Possible Catalytic Effects of Ice Particles on the Production of NOx by Lightning Discharges
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This work studied the feasibility of using Helmholtz resonator cavities embedded in low-pressure-turbine (LPT) airfoils to (1) reduce core noise by damping acoustic modes; (2) use the synthetic jets produced by the liner hole acoustic oscillations to improve engine efficiency by maintaining turbulent attached flow in the LPT at low-Reynolds-number cruise conditions; and (3) reduce engine nitrogen oxide emissions by lining the internal cavities with materials capable of catalytic conversion. Flat plates with embedded Helmholtz resonators, designed to resonate at either 3000 or at 400 Hz, were simulated using computational fluid dynamics. The simulations were conducted for two inlet Mach numbers, 0.25 and 0.5, corresponding to Reynolds numbers of 90 000 and 164 000 based on the effective chordwise distance to the resonator orifice. The results of this study are (1) the region of acoustic treatment may be large enough to have a benefit; (2) the jets may not possess sufficient strength to reduce flow separation (based on prior work by researchers in the flow control area); and (3) the additional catalytic surface area is not exposed to a high velocity, so it probably does not have any benefit.
In support of the National Climate Assessment (NCA) program, satellite Lightning Imaging Sensor (LIS) data is used to estimate lightning nitrogen oxides (LNOx) production over the southern portion of the conterminous US. The total energy of each flash is estimated by analyzing the LIS optical event data associated with each flash (i.e., event radiance, event footprint area, and derivable event range). The LIS detects an extremely small fraction of the total flash energy; this fraction is assumed to be constant apart from the variability associated with the flash optical energy detected across the narrow (0.909 nm) LIS band. The estimate of total energy from each flash is converted to moles of LNOx production by assuming a chemical yield of 10(17) molecules Joule(-1). The LIS-inferred variable LNOx production from each flash is summed to obtain total LNOx production, and then appropriately enhanced to account for LIS detection efficiency and LIS view time. Annual geographical plots and time series of LNOx production are provided for a 16 year period (1998-2013).
Lightning nitrogen oxides (LNOx) indirectly influences our climate since these molecules are important in controlling the concentration of ozone (O3) and hydroxyl radicals (OH) in the atmosphere [Huntrieser et al., 1998]. In support of the National Climate Assessment (NCA) program, satellite Lightning Imaging Sensor (LIS; Christian et al. [1999]; Cecil et al. [2014]) data is used to estimate LNOx production over the southern portion of the conterminous US for the 16 year period 1998-2013.
An experimental and computational study was conducted to evaluate the performance and emissions characteristics of a candidate Lean Direct Injection (LDI) combustor configuration with a mix of simplex and airblast injectors. The National Combustion Code (NCC) was used to predict the experimentally measured EINOx emissions for test conditions representing low power, medium power, and high-power engine cycle conditions. Of the six cases modeled with the NCC using a reduced-kinetics finite-rate mechanism and lagrangian spray modeling, reasonable predictions of combustor exit temperature and EINOx were obtained at two high-power cycle conditions.
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The focus of this analysis is on lightning-generated nitrogen oxides (LNOx) and their distribution for two thunderstorms observed during the Deep Convective Clouds and Chemistry (DC3) field campaign in May-June 2012. The Weather Research and Forecasting Chemistry (WRF-Chem) model is used to perform cloud-resolved simulations for the May 29-30 Oklahoma severe convection, which contained one supercell, and the June 6-7 Colorado squall line. Aircraft and ground-based observations (e.g., trace gases, lightning and radar) collected during DC3 are used in comparisons against the model-simulated lightning flashes generated by the flash rate parameterization schemes (FRPSs) incorporated into the model, as well as the model-simulated LNOx predicted in the anvil outflow. Newly generated FRPSs based on DC3 radar observations and Lightning Mapping Array data are implemented in the model, along with previously developed schemes from the literature. The results of these analyses will also be compared between storms to investigate which FRPSs were most appropriate for the two types of convection and to examine the variation in the LNOx production. The simulated LNOx results from WRF-Chem will also be compared against other previously studied mid-latitude thunderstorms.
Lightning generates relatively large but uncertain quantities of nitrogen oxides, critical precursors for ozone and hydroxyl radical (OH), the primary tropospheric oxidants. Lightning nitrogen oxide strongly influences background ozone and OH due to high ozone production efficiencies in the free troposphere, effecting small but non-negligible contributions to surface pollutant concentrations. Lightning globally contributes 3-4 ppbv of simulated annual-mean policy-relevant background (PRB) surface ozone, comprised of local, regional, and hemispheric components, and up to 18 ppbv during individual events. Feedbacks via methane may counter some of these effects on decadal time scales. Lightning contributes approximately 1 percent to annual-mean surface particulate matter, as a direct precursor and by promoting faster oxidation of other precursors. Lightning also ignites wildfires and contributes to nitrogen deposition. Urban pollution influences lightning itself, with implications for regional lightning-nitrogen oxide production and feedbacks on downwind surface pollution. How lightning emissions will change in a warming world remains uncertain.
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The TROPOspheric Monitoring Instrument (TROPOMI) is used to derive top-down NOXemissions for twolarge power plants and three megacities in North America. Wefirst re-process the vertical column NO2with an improved airmass factor to correct for a known systematic low bias in the operational retrieval near urban centers. For the two power plants,top-down NOXemissions agree to within 10% of the emissions reported by the power plants. We then derive top-down NOXemissions rates for New York City, Chicago, and Toronto, and compare them to projected bottom-up emissions inventories. Inthis analysis of 2018 NOXemissions, wefind a +22% overestimate for New York City, a−21% underestimate in Toronto, andgood agreement in Chicago in the projected bottom-up inventories when compared to the top-down emissions. Top-downNOXemissions also capture intraseasonal variability, such as the weekday versus weekend effect (emissions are +45% larger onweekdays versus weekends in Chicago). Finally, we demonstrate the enhanced capabilities of TROPOMI, which allow us toderive a NOXemissions rate for Chicago using a single overpass on July 7, 2018. The large signal-to-noise ratio of TROPOMI iswell-suited for estimating NOXemissions from relatively small sources and for sub-seasonal timeframes.
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