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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Negative ions in the coma of Comet Halley

The detection of negatively charged cometary ions in the inner coma of Comet Halley is reported. These ions are observed in three broad mass peaks at 7-19, 22-65, and 85-110 AMU, with densities reaching greater than about 1/cu cm, about 0.05/cu cm, and about 0.04/cu cm, respectively, at a distance of about 2300 km from the nucleus. The ion species thought to be present include O(-), OH(-), C(-), CH(-), CN(-) and heavier complex CHO molecular ions. As negative ions are easily destroyed by solar radiation at about 1 AU, an efficient production mechanism, so far unidentified, is required to account for the observed densities. The detection of negative ions in the coma near 1 AU implies that negative ions should also be present in similar neutral gas and dust environment farther away from the sun. If the negative-ion densities are large enough, they could play an important part in physical processes such as radiative transfer or charge exchange.

Chaizy, P.↗
NASA NTRS1991

Effect of the rotational-vibrational excitation on molecular diameters

The kinetic molecular diameters of rotationally and vibrationally excited diatomic molecules and molecular ions are derived as functions of the rotational and vibrational quantum numbers of the molecules. Typical molecular diameters are studied in two cases: in low-temperature gas, where the molecular diameter is independent of the degree of rotational-vibrational excitation of the molecules, and in high-temperature gas, where the molecular diameter depends on the degree of rotational-vibrational excitation of the molecules. The rotational-vibrational excitation of molecules is shown to have a meaningful effect on the collisional properties of gases. The effect is stronger in gases of weakly-bound molecules.

Kang, S. H.↗
NASA NTRS1986

Mass and energy balance of the cold Io torus

A new model of the cold Io torus is described. Ions and energy are injected into the system by independent processes so that the mass balance is isolated from the energy balance. The primary source of energy is local ionization and acceleration of hot pickup ions resulting from charge exchange between thermal ions and an extended cloud of Iogenic sulfur and oxygen atoms. The primary energy loss mechanism of the plasma is collisionally excited line emission at optical wavelengths. The primary ion source is radial diffusion inward from the hot torus on a time scale of 140-710 days. The primary ion loss mechanism is a novel two-step enhanced recombination mechanism involving charge exchange between thermal ions and an extended cloud of neutral SO2 molecules, followed by rapid dissociative recombination of the resultant molecular ion. The model provides a self-consistent solution which reconciles a number of diverse observations with known physical processes.

Moreno, M. A.↗
NASA NTRS2013

A Global Atmospheric Model of Meteoric Iron

The first global model of meteoric iron in the atmosphere (WACCM-Fe) has been developed by combining three components: the Whole Atmosphere Community Climate Model (WACCM), a description of the neutral and ion-molecule chemistry of iron in the mesosphere and lower thermosphere (MLT), and a treatment of the injection of meteoric constituents into the atmosphere. The iron chemistry treats seven neutral and four ionized iron containing species with 30 neutral and ion-molecule reactions. The meteoric input function (MIF), which describes the injection of Fe as a function of height, latitude, and day, is precalculated from an astronomical model coupled to a chemical meteoric ablation model (CABMOD). This newly developed WACCM-Fe model has been evaluated against a number of available ground-based lidar observations and performs well in simulating the mesospheric atomic Fe layer. The model reproduces the strong positive correlation of temperature and Fe density around the Fe layer peak and the large anticorrelation around 100 km. The diurnal tide has a significant effect in the middle of the layer, and the model also captures well the observed seasonal variations. However, the model overestimates the peak Fe+ concentration compared with the limited rocket-borne mass spectrometer data available, although good agreement on the ion layer underside can be obtained by adjusting the rate coefficients for dissociative recombination of Fe-molecular ions with electrons. Sensitivity experiments with the same chemistry in a 1-D model are used to highlight significant remaining uncertainties in reaction rate coefficients, and to explore the dependence of the total Fe abundance on the MIF and rate of vertical transport.

meteoric inputfunction↗
NASA NTRS1987

Thermal ion complexities observed within the Spacelab 2 bay

Examples of prominent thermal ion composition variations characteristic of the Shuttle environment as observed from within the open cargo bay on the Spacelab 2 mission are discussed. Although the prominent ionization source is the inflow of the ambient plasma, water ions of Shuttle origin were present throughout the mission, and there was evidence for a local source of molecular ions NO(+) and/or O(2+) which also exist in the ionosphere. Bursts in the fluxes of these contaminant species were frequently observed coincident with thruster firings, while O(+) depletions or enhancements could occur depending on the scattering geometry. These effects bring into question whether reliable ambient thermal ion measurements can be made from the vicinity of such vehicles. The presence of significant inflows of contaminant ions into the bay within the Shuttle wake also indicates that Shuttle emissions play a significant role in the evolution of its wake structure.

Grebowsky, J. M.↗
NASA NTRS1993

Ion measurements during Pioneer Venus reentry: Implications for solar cycle variation of ion composition and dynamics

During the final, low solar activity phase of the Pioneer Venus (PV) mission, the Orbiter Ion Mass Spectrometer (OIMS) measurements found all ion species, in the midnight-dusk sector, reduced in concentration relative to that observed at solar maximum. Molecular ion species comprised a greater part of the total ion concentration as O(+) and H(+) had the greatest depletions. The nightside ionospheric states were strikingly similar to the isolated solar maximum 'disappearing' ionospheres. Both are very dynamic states characterized by a rapidly drifting plasma and 30-100 eV superthermal O(+) ions.

Grebowsky, J. M.↗
NASA NTRS1993

Ion Measurements During Pioneer Venus Reentry: Implications for Solar Cycle Variation of Ion Composition and Dynamics

During the final, low solar activity phase of the Pioneer Venus mission, the Orbiter Ion Mass Spectrometer measurements found all ion species, in the midnight-dusk sector, reduced in concentration relative to that observed at solar maximum. Molecular ion species comprised a greater part of the total ion concentration as O(+) and H(+) had the greatest depletions. The nightside ionospheric states were strikingly similar to the isolated solar maximum "disappearing" ionospheres. Both are very dynamic states characterized by a rapidly drifting plasma and 30-100 eV superthermal O(+) ions.

Grebowsky, J. M.↗
NASA NTRS1974

Formation of O3/+/ by the reaction of metastable O2/+/ ions with O2

The high resolution of the photoionization mass spectrophotometer was utilized to resolve some doubts about the participating species in the reaction of metastable oxygen molecular ions with oxygen molecules to yield ozone ions and oxygen radicals. It is found from inspection of the appearance potential of the ozone ion that an a4 Pi-excited state is responsible for the formation of ozone near the appearance potential of these lines.

Ajello, J. M.↗
NASA NTRS1980

A thermalized ion explosion model for high energy sputtering and track registration

A velocity spectrum of neutral sputtered particles as well as a low resolution mass spectrum of sputtered molecular ions was measured for 4.74 MeV F-19(+2) incident of UF4. The velocity spectrum is dramatically different from spectra taken with low energy (keV) bombarding ions, and is shown to be consistent with a hot plasma of atoms in thermal equilibrium inside the target. A thermalized ion explosion model is proposed for high energy sputtering which is expected to describe track formation in dielectric materials. The model is shown to be consistent with the observed total sputtering yield and the dependence of the yield on the primary ionization rate of the incident ion.

Seiberling, L. E.↗
NASA NTRS1975

Confirmation of interstellar N2H/+/

The proposed identification of the triplet of interstellar lines recently discovered at 93.174 GHz with the molecular ion N2H(+) is confirmed by resolving the predicted hyperfine structure of the inner nitrogen nucleus in the narrow-line molecular source OMC-2 in the Orion Nebula. The hyperfine constants of N2H(+) are derived from the observational data, and the rest center frequency of the J = 1-0 rotational transition is determined. It is noted that the full width at half-maximum of the weakest line (F sub 1 = 0-1) is only 230 kHz (0.74 km/sec in radial velocity), making it the narrowest molecular emission line (excluding maser point sources) thus far observed in the direction of a H II region or IR source.

Thaddeus, P.↗
NASA NTRS2001

In Situ Measurements of Meteoric Ions

Metal ions found in the atmosphere above 60 km are the result of incoming meteoroid atmospheric ablation. Layers of metal ions are detected by sounding rocket in situ mass spectrometric sampling in the 80 to 130 km region, which coincides with the altitude region where meteors are observed. Enhancements of metal ion concentrations occur during meteor showers. Even outside of shower periods, the metal ion altitude profiles vary from measurement to measurement. Double layers are frequent at middle latitudes. More than 40 different meteoric atomic and molecular ions, including isotopes, have been detected. Atmospheric metal ions on average have an abundance that matches chrondritic material, the same composition as the early solar system. However there are frequently local departures from this composition due to differential ablation, species dependent chemistry and mass dependent ion transport. Metal ions react with atmospheric O2, O, O3, H2O and H2O2 to form oxygenated and hydrogenated ionic compounds. Metal atomic ions at high altitudes have long lifetimes. As a result, these ions, in the presence of Earth's magnetic field, are transported over long distances by upper atmospheric winds and ionospheric electric fields. Satellite measurements have detected metal ions as high as, approximately 1000 km and have revealed circulation of the ions on a global scale.

Grebowsky, Joseph M.↗
NASA NTRS1980

A study of the cleft region using synoptic ionospheric plasma data obtained by the polar orbiting satellites Aeros-B and Isis-2

The concentrations of O(+) and NO(+) in the dayside high-latitude cleft region of the ionosphere are investigated based on synoptic particle and plasma measurements obtained by the polar orbiting Aeros-B and Isis-2 satellites. At a time when the orbital planes of the satellites are almost at right angles to each other, three maxima in ion temperature are observed, with two of them accompanied by an increased electron temperature and electron density irregularities, and the density of the molecular ions NO(+) and O2(+) is found to increase at the expense of O(+) density. Results are discussed in terms of a theory relating perpendicular electric fields to oxygen atom reaction rates. Systematic analysis of the Aeros data base reveals 14 additional instances of O(+) to NO(+) conversion, with a large variety of forms and structures reflecting the complex structure and dynamics of the high-latitude dayside ionosphere.

Kist, R.↗
NASA NTRS1984

Interactions between the orbiting Space Shuttle and the ionosphere

This paper presents an analysis of interactions between the Space Shuttle Orbiter and the ionosphere based on thermal plasma data obtained from a Spherical Retarding Potential Analyzer (SRPA) and a Langmuir Probe (LP) flown on the third Space Shuttle flight (STS-3) in March 1982. While previous work on spacecraft-plasma interactions has dealt with wake effects, the present work deals with effects that are seen in ram conditions that have not been previously discussed. One observation is a higher degree of plasma turbulence than has been reported from unmanned spacecraft measurements that manifests itself as a frequency component at 2.2 kHz in the SRPA signal. Also seen are unusually high number densities of what appear to be ions with a mass of at least 30 or 32 amu and a temperature in the range 2000-3000 K. Coincident with the enhanced molecular ion species, the temperature of the thermal electrons is seen elevated to above 5000 K. It is hypothesized that these measurements are evidence for a plasma instability resulting from the motion of the outgassing Orbiter through the ionosphere.

Siskind, D. E.↗
NASA NTRS1996

Products of Dissociative Recombination in the Ionosphere

SRI International undertook a novel experimental measurement of the product states formed by dissociative ro-combination (DR) of C2(+), NO(+), and N2(+) as a function of both electron energy and reactant ion vibrational level. For these measurements we used a recently developed experimental technique for measuring dissociation product distributions that allows both the branching ratios to be accurately determined and the electronic and ro-vibrational state composition of the reactant ions to be specified. DR is the dominant electron loss mechanism in all regions of the ionosphere. In this process, electron attachment to the molecular ion produces an unstable neutral molecule that rapidly dissociates.

Cosby, Philip↗
NASA NTRS1993

Equatorial ion composition, 140-200 km, based on Atmosphere Explorer E data

We have used in situ measurements of ion composition and horizontal winds, taken from equatorial orbiting Atmosphere Explorer E in eccentric orbit during 1975-1976 to investigate the bottomside ionosphere at altitudes 140-200 km. Representative daytime altitude profiles of ionization were stable against wide variations in horizontal wind patterns. Special features that sometimes appeared in the structured nightside ionization were apparent ion composition waves, intermediate layers of enhanced ionization, and ionization depletions similar to equatorial ionization bubbles. Apparent ion composition waves displayed a horizontal wave length of about 650 km. Enhanced layers of ionization appeared to be newly separated from the bottomside midnight F layer; its ions were primarily NO(+) and O2(+) without significant densities of metallic ions, an indication that metallic ions are not required to produce the layers at altitudes above 140 km. Equatorial ionization depletions were observed at lower altitudes than previously reported and displayed molecular ion depletions as well as O(+) depletions.

Miller, N. J.↗
NASA NTRS1989

Fast molecular shocks. I - Reformation of molecules behind a dissociative shock

The physical and chemical processes that operate in the cooling gas behind a fast, dissociative, single-fluid shock propagating in a dense interstellar cloud are discussed. The treatment extends previous theoretical work on fast molecular shocks by including the effects of the conversion of Ly-alpha photons into radiation of the two-photon continuum and into H2 Lyman band emission lines, the effects of CO photodissociation following line absorption, and the formation and destruction of molecules containing the elements nitrogen, silicon, and sulphur, and of the complex hydrocarbons. Abundance profiles for the molecular species of interest are presented. After molecular hydrogen begins to reform, by means of gas phase and grain surface processes, the neutral species OH, H2O, O2, CO, CN, HCN, N2, NO, SO, and SiO reach substantial abundances. The molecular ions HeH(+), OH(+), SO(+), CH(+), H2(+), and H3(+), are produced while the gas is still hot and partially ionized. Emissions from them provide a possible diagnostic probe of fast molecular shocks.

Neufeld, David A.↗
NASA NTRS1990

Unidentified ions in comets

Optical spectra were taken of comets Halley, West, and Brorsen-Metcalf in the wavelength region 3200 to 6400 A. These spectra were offset approximately 10(exp -5) to 10(exp -6) km tailward from the nucleus so that the features detected were all ions with the exception of a very small residual C2 emission at 5165 A. The full labeled tail spectrum of comet Halley is given. While most of the features detected are attributable to CO(+), H2O(+), CO2(+), CH(+), and OH(+), there are three moderately strong bands in the spectra of comets Halley and Brorsen-Metcalf which remain unidentified. These features were not detected in comet West. All three spectra in the 4800 to 5400 A region are presented, Brorsen-Metcalf is the gassiest of the three. The central wavelengths of the unidentified features are 4930, 5300, and 6000 A. In an effort to identify the ions responsible for these features as well as to confirm previous identifications, laboratory spectra of ions were compared with the comet spectra. H2O(+) and CO(+) are known to have extensive emission in the 4800 to 6200 A region. Therefore, the possibility that these unidentified features are due to H2O(+) and CO(+) was investigated. A search for the following bands was conducted: H2O(+) (11-0), H2O(+) (12-0), H2O(+) (13-1), CO(+) (1-1), and CO(+) (0-0). CO(+) (1-1) and CO(+) (0-0) were previously identified and are present in all the spectra examined. The H2O(+) (11-0) band was identified. Comparison of the H2O(+) (11-0) synthetic spectrum with comet Brorsen-Metcalf data is presented. The relative fluxes of the blended H2O(+) lines in the synthetic spectrum match those of the cometary data. After eliminating H2O(+) and CO(+) as significant contributors to the stronger unidentified features, spectra of ions which are not yet identified in the optical region of comets were compared to the data. These ions are NH(+), CS(+), and C2(+). None of these ions appears to be a significant contributor to the optical spectra of these three comets. In conclusion, H2O(+) (11-0) was unabiguously identified in cometary optical spectra. No other molecular ion for which there are laboratory spectra can explain the unidentified features found in the ion tails of comets Halley and Brorsen-Metcalf.

Engel, Lisa↗
NASA NTRS2001

Meteoric Ions in Planetary Ionospheres

Solar system debris, in the form of meteoroids, impacts every planet. The flux, relative composition and speed of the debris at each planet depends on the planet's size and location in the solar system. Ablation in the atmosphere evaporates the meteoric material and leaves behind metal atoms. During the ablation process metallic ions are formed by impact ionization. For small inner solar system planets, including Earth, this source of ionization is typically small compared to either photoionization or charge exchange with ambient molecular ions. For Earth, the atmosphere above the main deposition region absorbs the spectral lines capable of ionizing the major metallic atoms (Fe and Mg) so that charge exchange with ambient ions is the dominant source. Within the carbon dioxide atmosphere of Mars (and possibly Venus), photoionization is important in determining the ion density. For a heavy planet like Jupiter, far from the sun, impact ionization of ablated neutral atoms by impacts with molecules becomes a prominent source of ionization due to the gravitational acceleration to high incident speeds. We will describe the processes and location and extent of metal ion layers for Mars, Earth and Jupiter, concentrating on flagging the uncertainties in the models at the present time. This is an important problem, because low altitude ionosphere layers for the planets, particularly at night, probably consist predominantly of metallic ions. Comparisons with Earth will be used to illustrate the differing processes in the three planetary atmospheres.

Pesnell, W. D.↗