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At least 127 records · Page 7

Stress-rupture strength and microstructural stability of W-HF-C wire-reinforced superalloy composites

W-Hf-C superalloy composites were found to be potentially useful for turbine-blade applications on the basis of stress-rupture strength. The 100- and 1000-hour rupture strengths obtained for 70 volume percent fiber composites tested at 1090 C were 420 and 280 MN/sq m. The investigation indicated that with better quality fibers, composites having 100- and 1000-hour rupture strengths of 570 and 370 MN/sq m may be obtained. Metallographic studies indicated sufficient fiber-matrix compatibility for long-term applications at 1090 C for 1000 hours or more.

Petrasek, D. W.↗

The temporal structure of HF and VHF radiations during Florida lightning return strokes

Measurements have been made of the HF and VHF radiation at 3, 30, 139, and 295 MHz produced during lightning return strokes, in correlation with wideband electric field measurements covering from about 300 Hz to 2 MHz. Intense pulses of RF are observed during the first return stroke in a discharge to ground, but with a 10-30 µsec time delay between the beginning of the stroke and the occurrence of significant RF radiation. The delay occurs at all frequencies and is short enough to suggest that the main channel and/or branches are the main initial sources of RF during the first stroke. During a subsequent return stroke, the RF starts an average of 265 µsec prior to the onset of the stroke. At 139 and 295 MHz, the subsequent stroke RF lasts only about 115 µsec; however, at 3 MHz, the radiation frequently persists up to and during the stroke.

David M Le Vine↗

Stratospheric HF and HCl observations /15 June 1981/

Balloon measurements of the stratospheric HF/HCl ratio are reported. Seven far-infrared rotational lines of HF and HCl were observed at elevation angles of 25, 18 and 8 deg by a far-infrared Fourier-transform spectrometer on board a balloon platform at 28.5 km. Analysis of line intensities yields an average HF/HCl ratio of 0.18 + or - 0.02 at an effective altitude of 33 km, with a water vapor mixing ratio of about 4 ppmv. Results are noted to be in reasonable agreement with the calculated profile of Sze and Ko (1981) with 4.5 ppmv H2O.

Traub, W. A.↗

Measured spectral amplitude of lightning sferics in the HF, VHF, and UHF bands

An experimental study was carried out to measure the spectral amplitude of lightning sferics at 22.5 MHz, 225 MHz, and 2.25 GHz. This effort included the detection, storage, and analysis of RF emission data to accurately determine the relative electric field strength produced by the lightning associated with a typical local thunderstorm. These measured spectral amplitudes are normalized and plotted relative to similar data from other investigators. These data support a 1/F to the 2nd to 1/F to the 3rd slope for sferics at frequencies above the HF range.

Shumpert, T. H.↗

Pb, Sr, Nd and Hf isotopic evidence of multiple sources for Oahu, Hawaii basalts

Pb, Sr, Nd and Hf isotopic compositions of Oahu volcanics indicate that the three principal volcanic series on Oahu Koolau, Honolulu and Waianae - were derived from isotopically distinct sources. Honolulu and Waianae basalts plot on the Nd-Pb-Sr 'mantle plane' whereas Koolau data plot distinctly below the plane.

Stille, P.↗

Hf chronometer for the early solar system

It is now widely believed that Al-26 (half-life, 7.2 x 10 to the 5th yr) and Pd-107 (half-life, 6.5 x 10 to the 6th yr) were present in the early solar system. The nucleosynthetic event responsible for the production of these nuclei must therefore have occurred no more than a few million years before the formation of solid bodies. It is possible that this event also gave a rise to the I-129 believed to be present in the early solar system. The last event to contribute Pu-244 to the solar system, however, occurred approximately 10 to the 8th yr before the time of solidification. It is noted that this latter time scale is also consistent with the lack of evidence for a Cm-247 chronometer. It is proposed that Hf-182 (half-life, 9 x 10 to the 6th yr) can resolve the question whether heavy-element nonactinide nucleosynthesis occurred during the (Al-26)-producing event. It is believed that an answer to this question will help to clarify the chronology of the formation of the solar system and will help to determine the astrophysical sites of heavy-element nucleosynthesis.

Norman, E. B.↗

A study of the solidification parameters influencing structures and properties in MAR-M246(Hf)

The nickel-base superalloy MAR-246(Hf) was studied to determine the factors affecting basic morphology and fatigue properties. Of particular interest was the degradation of fatigue properties with deviation from the 001 growth orientation. Examination of directionally solidified samples showed a dependence of carbide shape and interdentritic segregation on growth rate. Heat treatment studies focused on the gamma prime structure, determining that it reaches maximum growth after twenty-four hours but its size and stability depends on the temperature of the treatment. Fatigue test specimens were oriented crystallographically in the failed and unfailed regions and found to have rotated their orientation during the testing if they were located a significant distance from 001. This would place increased strain on the crystal and precipitate early failure.

Johnston, M. H.↗

Mesopheric turbulence intensities measured with a HF radar at 35 deg S. Part 2

A theory was developed for extracting turbulence energy dissipation rates from spectra measured with a radar. It is shown that factors apart from turbulence contribute to the observed spectral widths, and that these factors must be considered if accurate estimates of energy dissipation rates are to be obtained. In particular, beam-width broadening and shear broadening are important. The first results obtained with this theory are presented. The rules were obtained using the large HF array at Adelaide, Australia, primarily during the Southern Hemisphere winter of 1981. Results are consistent with rocket measurements of turbulence, with typical values varying between 0.01 and 1/0.2 W kg at 80-90 km altitude.

Hocking, W. K.↗

Alternatives for satellite sound broadcast systems at HF and VHF

The National Aeronautics and Space Administration and the United States Information Agency (USIA) are currently engaged in a joint program to assess the technical and economic feasibility of direct sound broadcast satellite systems to meet USIA mission needs. The cooperative effort calls for a series of interrelated studies to provide the respective Agency managements with information on the potential role of direct broadcast satellites. Initial studies focused on HF propagation phenomena and broadcast coverage requirements. These studies served as the basis for parallel systems studies currently in progress. The systems studies are to provide a data base on various satellite configurations and systems concepts capable of supporting potential broadcast requirements ranging from a small fraction to a substantial addition to USIA requirements. Antenna concepts for LEO and GEO orbits are briefly described.

Leroy, B. E.↗

Quantitative study on dispersion relations of TIDs observed by an HF Doppler array

A quantitative study on the dispersion relation of traveling ionospheric disturbances (TIDs) was performed by using data obtained by an HF Doppler array. Observed data at three stations are digitized continuously with a sampling period of 10 sec. A schematic illustration of a running analysis method is given. Fourier components omega's and their wave vectors k's of the TIDs are calculated from these subset data from three stations by means of the cross-spectrum analysis. Diagrams of horizontal trace velocity V sub ph versus wave period T were also obtained. From these diagrams one can see clear cutoff periods of the internal mode of the atmospheric gravity waves. A morphological classification of the mode of the omega - k and V sub ph - T obtained through one year was performed. The estimation of the horizontal velocity vectors of the thermospheric wind form their dispersion relations was performed also. A key point of the method of obtaining the vectors is to estimate the tilt, in azimuthally different omega - k diagrams, of a resonant branch ascribed to the Brunt oscillations.

Tsutsui, M.↗

Estimation of neutral wind velocity in the ionospheric heights by HF-Doppler technique

Three net stations located about 100 kilometers apart were set up around the station of the standard frequency and time signals (JJY) in central Japan and measurements of atmospheric gravity waves in the ionospheric heights (F-region, 200 to 400 km) were made by means of the HF-Doppler technique during the period of February 1983 to December 1983. The frequencies of the signals received are 5.0, 8.0 and 10.0 MHz, but only the 8.0 MHz signals are used for the present study, because no ambiguities due to the interference among other stations such as BPM, BSF, etc. exist by the use of 8.0 MHz. Two main results concerning the horizontal phase velocity of the atmospheric gravity waves with periods of 40 to 70 min may be summarized as follows: (1) the value of the phase velocity ranges from 50 m/s to 300 m/s; (2) the direction of the gravity wave propagation shows a definite seasonal variation. The prevailing direction of the gravity waves in winter is from north to south, which is consistent with the results obtained from other investigations. On the other hand, the two directions, from northeast to southwest and from southeast to northeast, dominate in summer.

Kitamura, T.↗

Benchmark full configuration-interaction calculations on HF and NH2

Full configuration-interaction (FCI) calculations are performed at selected geometries for the 1-sigma(+) state of HF and the 2-B(1) and 2-A(1) states of NH2 using both DZ and DZP gaussian basis sets. Higher excitations become more important when the bonds are stretched and the self-consistent field (SCF) reference becomes a poorer zeroth-order description of the wave function. The complete active space SCF - multireference configuration-interaction (CASSCF-MRCI) procedure gives excellent agreement with the FCI potentials, especially when corrected with a multi-reference analog of the Davidson correction.

Bauschlicher, C. W., Jr.↗

Benchmark full configuration-interaction calculations on HF and NH2

Full configuration-interaction (FCI) calculations are performed at selected geometries for the 1-sigma(+) state of HF and the 2-B(1) and 2-A(1) states of NH2 using both DZ and DZP gaussian basis sets. Higher excitations become more important when the bonds are stretched and the self-consistent field (SCF) reference becomes a poorer zeroth-order description of the wave function. The complete active space SCF - multireference configuration-interaction (CASSCF-MRCI) procedure gives excellent agreement with the FCI potentials, especially when corrected with a multi-reference analog of the Davidson correction.

Bauschlicher, C. W., Jr.↗

Solidification Effects in MAR-M246(Hf) Alloy

Fatigue properties degraded with crystallographic orientations greater than 10 degrees from {001} axis. Influence of solidification and heat-treatment parameters on structure and fatigue properties of nickel-based superalloy MAR-M246(Hf) described in 24-page report. Superalloys have high strength and corrosion resistance at temperatures up to 1,400 degrees C; their uses range from petrochemical equipment to marine, industrial, aircraft, and vehicular gas turbines.

Johnston, M. H.↗

Pb, Sr, Nd, and Hf isotopic constraints on the origin of Hawaiian basalts and evidence for a unique mantle source

The isotopic Pb, Sr, Nd, and Hf compositions of rocks from nine Hawaiian volcanos are determined using the analytical procedures described by Tatsumoto and Unruh (1976) and Patchett and Tatsumoto (1980). The results are presented in graphs, tables, and maps and characterized in detail. The mantle plume, the oceanic lithosphere, and the depleted mantle are identified as distinct sources of the Hawaiian basalts, with different mechanisms responsible for the formation of shield-building tholeiites, late-stage alkalic rocks, and posterosional basalts. The uniqueness of the Hawaiian basalts and the possibility that the Koolau end member represents an undepleted 'primitive' mantle reservoir are considered.

Stille, P.↗

Full CI studies of the collinear transition state for the reaction F + H2 yields HF + H

Full CI calculations on the collinear transition state for the reaction F + H2 yields HF + H are reported. The full CI results are compared with those obtained from single-reference and multireference CI calculations and from single-reference CPF calculations. In general, only those methods which attempt to account for the effects of higher excitations, such as CPF or CI plus the Davidson correction, yield a transition-state location and barrier height in good agreement with the full CI. In an extended basis, the effect of higher excitations is estimated to lower the barrier by as much as 1.5 kcal/mol; such an effect would essentially eliminate the present discrepancy between theory and experiment.

Bauschlicher, Charles W., Jr.↗

Thermal-mechanical fatigue crack growth in B-1900+Hf

Thermal-mechanical fatigue crack growth (TMFCG) rates in B-1900+Hf were measured under strain-controlled conditions in the temperature range 400-925 C. A poor correlation between isothermal and TMFCG rates under elastic and fully plastic conditions was observed when test data were analyzed using a strain-based approach. A stress-based approach taking into account the hardening and softening behavior of the material and load shedding provided an adequate description of the isothermal and TMFCG rates. Also, the isothermal crack growth rates at minimum and maximum temperatures provided upper and lower bounds, respectively, on the TMFCG rates.

Marchand, N.↗

Thermal stability of the nickel-base superalloy B-1900 + Hf with tantalum variations

The microstructure of the solutionized and aged nickel-base superalloy B-1900 + Hf was examined after additional aging at 982 C for 72, 250, and 1000 hours. Alloy compositions that were examined contained the normal 1.34 at. pct (4.3 wt pct) Ta as well as 0.67 at. pct and zero Ta levels. The gamma-prime phase agglomerated, became platelike in morphology, and decreased in volume fraction for all three alloys throughout the aging treatments. Changes which occurred in the gamma and gamma-prime phase compositions were nearly complete after 72 hours of aging while changes in the MC carbide composition continued throughout the aging. Blocky M6C carbides precipitated along the grain boundaries of all three alloys in the first 72 hours of aging. In addition, an acicular form of this Mo/Cr/Ni-rich carbide developed in the intragranular regions of the Ta-containing alloys.

Harmon, B. S.↗