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At least 127 records · Page 7

Effects of coronal disturbances on the ionization state of the solar wind

A theoretical investigation of the relationship between physical conditions in coronal disturbances and the ionization states of the resulting perturbed solar wind was conducted. Available measurements of active solar wind associated with solar flares often show an enhanced degree of ionization (e.g., Fe(+17)), implying that the measured solar wind material is flare-heated at its coronal source. In contrast, other active solar wind flows sometimes show anomalously low degrees of ionization (e.g., He(+)), implying that some solar material is expelled from the corona without ever reaching coronal temperatures. The effects of impulsive heat and/or momentum addition in the corona on the hydrodynamics and ionization state of the corona and solar wind were studied. One of the primary objectives of the current grant was the development of a software package suitable for: (1) generating models for the effects of impulsive heat and/or momentum deposition on plasma temperatures, densities and flow velocities; and (2) calculating the ionization state of the solar wind as a function of the location, duration and magnitude of heat and/or momentum deposition.

Withbroe, G. L.↗

Analysis of nighttime E-region winds and ionization production

In the analysis existing measurements of nighttime E-region electron densities are separated in two groups. The first group includes a series of five rocket measurements which were taken during the night of February 22, 1968. The second group consists of a collection of rocket measurements taken near midnight at Wallops Island, Virginia, under varying conditions of geomagnetic activity. Information is obtained about the ionization production as well as the dynamics in the nighttime E region.

Geller, M. A.↗

Optical depth to reionization from perturbative 21 cm clustering

The optical depth τ is the least well determined parameter in the standard model of cosmology, and one whose precise value is important for both understanding reionization and for inferring fundamental physics from cosmological measurements. Here, we forecast how well future epoch of reionization experiments could constraint τ using a symmetries-based bias expansion that highlights the special role played by anisotropies in the power spectrum on large scales. Given a parametric model for the ionization evolution inspired by the physical behavior of more detailed reionization simulations, we find that future 21 cm experiments could place tight constraints on the timing and duration of reionization and hence constraints on τ that are competitive with proposed, space-based CMB missions provided they can measure k ≈ 0.1 h Mpc -1 with a clean foreground wedge across redshifts spanning the most active periods of reionization, corresponding to ionization fractions 0.2 ≲ x ≲ 0.8. Significantly improving upon existing CMB-based measurements with next-generation 21 cm surveys would require substantially longer observations (~ 5 years) than standard $\mathscr{O}$(1000 hour) integration times. Precise measurements of smaller scales will not improve constraints on τ until a better understanding of the astrophysics of reionization is achieved. In the presence of noise and foregrounds even future 21 cm experiments will struggle to constrain τ if the ionization evolution deviates significantly from simple parametric forms.

79 ASTRONOMY AND ASTROPHYSICS↗

Narrow Line Seyfert 1 Galaxies and the Evolution of Galaxies and Active Galaxies

Narrow Line Seyfert 1 galaxies (NLS1s) are intriguing due to their continuum as well as emission line properties. The observed peculiar properties of the NLS1s are believed to be due to accretion rate close to Eddington limit. As a consequence, for a given luminosity, NLS1s have smaller black hole (BH) masses compared to normal Seyfert galaxies. Here we argue that NLS1s might be Seyfert galaxies in their early stage of evolution and as such may be low redshift, low luminosity analogues of high redshift quasars. We propose that NLS1s may reside in rejuvenated, gas rich galaxies. The also argue in favor of collisional ionization for production of FeII in active galactic nuclei (AGN).

Mathur, Smita↗

A duty cycle hypothesis for the central engines of LINERs

A recent ultraviolet snaphsot imaging survey of the nuclei of nearby galaxies detected a compact nuclear ultraviolet source in only five of the 26 LINERs (low-ionization nuclear emission-line regions) included in the observed sample. Motivated by this observational result, we examine the possibility that all LINERs are powered by photoionization from a nuclear source, which is, however, active only for 20% of the time. We show that decay times of low-ionization species can be of the order of one to a few centuries, and we demonstrate through time-dependent photoionization calculations that if the nuclear ionizing source is active for only a fraction of the time, this would not be readily noticeable in the emission-line spectrum. We suggest that the activity cycle is related to episodic accretion events which are associated with the tidal disruption of stars by a central black hole. The time interval between tidal disruptions is of the same order as the emission-line decay time, with the accretion episode following each disruption lasting a few decades. These estimates appear to support the duty cycle hypothesis. Some observational consequences of the proposed scenario are also discussed.

Eracleous, Michael↗

The ionosphere.

Atmospheric ionization, discussing formation of different ionospheric regions

SOLAR ACTIVITY↗

Vertical Architecture Solution-Processed Quantum Dot Photodetectors with Amorphous Selenium Hole Transport Layer

Colloidal quantum dots (CQDs) provide wide spectral tunability and high absorption coefficients owing to quantum confinement and large oscillator strengths, which along with solution processability, allow a facile, low-cost, and room-temperature deposition technique for the fabrication of photonic devices. However, many solution-processed CQD photodetector devices demonstrate low specific-detectivity and slow temporal response. To achieve improved photodetector characteristics, limiting carrier recombination and enhancing photogenerated carrier separation are crucial. In this study, we develop and present an alternate vertical-stack photodetector wherein we use a solution-processed quantum dot photoconversion layer coupled to an amorphous selenium (a-Se) wide-bandgap charge transport layer that is capable of exhibiting single-carrier hole impact ionization and is compatible with active-matrix readout circuitry. This a-Se chalcogenide transport layer enables the fabrication of high-performance and reliable solution-processed quantum dot photodetectors, with enhanced charge extraction capabilities, high specific detectivity (D* ~ 0.5–5 × 10 12 Jones), fast 3 dB electrical bandwidth (3 dB BW ~ 22 MHz), low dark current density (J D ~ 5–10 pA/cm 2 ), low noise current (i n ~ 20–25 fW/Hz 1/2 ), and high linear dynamic range (LDR ~130–150 dB) across the measured visible electromagnetic spectrum (~405–656 nm).

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Covalent narlaprevir- and boceprevir-derived hybrid inhibitors of SARS-CoV-2 main protease

Emerging SARS-CoV-2 variants continue to threaten the effectiveness of COVID-19 vaccines, and small-molecule antivirals can provide an important therapeutic treatment option. The viral main protease (Mpro) is critical for virus replication and thus is considered an attractive drug target. We performed the design and characterization of three covalent hybrid inhibitors BBH-1, BBH-2 and NBH-2 created by splicing components of hepatitis C protease inhibitors boceprevir and narlaprevir, and known SARS-CoV-1 protease inhibitors. A joint X-ray/neutron structure of the M pro /BBH-1 complex demonstrates that a Cys145 thiolate reaction with the inhibitor’s keto-warhead creates a negatively charged oxyanion. Protonation states of the ionizable residues in the M pro active site adapt to the inhibitor, which appears to be an intrinsic property of M pro . Structural comparisons of the hybrid inhibitors with PF-07321332 reveal unconventional F···O interactions of PF-07321332 with Mpro which may explain its more favorable enthalpy of binding. BBH-1, BBH-2 and NBH-2 exhibit comparable antiviral properties in vitro relative to PF-07321332, making them good candidates for further design of improved antivirals.

60 APPLIED LIFE SCIENCES↗

Refining the thermochemical properties of CF, SiF, and their cations by combining photoelectron spectroscopy, quantum chemical calculations, and the Active Thermochemical Tables approach

Fluorinated species have a pivotal role in semiconductor material chemistry and some of them have been detected beyond the Earth's atmosphere. Achieving good energy accuracy on fluorinated species using quantum chemical calculations has long been a challenge. In addition, obtaining direct experimental thermochemical quantities has also proved difficult. Here, we report the threshold photoelectron and photoion yield spectra of SiF and CF radicals generated with a fluorine reactor. The spectra were analysed with the support of ab initio calculations, resulting in new experimental values for the adiabatic ionisation energies of both CF (9.128 ± 0.006 eV) and SiF (7.379 ± 0.009 eV). Using these values, the underlying thermochemical network of Active Thermochemical Tables was updated, providing further refined enthalpies of formation and dissociation energies of CF, SiF, and their cationic counterparts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Measurement on the lunar surface of impact-produced plasma clouds.

Simultaneous enhancements of low-energy ions and negative-particle fluxes due to the impact of the Apollo 14 lunar module were observed by the lunar-based charged-particle lunar-environment experiment (CPLEE). The impact occurred 66 km away from CPLEE, and the time delay between impact and flux onset was approximately 1 min. It is argued that the observed charged particles could not have energized at the instant of impact but rather that the impact produced expanding gas clouds and that constituents of these clouds were ionized and accelerated by some continuously active acceleration mechanism. It is further shown that the acceleration mechanism could not have been a static electric field but rather is possibly a consequence of interaction between the solar wind and the gas cloud.

Reasoner, D. L.↗

Stratospheric condensation nuclei and possible solar influences

Balloon-borne measurements of condensation nuclei and H2SO4 molecules in large negative ion clusters have been made in the stratosphere at around 30 km altitude. The nuclei observed were in the 0.01-0.1 micron diameter range. Consideration was given to sunspot activity as a triggering event for ionization of upper atmospheric H2SO4 species and subsequent formation of the nuclei. A numerical model was defined for a steady state between the H2SO4 association and ion recombination in order to determine a critical nucleation rate. It is concluded that condensation nuclei are produced in ion nucleation in an H2SO4 supersaturated polar cloud chamber, with the process being initiated by solar flare particle ionization.

Hofmann, D. J.↗

Search for auroral belt E-parallel fields with high-velocity barium ion injections

In April 1984, four high-velocity shaped-charge Ba(+) injections were conducted from two sounding rockets at 770-975 km over northern Alaska under conditions of active auroral and magnetic disturbance. Spatial ionization (brightness) profiles of high-velocity Ba(+) clouds from photometric scans following each release were found to be consistent with the 28-sec theoretical time constant for Ba photoionization determined by Carlsten (1975). These observations therefore revealed no evidence of anomalous fast ionization predicted by the Alfven critical velocity hypothesis.

Heppner, J. P.↗

Potentiostatic and ac impedance studies of the hydrogen electrodes used in Ni/H2 batteries

In a study of electrode activity for hydrogen evolution and hydrogen ionization, knowledge of the detailed kinetics and of the surface coverage by adsorbed hydrogen is essential. In the Ni/H2 battery, the hydrogen electrode is subjected to high hydrogen pressure; elucidation of the variation of kinetic parameters with hydrogen pressure is therefore of interest. Potentiostatic and ac impedance spectroscopic techniques were used in the present study. The equivalent circuit of the reaction, the kinetic parameters, and their pressure dependence have been determined.

Le Helloco, Jean-Guy↗

From Starspots to Stellar Coronal Mass Ejections Revisiting Empirical Stellar Relations

Upcoming missions, including the James Webb Space Telescope, will soon characterize the atmospheres of terrestrial-type exoplanets in habitable zones around cool K- and M-type stars searching for atmospheric biosignatures. Recent observations suggest that the ionizing radiation and particle environment from active cool planet hosts may be detrimental for exoplanetary habitability. Since no direct information on the radiation field is available, empirical relations between signatures of stellar activity, including the sizes and magnetic fields of starspots, are often used. Here, we revisit the empirical relation between the starspot size and the effective stellar temperature and evaluate its impact on estimates of stellar flare energies, coronal mass ejections, and fluxes of the associated stellar energetic particle events.

Konstantin Herbst↗

On Synthetic Absorption Line Profiles of Thermally Driven Winds from Active Galactic Nuclei

The warm absorbers observed in more than half of all nearby active galactic nuclei are tracers of ionized outflows located at parsec-scale distances from the central engine. If the smallest inferred ionization parameters correspond to plasma at a few 104 K, then the gas undergoes a transition from being bound to unbound, provided it is further heated to ∼106 K at larger radii. Dannen et al. recently discovered that, under these circumstances, thermally driven wind solutions are unsteady and even show very dense clumps due to thermal instability. To explore the observational consequences of these new wind solutions, we compute line profiles based on the one-dimensional simulations of Dannen et al. We show how the line profiles from even a simple steady-state wind solution depend on the ionization energy (IE) of absorbing ions, which is a reflection of the wind ionization stratification. To organize the diversity of the line shapes, we group them into four categories: weak Gaussians, saturated boxy profiles with and without an extended blue wing, and broad weak profiles. The lines with profiles in the last two categories are produced by ions with the highest IE that probe the fastest regions. Their maximum blueshifts agree with the highest flow velocities in thermally unstable models, both steady-state and clumpy versions. In contrast, the maximum blueshifts of the highest-IE lines in thermally stable models can be less than half of the actual solution velocities. Clumpy solutions can additionally imprint distinguishable absorption troughs at widely separated velocities.

Shalini Ganguly↗

Shielding Considerations for CubeSat Structures During Solar Maximum

The purpose of this lessons learned is to communicate the utility of shielding in small spacecraft planning for the support of mission assurance and reliability. Numerous SmallSats have been flying in polar low earth orbit for scientific, communications, technology demonstrations, and imaging with academic, commercial, and government interests. Shielding has been part of mission assurance and reliability from the advent of long duration spacecraft missions. The Shields-1 CubeSat has been operating in polar low earth orbit since 16 December 2018 with atomic number (Z)-grade radiation shielding and demonstrates shielding effectiveness. Shields-1 has collected a representative example of solar minimum data in 2019 with 8 Teledyne dosimeters over varying shielding effectiveness. It serves as current experimental data and has been compared with NOVICE Shielding estimates using the AP8 –AE8 trapped radiation model with the Shields-1 CAD and generic CubeSat 3 unit (U) models. Using NOVICE model radiation analysis coding, the shielding effectiveness's, based on a generic CubeSat 3U structure with 4 electronic boards, were estimated for aluminum wall thicknesses ranging from 0.204 cmto4.44 cm (0.550 g/cm2–12.0 g/cm2) thick aluminum. For modeled polar orbiting spacecraft, solar maximum total ionizing dose (TID)increases by nearly a magnitude for thin-walled aluminum 0.550g/cm2-0.686 g/cm2(0.204 cm –0.254 cm) typical CubeSat structures. The shielding effectiveness by NOVICE Sigma estimates, which is a shielding sphere approximation around a detector, showed a linear relationship with wall thickness, which increased over the wall thickness by a ratio of 1.43 determined by linear regression analysis. Using NOVICE Adjoint Monte-Carlo Modeling of solar minimum and solar maximum with the inclusion of a worst-case solar particle event over a one year mission without geomagnetic shielding, the TID for minimum and maximum conditions for a generic 3U with a wall thickness of 0.254 cm is 158 RAD and 1540 RAD, respectively. The modeled total solar maximum TID is over estimated, because at low orbital latitudes a spacecraft will have shielding from Earth's magnetic field. However, TID will still be significant at high latitudes over the poles, where a spacecraft is exposed in a solar particle event. In contrast, to a thin walled generic 3U CubeSat, Shields-1 electronics enclosure has a shielding effectiveness of 21.3 g/cm2from NOVICE Sigma modeling and is expected to show reduced total ionizing dose increases during the present active Solar Cycle 25 period. Because solar particle events during solar maximum increase TID on electronic parts with thin-walled shielding in short periods of time, it is a mission assurance and reliability consideration on the spacecraft’s mission value versus adding shielding for risk reduction of premature spacecraft or instrument payload loss. Since the volumes of many instruments and system electronics have reduced with small spacecraft, shielding material costs and weight penalties have diminished. A small spacecraft project budget and schedule may limit traditional radiation-hardened part use and radiation testing requirements, where shielding can contribute to mission assurance and reliability with reduced costs.

Shields-1↗

Shielding Considerations for CubeSat Structures During Solar Maximum

The purpose of this lessons learned paper is to communicate the utility of shielding in small spacecraft planning for the support of mission assurance and reliability. Numerous SmallSats have been flying in polar low Earth orbit for science, communications, technology demonstrations, and imaging with academic, commercial, and government interests. Shielding has been part of mission assurance and reliability from the advent of long duration spacecraft missions. The Shields-1 CubeSat has been operating in polar low Earth orbit since 16 December 2018 with atomic number (Z)-grade radiation shielding and demonstrates shielding effectiveness. Shields-1 has collected a representative example of solar minimum data in 2019 with eight Teledyne µDosimeters over varying shielding effectivenesses. It serves as current experimental data and has been compared with NOVICE Shielding estimates using the AP8 – AE8 trapped radiation model with the Shields-1 CAD and generic CubeSat three unit (3U) models. Using NOVICE model radiation analysis coding, the shielding effectivenesses, based on a generic CubeSat 3U structure with four electronic boards, were estimated for aluminum wall thicknesses ranging from 0.204 cm to 4.44 cm (0.550 g/cm 2 to 12.0 g/cm 2 ). For modeled polar orbiting spacecraft, solar maximum total ionizing dose (TID) increases by nearly a magnitude for thin-walled aluminum 0.550-g/cm 2 - 0.686-g/cm 2 (0.204-cm – 0.254-cm) typical CubeSat structures. The shielding effectiveness estimated by NOVICE Sigma, which is a shielding sphere approximation around a detector, showed a linear relationship with wall thickness, which increased over the wall thickness by a ratio of 1.43 determined by linear regression analysis. Using NOVICE Adjoint Monte-Carlo Modeling of solar minimum and solar maximum with the inclusion of a worst-case solar particle event over a one-year mission without geomagnetic shielding, the TID for minimum and maximum conditions for a generic 3U with a wall thickness of 0.254 cm is 158 RAD and 1540 RAD, respectively. The modeled total solar maximum TID is over estimated, because at low orbital latitudes a spacecraft will have shielding from the Earth’s magnetic field. However, TID will still be significant at high latitudes over the poles, where a spacecraft is exposed in a solar particle event. In contrast to a thin-walled generic 3U CubeSat, the Shields-1 electronics enclosure has a shielding effectiveness of 21.3 g/cm 2 from NOVICE Sigma modeling and is expected to show reduced total ionizing dose increases during the present active Solar Cycle 25 period. Because solar particle events during solar maximum increase TID on electronic parts with thin-walled shielding in short periods of time, it is a mission assurance and reliability consideration on the mission value of the spacecraft versus adding shielding for risk reduction of premature spacecraft or instrument payload loss. Since the volumes of many instruments and system electronics have reduced with small spacecraft, shielding material costs and weight penalties have diminished. A small spacecraft project budget and schedule may limit traditional radiation-hardened part use and radiation testing requirements, where shielding can contribute to mission assurance and reliability with reduced costs.

Shields-1↗

Characterization and Evaluation of Scintillating Fiber System Components

Idaho National Laboratory is studying long scintillation fibers (SF) in a project called “TRIPWIRE” which aims to verify containment in inaccessible nuclear waste repositories. This system will continuously monitor ionizing radiation, electromagnetic fields, and seismic activity in the vicinity of nuclear waste. Previous experiments have determined a better alternative to long SF is to couple shorter SF to kilometer scale optical fiber (OF) to reach electronics far outside of the repository. Minor signal attenuation from coupling these fibers has been observed using optical spectrometry. This experiment characterized two photomultiplier tubes (PMT) to reduce this loss by matching their spectral response characteristics to the SF’s emission spectrum. The experiment created a comparison between the two PMTs showing results that suggest other characteristics are playing a major role in improving signal attenuation when the SF is coupled to OF.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗