Structure and reactivity of sodium aluminate complexes in alkaline solutions
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Nienhuis, Emily T.↗
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Results for “Hydrogen scatter”
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Beam Spin Asymmetry Measurements of Deeply Virtual $π$ 0 Production with CLAS12
The new experimental measurements of beam spin asymmetry were performed for the deeply virtual exclusive $π$ 0 production in a wide kinematic region with the photon virtualities $Q$ 2 up to 8 GeV 2 and the Bjorken scaling variable $x$ $B$ in the valence regime. The data were collected by the CE BAF Large Acceptance Spectrometer (CLAS12) at Jefferson Lab with longitudinally polarized 10.6 GeV electrons scattered on an unpolarized liquid-hydrogen target. Sizable asymmetry values indicate a substantial contribution from transverse virtual photon amplitudes to the polarized structure functions. The interpretation of these measurements in terms of the Generalized Parton Distributions (GPDs) demonstrates their sensitivity to the chiral-odd GPD $\overline{E}$ $T$ , which contains information on quark transverse spin densities in unpolarized and polarized nucleons and provides access to the proton’s transverse anomalous magnetic moment. Additionally, the data were compared to a theoretical model based on a Regge formalism that was extended to the high photon virtualities.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
Estimating ionization states and continuum lowering from ab initio path integral Monte Carlo simulations for warm dense hydrogen
Warm dense matter (WDM) is an active field of research, with applications ranging from astrophysics to inertial confinement fusion. Ionization degree and continuum lowering are important quantities to understand how materials behave under these conditions, but can be difficult to diagnose since experimental campaigns are limited and often require model-dependent analysis. This is especially true for hydrogen, which has a comparably low scattering cross section, making high-quality data particularly difficult to obtain. Consequently, building equation of state tables often relies on simulations in combination with untested approximations to extract properties from experiments. Here, we investigate an approach for extracting the ionization potential depression and ionization degree—quantities which are otherwise not directly accessible from the physical model—from first-principles path integral Monte Carlo (PIMC) simulations utilizing a chemical model. In contrast to experimental measurements, where noise and nonequilibrium effects add to the uncertainty of the inferred parameters, PIMC simulations provide a clean signal with well-defined thermodynamic conditions. Comparisons against commonly used models show a qualitative agreement, but we find deviations primarily for the high-density and high-temperature cases. We also demonstrate the decreasing sensitivity of the dynamic structure factor with respect to both ionization and continuum lowering for increasing scattering angles in x-ray Thomson scattering experiments. Our work has important implications for the design of future experiments, but also offers qualitative understanding of structure factors and the imaginary-time correlation function obtained from first-principles quantum Monte Carlo simulations.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Precision measurement of the electron energy-loss function in tritium and deuterium gas for the KATRIN experiment
Abstract The KATRIN experiment is designed for a direct and model-independent determination of the effective electron anti-neutrino mass via a high-precision measurement of the tritium $$\upbeta $$ β -decay endpoint region with a sensitivity on $$m_\nu $$ m ν of 0.2 $$\hbox {eV}/\hbox {c}^2$$ eV / c 2 (90% CL). For this purpose, the $$\upbeta $$ β -electrons from a high-luminosity windowless gaseous tritium source traversing an electrostatic retarding spectrometer are counted to obtain an integral spectrum around the endpoint energy of 18.6 keV. A dominant systematic effect of the response of the experimental setup is the energy loss of $$\upbeta $$ β -electrons from elastic and inelastic scattering off tritium molecules within the source. We determined the energy-loss function in-situ with a pulsed angular-selective and monoenergetic photoelectron source at various tritium-source densities. The data was recorded in integral and differential modes; the latter was achieved by using a novel time-of-flight technique. We developed a semi-empirical parametrization for the energy-loss function for the scattering of 18.6-keV electrons from hydrogen isotopologs. This model was fit to measurement data with a 95% $$\hbox {T}_2$$ T 2 gas mixture at 30 K, as used in the first KATRIN neutrino-mass analyses, as well as a $$\hbox {D}_2$$ D 2 gas mixture of 96% purity used in KATRIN commissioning runs. The achieved precision on the energy-loss function has abated the corresponding uncertainty of $$\sigma (m_\nu ^2)< {{10}^{-2}}{\hbox {eV}^{2}}$$ σ ( m ν 2 ) < 10 - 2 eV 2 [1] in the KATRIN neutrino-mass measurement to a subdominant level.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
Femtosecond two-photon-resonant parametric four-wave mixing detection of atomic hydrogen
Here, we demonstrate an ultrafast parametric four-wave mixing method for the collisional-quenching-free detection of atomic hydrogen. Two photons of 243 nm light resonantly excite the n = 1 to n = 2 transition of atomic hydrogen, and a third probe photon scatters from the electronic coherence to generate the parametric emission of a degenerate signal photon. Laser-induced photofragmentation fluorescence from water, also excited with the same 243 nm pulses, is used as a convenient method to visualize beam overlap in space and time. The femtosecond time resolution enables the suppression of unwanted nonresonant contributions to the signal and separation from resonant mixing in water molecules because of the significantly different coherence lifetimes. A folded BOXCARS phase-matching configuration yields a spatially isolated, laser-like, signal beam, amenable to measurements in highly luminous backgrounds. Measurements in an H 2 /CH 4 /air flame demonstrate quantitative agreement with simulated H-atom concentration profiles. A coherence decay time constant of 42 ps is recorded in the atmospheric pressure flame.
Kliewer, Christopher Jesse [Sandia National Labora↗
Ruling Out the Onset of Color Transparency up to Q2 = 14.2 GeV2 in Quasielastic 12C(e,e'p) Scattering
Color Transparency (CT) is a prediction of QCD that at high momentum transfer Q2, a system of quarks which would normally interact strongly with nuclear matter could form a small color-neutral object whose compact transverse size would be maintained for some distance, passing through the nucleus undisturbed. A clear signature of CT would be a dramatic rise in nuclear transparency T with increasing Q2. CT emerges as a deviation from Glauber multiple scattering theory, which predicts constant T. While a rise in nuclear transparency would provide an unequivocal validation of QCD factorization theorems, the complex nature of nuclear interactions renders its observation difficult to predict. The E12-06-107 experiment at JLab measured T in quasielastic electron-proton scattering with carbon-12 and liquid hydrogen targets, for Q2 between 8.0 and 14.2 GeV2 , a range over which models of CT predicted that T might differ appreciably from Glauber calculations. Supported in part by US DOE grant DE-FG02-03ER41240.
Matter, John↗
MEASUREMENT OF Fn 2 /Fp 2 FROM DEEP INELASTIC ELECTRON SCATTERING OFF A=3 MIRROR NUCLEI AT JEFFERSON LAB
This research is part of the Je?erson Lab MARATHON experiment (MeAsurement of the Fn 2 /Fp 2 , d/u RAtios and A = 3 EMC E?ect in Deep Inelastic Electron Scattering Off the Tritium and Helium MirrOr Nuclei). MARATHON is an experiment on electron deep inelastic scattering off the 3H, 3He mirror nuclei. It has extracted, from the measured deep inelastic scattering cross section ratio o? 3H and 3He, the ratio of the neutron to proton inelastic structure functions Fn 2 /Fp 2 . The extraction has taken advantage of the isospin symmetry of the A = 3 mirror nuclei within a novel technique, which avoids the theoretical uncertainties that are present in the SLAC experiments of the 1970s, which used hydrogen and deuterium targets. The experiment was performed using the upgraded 11 GeV beam of the Jefferson Lab electron accelerator, the Hall A Experimental Facility, and a newly designed cryogenic, high-pressure gas target system containing 3H and 3He cells. Electrons scattered o? the gas targets were detected in the two superconducting, high-resolution magnetic spectrometers of Hall A. The cross section data cover the four-momentum transfer squared range 2.0 < Q2 < 14.0 (GeV/c)2, and the Bjorken x scaling variable range 0.19 < x < 0.83. The experiment also measured, for calibration purposes, electron deep inelastic scattering off hydrogen and deuterium at selected kinematics.
Su, Tong↗
Understanding the Structure and Dynamics of Complex Biomembrane Interactions by Neutron Scattering Techniques
The membrane is one of the key structural materials of biology at the cellular level. Composed predominantly of a bilayer of lipids with embedded and bound proteins, it defines the boundaries of the cell and many organelles essential to life and therefore is involved in almost all biological processes. Membrane-specific interactions, such as drug binding to a membrane receptor or the interactions of an antimicrobial compound with the lipid matrix of a pathogen membrane, are of interest across the scientific disciplines. Herein we present a review, aimed at nonexperts, of the major neutron scattering techniques used in membrane studies: small-angle neutron scattering, neutron membrane diffraction, neutron reflectometry, quasielastic neutron scattering, and neutron spin echo. Neutron scattering techniques are well suited to studying biological membranes. The nondestructive nature of cold neutrons means that samples can be measured for long periods without fear of beam damage from ultraviolet, electron, or X-ray radiation, and neutron beams are highly penetrating, thus offering flexibility in samples and sample environments. Most important is the strong difference in neutron scattering lengths between the two most abundant forms of hydrogen, protium and deuterium. Changing the relative amounts of protium/deuterium in a sample allows the production of a series of neutron scattering data sets, enabling the observation of differing components within complex membrane architectures. This approach can be as simple as using the naturally occurring neutron contrast between different biomolecules to study components in a complex by changing the solution H 2 O/D 2 O ratio or as complex as selectively labeling individual components with hydrogen isotopes. This review presents an overview of each experimental technique with the neutron instrument configuration, related sample preparation and sample environment, and data analysis, highlighted by a special emphasis on using prominent neutron contrast to understand structure and dynamics. This review gives researchers a practical introduction to the often enigmatic suite of neutron beamlines, thereby lowering the barrier to taking advantage of these large-facility techniques to achieve new understandings of membranes and their interactions with other molecules.
59 BASIC BIOLOGICAL SCIENCES↗
Estimating the impact of foregrounds on the future detection of Rayleigh scattering
Rayleigh scattering of the cosmic microwave background (CMB) by neutral hydrogen shortly after recombination leaves frequency-dependent imprints on intensity and polarization fluctuations. High signal-to-noise observations of CMB Rayleigh scattering would provide additional insight into the physics of recombination, including greater constraining power for parameters like the primordial helium fraction, the light relic density, and the sum of neutrino masses. However, such a measurement of CMB Rayleigh scattering is challenging due to the presence of astrophysical foregrounds, which are more intense at the high frequencies, where the effects of Rayleigh scattering are most prominent. Here we forecast the detectability of CMB Rayleigh scattering including foreground removal using blind internal linear combination methods for a set of near-future surveys. Furthermore, we show that atmospheric effects for ground-based observatories and astrophysical foregrounds pose a significant hindrance to detecting CMB Rayleigh scattering with experiments planned for this decade, though a high-significance measurement should be possible with a future CMB satellite.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Femtosecond Electronic and Hydrogen Structural Dynamics in Ammonia Imaged with Ultrafast Electron Diffraction
Directly imaging structural dynamics involving hydrogen atoms by ultrafast diffraction methods is complicated by their low scattering cross-sections. Here we demonstrate that megaelectronvolt ultrafast electron diffraction is sufficiently sensitive to follow hydrogen dynamics in isolated molecules. In a study of the photodissociation of gas phase ammonia, we simultaneously observe signatures of the nuclear and corresponding electronic structure changes resulting from the dissociation dynamics in the time-dependent diffraction. Both assignments are confirmed by ab initio simulations of the photochemical dynamics and the resulting diffraction observable. While the temporal resolution of the experiment is insufficient to resolve the dissociation in time, our results here represent an important step towards the observation of proton dynamics in real space and time.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
How oxygen passivates polycrystalline nickel surfaces
The passivation of polycrystalline nickel surfaces against hydrogen uptake by oxygen is investigated experimentally with low energy ion scattering (LEIS), direct recoil spectroscopy (DRS), and thermal desorption spectroscopy (TDS). These techniques are highly sensitive to surface hydrogen, allowing the change in hydrogen adsorption in response to varying amounts of oxygen exposure to be measured. The chemical composition of a nickel surface during a mixed oxygen and hydrogen exposure was characterized with LEIS and DRS, while the uptake and activation energies of hydrogen on a nickel surface with preadsorbed oxygen were quantified with TDS. By and large, these measurements of how the oxygen and hydrogen surface coverage varied in response to oxygen exposure were found to be consistent with predictions of a simple site-blocking model. This finding suggests that, despite the complexities that arise due to polycrystallinity, the oxygen-induced passivation of a polycrystalline nickel surface against hydrogen uptake can be approximated by a simple site-blocking model.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Search for active and inactive ion insertion sites in organic crystalline materials
The position of mobile active and inactive ions, specifically ion insertion sites, within organic crystals, significantly affects the properties of organic materials used for energy storage and ionic transport. Identifying the positions of these atomic (and ionic) sites in an organic crystal is challenging, especially when the element has low X-ray scattering power, such as lithium (Li) and hydrogen, which are difficult to detect by powder X-ray diffraction. First-principles calculations, exemplified by density functional theory (DFT), are very practical for confirming the relative stability of ion positions in materials. However, the lack of effective strategies to identify ion sites in these organic crystalline frameworks renders this task extremely challenging. This work presents two algorithms: the (i) efficient location of ion insertion sites from extrema in electrostatic local potential and charge density (ELIISE), and the (ii) ElectRostatic InsertioN (ERIN), which leverage charge density and electrostatic potential fields accessed from first-principles calculations, combined with the Simultaneous Ion Insertion and Evaluation (SIIE) workflow. SIIE inserts all ions simultaneously—to determine ion positions in organic crystals. We demonstrate that these methods accurately reproduce known ion positions in 16 organic materials and identify previously overlooked low-energy sites in tetralithium 2,6-naphthalenedicarboxylate (Li4NDC), an organic electrode material, highlighting the importance of inserting all ions simultaneously, as in the SIIE workflow. These algorithms are also integrated with off-the-shelf machine learning potentials, yielding promising results comparable to first-principles findings.
Gopidi, Harshan Reddy [Argonne National Laboratory↗
Investigating the p--π ± and p--p--π ± dynamics with femtoscopy in pp collisions at $\sqrt{s}$ = 13 TeV
The interaction between pions and nucleons plays a crucial role in hadron physics. It represents a fundamental building block of the low-energy QCD dynamics and is subject to several resonance excitations. This work studies the p--π ± dynamics using femtoscopic correlations in high-multiplicity pp collisions at $\sqrt{s}$ = 13 TeV measured by ALICE at the LHC. As the final-state interaction between protons and pions is well constrained by scattering experiments and the study of pionic hydrogen, the results give access to information on the particle-emitting source in pp collisions using the femtoscopy methods. The scaling of the source size of primordial protons and pions against their pair transverse mass is extracted. The results are compared with the source sizes studied with p–p, p--K + , and π ± –π ± pairs by ALICE in the same collision system and are found to be in agreement for the different particle pairs. This reinforces recent findings by ALICE of a common emission source for all hadron-pairs in pp collisions at LHC energies. Furthermore, the p--p--π ± systems are studied using three-particle femtoscopy in pp collisions at TeV. The presence of three-body effects is analyzed utilizing the cumulant expansion method. In this formalism, the known two-body interactions are subtracted in order to isolate the three-body effects. For both, p--p--π + and p--p--π – , a non-zero cumulant is found, indicating effects beyond pairwise interactions. These results give information on the coupling of the pion to multiple nucleons.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Dihadron beam spin asymmetries on an unpolarized hydrogen target with CLAS12
The semi-inclusive deep inelastic scattering process, where an electron scatters off a proton target at high enough energy that the process can be described by the scattering off a single constituent particle, offers targeted access to the internal structure of the nucleon. The process can be described in two phases by parton distribution functions (PDFs), which describe the likelihood of finding a quark or gluon in a particular state inside of the nucleon and then by fragmentation functions (FFs) which describe the likelihood of forming a particular final state particle.
Hayward, Timothy↗
Constraining dark matter-proton scattering from molecular cloud ionization
Optically dense clouds in the interstellar medium composed predominantly of molecular hydrogen, known as molecular clouds, are sensitive to energy injection in the form of photon absorption, cosmic-ray scattering, and dark matter (DM) scattering. The ionization rates in dense molecular clouds are heavily constrained by observations of abundances of various molecular tracers. Recent studies have set constraints on the DM-electron scattering cross section using measurements of ionization rates in dense molecular clouds. Here we calculate the analogous bounds on the DM-proton cross section using the molecular Migdal effect, recently adapted from the neutron scattering literature to the DM context. These bounds may be the strongest limits on a strongly coupled DM subfraction, and represent the first application of the Migdal effect to astrophysical systems. Published by the American Physical Society 2024
Astronomy & Astrophysics↗
Quantitative near-field water–air spray measurements at elevated pressures by neutron radiography imaging
Extensive experimental research on high-pressure spray has been conducted for decades to deepen our understanding and optimize its use in transportation, aviation, and propulsion applications; however, the near-field and in-nozzle flow characteristics are not fully understood. Dense near-field spray is among the most challenging diagnostic tasks since light is severely scattered and diffused by the liquid droplets and columns. In this work, the near-field spray and in-nozzle flow characteristics of an aeration nozzle at elevated pressures were characterized by neutron radiography imaging at the Oak Ridge National Laboratory High Flux Isotope Reactor. Neutron imaging benefits via strong penetration depths for some metals (i.e., aluminum, lead, and steel) and is sufficiently sensitive to detection of light elements, especially for hydrogen-based molecules, due to the large incoherent scattering cross section of neutrons. Both two-dimensional snapshots of the near-field spray and a three-dimensional tomographic scan of the nozzle geometry and in-nozzle water were obtained. This work provides new quantitative characterization of practical metal nozzle geometry for accurate boundary conditions, internal flow patterns inside the nozzle, and high-pressure spray flows. In conclusion, the findings may be used to improve performance and operating conditions of transportation vehicles and propulsion systems.
42 ENGINEERING↗
Hydrogen motion in near stoichiometric yttrium dihydride at elevated temperatures
The high-temperature motion of hydrogen in near stoichiometric yttrium dihydride (YH x , x = 1.62 and 1.87 at.%) was investigated using incoherent quasi-elastic neutron scattering and Density Functional Theory (DFT) calculations as a function of hydrogen stoichiometry. Translational motion (diffusivity) of hydrogen in yttrium dihydride was only observed in a temperature range of 1073–1173 K under vacuum environment. Here, the hydrogen motion was found to be limited to the tetrahedral sublattice, and diffusivity of hydrogen was observed to increase with decreasing hydrogen stoichiometry. The same behavior was also supported with DFT calculations. The DFT results also indicated that certain migration paths with smaller energy barriers favored H jump resulting in higher diffusivities.
08 HYDROGEN↗
Jefferson Lab High Precision Proton Radius Measurement Experiment: PRad
Proton is not a point-like particle; it has a finite size and an internal structure. The proton charge radius is usually measured through two different methods: using spectroscopy of hydrogen atoms, or through electron-proton (e - p) elastic scattering at low momentum transfer. In 2010, Phol et al [1] published a new measurement for proton charge radius obtained using the spectroscopy method from muonic hydrogen atoms. An ordinary hydrogen (H) atom is a bound state of an electron orbiting a proton. Likewise, a muonic hydrogen atom has a muon orbiting a proton. Since a muon has 200 times more mass than an electron, resulting in a much smaller orbiting radius, its orbit is much more sensitive to the proton charge distribution in space than the electron’s of an ordinary H-atom. Thus, the measurement from muonic hydrogen provides a 10 times more precise result than the previous methods. The radius from the muonic hydrogen measurement reported in [1] was significantly smaller than all the p
Bai, Xinzhan↗