiré Exchange Effect in Twisted WSe 2 /WS 2 Heterobilayer

Moiré superlattices of layered transition metal dichalcogenides are proven to host periodic electron crystals due to strong correlation effects. These electron crystals can also be intertwined with intricate magnetic phenomena. Here, in this Letter, we present our findings on the moiré exchange effect, resulting from the modulation of local magnetic moments by electron crystals within well-aligned WSe 2 /WS 2 heterobilayers. Employing polarization-resolved magneto-optical spectroscopy, we unveil a high-energy excitonic resonance near one hole per moiré unit cell (v=–1), which possesses a giant g factor several times greater than the already very large g factor of the WSe 2 A exciton in this heterostructure. Supported by continuum model calculations, these high-energy states are found to be dark excitons brightened through Umklapp scattering from the moiré mini-Brillouin zone. When the carriers form a Mott insulating state near v=–1, the Coulomb exchange between doped carriers and excitons forms an effective magnetic field with moiré periodicity. This moiré exchange effect gives rise to the observed giant g factor for the excitonic Umklapp state.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Sub-100-fs energy transfer in coenzyme NADH is a coherent process assisted by a charge-transfer state

Excitation energy transfer (EET) is a key photoinduced process in biological chromophoric assemblies. Here we investigate the factors which can drive EET into efficient ultrafast sub-ps regimes. We demonstrate how a coherent transport of electronic population could facilitate this in water solvated NADH coenzyme and uncover the role of an intermediate dark charge-transfer state. High temporal resolution ultrafast optical spectroscopy gives a 54 ± 11 fs time constant for the EET process. Nonadiabatic quantum dynamical simulations computed through the time-evolution of multidimensional wavepackets suggest that the population transfer is mediated by photoexcited molecular vibrations due to strong coupling between the electronic states. The polar aqueous solvent environment leads to the active participation of a dark charge transfer state, accelerating the vibronically coherent EET process in favorably stacked conformers and solvent cavities. Our work demonstrates how the interplay of structural and environmental factors leads to diverse pathways for the EET process in flexible heterodimers and provides general insights relevant for coherent EET processes in stacked multichromophoric aggregates like DNA strands.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Optical characterization of deep-level defects in n-type Al x In y Ga 1- x - y P for the development of solid-state photomultiplier analogs

Characterizing intrinsic defects is an essential step in evaluating materials for novel optoelectronic device applications. For photomultipliers, suppressing dark currents is critical, but a tradeoff is present between maximizing the band gap while remaining sensitive to the wavelength of interest and minimizing the incorporation of fresh defects by growing not-yet-optimized alloys. We present a series of capacitance-based measurements, including deep-level optical spectroscopy, steady-state photocapacitance, and illuminated capacitance-voltage, on photodiodes with lightly n-type Al x In y Ga 1−x−y P absorber regions. Several deep levels are identified, including one near the midgap. Although the inclusion of aluminum increases each trap density by approximately 10×, the hole capture cross-section also appears to decrease, suggesting that Shockley–Read–Hall dark currents may be suppressed. These materials may be good candidates for the development into silicon photomultiplier analogs with a wider bandgap for scintillator applications.

III–V↗

DOE OSTI2026

HOLISMOKES XIX

We present imaging and spectroscopic observations of supernova SN 2025wny, associated with the lens candidate PS1 J0716+3821. Photometric monitoring from the Lulin and Maidanak observatories confirms multiple point-like images, consistent with SN 2025wny being strongly lensed by two foreground galaxies. Optical spectroscopy of the brightest image with the Nordic Optical Telescope and the University of Hawaii 88-inch Telescope allowed us to determine the redshift to be z SN = 2.008 ± 0.001, based on narrow absorption lines originating in the interstellar medium of the supernova host galaxy. At this redshift, SN 2025wny shows a very high rest-frame UV flux and broad spectral features even weeks after the explosion, which is consistent with superluminous supernovae of Type I. We find a high ejecta temperature and depressed spectral lines compared to other similar objects. We also measured, for the first time, the redshift of the fainter of the two lens galaxies (the ‘perturber’) to be z p = 0.375 ± 0.001, which is fully consistent with the DESI spectroscopic redshift of the main deflector at z d = 0.3754. Thus, SN 2025wny represents the first confirmed galaxy-scale strongly lensed supernova with time delays likely in the range of days to weeks, as judged from the image separations. This makes SN 2025wny suitable for cosmography, offering a promising new system for independent measurements of the Hubble constant. Following a tradition in the field of strongly lensed supernovae, we give SN 2025wny the nickname SN Winny.

Taubenberger, Stefan↗

NASA NTRS1991

Optical and ultraviolet spectroscopy of three F + B binary stars

Optical and ultraviolet spectroscopy is presented for three F + B objects that are members of the first group of strongly interacting, F II + B systems. The data obtained confirm that HD 59771, HD 242257, and CoD -30 5135 are all binary star systems consisting of a luminous F-type component and a B star. Strong, variable H-alpha emission is seen in all the stars. It is found that the UV spectrum of HD 59771 resembles the spectrum of HD 207739. CoD -30 5135 has the most dramatic mid-UV spectrum seen among the scores of observed cool + hot star systems.

Bopp, Bernard W.↗

NASA NTRS1997

The Nature of the Optical "Jets" in the Spiral Galaxy NGC 1097

We present new observations of the jet features in the barred spiral galaxy NGC 1097, including optical spectroscopy of the brightest jet features, two-color optical imagery, new VLA mapping at 327 MHz, and archival 1.4 GHz VLA data reprocessed for improved sensitivity. No optical emission lines appear to an equivalent width limit of 15-30 A (depending on the line wavelength). The jets are uniformly blue, with B - V = 0.45 for the two well-observed jets R1 and R2. No radio emission from the jets is detected at either frequency; the 327-MHz data set particularly stringent limits on "fossil" emission from aging synchrotron electrons. The morphology of the jets is shown to be inconsistent with any conical distribution of emission enhanced by edge-brightening; their combination of transverse profile and relative narrowness cannot be reproduced with cone models. The optical colors, lack of radio emission, and morphology of the features lead us to conclude that they are tidal manifestations, perhaps produced by multiple encounters of the small elliptical companion NGC 1097A with the disk of NGC 1097. We present photometric and morphological comparisons to the tail of NGC 465 1, which is similar in scale and morphology to the northeast "dogleg" feature R1 in NGC 1097.

Wehrle, Ann E.↗

NASA NTRS1997

The Nature of the Optical Jets in the Spiral Galaxy NGC 1097

spiral↗

NASA NTRS1990

Electron-impact spectroscopy

The methods of electron impact spectroscopy and cross section measurements are discussed and compared to optical spectroscopy. A brief summary of the status of this field and the available data is given.

Trajmar, S.↗

NASA NTRS1990

A preliminary optical study of the intergalactic H I cloud in Virgo

A possible optical counterpart of the intergalactic H I cloud in the Virgo Cluster, discovered by Giovanelli and Haynes, is reported. It is a blue, 17 mag, irregular galaxy, and it is located near the peak of the H I emission. No other optical objects which can be obviously associated with the cloud are found in the area from which the H I emission was detected, and no extended, low surface brightness counterpart is seen in these data. If the irregular galaxy is really associated with the H I cloud, the overall properties of the system would be similar to those of a number of other known gas-rich dwarf galaxies. However, the system has an unusually large hydrogen to light ratio, and a large spatial extent, and it could be dynamically young. Optical spectroscopy is needed in order to establish whether the proposed optical counterpart is indeed correct, and if so, to determine the stage of its chemical evolution.

Djorgovski, S.↗