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At least 127 records · Page 7

Isotope ratios and chemical fractionation of CO in Lynds 134

A radio observation of (C-12)(O-17) in the dust cloud Lynds 134 is reported, and the question of the (C-13)(O-16)/(C-12)(O-18) ratio across this cloud is considered. A value of approximately 0.28 is obtained for the (C-12)(O-17) column-density ratio, and it is shown that the (C-13)(O-16)/(C-12)(O-18) ratio is very different at two positions in the cloud separated by about 3.75 arcmin. (C-13)(O-16)/(C-12)(O-18) column-density ratios are calculated on the assumption of LTE and found to have a mean value of 4.8 at six positions in the most obscured part of the cloud; the same ratio is determined to be much larger and variable outside the cloud core. It is suggested that chemical fractionation of CO is occurring in this cloud, that (C-13)(O-16) is considerably enriched in its outer regions, and that the cloud's C-12/C-13 ratio is approximately 104.

Dickman, R. L.↗

Concentrations and isotope ratios of carbon, nitrogen and sulfur in ocean-floor basalts

Ocean floor basalts studied from the Galapagos Ridge, FAMOUS area, Cayman Trough and Kilauea east rift contain 20-200 ppm carbon and 0.3-2.8 ppn nitrogen as sums of the vesicle-filling gases CO2 and N2 and dissolved species. The wide range of carbon contents found is due partly to the different extent of outgassing of vesicle-filling gases and partly to depth dependency of dissolved CO2 in the basalts. Sulfate commonly exists with sulfide in these basalts, and the sulfate/sulfide ratio increases with increasing water content, perhaps reflecting the higher oxidation potential in basalt melt of the higher water content.

Sakai, H.↗

The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH3, PH3, C2H2, C2H6, CH3D, CH4, and the Saturnian D/H isotopic ratio

The vertical distributions and mixing ratios of minor constituents in the northern hemisphere of Saturn are investigated. Results are obtained for NH3, PH3, C2H2, C2H6, CH3D, and CH4; the D/H ratio is obtained from the CH4 and CH3D abundances. The NH3 mixing ratio in the upper atmosphere is found to be compatible with the saturated partial pressure. The inferred PH3/H2 ratio of 1.4 + or - 0.8 x 10 to the -6th is higher than the value derived from the solar P/H ratio. The stratospheric C2H2/H2 and C2H6/H2 ratios are, respectively, 2.1 + or - 1.4 x 10 to the -7th and 3.0 + or - 1.1 x 10 to the -6th; the latter decreases sharply below the 20-50 mbar level. The results for CH3D/H2 and CH4/H2 imply an enrichment of Saturn's upper atmosphere in carbon by a factor of at least three over the solar abundance. The interpretation of two NH3 lines in the five-micron window suggests a NH3/H2 ratio at the two bar level below the solar value.

Courtin, R.↗

The lithium isotope ratio in five F or G dwarfs

Observations of the 6707-A LiI doublet obtained at high resolution and photometric precision are reported for two F dwarfs and three G dwarfs known to have narrow lines and strong 6707-A absorption. Adjacent lines of Ca 1 and Fe 1 are used to predetermine accurately the position and the broadening of theoretical LiI profiles fitted to the observed ones, leaving the abundances of Li-6 and Li-7 as the only adjustable parameters of the calculated profiles. Upper limits R = (Li-6)/(Li-7) less than 0.1 are obtained for four of the stars, while R is less than about 0.1 for Xi UMa A. The total Li/H abundances range from 3 x 10 to the -10th to 10 x 10 to the -10th, with uncertainties probably not exceeding a factor of 2.

Hobbs, L. M.↗

Carbon monoxide isotope ratios in galactic centers and disks

For each of the six galaxies whose mm-wavelength emission of CO and C-13O were observed from both the center and the disk, and the ratio of integrated intensities P(CO)/P(C-13O) is noted to vary markedly from galactic center to galactic center, from galactic disk to galactic disk, and from point to point within a given galaxy. The observed integrated intensity ratios vary from 3 to 16, indicating that the use of a constant P(CO) to sigma(H2) conversion to derive H2 surface densities from extragalactic CO observations can produce major errors.

Rickard, L. J.↗

Thermal spectroscopy of Neptune - The stratospheric temperature, hydrocarbon abundances, and isotopic ratios

NASA-IRTF observations of Neptune's disk-averaged spectrum are presently used, in conjunction with a lower-resolution spectrum, to furnish a more reliable absolute intensity calibration of portions of Neptune's disk-averaged spectrum. The temperature profile adopted is consistent with the size and shape of the H2 J = 3-1 quadrupole feature detected in the emission. High-resolution measurements of (C-13C-12)H6 and (C-12)2H6 imply C-12/C-13 of 78 +/- 26; this is consistent with solar and telluric values.

Orton, Glenn S.↗

Mineralogy, Three Dimensional Structure, and Oxygen Isotope Ratios of Four Crystalline Particles from Comet 81P/Wild 2

Preliminary examinations of small dust particles from comet 82P/Wild 2 revealed many expected and unexpected features. Among them the most striking feature is the presence of abundant crystalline material in the comet. Synchrotron radiation X-ray diffraction and microtomography are the most efficient methods to detect and describe bulk mineralogical features of crystalline cometary particles. In the present study, in addition to these two non-destructive techniques, electron microscopy and ion-probe mass spectrometry were carried out on the four crystalline particles.

Nakamura, T.↗