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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

The perplexing continuum slope of Mars: Effects of thin ferric coatings and viewing geometry

The experiment discussed here was designed to constrain interpretations of variations in continuum slope variations which define several spectral annuli on the flanks of Olympus Mons, observed in the Imaging Spectrometer (IMS) data. The IMS Olympus Mons data reveal that the rings, seen as alternating brighter and darker reflectance in Viking data, correspond to annuli of alternating shallower and steeper continuum slope. At least three factors contributing to continuum slope are identified: ferric coating thickness, viewing geometry, and surface texture. Because the Olympus Mons spectral annuli were observed at nearly constant backscatter geometries in the ISM data, with only slight viewing variations due to the volcanoe's flank slopes, the difference of continuum slope between annuli probably cannot be explained by viewing geometry alone. This suggests that the variation of some fundamental surface characteristics, such as ferric dust/rind thickness or surface texture, is the cause of the Olympus Mons special annuli observed in the ISM imaging spectrometer data.

Fischer, Erich M.↗
NASA NTRS1994

The 3.2-3.6 micron spectra of monoceros R2/IRS-3 and Elias 16

We have obtained 3.2-3.6 micron spectra, with a resolution lambda/delta-lambda approximately 750, of the protostar Mon R2/IRS-3 and of Elias 16, a background K giant behind the Taurus molecular cloud. A feature at 3,482 microns (2872/cm), with a full width at half-maximum of 0.09 microns (76/cm), is clearly seen in Mon R2/IRS-3. This feature is not detected in Elias 16. The 3.482 micron feature in Mon R2/IRS-3 is similar to a feature at 3.466-3.478 microns (2875-2885/cm) detected by Allamandola et al. in four protostars and attributed by these authors to a CH stretch in hydrocarbons dominated by sp3-bonded carbon. Neither Mon R2/IRS-3 nor Elias 16 shows absorption at 3.540 microns (2825/cm), which has been detected in two of the four protostars observed by Allamandola et al. and attributed by them to CH3OH ice. Our limit on CH3OH ice toward Elias 16 is compared to models of gas-grain chemistry in dark clouds. Our results confirm those of Allamandola et al. that at this resolution the 3.4 micron absorption due to dust in molecular clouds has very different spectral structure than that due to dust in the diffuse interstellar medium.

Sellgren, K.↗
NASA NTRS1998

CNO Processing in Massive Algol Binaries

This program, used ultraviolet observations by the IUE Observatory along with other tools to search for abundance anomalies indicative of CNO processing in the secondary (mass-donating) stars of six interacting binary systems. Related IUE-based activities were also undertaken under this grant. Two Supplements to the grant were awarded. Supplement No. 1 was in connection with the NASA Grant Supplements for Education program, for a workshop for elementary school science teachers. The two sessions of the workshop were held October 24 and November 14, 1992. Eighteen school teachers from central Pennsylvania, grades 1-7, participated in the workshop, for which they received one unit of in-service training credit from their Intermediate Unit. Supplement No. 2 was awarded for additional IUE observations of the Algol stars V342 Aql and TU Mon. Observations of all six candidate stars were made with IUE, and attention was narrowed to TU Mon in particular, for which further IUE observations were made using Director's discretionary time. Observations of TU Mon were also carried out with the Voyager UV spectrometers, and optical spectroscopy was obtained on several occasions at Penn State's Black Moshannon Observatory. Photometric data on TU Mon were acquired by Dr. Paul Etzel at Mt. Laguna Observatory (MLO). McGouldrick was employed part-time during the Fall academic semester to assist in accessing the IUE Archive, and to correlate data on some cataclysmic variables and related objects that were observed with both IUE and the Voyager Far Ultraviolet Spectrometers. Approximately 21 relevant binary systems were observed with the Voyager UVS over the past decade, and a paper is being prepared for eventual publication that will serve as an index to the UVS data archive on these stars, providing observation dates, mean count rates in far and extreme UV bands, and a discussion of the relevant literature concerning the far UV behavior (including correlative IUE information from the archive and the literature). Much of the activity under the grant was in connection with V342 Aquilae, a 3.39 day Algol system thought to be in a state of rapid mass transfer. The goal was to combine optical and ultraviolet data to arrive at a robust, informative interpretation of this unique binary system. Complete orbital phase coverage of V342 Aql was obtained spectroscopically and photometrically.

Wade, Richard A.↗
NASA NTRS2001

Mars Flyer Rocket Propulsion Risk Assessment: ARC Testing

This report describes the investigation of a 10-N, bipropellant thruster, operating at -40 C, with monomethy1hydrazine (MMH) and 25% nitric oxide in nitrogen tetroxide (MON-25). The thruster testing was conducted as part of a risk reduction activity for the Mars Flyer, a proposed mission to fly a miniature airplane in the Martian atmosphere. Testing was conducted using an existing thruster, designed for MMH and MON-3 propellants. MON-25 oxidizer was successfully manufactured from MON-3 by the addition of nitric oxide. The thruster was operated successfully over a range of propellant temperatures (-40 to 21 C and feed pressures (6.9 to 20.7 kPa). The thruster hardware was always equal or lower than the propellant temperature. Most tests were 30- and 60-second durations, with 600- and 1200-second duration and pulse testing also conducted. When operating at -40 C, the mixture ratio of the thruster shifted from the nominal value of 1.65 to about 1.85, probably caused by an increase in MMH viscosity, with a corresponding reduction in MMH flowrate. Specific impulse at - 40 C (at nominal feed pressures) was 267 sec, while performance was 277 sec at 21 C. This difference in performance was due, in part, to the mixture ratio shift.

Source record↗
NASA NTRS2003

The Seasonal Behavior of Water Ice Clouds in the Tharsis and Valles Marineris Regions of Mars: Mars Orbiter Camera Observations

The Mars Orbiter Camera (MOC) was used to obtain global maps of the Martian surface. The maps used were acquired between March 15, 1999 (LS = 110 ) and July 31, 2001 (L(sub s) = 110), corresponding to approximately one and a quarter martian years. In this work we focused on water ice clouds associated with the surface features of Olympus Mons, Ascraeus Mons, Pavonis Mons, Arsia Mons, Alba Patera, and the Valles Marineris canyon system. Using these data, we have made three types of quantitative measurements to characterize the cloud activity: 1) cloud area and location, 2) cloud height, and 3) cloud optical depth. We have also searched for short period variations in the cloud areas.

J L Benson↗
NASA NTRS2003

Application of THEMIS Data to an Investigation of a Long Lava Flow in the Tharsis Montes Region of Mars

The Tharsis region of Mars has long been known for the numerous lava flows radiating from the Tharsis Montes shield volcanoes. A 480-km-long flow southwest of Ascraeus Mons has been the subject of previous investigations using Viking and MGS data. The new data currently being obtained with the Thermal Emission Imaging System (THEMIS) on the Mars Odyssey spacecraft can shed new light on the volcanology of Martian lava flows, illustrated in this paper by two THEMIS images of the previously studied flow near Ascraeus Mons. The lava flow examined is on the western flank of the topographic saddle between the Ascraeus Mons and Pavonis Mons shield volcanoes. Flow morphology in the dust-covered Tharsis region is revealed in exquisite detail in daytime IR and VIS images from THEMIS, which will aid in documentation and analysis of lava flow features on Mars and improve constraints for volcanic modeling.

Zimbelman, J. R.↗
NASA NTRS2021

Multiwavelength Observations of the RV Tauri Variable System U Monocerotis: Long-term Variability Phenomena That Can Be Explained by Binary Interactions with a Circumbinary Disk

We present an X-ray through submillimeter observations of the classical RV Tauri(RVb-type)variable U Mon, apost-asymptotic giant branch(AGB)binary with a circumbinary disk(CBD). Our SMA observations indicate aCBD diameter of550 au. Our XMM-Newton observations make U Mon thefirst RV Tauri variable detected inX-rays. The X-ray emission is characteristic of a hot plasma(∼10 MK), withLX=5×1030erg s−1, and weconsider its possible origin from U Mon, its companion, and/or binary system interactions. Combining DASCHand AAVSO data, we extend the time-series photometric baseline back to the late 1880s andfind evidence thatU Mon has secular changes that appear to recur on a timescale of∼60 yr, possibly caused by a feature in the CBD.From literature radial velocities wefind that the binary companion is a∼2MeA-type main-sequence star. Theorientation of the binary’s orbit lies along our line of sight(ω=95°), such that apastron corresponds to photometricRVb minima, consistent with the post-AGB star becoming obscured by the near side of the CBD. In addition, wefind the size of the inner-CBD hole(∼4.5–9au)to be comparable to the binary separation, implying that one orboth stars may interact with the CBD at apastron. The obscuration of the post-AGB star implicates the companionas the likely source of the enhanced Hαobserved at RVb minima and of the X-ray emission that may arise fromaccreted material.

Laura D Vega↗
NASA NTRSDate not supplied

The geologic evolution of Imdr Regio: a possible active hot spot on Venus

Imdr Regio is a large igneous rise that extends approximately from 35ºS-50ºS and 195ºE-225ºE between the plains of Helen, Nsomeka and Wawalag Planitiae. Imdr Regio was classified as a volcano-dominated igneous rise with a minimum-maximum diameter of 1200-1400 km and a swell height of 1.6 km. The major volcanic feature in Imdr Regio is Idunn Mons (46.5ºS/214.5ºE), a large volcano. Studies using the 1 mm (derived) surface emissivity from the Venus Express mission of the volcanic flows surrounding Idunn Mons suggest that high emissivity values in the volcano flanks are related to relatively unweathered basaltic rock and therefore indicative of a recent or even ongoing volcanic activity in Idunn Mons. Building on this previous work, here we present the first preliminary geologic map of Imdr Regio, characterize the different types of volcanism besides Idunn Mons, and their relationship with the rift and other regional structures, and discuss its geologic evolution.

I. López↗
DOE OSTI2022

Economic analysis of the benefits to petroleum refiners for low carbon boosted spark ignition biofuels

A refinery modeling framework is developed to estimate the benefits of blending high-quality biofuels directly with refinery gasoline components for attaining a premium grade fuel (also termed as Co-Optima Boosted SI gasoline here). Our results change the paradigm of bio-blendstocks (BBs) being competitors to fossil components, by identifying opportunities for refineries to add value to their product slate, from some favorable BB properties. This potential value can be characterized by calculating the breakeven value (BEV), as defined down below. The proposed modeling framework incorporates extensive data from (1) projected product over the next few decades, (2) crude oil and refinery products pricing, and (3) fuel specifications. The complete refinery models serve as a basis for assessing the value of biofuels, assuming profitability remains the same for representative petroleum refinery configurations. Our assessment showed wide range of variation of biofuels BEV from $\$$20-$\$$120/bbl, within the considered blending level and crude prices. Further, the BEV was correlated with the fuel octane ratings such as octane numbers (research, RON and motor octane numbers, MON) and both antiknock index (AKI, average of RON and MON) and sensitivity (S, difference between RON and MON), with a slightly higher correlation with the sensitivity. However, the expected decrease in gasoline demand for the upcoming years could negatively impact biofuels demand and value, in a business-as-usual scenario. Our analysis also showed a more valuable bio-blendstocks incorporation in smaller refineries since they can enhance the capabilities for producing specialty, high-value fuels/products, and introduce high octane-barrels into otherwise constrained blending operations. Additional implications towards refiners include opportunities to rebalance operations, access to high-value fuel markets, and synchronization with broader transportation industry trends. Furthermore, results indicate the value of Co-Optima boosted spark ignition (BSI) efficiency gains can extend to refiners to incentivize decarbonization and diversified feedstock production.

09 BIOMASS FUELS↗
DOE OSTI2020

Identifying and Tuning the In Situ Oxygen-Rich Surface of Molybdenum Nitride Electrocatalysts for Oxygen Reduction

Rigorous in situ studies of electrocatalysts are required to enable the design of higher performing materials. Nonplatinum group metals for oxygen reduction reaction (ORR) catalysis containing light elements such as O, N, and C are known to be susceptible to both ex situ and in situ oxidation, leading to challenges associated with ex situ characterization methods. We have previously shown that the bulk O content plays an important role in the activity and selectivity of Mo–N catalysts, but further understanding of the role of composition and morphological changes at the surface is needed. Here, we report the measurement of in situ surface changes to a molybdenum nitride (MoN) thin film under ORR conditions using grazing incidence X-ray absorption and reflectivity. We show that the half-wave potential of MoN can be improved by ~90 mV by potential conditioning up to 0.8 V versus RHE. Utilizing electrochemical analysis, dissolution monitoring, and surface-sensitive X-ray techniques, we show that under moderate polarization (0.3–0.7 V vs RHE) there is local ligand distortion, O incorporation, and amorphization of the MoN surface, without changes in roughness. Furthermore, with a controlled potential hold procedure, we show that the surface changes concurrent with potential conditioning are stable under ORR relevant potentials. Conversely, at higher potentials (≥0.8 V vs RHE), the film incorporates O, dissolves, and roughens, suggesting that in this higher potential regime, the performance enhancements are due to increased access to active sites. Density functional theory calculations and Pourbaix analysis provide insights into film stability and O incorporation as a function of potential. These findings coupled with in situ electrochemical surface-sensitive X-ray techniques demonstrate an approach to studying nontraditional surfaces in which we can leverage our understanding of surface dynamics to improve performance with the rational, in situ tuning of active sites.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Phylogenetic Diversity and Mycotoxin Potential of Emergent Phytopathogens Within the Fusarium tricinctum Species Complex

Recent studies on multiple continents indicate members of the Fusarium tricinctum species complex (FTSC) are emerging as prevalent pathogens of small-grain cereals, pulses, and other economically important crops. These understudied fusaria produce structurally diverse mycotoxins, among which enniatins (ENNs) and moniliformin (MON) are the most frequent and of greatest concern to food and feed safety. Herein a large survey of fusaria in the Fusarium Research Center and Agricultural Research Service culture collections was undertaken to assess species diversity and mycotoxin potential within the FTSC. A 151-strain collection originating from diverse hosts and substrates from different agroclimatic regions throughout the world was selected from 460 FTSC strains to represent the breadth of FTSC phylogenetic diversity. Evolutionary relationships inferred from a five-locus dataset, using maximum likelihood and parsimony, resolved the 151 strains as 24 phylogenetically distinct species, including nine that are new to science. Of the five genes analyzed, nearly full-length phosphate permease sequences contained the most phylogenetically informative characters, establishing its suitability for species-level phylogenetics within the FTSC. Fifteen of the species produced ENNs, MON, the sphingosine analog 2-amino-14,16-dimethyloctadecan-3-ol (AOD), and the toxic pigment aurofusarin (AUR) on a cracked corn kernel substrate. Interestingly, the five earliest diverging species in the FTSC phylogeny (i.e., F. iranicum, F. flocciferum, F. torulosum, and Fusarium spp. FTSC 8 and 24) failed to produce AOD and MON, but synthesized ENNs and/or AUR. Moreover, our reassessment of nine published phylogenetic studies on the FTSC identified 11 additional novel taxa, suggesting this complex comprises at least 36 species.

Plant Sciences↗
DOE OSTI2023

Artificial Neural Network Models for Octane Number and Octane Sensitivity: A Quantitative Structure Property Relationship Approach to Fuel Design

Octane sensitivity (OS), defined as the research octane number (RON) minus the motor octane number (MON) of a fuel, has gained interest among researchers due to its effect on knocking conditions in internal combustion engines. Compounds with a high OS enable higher efficiencies, especially within advanced compression ignition engines. RON/MON must be experimentally tested to determine OS, requiring time, funding, and specialized equipment. Thus, predictive models trained with existing experimental data and molecular descriptors (via quantitative structure-property relationships (QSPRs)) would allow for the preemptive screening of compounds prior to performing these experiments. Here, the present work proposes two methods for predicting the OS of a given compound: using artificial neural networks (ANNs) trained with QSPR descriptors to predict RON and MON individually to compute OS (derived octane sensitivity (dOS)), and using ANNs trained with QSPR descriptors to directly predict OS. Twenty-five ANNs were trained for both RON and MON and their test sets achieved an overall 6.4% and 5.2% error, respectively. Twenty-five additional ANNs were trained for both dOS and OS; dOS calculations were found to have 15.3% error while predicting OS directly resulted in 9.9% error. A chemical analysis of the top QSPR descriptors for RON/MON and OS is conducted, highlighting desirable structural features for high-performing molecules and offering insight into the inner mathematical workings of ANNs; such chemical interpretations study the interconnections between structural features, descriptors, and fuel performance showing that connectivity, structural diversity, and atomic hybridization consistently drive fuel performance.

09 BIOMASS FUELS↗
DOE OSTI2021

Effect of biochanin A on the rumen microbial community of Holstein steers consuming a high fiber diet and subjected to a subacute acidosis challenge

Subacute rumen acidosis (SARA) occurs when highly fermentable carbohydrates are introduced into the diet, decreasing pH and disturbing the microbial ecology of the rumen. Rumen amylolytic bacteria rapidly catabolize starch, fermentation acids accumulate in the rumen and reduce environmental pH. Historically, antibiotics ( e . g ., monensin, MON) have been used in the prevention and treatment of SARA. Biochanin A (BCA), an isoflavone produced by red clover ( Trifolium pratense ), mitigates changes associated with starch fermentation ex vivo . The objective of the study was to determine the effect of BCA on amylolytic bacteria and rumen pH during a SARA challenge. Twelve rumen fistulated steers were assigned to 1 of 4 treatments: HF CON (high fiber control), SARA CON, MON (200 mg d -1 ), or BCA (6 g d -1 ). The basal diet consisted of corn silage and dried distiller’s grains ad libitum . The study consisted of a 2-wk adaptation, a 1-wk HF period, and an 8-d SARA challenge (d 1–4: 40% corn; d 5–8: 70% cracked corn). Samples for pH and enumeration were taken on the last day of each period (4 h). Amylolytic, cellulolytic, and amino acid/peptide-fermenting bacteria (APB) were enumerated. Enumeration data were normalized by log transformation and data were analyzed by repeated measures ANOVA using the MIXED procedure of SAS. The SARA challenge increased total amylolytics and APB, but decreased pH, cellulolytics, and in situ DMD of hay (P < 0.05). BCA treatment counteracted the pH, microbiological, and fermentative changes associated with SARA challenge (P < 0.05). Similar results were also observed with MON (P < 0.05). These results indicate that BCA may be an effective alternative to antibiotics for mitigating SARA in cattle production systems.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Prediction of Research/Motor Octane Number and Octane Sensitivity Using Artificial Neural Networks

Octane sensitivity (OS), dfined as the research octane number (RON) minus the motor octane number (MON) of a given fuel, has gained interest among researchers due to its apparent ffect on knocking conditions in internal combustion engines. Compounds with a high OS enable higher efficiencies, especially with respect to advanced compression ignition engines. RON/MON must be experimentally tested to determine OS; however, the experimental methods utilized require a substantial amount of time, a significant monetary investment, and specialized equipment. To this end, predictive computational models trained with existing experimental data and molecular properties would allow for the preemptive screening of compounds prior to performing these experiments. The present work proposes two methods for predicting the OS of a given compound: using artficial neural networks (ANNs) trained with quantitative structure-property relationship (QSPR) descriptors to predict RON and MON individually to compute OS from RON/MON predictions (derived octane sensitivity, dOS), and using an ANN trained with QSPR descriptors to directly predict OS. ANNs trained to predict RON and MON achieved test set root-mean-square errors (RMSEs) of 10.499 and 7.551 respectively. dOS calculations were found to have a test set RMSE of 6.432 while predicting OS directly resulted in a test set RMSE of 7.019, showing it is more bene cial to obtain OS from RON/MON predictions than predicting it directly. Furthermore, relationships between individual QSPR descriptors and RON/MON/OS are discussed, highlighting correlations between specfic molecular features and these properties.

09 BIOMASS FUELS↗
DOE OSTI2021

Octane Index Applicability over the Pressure-Temperature Domain

Modern boosted spark-ignition (SI) engines and emerging advanced compression ignition (ACI) engines operate under conditions that deviate substantially from the conditions of conventional autoignition metrics, namely the research and motor octane numbers (RON and MON). The octane index (OI) is an emerging autoignition metric based on RON and MON which was developed to better describe fuel knock resistance over a broader range of engine conditions. Prior research at Oak Ridge National Laboratory (ORNL) identified that OI performs reasonably well under stoichiometric boosted conditions, but inconsistencies exist in the ability of OI to predict autoignition behavior under ACI strategies. Instead, the autoignition behavior under ACI operation was found to correlate more closely to fuel composition, suggesting fuel chemistry differences that are insensitive to the conditions of the RON and MON tests may become the dominant factor under these high efficiency operating conditions. This investigation builds on earlier work to study autoignition behavior over six pressure-temperature (PT) trajectories that correspond to a wide range of operating conditions, including boosted SI operation, partial fuel stratification (PFS), and spark-assisted compression ignition (SACI). A total of 12 different fuels were investigated, including the Co-Optima core fuels and five fuels that represent refinery-relevant blending streams. It was found that, for the ACI operating modes investigated here, the low temperature reactions dominate reactivity, similar to boosted SI operating conditions because their PT trajectories lay close to the RON trajectory. Additionally, the OI metric was found to adequately predict autoignition resistance over the PT domain, for the ACI conditions investigated here, and for fuels from different chemical families. This finding is in contrast with the prior study using a different type of ACI operation with different thermodynamic conditions, specifically a significantly higher temperature at the start of compression, illustrating that fuel response depends highly on the ACI strategy being used.

02 PETROLEUM↗
NASA NTRS1977

Some Martian Volcanic Features as Viewed from the Viking Orbiters

A summary is presented of the results of some new observations on Martian volcanic features made from the Viking orbiters. Most of these observations are concerned with the Tharsis and Alba regions. The youth, size, and style of the volcanic features in these areas render them particularly susceptible to analysis. Excellent coverage was also acquired of Apollinaris Patera. It has many features of the Tharsis shields, with a cliff around its circumference and a large central caldera. Olympus Mons and its vicinity are examined, taking into account the shield of Olympus Mons, mass movement features along the basal scarp, the basal plains, the relative ages of Olympus Mons and the basal plains, and grooved terrain.

Carr, M. H.↗
NASA NTRS1983

A nebula around Nova BT Monocerotis

H-alpha observations of Nova BT Mon obtained on December 15, 1981 using an 800x800-pixel CCD detector on the double spectrograph of the 5-m Hale telescope at Palomar Observatory are reported. The reciprocal dispersion at H-alpha was 6.04 A/pixel and the angular scale along the 1.0-arcsec-wide east-west slit was 0.58 arcsec/pixel; resolution of the combined, processed image is about 12 A. A ring-shaped nebular emission with a center displaced slightly from the stellar image and an expansion distance to BT Mon of about 1800 pc was detected. The velocity diameter is found to be about 1500 km/sec along the ridge line and 2100 km/sec along the 10-unit contour. The mass of the visible nebula is estimated as 0.00003 solar mass, similar to the BT Mon ejection mass determined by Schaefer and Patterson (1983).

Marsh, T. R.↗
NASA NTRS1984

Discovery of solar system-size halos around young stars

Near-infrared speckle interferometric observations of five pre-main-sequence stars reveal a core-halo structure around two of these stars: HL Tau and R Mon. The halo light distribution is shown to arise from scattered light from small circumstellar particles. Halo sizes of 320 x 200 AU (alpha x delta FWHM) and 1300 x 1300 AU are deduced for HL Tau and R Mon, respectively, and the halo light is substantially bluer than the stellar light. The minimum mass of small particles in the scattering regions is comparable to the earth's mass in HL Tau and ten times greater in R Mon. Mass loss from the stars is almost certainly insufficient to produce the halo matter. The halos probably consist of relatively slowly moving matter bound gravitationally to the stars. From the size and mass of the circumstellar matter, it appears likely that these halos are in the early stage in the formation of planet-forming disks around the young stars.

Beckwith, S.↗