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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

From models to reality: a systematic review on simulated and measured residential heat pump energy savings

High-performance HVAC solutions are central to residential energy management. A substantial share of these are electric, reversible-cycle systems, with heat pumps representing the largest portion of current and near-term adoption. This review synthesizes peer-reviewed and grey literature on residential space heating and cooling heat pumps. The academic literature is dominated by modeling (73.8%), with limited field measurement (13.1%). Grey literature from United States serve as a supplemental resource providing measured savings. Conversions from electric-resistance heating consistently show the largest site energy reductions, while oil/propane baselines yield moderate savings, and gas baseline scenario often deliver small and region-dependent savings. This study cross-checks the grey literature measured data with simulation data filtered from the ResStock dataset. The comparison indicates a discrepancy between simulations and measured data: simulated site EUIs are typically lower than measured EUIs, but percentage energy savings fall in similar ranges, implying simulations capture directional effects while underestimating energy use. Factors associated with variability and model–measurement differences include system characterization and control representation (e.g., backup heat engagement, thermostat/setpoint strategies, commissioning/installation quality), occupant behavior, weather normalization, metering scope, and envelope characterization. This paper also outlines the proposed methodology for comparing simulation and measured data for heat pumps. It emphasizes the metrics used for comparison and units harmonization, building characteristics matching, and compact metadata are needed for simulations to match measured data. The proposed methodology is expected to improve the credibility of simulated savings as measured evidence grows.

Yu, Lili↗
DOE OSTI2021

Intrinsic nanostructure induced ultralow thermal conductivity yields enhanced thermoelectric performance in Zintl phase Eu2ZnSb2

Abstract The Zintl thermoelectric phase Eu 2 ZnSb 2 has a remarkable combination of high mobility and low thermal conductivity that leads to good thermoelectric performance. The key feature of this compound is a crystal structure that has a Zn-site with a 50% occupancy. Here we use comparison of experimental thermal conductivity measurements and first principles thermal conductivity calculations to characterize the thermal conductivity reduction. We find that partial ordering, characterized by local order, but Zn-site disorder on longer scales, leads to an intrinsic nanostructuring induced reduction in thermal conductivity, while retaining electron mobility. This provides a direction for identifying Zintl compounds with ultralow lattice thermal conductivity and good electrical conductivity.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Observation of electron orbital signatures of single atoms within metal-phthalocyanines using atomic force microscopy

Resolving the electronic structure of a single atom within a molecule is of fundamental importance for understanding and predicting chemical and physical properties of functional molecules such as molecular catalysts. However, the observation of the orbital signature of an individual atom is challenging. We report here the direct identification of two adjacent transition-metal atoms, Fe and Co, within phthalocyanine molecules using high-resolution noncontact atomic force microscopy (HR-AFM). HR-AFM imaging reveals that the Co atom is brighter and presents four distinct lobes on the horizontal plane whereas the Fe atom displays a “square” morphology. Pico-force spectroscopy measurements show a larger repulsion force of about 5 pN on the tip exerted by Co in comparison to Fe. Our combined experimental and theoretical results demonstrate that both the distinguishable features in AFM images and the variation in the measured forces arise from Co’s higher electron orbital occupation above the molecular plane. The ability to directly observe orbital signatures using HR-AFM should provide a promising approach to characterizing the electronic structure of an individual atom in a molecular species and to understand mechanisms of certain chemical reactions.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Surface electrons in inverted layers of p-HgCdTe

Anodic oxide passivation of p-type HgCdTe generates an inversion layer. Extremely high Hall mobility data for electrons in this layer indicated the presence of a two-dimensional electron gas. This is verified by use of the Shubnikov-de Haas effect from 1.45 to 4.15 K. Data are extracted utilizing a numerical second derivative of dc measurement. Three sub-bands are detected. Their relative occupancies are in excellent agreement with theory and with experimental results obtained on anodic oxide as accumulation layers of n-type HgCdTe. The effective mass derived is comparable to what was expected.

Schacham, Samuel E.↗
NASA NTRSDate not supplied

Clutter Assessment for an Autonomous Multi-Agent Search Mission

This paper presents a method for evaluating the amount of clutter in a region where autonomous vehicles in a multi-agent system must operate based on LIDAR point cloud measurements. The point cloud is used to generate an occupancy grid which is then projected onto a 2D plane of vehicle motion, constituting an image. A series of Gaussian radial basis functions (GRBFs) is created, each centered at an occupied pixel in a 2D image, and summed together to form the clutter field. The clutter field is a representation of the density and permeability of the space at each coordinate. The clutter field is then approximated such that iso-clutter contours are simple geometric objects so that intelligent machine assets can easily query the distance between them and any given point in an environment. In this way, agents are able to determine whether to enter into or steer away from areas of interest. Each vehicle has a clutter threshold representing the clutter value of the space in which it can safely maneuver. The iso-clutter contour corresponding to a vehicle’s clutter threshold is treated as the boundary of an obstacle to be avoided. A simulation is presented where a multi-agent system is tasked with persistent observation of a cluttered area. Each vehicle in the simulation has a different clutter threshold. The vehicles use a potential field-based guidance algorithm, and an allocation of vehicles to specific regions of the space emerges.

multi-agent↗
DOE OSTI2021

Structure of the electrical double layer at the ice–water interface

The surface of ice in contact with water contains sites that undergo deprotonation and protonation and can act as adsorption sites for aqueous ions. Therefore, an electrical double layer should form at this interface and existing models for describing the electrical double layer at metal oxide–water interfaces should be able to be modified to describe the surface charge, surface potential, and ionic occupancy at the ice–water interface. I used a surface complexation model along with literature measurements of the zeta potential of ice in brines of various strength and pH to constrain equilibrium constants. I then made predictions of ion site occupancy, surface charge density, and partitioning of counterions between the Stern and diffuse layers. The equilibrium constant for cation adsorption is more than 5 orders of magnitude larger than the other constants, indicating that this reaction dominates even at low salinity. Deprotonated OH sites are predicted to be slightly more abundant than dangling O sites, consistent with previous work. Surface charge densities are on the order of ±0.001 C/m2 and are always negative at the moderate pH values of interest to atmospheric and geophysical applications (6–9). In this pH range, over 99% of the counterions are contained in the Stern layer. This suggests that diffuse layer polarization will not occur because the ionic concentrations in the diffuse layer are nearly identical to those in the bulk electrolyte and that electrical conduction and polarization in the Stern layer will be negligible due to reduced ion mobility.

Daigle, Hugh (ORCID:0000000260628321)↗
DOE OSTI2023

Comparing Occupant Light Exposure in Factory and Office Spaces

There is an increasing desire to provide healthy workplace environments that better serve people while minimizing the impact on the planet. Building recommendations help designers to incorporate the latest research and best practices, but translating research studies conducted in different settings to broader recommendations is challenging. This is particularly true for lighting, with researchers continuing to learn more about circadian, neuroendocrine, and neurobehavioral responses to light. The recommendations are regularly adjusting to incorporate the latest research as well as feedback from practitioners implementing these recommendations. There remains a need to better document the actual light exposure that people experience over the course of a day and across seasons, so that researchers can better understand the influence of light on people and recommendations can be refined. Thankfully, advances in sensor technology are making this more possible than ever. PNNL collaborated with ETC Inc. to understand actual occupant light exposure in factory and office spaces at ETC’s Headquarters in Middleton, WI. The primary building at ETC headquarters opened in 2004 and houses approximately 800 employees that contribute to central business functions, customer support, research and development, as well as the company’s primary 60,000 ft2 manufacturing facility. Vertical light exposure measurements including electric light and daylight were recorded in factory, research and development, and office work areas at occupant eye height. This document will focus on lighting measurements collected in six factory and office locations across work location, season, and time of day. Ultimately, detailed lighting measurements can be coupled with employee surveys to support development of satisfactory work environments.

42 ENGINEERING↗
DOE OSTI2023

Electron paramagnetic resonance dose measurements in teeth of tissue donors to the United States Transuranium and Uranium Registries

Abstract The United States Transuranium and Uranium Registries (USTUR) is a research program that studies actinide biokinetics in occupationally exposed individuals with known intakes of these elements. Electron paramagnetic resonance (EPR) in tooth enamel was applied to reconstruct external doses of nine USTUR registrants. Only in two cases there is a reasonable agreement between the EPR-measured dose and the worksite external dose record. For two registrants, high EPR doses can be explained by possible cancer radiotherapy. For the remaining five cases, EPR doses significantly exceed official occupational doses with no plausible explanation for the observed discrepancy. More EPR dose measurements need to be done to explain this anomaly.

Environmental Sciences & Ecology↗
DOE OSTI2026

Kondo effect in ferromagnetic quantum critical CeRh 6 ⁢Ge 4

The mechanism of a pressure-induced quantum critical point in the heavy fermion ferromagnet CeRh 6 ⁢Ge 4 has attracted interest, as ferromagnetic quantum criticality in a clean itinerant Ce compound is typically avoided. The localized versus itinerant character of the 4⁢𝑓 electrons is a key aspect for understanding this behavior. We investigated the electronic structure of the 4⁢𝑓 shell in CeRh 6 ⁢Ge 4 using core-level photoelectron and x-ray absorption spectroscopy, demonstrating the hybridization of Ce 4⁢𝑓 with the conduction electrons. Linearly polarized x-ray absorption reveals a temperature-dependent linear dichroism consistent with the crystal-electric-field sequence as inferred from the static susceptibility. This dichroism cannot be described by an ionic full-multiplet model alone, but is reproduced by including the Kondo effect within a single-impurity Anderson model in the noncrossing approximation. The Kondo effect mixes higher-lying crystal-field states into a resulting multiorbital ground state with 4⁢𝑓 occupancy, 𝑛 𝑓 ∼ 0.9. Deviations at low temperatures between the measured linear dichroism and calculated dichroism suggest an orbital-dependent Kondo effect. A scenario in which there is a multiorbital ground state and orbital-dependent Kondo hybridization should be a starting point for a model of pressure-induced criticality in CeRh 6 ⁢Ge 4 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2019

Evidence-based Approach to Establish Space Suit Carbon Dioxide Limits

A literature survey was conducted to assess if published data (evidence) could help inform a space suit carbon dioxide (CO2) limit. The search identified more than 120 documents about human interaction with elevated CO2. Until now, the guiding philosophy has been to drive space suit CO2 as low as reasonably achievable. NASA’s EVA Office requested an evidencebased approach to support a new generation of exploration-class extravehicular activity (EVA) space suits. Specific literature data about CO2 are not available for EVA in microgravity because EVA is an operational activity and not a research platform. However, enough data from groundbased research are available to facilitate a consensus of expert opinion on space suit CO2 limits. The compilation of data in this report can answer many but not all concerns about the consequences of hypercapnic exercise in a space suit. Inspired partial pressure of CO2 (PICO2) and not dry-gas partial pressure of CO2 (PCO2) is the appropriate metric for hypercapnic dose to establish space suit CO2 limits. The reduction of inspired gas partial pressures by saturation of the inspired gases with water vapor at 37°C is a significant factor under conditions of hypobaric space suit operation. Otherwise healthy EVA astronauts will exhibit wide variability in responses to acute hypercapnia while at rest and during exercise. What is clear from the literature is the absence of prospective (objective) accept or reject criteria for CO2 exposure in general, and no such criteria exist for operating a space suit. There is no absolute “Gold Standard” for an acceptable acute hypercapnic limit, just a gradual decrease in performance as CO2 increases. Acceptable CO2 exposure limits are occupation, situation (learned or novel tasks), and personspecific. Investigators who measured hypercapnic physiology rarely correlated those changes to neurocognitive symptoms, and those that measured hypercapnic neurocognition rarely correlated those changes with physiology. Some answers about changes in neurocognition and functional EVA performance during hypercapnic exercise in a space suit await new research.

Conkin, Johnny↗
DOE OSTI2020

Are low-cost sensors good enough for IAQ controls?

This study used laboratory testing to evaluate low-cost (about $\$ 200$ US) IAQ monitors that measured PM2.5 to determine if they are suitable for controlling IAQ for ventilation or air cleaning systems. Current Indoor Air Quality (IAQ) standards and approaches to minimizing pollutants depend almost exclusively on using dilution with outdoor air for some generic, continuously generated contaminant (e.g., ASHRAE Standard 62.2-2016). Some standards include measurement of CO 2 (e.g., EN 13779 standard (CEN, 2007) and NEN 8088 (NEN, 2011)) – however this is not because CO 2 itself is a pollutant of concern, but rather because it can be used as an occupancy indicator or as something that correlates with bioeffluents. Ideally, we would like to measure contaminant concentrations directly and ventilate to control their concentration within acceptable limits. This would ensure that concentrations do not got too high (as they can if emission rates exceed our assumptions) and also allow for ventilation reductions, and resulting energy savings, if concentrations are low. Until recently, it was impractical to consider direct contaminant control in residential (and many commercial) spaces due to the high cost and maintenance requirements for monitoring equipment. In the past couple of years low-cost sensors have been developed for some contaminants of concern – the greatest example of which is for particles. These sensors have been incorporated into low-cost (<$250 US) IAQ monitors. Finally, this has opened up the possibility of direct control of ventilation (and filtration systems) by sensing particles. However, it is important to evaluate these monitors to determine if their results are sufficiently good to control a ventilation system.

47 OTHER INSTRUMENTATION↗
NASA NTRS1986

NASA seat experiment and occupant responses

Results of the crash test of a remotely piloted transport aircraft instrumented to measure a NASA energy-absorbing transport seat are given. Human tolerance limits to acceleration and a dynamic response index model are discussed. It was found that the acceleration levels at the rear of the airplane were quite low and were below the stroking threshold of the NASA EA-seat. Therefore, dummies in the standard and EA-seat responded approximately the same. All longitudinal accelerations were quite low for the primary impact with very low forces measured in the lap belts. The vertical (spineward) acceleration levels measured in the dummies were also relatively low and very survivable from an impact tolerance standpoint. The pilot with an 18 G peak acceleration received by far the highest vertical acceleration and could have possibly received slight spinal injury.

Fasanella, E. L.↗
DOE OSTI2022

Constraining the galaxy-halo connection of infrared-selected unWISE galaxies with galaxy clustering and galaxy-CMB lensing power spectra

We present the first detailed analysis of the connection between galaxies and their dark matter halos for the unWISE galaxy catalog—a full-sky, infrared-selected sample built from WISE data, containing over 500 million galaxies. Using unWISE galaxy-galaxy autocorrelation and Planck CMB lensing-galaxy cross-correlation measurements down to 10 arcmin angular scales, we constrain the halo occupation distribution (HOD), a model describing how central and satellite galaxies are distributed within dark matter halos, for three unWISE galaxy samples at mean redshifts z ¯ ≈ 0.6 , 1.1, and 1.5, assuming a fixed cosmology at the best-fit Planck Λ CDM values. We constrain the characteristic minimum halo mass to host a central galaxy, M min HOD = 1.8 3 - 1.63 + 0.41 × 10 12 M ⊙ / h , 5.22 - 4.80 + 0.34 × 10 12 M ⊙ / h , 6.60 - 1.11 + 0.30 × 10 13 M ⊙ / h and the mass scale at which one satellite galaxy per halo is found, M 1 ' = 1.1 3 - 0.70 + 0.32 × 10 13 M ⊙ / h , 1.18 - 1.11 + 0.30 × 10 13 M ⊙ / h , 1.23 - 1.17 + 0.14 × 10 14 M ⊙ / h for the unWISE samples at z ¯ ≈ 0.6 , 1.1, and 1.5, respectively. We find that all three samples are dominated by central galaxies, rather than satellites. Using our constrained HOD models, we infer the effective linear galaxy bias for each unWISE sample, and find that it does not evolve as steeply with redshift as found in previous perturbation-theory-based analyses of these galaxies. We discuss possible sources of systematic uncertainty in our results, the most significant of which is the uncertainty on the galaxy redshift distribution. Our HOD constraints provide a detailed, quantitative understanding of how the unWISE galaxies populate the underlying dark matter halo distribution. These constraints will have a direct impact on future studies employing the unWISE galaxies as a cosmological and astrophysical probe, including measurements of ionized gas thermodynamics and dark matter profiles via Sunyaev-Zel’dovich and lensing cross-correlations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Real time side-by-side experimental validation of energy and comfort performance of a zero net energy retrofit package for small commercial buildings

Making buildings zero-net energy (ZNE) is one of the major strategies for achieving carbon emission reduction goals. For this strategy to be successful, it entails a very significant reduction in energy use – 50% or more. In small commercial buildings, however, owners and building management teams usually have limited resources for identifying, analyzing, and procuring appropriate retrofit measures for reducing such use. An approach to overcome this limitation is the development of bundles of energy efficiency measures that can be presented to building owners/operators as a comprehensive package. The research presented in this paper focuses on an experimental evaluation of the impacts of a retrofit package developed for small office buildings in California. Performing this evaluation in a full-scale whole-building integrated systems test facility allowed a side-by-side evaluation in real time, against a reference case, of the impact of the retrofit package not only on energy use but also on visual and thermal comfort. Here, the retrofit package evaluated is comprised of a combination of HVAC, lighting (including daylighting), and plug load measures. The evaluation occurred at different times of the year in order to account for seasonal variations in environmental conditions, including solar angles and weather. The experimental facility allowed testing for two different façade orientations: south and west. Results show that the proposed ZNE retrofit package can save significant amounts of energy for small commercial buildings. During cooling-prevalent periods, total energy savings were 65% for south orientation and 68% for west orientation; during heating-prevalent periods total energy savings were 22% for south orientation and 25% for west orientation. Measurements indicate that the ZNE retrofit package resulted in small but not very significant changes in comfort levels for building occupants.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2011

Planning Image-Based Measurements in Wind Tunnels by Virtual Imaging

Virtual imaging is routinely used at NASA Ames Research Center to plan the placement of cameras and light sources for image-based measurements in production wind tunnel tests. Virtual imaging allows users to quickly and comprehensively model a given test situation, well before the test occurs, in order to verify that all optical testing requirements will be met. It allows optimization of the placement of cameras and light sources and leads to faster set-up times, thereby decreasing tunnel occupancy costs. This paper describes how virtual imaging was used to plan optical measurements for three tests in production wind tunnels at NASA Ames.

Kushner, Laura Kathryn↗
DOE OSTI2021

A framework for estimating the energy-saving potential of occupant behaviour improvement

Energy-related occupant behaviour in buildings has demonstrated considerable energy-saving potential. However, the current modelling method of occupant behaviour does not give sufficient considerations on the implementation difficulty of behaviour and provide a holistic map from survey data to various behaviour models. This article proposes a holistic survey-and-simulation-based framework for estimating the energy-saving potential of occupant behaviour improvement. In the framework, seven typical categories of occupant behaviour models are identified based on the survey results. According to the implementation difficulty, the models are integrated into four behaviour styles (baseline, wasteful, moderate and austere) to represent different levels of energy-saving consciousness of occupants. Based on a case study with a nationwide survey in Singapore, there are remarkable energy savings potential if occupant behaviour is improved; the building energy consumption can be reduced by up to 9.5% with the moderate behaviour improvement, and up to 21.0% with the aggressive behaviour improvement. The simulation results accord well with the measured results within a reasonable range of deviation. The framework can be applied to estimate the energy-saving potential of occupant behaviour improvement in a building with affordable cost, and the findings can inform a behaviour improvement programme with effective and efficient measures.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Photometric Objects Around Cosmic Webs (PAC) Delineated in a Spectroscopic Survey. IV. High-precision Constraints on the Evolution of the Stellar–Halo Mass Relation at Redshift z < 0.7

Taking advantage of the Photometric objects Around Cosmic webs method developed in Paper I, we measure the excess surface density $\overline{n}$ 2 w p of the photometric objects around spectroscopic objects down to stellar masses 10 8.0 M ⊙ , 10 9.2 M ⊙ , and 10 9.8 M ⊙ in the redshift ranges of z s < 0.2, 0.2 < z s < 0.4, and 0.5 < z s < 0.7, respectively, using data from the DESI Legacy Imaging Surveys and spectroscopic samples from the Sloan Digital Sky Survey (i.e., the Main, LOWZ, and CMASS samples). We model the measured in an N-body simulation, using the abundance matching method, and we constrain the stellar–halo mass relations (SHMRs) in the three redshift ranges to percent levels. With the accurate modeling, we demonstrate that the stellar mass scatter for a given halo mass is nearly a constant, and that the empirical form of Behroozi et al. describes the SHMR better than the double-power-law form at low mass. Our SHMR accurately captures the downsizing of massive galaxies from z s = 0.7, while it also indicates that small galaxies are still growing faster than their host halos. The galaxy stellar mass functions (GSMFs) from our modeling are in perfect agreement with the model-independent measurements in Paper III, although the current work extends the GSMFs to a much smaller stellar mass. Based on the GSMFs and the SHMRs, we derive the stellar mass completeness and halo occupation distributions for the LOWZ and CMASS samples, which are useful for correctly interpreting their cosmological measurements, such as galaxy–galaxy lensing and redshift space distortion.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Occupational and dietary differences in hydroxylated and methoxylated PBDEs and metals in plasma from Puget Sound, Washington, USA region volunteers

BACKGROUND: Electronic waste (E-waste) recycling is a rapidly growing occupation in the USA with the potential for elevated exposure to flame retardants and metals associated with electronic devices. We previously measured polybrominated diphenyl ethers (PBDEs) in plasma from E-waste workers and found them similar to non-E-waste workers. OBJECTIVES: This study focused on structurally related PBDE derivatives, the hydroxylated (OH-PBDEs) and methoxylated (MeO-PBDEs) forms along with metals known to occur in E-waste. Humans can metabolize PBDEs and some MeO-PBDEs into OH-PBDEs, which is a concern due to greater health risks associated with OH-PBDEs METHODS: We measured 32 different OH-PBDEs and MeO-PBDEs in plasma samples provided by 113 volunteers living in the greater Puget Sound region of Washington State, USA. We measured 14 metals in a subset of 10 E-waste and 10 non-E-waste volunteers. Volunteers were classified based on occupational and dietary habits: work outdoors and weekly consume = 5 seafood servings (outdoor), electronic waste recycling (E-waste) or non-specific indoor occupations (indoor). A two-week food consumption diary was obtained from each volunteer prior to blood sampling. RESULTS: OH-PBDEs were detected in all volunteers varying between 0.27 – 102 ng/g/g-lipid. The MeO-PBDEs were detected in most, but not all volunteers varying between 0 – 60.4 ng/g/g-lipid. E-waste recyclers had OH-PBDE and MeO-PBDE plasma levels that were similar to the indoor group. The outdoor group had significantly higher levels of MeO-PBDEs, but not OH-PBDEs. Comparison of plasma concentrations of BDE-47 with its known hydroxylated metabolites suggested OH-PBDE levels were likely determined by biotransformation and at least two subpopulations identified differing in their apparent rates of OH-PBDE formation. The metals analysis indicated no significant differences between E-waste workers and non-E-waste workers. CONCLUSIONS: Our results indicate E-waste workers do not have elevated plasma levels of these contaminants relative to non-E-waste workers with similar dietary habits.

Schultz, Irvin↗