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At least 127 records · Page 7

The effect of building retrofit measures on CO2 emission reduction – A case study with U.S. Medium office buildings

Building retrofit has great potential to reduce CO2 emissions since buildings are responsible for 36% of emissions in the United States. Several existing studies have examined the effect of building retrofit measures on CO2 emission reduction. However, these studies oversimplified emission factors of electricity by adopting constant annual emission factors. This study uses hourly emission factors of electricity to analyze the effect of building retrofit measures on emission reduction using U.S. medium office buildings as an example. We analyzed CO2 emission reduction effects of eight building retrofit measures that related to envelop and mechanical system in five locations: Tampa, San Diego, Denver, Great Falls, and International Falls. The main findings are: (1) estimating CO2 emission reduction with constant emission factors overestimates the emission reduction for most measures in San Diego, while it underestimates the emission reduction for most measures in Denver and International Falls; (2) The same retrofit measure may have different effects in CO2 emission reduction depending on the climates. For instance, improving lighting efficiency and improving equipment efficiency have less impacts in emission reduction in cold climates than hot climates; and (3) The most energy efficient measure may not be the most emission efficient measure. For example, in Great Falls, the most energy efficient measure is improving equipment efficiency, but the most emission efficient measure is improving heating efficiency.

Lou, Yingli↗

Using spectral methods to obtain particle size information from optical data: applications to measurements from CARES 2010

Abstract. Multi-wavelength in situ aerosol extinction, absorption and scattering measurements made at two ground sites during the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) are analyzed using a spectral deconvolution method that allows extraction of particle-size-related information, including the fraction of extinction produced by the fine-mode particles and the effective radius of the fine mode. The spectral deconvolution method is typically applied to analysis of remote sensing measurements. Here, its application to in situ measurements allows for comparison with more direct measurement methods and validation of the retrieval approach. Overall, the retrieved fine-mode fraction and effective radius compare well with other in situ measurements, including size distribution measurements and scattering and absorption measurements made separately for PM1 and PM10, although there were some periods during which the different methods yielded different results. One key contributor to differences between the results obtained is the alternative, spectrally based definitions of fine and coarse modes from the optical methods, relative to instruments that use a physically defined cut point. These results indicate that for campaigns where size, composition and multi-wavelength optical property measurements are made, comparison of the results can result in closure or can identify unusual circumstances. The comparison here also demonstrates that in situ multi-wavelength optical property measurements can be used to determine information about particle size distributions in situations where direct size distribution measurements are not available.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Collar Properties and Measurement Time Confer Minimal Bias Overall on Annual Soil Respiration Estimates in a Global Database

Abstract Measuring the soil‐to‐atmosphere carbon dioxide (CO 2 ) flux (soil respiration, R S ) is important to understanding terrestrial carbon balance and to forecasting climate change. Such measurements are frequently made using measurement collars permanently inserted into the soil surface. However, differences in measurement duration and frequency, as well as collar properties, may lead to biases in the estimation of annual R S . Using a newly updated global R S database (SRDB‐V5), we investigated the annual R S bias associated with five methodological factors: collar height, collar coverage area, collar insertion depth, measurement duration, and measurement frequency. We found that annual R S was negatively correlated with collar insertion depth, consistent with the idea that collar insertion cuts roots and thus reduces R S . Annual R S was also negatively related with collar height and collar coverage area, perhaps because uniform head‐space mixing is difficult to achieve in larger volume chambers; however, these effects were quantitatively small (bias of ~2% to 10% of mean R S ). We found no correlation of measurement duration or measurement frequency with annual R S . These findings suggest that variation in R S methodology generally introduces minimal bias overall. Therefore, compilations of minimally adjusted annual R S measurements provide a reliable resource for synthesis studies, global annual R S modeling, and investigation of how soil carbon responds to climate change.

Jian, Jinshi↗

Improved Cumulative Fission Yield Measurements with Fission Spectrum Neutrons on 235 U

Two isotopically-characterized targets of high-purity (99.84±0.03%) 235 U-oxide and a neutron dosimetry package were exposed to a pulsed neutron irradiation using the Godiva critical assembly at the National Criticality Experiments Research Center. Following irradiation, the fissioned targets were counted with a broad-energy germanium detector. Estimates of the total fissions for each target were made using measurements of well-known fission products. The total fission values were then used to measure the fission yields of 21 fission products with half-lives between 636 and 119,700 seconds. Mean values of seventeen of the measured fission products fell within the 95% confidence level of the Evaluated Nuclear Data Files VII.1/b (ENDF/B-VII.1) using the larger of the two uncertainties: 84g Br, 89 Rb, 91 Sr, 93 Y, 97 Zr, 101 Mo, 105 Ru, 128 Sn, 129 Sb, 130g Sb, 131 Sb, 131m Te, 133 I, 135 I, 141 Ba, 142 Ba, and 142 La. Seven isotopes were measured to better precision than is listed in the ENDF/B-VII.1 database: 89 Rb, 93 Y, 128 Sn, 129 Sb, 130g Sb, 131m Te, and 133 I. Four of the measured isotopes were found to be statistically different from the ENDF/B-VII.1 database: 94 Y, 134 Te, 134 I, and 138 Xe. Two of the isotopic analyses conducted in this paper fit the parent and daughter data simultaneously. The parent-daughter pairs measured in this way were the 134 Te/I and 142 Ba/La pairs. The fission yield results obtained in this way are unique, especially for 134 I, because the parent and daughter half-lives are so close. Here, given the limited number of direct measurements of the 134 Te/I pair from fast neutron induced fission and the seemingly high estimate for 134 Te from previous work, it is likely that the value in this paper is more accurate; however, additional measurements of this pair are needed to validate this assertion.

42 ENGINEERING↗

The CU 2-D-MAX-DOAS instrument – Part 2: Raman scattering probability measurements and retrieval of aerosol optical properties

Abstract. The multiannual global mean of aerosol optical depth at 550 nm (AOD550) over land is ∼ 0.19, and that over oceans is ∼ 0.13. About 45 % of the Earth surface shows AOD550 smaller than 0.1. There is a need for measurement techniques that are optimized to measure aerosol optical properties under low AOD conditions. We present an inherently calibrated retrieval (i.e., no need for radiance calibration) to simultaneously measure AOD and the aerosol phase function parameter, g, based on measurements of azimuth distributions of the Raman scattering probability (RSP), the near-absolute rotational Raman scattering (RRS) intensity. We employ radiative transfer model simulations to show that for solar azimuth RSP measurements at solar elevation and solar zenith angle (SZA) smaller than 80°, RSP is insensitive to the vertical distribution of aerosols and maximally sensitive to changes in AOD and g under near-molecular scattering conditions. The University of Colorado two-dimensional Multi-AXis Differential Optical Absorption Spectroscopy (CU 2-D-MAX-DOAS) instrument was deployed as part of the Two Column Aerosol Project (TCAP) at Cape Cod, MA, during the summer of 2012 to measure direct sun spectra and RSP from scattered light spectra at solar relative azimuth angles (SRAAs) between 5 and 170°. During two case study days with (1) high aerosol load (17 July, 0.3 < AOD430 < 0.6) and (2) near-molecular scattering conditions (22 July, AOD430 < 0.13) we compare RSP-based retrievals of AOD430 and g with data from a co-located CIMEL sun photometer, Multi-Filter Rotating Shadowband Radiometer (MFRSR), and an airborne High Spectral Resolution Lidar (HSRL-2). The average difference (relative to DOAS) for AOD430 is +0.012 ± 0.023 (CIMEL), −0.012 ± 0.024 (MFRSR), −0.011 ± 0.014 (HSRL-2), and +0.023 ± 0.013 (CIMELAOD − MFRSRAOD) and yields the following expressions for correlations between different instruments: DOASAOD = −(0.019 ± 0.006) + (1.03 ± 0.02) × CIMELAOD (R2 = 0.98), DOASAOD = −(0.006 ± 0.005) + (1.08 ± 0.02) × MFRSRAOD (R2 = 0.98), and CIMELAOD = (0.013 ± 0.004) + (1.05 ± 0.01) × MFRSRAOD (R2 = 0.99). The average g measured by DOAS on both days was 0.66 ± 0.03, with a difference of 0.014 ± 0.05 compared to CIMEL. Active steps to minimize the error in the RSP help to reduce the uncertainty in retrievals of AOD and g. As AOD decreases and SZA increases, the RSP signal-to-noise ratio increases. At AOD430 ∼ 0.4 and 0.10 the absolute AOD errors are ∼ 0.014 and 0.003 at 70° SZA and 0.02 and 0.004 at 35° SZA. Inherently calibrated, precise AOD and g measurements are useful to better characterize the aerosol direct effect in urban polluted and remote pristine environments.

54 ENVIRONMENTAL SCIENCES↗

Towards in-situ high precision local material velocity measurements in lattice materials under dynamic compression

The study of dynamic compression of materials requires high precision spatial and temporal resolution to infer the material state at any given time. In ultra-fast imaging experiments such as those performed at the Dynamic Compression Sector at the Advanced Photon Source, the current CCD frame rate is less than the X-ray pulse rate necessitating that 4 CCDs be used to image a single scintillator screen to obtain the same projection of transmitted or diffracted beam at time intervals synchronized with the X-ray beam. The use of multiple-camera setups is often employed for a variety of reasons including enhancing the temporal resolution through interleaving frames or increasing the number of viewpoints, for example. Physical corrections are made to have each CCD approximately viewing the same field of view, however we present corrections that can be made after the data collection to further refine and be able to compare movements and changes in the sample between independent CCDs. These software corrections enable higher precision and higher fidelity comparison of position changes due to sample deformation. Furthermore, we present a method to correct images (or frames) as a demonstration toward high fidelity displacement measurements in these types of ultra-fast multi-camera setup experiments.

36 MATERIALS SCIENCE↗

The Q{sub Weak}{sup p} Experiment A Search For Physics Beyond The Standard Model Via A Measurement Of The Proton's Weak Charge

The Qweak collaboration is currently preparing a measurement of the proton's weak charge Q{sub W}{sup p} = (1-4 sin{sup 2{theta}}{sub W}) at the Thomas Jefferson National Accelerator Facility (TJNAF). The experiment has been designed to produce a 4.1% measurement of the weak charge, via a 2.5% measurement of the parity violating asymmetry in the number of elastically scattered 1 GeV electrons from protons, at forward angles. At the proposed precision, the experiment would produce a 0.3% measurement of the weak mixing angle at a momentum transfer of {approx_equal} 16 GeV, making it the most precise stand alone measurement of the weak mixing angle at low momentum transfer. In combination with other parity measurements, Qweak will also provide a high precision determination of the weak charges of the up and down quarks. Our proposed measurement of Q{sub W}{sup p} will be performed with significantly smaller statistical and systematic errors than existing low Q{sup 2} data. Any significant deviation from the Standard Model prediction at low momentum transfer (Q{sup 2}) would be a signal of new physics, whereas agreement would place new and significant constraints on possible Standard Model extensions. The experiment is currently being installed. Commissioning of the experiment will begin in May 2010 and the first production data will be taken in the Fall of 2010.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Measuring the x-ray resolving power of bent potassium acid phthalate diffraction crystals

This report presents the results from measuring the X-ray resolving power of a curved potassium acid phthalate (KAP(001)) spectrometer crystal using two independent methods. It is part of a continuing effort to measure the fundamental diffraction properties of bent crystals that are used to study various characteristics of high temperature plasmas. Bent crystals like KAP(001) do not usually have the same diffraction properties as corresponding flat crystals. Models that do exist to calculate the effect of bending the crystal on the diffraction properties have simplifying assumptions and their accuracy limits have not been adequately determined. The type of crystals that we measured is being used in a spectrometer on the Z machine at Sandia National Laboratories in Albuquerque, New Mexico. The first technique for measuring the crystal resolving power measures the X-ray spectral line width of the characteristic lines from several metal anodes. The second method uses a diode X-ray source and a double crystal diffractometer arrangement to measure the reflectivity curve of the KAP(001) crystal. The width of that curve is inversely proportional to the crystal resolving power. The measurement results are analyzed and discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Measurements of dynamic surface changes by digital holography for in situ plasma erosion applications

There are currently few viable diagnostic techniques for in situ measurement of plasma facing component erosion. Digital holography is intended to fill this gap. Progress on the development of single and dual CO 2 laser digital holography diagnostics for in situ plasma facing component erosion is discussed. The dual laser mode’s synthetic wavelength allows the measurable range to be expanded by a factor of ~400 compared to single laser digital holography. This allows the diagnostic to measure surface height changes of up to 4.5 μm in single laser mode and up to 2 mm in dual laser mode. Results include ex situ measurements of plasma eroded targets and also dynamic measurements of nm and μm scale motion of a target mounted on a precision translation stage. Dynamic measurements have successfully been made with the system operating in both single and dual laser modes, from ~50 nm to ~4 μm in single laser mode and up to ~400 μm in dual laser mode (limited only by the stage speed and camera acquisition duration). These results demonstrate the feasibility of using digital holography to characterize plasma facing component erosion dynamically, i.e., during plasma exposure. Results of proof-of-principle in situ digital holographic measurements of targets exposed to an electrothermal arc plasma source are presented.

Smith, Cary↗