Investigation of the kinetics of crystallization of molten binary and ternary oxide systems Quarterly status report, 1 Jun. - 31 Aug. 1967
Crystallization kinetics of molten binary and ternary oxide systems
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Crystallization kinetics of molten binary and ternary oxide systems
Crystal growth kinetics of molten oxides containing yttria or lanthana
Reaction kinetics of crystallized molten binary and ternary oxide glass making compositions
Cl gas solubility in molten lead chloride- potassium chloride mixtures, temperature and KCl concentration dependence and existence of exchange process
Molten salts thermodynamic properties, discussing pure salts corresponding states and binary mixtures conformal solution theories, using model ionic melt
Thermal conductivity of molten alkali nitrates, obtaining law of corresponding states, discussing hot-wire transient method
Glass composition preparation and research on crystallization kinetics of molten binary and ternary oxide systems of glass
Compatibility tests of molten uranium with tungsten and tungsten-1.5 percent hafnium
Kinetics of crystallization of molten binary and ternary oxide systems
Kinetics of crystallization of molten binary and ternary oxide systems
Electrochemical behavior of the aluminum electrode in molten salt electrolytes
Anolyte studies of magnesium electrode in molten mixtures of lithium chloride, potassium chloride, and magnesium chloride
Electrochemistry of freshly generated titanium surfaces and stress corrosion cracking in aqueous solutions and in molten salts
Al electrodes in molten salt electrolytes, investigating electrochemical kinetics by polarization measurements
Molten salt battery has been developed with theoretical energy density of 5.2 j/kg (650 W-h/lb). Battery, which operates at 150 C, can be used in primary mode or as rechargeable battery. Battery has aluminum anode and chlorine cathode. Electrolyte is mixture of AlCl3, NaCl, and some alkali metal halide such as KCl.
Chondrule-like spherules were formed from individual freely falling subcooled droplets of alumina, enstatite, forsterite, enstatite-albite and forsterite-albite mixtures that had been melted with a focused continuous CO2 laser beam. Their textures (rimmed, excentro-radial, barred, glassy) are strikingly similar to those of many meteoritic chondrules. It is suggested that the phenomena associated with rapid crystallization from the supercooled melt are responsible for the various textures observed in the artificial spherules as well as in similar meteoritic chondrules. It is suggested that the textures observed would also result from rapid crystallization of relatively slowly cooling molten droplets that may have been produced in larger scale events, including condensation from a nebula of solar composition and solidification in an ambient medium of high temperature.
A molten salt system based on Al- and Cl2 carbon electrodes, with an AlCl3 alkali chloride eutectic as electrolyte, offers promise as a rechargeable, high energy density battery which can operate at a relatively low temperature. Electrode kinetic studies showed that the electrode reactions at the Al anode were rapid and that the observed passivation phenomena were due to the formation at the electrode surface of a solid salt layer resulting from concentration changes on anodic or cathodic current flow. It was established that carbon electrodes were intrinsically active for chlorine reduction in AlCl3-alkali chloride melts. By means of a rotating vitreous carbon disk electrode, the kinetic parameters were determined.
The response of molten metals to mechanical and thermal driving forces in nominal and microgravity is analyzed both theoretically and experimentally. The magnitude and transient behavior of internal fluid circulations, surface deformations, and globule trajectories and their effects on solidification in the Skylab electron beam sphere forming and metals melting experiments are determined. The theoretical approach consists of dimensional analysis of the governing differential equations. Experimental aspects include evaluation of specimens from terrestrial, KC-135 research aircraft, and actual Skylab tests and analysis of high speed movies taken during the melting processes. Several gravity variations and gravity independent results were successfully predicted based on expected differences and similarities in fluid dynamics.