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At least 127 records · Page 7

One-dimensional simulation and validation of divertor detachment induced through nitrogen seeding on HL-2A

Divertor detachment is a promising method to solve the power exhaust problem in tokamak devices or even in future magnetic fusion reactors. In this work, a detachment experiment (HL-2A shot #38008) with mixed gas seeding (60% nitrogen and 40% deuterium) is simulated using the SD1D module in BOUT++. In the process from attachment to detachment, the target electron temperature and the target ion saturation current in simulations are found to be consistent with the experimental results measured by Langmuir probes on the target plate. In order to understand the underlying detachment mechanism on HL-2A, this work analyses the role of different particle species in the cases with different seeding rates. It shows that the plasma density varies little and the density of neutrals (D and D 2 ) slightly decreases with the increase of nitrogen seeding rate, such that plasma–neutral interactions cannot effectively reduce plasma energy and plasma momentum in the divertor. The case with a high seeding rate predicts that increasing seeding rate cannot reach a target temperature lower than 2.5 eV, which is the required temperature for strong plasma–molecule interactions. Thus, the plasma–molecule interactions may not be important in the divertor during nitrogen seeding. Here this work also studies the parallel forces including (1) force due to the parallel electric field, (2) friction forces, (3) ion- and electron-thermal forces, and (4) collisional reactions (e.g. charge exchange recombination and ionisation). It is found that the friction force between nitrogen ions and other particle species (primarily D + ) is the dominant force towards the target, while ion- and electron-thermal forces are the dominant force pushing nitrogen ions back to upstream. Parallel forces determine the parallel distribution of nitrogen impurities, and therefore decide the region of nitrogen radiation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ultralight and fire-extinguishing current collectors for high-energy and high-safety lithium-ion batteries

Inactive components and safety hazards are two critical challenges in realizing high-energy lithium-ion batteries. Metal foil current collectors with high density are typically an integrated part of lithium-ion batteries yet deliver no capacity. Meanwhile, high-energy batteries can entail increased fire safety issues. Here we report a composite current collector design that simultaneously minimizes the ‘dead weight’ within the cell and improves fire safety. An ultralight polyimide-based current collector (9 μm thick, specific mass 1.54 mg cm-2) is prepared by sandwiching a polyimide embedded with triphenyl phosphate flame retardant between two superthin Cu layers (~500 nm). Compared to lithium-ion batteries assembled with the thinnest commercial metal foil current collectors (~6 µm), batteries equipped with our composite current collectors can realize a 16-26% improvement in specific energy and rapidly self-extinguish fires under extreme conditions such as short circuits and thermal runaway.

25 ENERGY STORAGE↗

Current Challenges in Efficient Lithium‐Ion Batteries’ Recycling: A Perspective

Abstract Li‐ion battery (LIB) recycling has become an urgent need with rapid prospering of the electric vehicle (EV) industry, which has caused a shortage of material resources and led to an increasing amount of retired batteries. However, the global LIB recycling effort is hampered by various factors such as insufficient logistics, regulation, and technology readiness. Here, the challenges associated with LIB recycling and their possible solutions are summarized. Different aspects such as recycling/upcycling techniques, worldwide government policies, and the economic and environmental impacts are discussed, along with some practical suggestions to overcome these challenges for a promising circular economy for LIB materials. Some potential strategies are proposed to convert such challenges into opportunities to maintain the global expansion of the EV and other LIB‐dependent industries.

25 ENERGY STORAGE↗

Validation of SOLPS-ITER simulations with kinetic, fluid, and hybrid neutral models for JET-ILW low-confinement mode plasmas

For JET L-mode plasmas in low-recycling conditions (electron temperature at the outer strike point, T e,ot ≳ 30 eV ), SOLPS-ITER simulations agree within the error bars for the experimental profiles at the low-field side (LFS) divertor target. The peak Balmer-α (Dα ) emission in the LFS divertor agrees within the error bars of the KS3 filterscope diagnostic, but is approximately 30% lower than the peak value of the KT1 spectrometer. Simulations have been performed with fluid, kinetic, and hybrid models for the neutrals. The large fluid-kinetic discrepancies of more than a factor 2 are successfully corrected by using a hybrid fluid-kinetic approach, for which kinetic atoms are transferred to the fluid population when the local Knudsen number of the atom becomes smaller than a user-defined transition Knudsen number Kn t . The hybrid-kinetic discrepancies are limited to a few % for Kn t ≤ 100 . When increasing the upstream density to high-recycling conditions, at the onset of detachment ( T e,ot ≈ 5 eV ), the simulations predict more than a factor 2 lower peak ion saturation current to the LFS divertor than the experiments. Also the Dα emission is underpredicted with approximately a factor 2. For these high-recycling conditions, the fluid-kinetic discrepancies are limited to maximum 50%, which are again corrected by using the hybrid approach.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Comparison of the Effects of Bipolar Membrane Preparation Conditions on the Mechanical Durability and Electrochemical Performance for Electrodialysis Applications

Bipolar membranes (BPMs) are enabling materials for electrochemical conversion technologies such as water electrolysis, fuel cells, CO 2 electrolysis, and electrodialysis (ED) for direct air/ocean capture of CO 2 . However, current BPM durability can suffer from chemical, mechanical, and performance degradation when operated at high current density (ion flux) and physical scale. Therefore, this limits its adoption in a wider applications space. BPMs have several known degradation mechanisms, including chemical breakdown of ion-exchange polymers, loss of junction adhesion, or physical breakdown due to shearing force and pressure swings in an electrodialysis cell. To assess the electrochemical stability and mechanical durability of BPMs under operational conditions, we investigated how fabrication conditions (including preconditioning, hot-pressing temperature and pressure, and catalyst loading) impact the adhesion of custom-made BPMs. T-peel studies were performed ex situ to quantify adhesive forces of BPMs, and bipolar membrane electrodialysis (BPMED) experiments were performed to assess the electrochemical performance of the corresponding BPMs. The results of this systematic comparison indicate that hydration and heated pressing create improved adhesion during the fabrication of BPMs, and BPMED testing shows that these fabrication techniques are not detrimental to the electrochemical performance of the BPMs.

36 MATERIALS SCIENCE↗

Energy and Power Evolution Over the Lifetime of a Battery

Li-ion batteries currently are dominant energy storage devices for electric vehicles. Rechargeable batteries with lower cost, longer lifetime, and higher safety are desired in support of building of a green grid infrastructure. The continued investment in new battery materials, novel battery structures, advanced manufacturing processes, and accelerated testing/validation of battery performance has led to significant progress in battery development and deployment. Battery safety/reliability, which is essential to the success of a battery technology in the real world, naturally becomes the next big topic in battery research. Recently, the increasing interest in long-duration storage, fast charging, battery secondary use, and material recycling to build a circular industry and sustainable material supply chain has compelled further attention to understand the energy/power evolution and safety over the lifetime of a battery. Here, in this short Viewpoint, we discuss some high-level analyses on the energy/power evolution of rechargeable batteries over their life cycles aiming to inspire more discussion on the safety and sustainability of some representative and emerging battery technologies.

25 ENERGY STORAGE↗

Effects of divertor electrical drifts on particle distribution and detachment near the divertor target plate in DIII-D

Strong impacts of drifts on the divertor plasma in–out asymmetry and detachment are demonstrated in DIII-D with an open divertor configuration. For forward toroidal field, B T , i.e., with the ion B × ∇B drift toward the divertor, the particle flux to the inner divertor, as represented by the Langmuir probe measured ion saturation current (J sat ), exhibits a double peak structure, with electron temperature, lower at the inner target. Reversing the B T direction reverses both the radial and poloidal E × B flows, leading to a broad particle flux profile in the outboard scrape-off layer (SOL) with a similar double-peak structure to that observed at the inner target with forward B T . The correlation of a double peak structure with divertor temperature profiles confirms physical coupling between the drift flow and sheath boundary condition and their strong impact on divertor profiles. In addition, under reversed B T conditions, increasing the density flattens the target temperature profile. However, J sat remains high away from the strike point, rendering it difficult to achieve an “effective” detached plasma, i.e., with effective reduction in both peak heat flux and peak temperature (in the far SOL). In contrast, divertor detachment with a cold and flat temperature profile can be achieved at both target plates with the forward B T .

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

First application of a digital mirror Langmuir probe for real-time plasma diagnosis

We report for the first time, a digital Mirror Langmuir Probe (MLP) has successfully sampled plasma temperature, ion saturation current, and floating potential together on a single probe tip in real time in a radio-frequency driven helicon linear plasma device. This is accomplished by feedback control of the bias sweep to ensure a good fit to I–V characteristics with a high frequency, high power digital amplifier, and field-programmable gate array controller. Measurements taken by the MLP were validated by a low speed I–V characteristic manually collected during static plasma conditions. Plasma fluctuations, induced by varying the axial magnetic field($\widetilde{f}$ = 10 Hz), were also successfully monitored with the MLP. Further refinement of the digital MLP pushes it toward a turn-key system that minimizes the time to deployment and lessens the learning curve, positioning the digital MLP as a capable diagnostic for the study of low radio-frequency plasma physics. These demonstrations bolster confidence in fielding such digital MLP diagnostics in magnetic confinement experiments with high spatial and adequate temporal resolution, such as edge plasma, scrape-off layer, and divertor probes.

47 OTHER INSTRUMENTATION↗

Stochastic fluctuation and transport of tokamak edge plasmas with the resonant magnetic perturbation field

Here we present that a statistical method known as the complexity–entropy analysis is useful to characterize a state of plasma turbulence and flux in the resonant magnetic perturbation (RMP) edge localized mode (ELM) control experiment. The stochastic pedestal top temperature fluctuation in the RMP ELM suppression phase is distinguished from the chaotic fluctuation in the natural ELM-free phase. It is discussed that the stochastic temperature fluctuation can be originated from the narrow layer of the field penetration on the pedestal top. The forced magnetic island can emit the resonant drift wave of comparable sizes (relatively low-k) in the RMP ELM suppression phase, and it can result in the generation of stochastic higher wavenumber fluctuations coupled to tangled fields around the island. The analysis of the ion saturation current measurement around the major outer striking point on the divertor shows that it also becomes more stochastic as the stronger plasma response to the RMP field is expected.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Synthesis and transport properties of epitaxial Bi (111) films on GaAs (111) substrates

In recent decades, the growth of ultrathin epitaxial bismuth (Bi) films on various substrates has garnered interest due to their unique electronic properties. We report upon the growth and electrical transport properties of epitaxial Bi (111) films in the thickness range of 5–32 nm deposited directly on GaAs (111) substrates, without a buffer layer. The quality of Bi films is found to depend on conditions for substrate treatment using Ar + ion-milling and annealing. Substrates milled at low ion beam currents display poor surface reconstruction after annealing, which hinders the growth of high-quality films. In contrast, substrates milled under optimized conditions led to reconstructed surfaces upon annealing, resulting in epitaxial Bi films with predominantly single-domain orientation. Although epitaxial films formed in both cases, transport measurements indicated significantly higher conductivity for films grown on optimally treated substrates. Measurements at low temperatures suggest that the transport properties are dominated by a surface state with high mobility electrons. Magneto-transport measurements suggest that conductivity and mobility improve progressively with increasing film thickness. For the thinnest 5 nm film, a hole-like state emerges, presumably as the electron-like state is gapped out. These results provide a robust methodology for growing high-quality epitaxial Bi films on GaAs (111) and offer insights into their unique transport properties and our ability to tune them.

Atomic force microscopy↗

Enhancement of detachment control with simplified real-time modelling on the KSTAR tokamak

Abstract Detachment control based on ion saturation current I sat measurements from Langmuir probes (LPs) is implemented in the KSTAR tokamak and shown to be capable of following dynamic and constant target trajectories with good accuracy, in H-mode, by moderating the flow rate of nitrogen or deuterium. I sat controllers normalize I sat in order to form attachment fraction ( A frac ) as their control parameter. The KSTAR implementation of A frac control differs from previous work in that it continuously calculates a model for attached I sat and uses that as the denominator in A frac , whereas prior implementations either record peak I sat at rollover as they pass it or take estimated I s a t , r o l l o v e r as a manual input prior to the shot. The KSTAR controller therefore does not need to keep track of rollover status and keep separate targets for pre- and post-rollover states, and it can automatically adapt to changes in scenario at any time. It is also less vulnerable to noise as it will not lock in an outlier as a rollover point.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Avalanche statistics of fluctuation-induced fluxes from the SLPM and the W7-AS stellarator

Measurements of fluctuating floating potentials and ion saturation currents at different radial locations in the Santander Linear Plasma Machine (Castellanos et al 2005 Plasma Phys. Control. Fusion47 2067) and at the edge of the W7-AS stellarator by means of radially movable Langmuir probes allow to infer the corresponding fluctuation-induced radial flux temporal series. Avalanche-like transport events are identified in the time series and statistically characterized in terms of avalanche size/duration/quiet-time distributions and size-duration scaling relations. Transport is diffusive in the inner and intermediate radial region of the SLPM r < r tr ≈ 2.6 cm, undergoing a transition at r tr , becoming non-diffusive in the outermost region of the device, r > r tr . Here, the results obtained at the edge of the W7-AS stellarator are similar to those found in SLPM for r > r tr , i.e. consistent with what would be expected for scale-free, self-similar plasma transport dynamics near a critical state.

Avalanches↗

Divertor detachment and heat exhaust mitigation control in KSTAR with tungsten divertor

KSTAR has recently undergone an upgrade to use a new tungsten divertor to run experiments in ITER-relevant scenarios. Even with a high melting point of tungsten, it is important to control the heat flux impinging on tungsten divertor targets to minimize sputtering and contamination of the core plasma. Heat flux on the divertor is often controlled by increasing the degree of detachment of scrape-off layer plasma from the target plates. In this work, we have demonstrated successful divertor detachment and heat exhaust dissipation control experiments using two different methods. The first method uses attachment fraction as a control variable which is estimated using ion saturation current measurements from embedded Langmuir probes in the divertor. The second method uses a novel machine-learning-based surrogate model of 2D UEDGE simulation database, DivControlNN. We demonstrated running inference operation of DivControlNN in realtime to estimate heat flux at the divertor and use it as the control variable in a feedback loop with impurity gas flow. We present interesting insights from these experiments including a systematic approach to tuning controllers and discuss future improvements in the control infrastructure and control variables for future burning plasma experiments.

KSTAR tungsten divertor operations↗

Disruptive neoclassical tearing mode seeding in DIII-D with implications for ITER

New studies identify the critical parameters and physics governing disruptive neoclassical tearing mode (NTM) onset. An m/n = 2/1 mode in DIII-D that begins to grow robustly after a seeding event (edge localized mode ELM or sawtooth precursor and crash) causes the mode rotation to drop close to the plasma's Er = 0 rest frame; this condition opens the stabilizing ion-polarization current 'gate' and destabilizes an otherwise marginally stable NTM. Our new experimental and theoretical insights and novel toroidal theory-based modeling are benchmarked and scalable to ITER and other future experiments. Here, the nominal ITER rotation at q = 2 is found to be stabilizing ('gate closed') except for MHD-induced transients that could 'open the gate'. Extrapolating from the DIII-D ITER baseline scenario (IBS) discharges, MHD transients are much more likely to destabilize problematic robustly growing 2/1 NTMs in ITER; this makes predictions of seeding and control of both ELMs and sawteeth imperative for more than just minimizing divertor pulsed-heat loading.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The effect of plasma shaping on high density H-mode SOL profiles and fluctuations in TCV

Abstract The impact of plasma shaping on the properties of high density H-mode scrape-off layer (SOL) profiles and transport at the outer midplane has been investigated on Tokamakà configuration variable. The experimental dataset has been acquired by evolving the upper triangularity while keeping the other parameters constant. The scan comprises δ u p values between 0.0 and 0.6, excluding negative triangularity scenarios. Within this study, a transition from type-I edge localised modes to the quasi-continuous exhaust regime takes place from low to high δ u p . The modification of the upstream SOL profiles has been assessed, in terms of separatrix quantities, within the α t turbulence control parameter theoretical framework (Eich et al 2020 Nucl. Fusion 60 056016). The target parallel heat load and the upstream near-SOL density profiles have been shown to broaden significantly for increasing α t . Correspondingly, in the far SOL a density shoulder formation is observed when moving from low to high δ u p . These behaviours have been correlated with an enhancement of the SOL fluctuation level, as registered by wall-mounted Langmuir probes as well as the thermal helium beam diagnostic. Specifically, both the background and the filamentary-induced fluctuating parts of the first wall ion saturation current signal are larger at higher δ u p , with filaments being ejected more frequently into the SOL. Comparison of two pulses at the extremes of the δ u p scan range, but with otherwise same input parameters, shows that the midplane neutral pressure does not change much during the H-mode phase of the discharge. This indicates that indirect effects of the change in geometry, linked to first wall recycling sources, should not play a significant role. The total core radiation increases at high δ u p , on account of a stronger plasma–wall interaction and resulting larger carbon impurity intake from the first wall. This is likely associated to the enhanced first wall fluctuations, as well as a smaller outer gap and the close-to-double-null magnetic topology at high shaping.

Stagni, A. (ORCID:0000000180841544)↗

Characterization of SOL profiles and turbulence in ICRF-heated plasmas in EAST

Scrape-off layer (SOL) profiles and turbulence in ion cyclotron range of frequency (ICRF)-heated plasmas are investigated by the reciprocating probe diagnostic system (FRPs) and gas puff imaging (GPI) diagnostic in EAST. A radio-frequency (RF) sheath potential reaching up to 100 V is identified proximate to the ICRF antennas. Notably, the amplitude of this RF sheath potential escalates in response to rising ICRF power and inversely with plasma density. When a RF sheath is present in the far SOL, a pronounced density ‘shoulder’ forms in front of the ICRF antennas, while the ‘shoulder’ fade away as the antenna and associated RF sheath shift outwards. A strong E r shear is revealed by measurements from both FRPs and GPI. Analysis of the poloidal wave number-frequency spectrum reveals suppression of high-frequency turbulence in the far SOL due to the RF sheath. This effect is manifested in the reduced autocorrelation time τ c and reduced average blob size δ blob of the SOL plasma. Intriguingly, the poloidal propagation direction of the low-frequency turbulence reverses from the electron to the ion diamagnetic drift direction at the RF sheath location. A surge of tungsten impurity is potentially attributed to the heightened interaction between the SOL plasmas and the wall material. Shifting the ICRF antennas outward, to alleviate heat spots, results in the relocation of the RF sheath to the shaded region of the main limiter. This shift amplifies the radial velocity of blobs in the far SOL and concurrently diminishes the SOL density when compared to conditions without ICRF injection. The properties of ion saturation current fluctuations are consistent with the stochastic model predictions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Tearing Stable Stationary ITER Baseline Operation in DIII-D

We present a tearing stable, stationary and reproducible operating solution for DIII-D plasmas characterized by the ITER Baseline Scenario normalized parameter set and shape. In these plasmas low differential rotation (Δf1,2) between the core and edge is identified as the single root cause of the onset of the primary limiting instability, the 2,1 Neoclassical Tearing Mode (NTM), while a group of other examined parameters have a much weaker impact on the stability. Explanation is offered by drift kinetic simulations, which show a six-fold reduction in the NTM onset threshold due to diminished stabilizing ion polarization currents when the seed island drift frequency ceases in the local plasma frame. Based on the experimental observation and the explanation provided by the theory, a new method is developed to sustain Δf1,2 by modifying the edge neoclassical potential through neutral gas fueling. This method enables stationary ITER baseline operation free of disruptive 2,1 tearing modes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗