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At least 127 records · Page 7

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NASA NTRS1976

Composite Golf Clubs

Babcock & Wilcox Co. under a partnership with Marshall Space Flight Center, produced composite materials, originally from the shuttle program, for improving golf clubs. Company used Marshall Space Flight Center's data summary file summarizing typical processing techniques and mechanical and physical properties of graphite and boron- reinforced composite materials. Reinforced composites provide combination of shaft rigidity and flexibility that provide maximum distance.

Source record↗

NASA NTRS2003

Carbon Nanotube Nanoelectrode Array for Ultrasensitive DNA Detection

A reliable nanoelectrode array based on vertically aligned multi-walled carbon nanotubes (MWNTs) embedded in SiO2 is used for ultrasensitive DNA detection. Characteristic nanoelectrode behavior is observed using low-density MWNT arrays for measuring both bulk and surface immobilized redox species such as K4Fe(CN)6. The open-end of MWNTs present similar properties as graphite edge-plane electrodes with wide potential window, flexible chemical functionalities, and good biocompatibility. Oligonucleotide probes are selectively functionalized at the open ends cf the nanotube array and specifically hybridized with oligonucleotide targets. The guanine groups are employed as the signal moieties in the electrochemical measurements. Ru(bpy)3(2+) mediator is used to further amplify the guanine oxidation signal. The hybridization of subattomoles of PCR amplified DNA targets is detected electrochemically by combining the MWNT nanoelectrode array with the Ru(bpy)32' amplification mechanism. This system provides a general platform of molecular diagnostics for applications requiring ultrahigh sensitivity, high-degree of miniaturization, and simple sample preparations.

Li, Jun↗

NASA NTRS2003

Carbon Nanotube Nanoelectrode Array as an Electronic Chip for Ultrasensitive Label-free DNA Detection

A reliable nanoelectrode array based on vertically aligned multi-walled carbon nanotubes (MWNTs) embedded in SiO2 is used for ultrasensitive DNA detection. Characteristic nanoelectrode behavior is observed using low-density MWNT arrays for measuring both bulk and surface immobilized redox species such as K4Fe(CN)6 and ferrocene derivatives. The open-end of MWNTs are found to present similar properties as graphite edge-plane electrodes with wide potential window, flexible chemical functionalities, and good biocompatibility. BRCA1 related oligonucleotide probes with 18 bp are selectively functionalized at the open ends of the nanotube array and specifically hybridized with oligonucleotide targets incorporated with a polyG tag. The guanine groups are employed as the signal moieties in the electrochemical measurements. R(bpy)(sup 2+, sub 3) mediator is used to further amplify the guanine oxidation signal. The hybridization of sub-attomoles of DNA targets is detected electrochemically by combining the MWNT nanoelectrode array with the R(bpy)(sup 2+, sub 3) amplification mechanism. This technique was employed for direct electrochemical detection of label-free PCR amplicon from a healthy donor through specific hybridization with the BRCA1 probe. The detection limit is estimated to be less than 1000 DNA molecules since abundant guanine bases in the PCR amplicon provides a large signal. This system provides a general platform for rapid molecular diagnostics in applications requiring ultrahigh sensitivity, high-degree of miniaturization, and simple sample preparation, and low-cost operation.

Li, Jun↗

NASA NTRS2004

Ultrasensitive Label-free Electronic Chip for DNA Analysis Using Carbon Nanotube Nanoelectrode Arrays

There is a strong need for faster, cheaper, and simpler methods for nucleic acid analysis in today s clinical tests. Nanotechnologies can potentially provide solutions to these requirements by integrating nanomaterials with biofunctionalities. Dramatic improvement in the sensitivity and multiplexing can be achieved through the high-degree miniaturization. Here, we present our study in the development of an ultrasensitive label-free electronic chip for DNA/RNA analysis based on carbon nanotube nanoelectrode arrays. A reliable nanoelectrode array based on vertically aligned multi-walled carbon nanotubes (MWNTs) embedded in a SiO2 matrix is fabricated using a bottom-up approach. Characteristic nanoelectrode behavior is observed with a low-density MWNT nanoelectrode array in measuring both the bulk and surface immobilized redox species. The open-end of MWNTs are found to present similar properties as graphite edge-plane electrodes, with a wide potential window, flexible chemical functionalities, and good biocompatibility. A BRCA1 related oligonucleotide probe with 18 bases is covalently functionalized at the open ends of the MWNTs and specifically hybridized with an oligonucleotide target as well as a PCR amplicon. The guanine bases in the target molecules are employed as the signal moieties for the electrochemical measurements. Ru(bpy)3(2+) mediator is used to further amplify the guanine oxidation signal. This technique has been employed for direct electrochemical detection of label-free PCR amplicon through specific hybridization with the BRCAl probe. The detection limit is estimated to be less than approximately 1000 DNA molecules, approaching the limit of the sensitivity by laser-based fluorescence techniques in DNA microarray. This system provides a general electronic platform for rapid molecular diagnostics in applications requiring ultrahigh sensitivity, high-degree of miniaturization, simple sample preparation, and low- cost operation.

Li, Jun↗

NASA NTRS2004

Representation of the Geosynchronous Plasma Environment for Spacecraft Charging Calculations

Historically, our ability to predict and postdict surface charging has suffered from both a lack of reliable secondary emission and backscattered electron yields and poor characterization of the plasma environment. One difficulty lies in the common practice of fitting the plasma data to a Maxwellian or Double Maxwellian distribution function, which may not represent the data well for charging purposes. For 13 years Los Alamos National Laboratory (LANL) has been accumulating measurements of electron and proton spectra from Magnetospheric Plasma Analyzer (MPA) instruments aboard a series of geosynchronous satellites. These data provide both a plasma characterization and the potential of the instrument ground. We use electron and ion flux spectra measured by the LANL MPA to examine how the use of different spectral representations of the charged particle environment in computations of spacecraft potentials during magnetospheric substorms affects the accuracy of the results. We calculate the spacecraft potential using both the measured fluxes and several different fits to these fluxes. These flux measurements and fits have been corrected for the difference between the measured and calculated potential. The potentials computed using the measured fluxes, the best available material properties of graphite carbon, and a secondary electron escape fraction of 81%, are within a factor of three of the measured potential for nearly all the data. Using a Kappa fit to the electron distribution function and a Maxwellian fit to the ion distribution function gives agreement similar to the calculations using the actual data. Alternative spectral representations, including Maxwellian and double Maxwellian for both species, lead to less satisfactory agreement between predicted and measured potentials.

Davis, V. A.↗

NASA NTRS1988

Bismaleimide-vinylpolystyrylpyridine graphite composites

Flammability, thermal, and selected mechanical properties of composites fabricated with epoxy and other thermally stable resin matrices are described. Properties which were measured included limiting-oxygen index, smoke evolution, thermal degradation products, total-heat release, heat-release rates, mass loss, flame spread, ignition resistance, thermogravimetric analysis and selected mechanical properties. This paper describes the properties of eight different graphite composite panels fabricated using four different resin matrices and two types of graphite reinforcement. The resin matrices included: XU71775/H795, a blend of vinylpolystyrylpyridine and bismaleimide; H795, a bismaleimide; Cycom 6162, a phenolic; and PSP 6022M, a polystyrylpyridine. The graphite fiber used was AS-4 in the form of either tape or fabric. The properties of these composites were compared with epoxy composites. It was determined that the blend of vinylpolystyrylpyridine and bismaleimide (XU71775/H795) with the graphite tape was the optimum design giving the lowest heat release rate.

Kourtides, D. A.↗

NASA NTRS1980

Environmental effects on graphite fiber reinforced PMR-15 polyimide

Studies were conducted to establish the effects of thermo-oxidative and hydrothermal exposure on the mechanical properties of T300 graphite fabric reinforced PMR-15 composites. The effects of hydrothermal exposure on the mechanical properties of HTS-2 continuous graphite fiber composites were also investigated. The thermo-oxidative stability characteristics of T300 fabric and T300 fabric/PMR-15 composites were determined. Flexural strengths of specimens were determined. The useful lifetime of T300 fabric/PMR-15 composites in air at 316 C was found to be about 100 hours. The useful lifetimes in air at 228 and 260 C were determined to be 500 and 1000 hours, respectively. Absorbed moisture was found to reduce the elevated temperature properties of both the T300 fabricate and HTS-2 continuous fiber composites. The moisture effect was found to be reversible.

Serafini, T. T.↗

NASA NTRS1982

Environmental effects on graphite fiber reinforced PMR-15 polyimide

Serafini, T. T.↗

NASA NTRS1977

Preliminary development of a fundamental analysis model for crack growth in a fiber reinforced composite material

A mathematical model for the strength of fiber reinforced composites containing specific flaws is described. The approach is to embed a local heterogeneous region surrounding the crack tip in an anisotropic elastic continuum. By consideration of the individual failure events activated near the flaw tip, a strength prediction can be made from basic properties of the composite constituents. Computations for arbitrary flaw size and orientation have been performed for unidirectional composites with linear elastic-brittle constituent behavior. The mechanical properties were those of graphite epoxy. With the rupture properties arbitrarily varied to test the capability of the model to reflect real fracture modes in fiber composites, it is shown that fiber breakage, matrix crazing, crack bridging, matrix-fiber debonding, and axial splitting all can occur during gradually increasing load prior to catastrophic fracture. Qualitative comparisons with experimental results on edge-notched unidirectional graphite epoxy specimens have also been made.

Kanninen, M. F.↗

NASA NTRS1971

CMB-13 research on carbon and graphite

Microstructural study of physical and mechanical properties of carbon and graphite

Smith, M. C.↗

NASA NTRS1985

Graphite fiber reinforced thermoplastic glass matrix composites for use at 1000 F

The fabrication and properties of the graphite fiber reinforced glass matrix composite system are described. By reinforcing borosilicate glass with graphite fibers it has been possible to develop a composite whose properties can be compared favorably with resin matrix counterparts. Both high elastic modulus and strength can be obtained and maintained to temperatures of approximately 600 C. In addition, composite dimensional stability is superior to resin or metal matrix systems due to the low thermal expansion behavior of the glass matrix.

Prewo, K. M.↗

NASA NTRS1975

Fundamental analysis of the failure of polymer-based fiber reinforced composites

A mathematical model predicting the strength of unidirectional fiber reinforced composites containing known flaws and with linear elastic-brittle material behavior was developed. The approach was to imbed a local heterogeneous region surrounding the crack tip into an anisotropic elastic continuum. This (1) permits an explicit analysis of the micromechanical processes involved in the fracture, and (2) remains simple enough to be useful in practical computations. Computations for arbitrary flaw size and orientation under arbitrary applied loads were performed. The mechanical properties were those of graphite epoxy. With the rupture properties arbitrarily varied to test the capabilities of the model to reflect real fracture modes, it was shown that fiber breakage, matrix crazing, crack bridging, matrix-fiber debonding, and axial splitting can all occur during a period of (gradually) increasing load prior to catastrophic failure. The calculations also reveal the sequential nature of the stable crack growth process proceding fracture.

Kanninen, M. F.↗

NASA NTRS2004

Modeling and Characterization of a Graphite Nanoplatelet/Epoxy Composite

A micromechanical modeling procedure is developed to predict the viscoelastic properties of a graphite nanoplatelet/epoxy composite as a function of volume fraction and nanoplatelet diameter. The predicted storage and loss moduli from the model are compared to measured values from the same material using Dynamical Mechanical Analysis, nanoindentation, and tensile tests. In most cases, the model and experiments indicate that for increasing volume fractions of nanoplatelets, both the storage and loss moduli increase. Also, in most cases, the model and experiments indicate that as the nanoplatelet diameter is increased, the storage and loss moduli decrease and increase, respectively.

Odegard, Gregory M.↗

NASA NTRS1978

Effect of thermal exposure on lubricating properties of polyimide films and polyimide-bonded graphite fluoride films

The effect of thermal exposure on the weight loss, adherence, friction, and wear properties of polyimide films and polyimide bonded graphite fluoride films was investigated. Films bonded to 304 stainless steel or 440C-HT steel were thermally exposed at temperatures of 315 ,345, 370, or 400 C for 100 hours or more and then evaluated, using a pin-on-disk machine, at temperatures of 25, 315, or 345 C in atmospheres of dry or moist air. Polyimide films were brittle after thermal exposure. Polyimide bonded graphite fluoride films had adherence and gave low friction and wear results; thus, they appear to be good candidates for solid lubrication applications where long thermal soaks are prevalent.

Fusaro, R. L.↗

NASA NTRS1988

Degradation of graphite-epoxy due to electron radiation

Experimental results are presented showing that electron irradiation has a variable effect on the properties of graphite-epoxy depending upon the test temperature and the property of interest. In general, compression properties are improved at cold temperature and degraded at elevated temperature. With the exception of some moduli, tensile and shear properties are degraded at both cold and elevated temperatures. Electron irradiation lowers the glass transition temperature of graphite/epoxy significantly. Property degradation of irradiated materials at the elevated temperature is associated with the reduction in Tg. It is shown that a (0) compression-strength test is the most sensitive test for exhibiting the effects of electron irradiation. Results from tests on neat resin also show that the bulk matrix is degraded after irradiation, and that the correlation between resin and composite response is good.

Herakovich, C. T.↗

NASA NTRS1986

Space radiation effects on the thermo-mechanical behavior of graphite-epoxy composites

This investigation of composite material properties utilized T300/934 graphite-epoxy that was subjected to 1.0 MeV electron radiation for a total dose of 1.0 x 10 to the 10th rads at a rate of 5.0 x 10 to the 7th rads/hour, simulating a worst-case exposure equivalent to 30 years in space. Mechanical testing was performed on 4-ply unidirectional laminates over the temperature range of -250 F (116 K) to +250 F (394 K). In-plane elastic tensile and shear properties as well as strength were obtained. The results show that electron radiation degrades the epoxy matrix and produces products that volatilize at the temperatures considered. These degradation products plasticize the epoxy at elevated temperatures and embrittle it at low temperatures, thereby altering the mechanical properties of the composite.

Milkovich, Scott M.↗

NASA NTRS1971

Improved brazing technique for pyrolytic graphite

Technique uses braze metal and joint design that together compensate for the difficult anisotropic properties of the graphite and are usable at elevated temperatures.

Bogowitz, R. G.↗

NASA NTRS1986

Lightweight, Fire-Resistant Graphite Composites

Aircraft safety improved with interior paneling made of new laminate with good thermophysical properties. Featuring lightweight graphite composite, laminate more heat-and flame-resistant and produces much less smoke in fire than commonly used epoxy-resin-containing laminates. New laminate prepared without epoxy resin. Graphite unidirectional cloth preimpregnated with blend of vinyl polystyrylpyridine and bismaleimide (VPSP-BMI). Either of two types of VPSP-BMI blend used, depending on method of preparation of chemicals and technique used to fabricate panel.

Kourtides, D. A.↗