DOE OSTI2013
Historical data show that heavy metals (including mercury) were released from Y -12 National Security Complex (NSC) at Oak Ridge, Tennessee, to the surrounding environments during its operation in 1950's. Studies have also shown that metals accumulated in the soil, rock, and groundwater, and are, at the present time, sources of contamination to nearby rivers and creeks (e.g., East Fork Poplar Creek, Bear Creek). For instance, mercury (Hg), zinc (Zn), cadmium (Cd) and lead (Pb) have been found and reported on the site groundwater. The groundwater type at the site is Ca-Mg-HCO{sub 3}. This paper presents a modeling application of PHREEQC, a model that simulates geochemical processes and couples them to flow and transport settings. The objective was to assess the capability of PHREEQC to simulate the transport of ionic species in groundwater at Oak Ridge, Tennessee; data were available from core holes and monitoring wells over a 736-m distance, within 60-300 m depths. First, predictions of the transport of major ionic species (i.e., Ca{sup 2+} and Mg{sup 2+}) in the water were made between monitoring wells and for GW-131. Second, the model was used to assess hypotheses under two scenarios of transport for Zn, Cd, Pb and Hg, in Ca-Mg-HCO{sub 3} water, as influenced by the following solid-liquid interactions: a) the role of ion exchange and b) the role of both ion exchange and sorption, the latter via surface complexation with Fe(OH){sub 3}. The transport scenario with ion exchange suggests that significant ion exchange is expected to occur for Zn, Cd and Pb concentrations, with no significant impact on Hg, within the first 100 m. Predictions match the expected values of the exchange coefficients relative to Ca{sup 2+} and Mg{sup 2+} (e.g., K{sub Ca/Zn} = K{sub Ca/Cd} > K{sub Ca/Pb} > K{sub Ca/Hg}). The scenario with both ion exchange and sorption does affect the concentrations of Zn and Cd to a small extent within the first 100 m, but does more meaningfully reduce the concentration of Pb, within the same distance, and also decreases the concentration of Hg in between core holes. Analysis of the above results, in the light of available literature on the ions of this study, does fundamentally support the capability of PHREEQC to predict the transport of major ions in a groundwater setting; it also generally supports the hypothesized role of ion exchange and sorption. The results indicate the potential of the model as a tool in the screening, selection and monitoring of remediation technologies for contaminated groundwater sites. (authors)
54 ENVIRONMENTAL SCIENCES↗