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At least 127 records · Page 7

On the paragenetic modes of minerals: A mineral evolution perspective

A systematic survey of 57 different paragenetic modes distributed among 5659 mineral species reveals patterns in the diversity and distribution of minerals related to their evolving formational environments. The earliest minerals in stellar, nebular, asteroid, and primitive Earth contexts were dominated by relatively abundant chemical elements, notably H, C, O, Mg, Al, Si, S, Ca, Ti, Cr, and Fe. Significant mineral diversification subsequently occurred via two main processes, first through gradual selection and concentration of rarer elements by fluid-rock interactions (for example, in hydrothermal metal deposits, complex granite pegmatites, and agpaitic rocks), and then through near-surface biologically mediated oxidation and weathering. We find that 3349 mineral species (59.2%) are known from only one paragenetic context, whereas another 1372 species (24.2%) are associated with two paragenetic modes. Among the most genetically varied minerals are pyrite, albite, hornblende, corundum, magnetite, calcite, hematite, rutile, and baryte, each with 15 or more known modes of formation. Among the most common paragenetic modes of minerals are near-surface weathering/oxidation (1998 species), subsurface hydrothermal deposition (859 species), and condensation at volcanic fumaroles (459 species). In addition, many species are associated with compositionally extreme environments of highly differentiated igneous lithologies, including agpaitic rocks (726 species), complex granite pegmatites (564 species), and carbonatites and related carbonate-bearing magmas (291 species). Biological processes lead to at least 2707 mineral species, primarily as a consequence of oxidative weathering but also through coal-related and other taphonomic minerals (597 species), as well as anthropogenic minerals, for example as byproducts of mining (603 minerals). However, contrary to previous estimates, we find that only ~34% of mineral species form exclusively as a consequence of biological processes. By far the most significant factor in enhancing Earth’s mineral diversity has been its dynamic hydrological cycle. At least 4583 minerals—81% of all species—arise through water-rock interactions. A timeline for mineral-forming events suggests that much of Earth’s mineral diversity was established within the first 250 million years. If life is rare in the universe, then this view of a mineralogically diverse early Earth provides many more plausible reactive pathways over a longer timespan than previous models. If, however, life is a cosmic imperative that emerges on any mineral- and water-rich world, then these findings support the hypothesis that life on Earth developed rapidly in the early stages of planetary evolution

Robert M. Hazen↗

An Overview of the CERES Radiation and Validation Experiment (CRAVE)

The Clouds and the Earth’s Radiant Energy System (CERES) experiment is one of the highest priority scientific satellite instruments developed for NASA’s Earth Observing System. The CERES Radiation and Validation Experiment (CRAVE) provides continuous world-class surface longwave and shortwave radiation measurements and validation of CERES and other satellite products. CRAVE consists of three sites (two active and one legacy). The legacy site was the CERES Ocean Validation Experiment, or COVE, located at Chesapeake Light Station (36.90 N, 75.71 W), 25 km off the coast of southeastern Virginia, USA. COVE was active from 2000-2016 but was deactivated due to structural concerns. The deactivation of COVE interrupted a rare long-term ocean/water scene dataset in the Baseline Surface Radiation Network (BSRN), the gold standard for surface radiation measurements. Shortly after the closure of COVE, Granite Island (46.72 N, 87.41 W), a new water site, was discovered and has been active since the summer of 2018. Granite Island is privately owned, located in Lake Superior, approximately 20 km north of Marquette, Michigan, USA, and 10 km to the nearest land point. The other CRAVE site is in Hampton, Virginia, USA, at Nasa Langley Research Center (37.10 N, 76.38 W), a land scene, and has been operating since December 2014. We will describe CRAVE and its importance, the uniqueness of each site and site logistics, participating networks and measurements made for radiometric, aerosol, meteorological and water skin temperature analysis. CRAVE measurements detecting smoke originating from Canadian wildfires with aerosol optical depths well over 2 and first results from a shortwave calibration round robin experiment will also be presented.

Bryan Fabbri↗

A thermal model for analysis of infrared images

A mathematical model derived from the equation of heat conduction was developed to assist in interpreting thermal infrared images acquired from aircraft and spacecraft. The model assumes steady state boundary conditions. It contains parameters of rock and soil properties, atmospheric effects, site location, and season. The results predicted provide an explanation for the thermal differences among granite, limestone, and dolomite recorded in the December 1968 daytime and predawn flights over the Mill Creek, Oklahoma test site, during which representative thermal inertia and albedo values were used. A second test of the model made use of data acquired during the June 1970 predawn overflight of Mill Creek. A simple model of transient heating of the ground was constructed as an extension of the overall model, in order to examine the effects of atmospheric perturbations. The results obtained are consistent with those of ground observations made at the time of the overflight.

Watson, K.↗

Multispectral techniques for general geological surveys evaluation of a four-band photographic system

A general geological survey at 1:62,500 scale of the well exposed rocks of the White Mountains and the adjacent volcanic desert plateau is reported. The tuffs, granites, sedimentary rocks and metavolcanic rocks in this arid region are varicolored and conventional black and white aerial photographs have been a useful mapping aid. A large number of true color and false color aerial photographs and multispectral viewer screen images of the study area are evaluated in order to consider what imagery is the most useful for distinguishing rock types. Photographs of true color film are judged the most useful for recognizing geographic locations.

Crowder, D., F.↗

Luminescence analysis of lunar samples returned by Apollo: Luminescence of Apollo 14 and Apollo 15 lunar samples

Luminescence measurements were made of Apollo 14 lunar samples with far UV X-ray, and proton irradiation and of Apollo 15 lunar samples with X-ray irradiation. Preliminary efficiencies with the far UV are in the range 0.001 to 0.01; efficiencies with X-rays and protons are in the range 10 to the -8th to 10 to the -6th powers. The crystalline igneous rocks show higher efficiencies, in general, than the breccias and glasses, and the ratio of intensity of the green to the blue luminescence peak tends to be higher for the crystalline igneous rocks than for breccias and glasses. Therefore, both the efficiency and the spectral character appear to have a systematic relationship to lithologic type (granitic versus gabbroic versus fragmental) and to geologic history and processes on the moon (shocked versus unshocked or only mildly shocked material).

Greenman, N. N.↗

Infrared and Raman spectroscopic studies of structural variations in minerals from Apollo 11, 12, 14 and 15 samples, volume 3

Infrared and Raman vibrational spectroscopic data, yielding direct information on molecular structure, were obtained for single grains ( 150 microns) of minerals, basalts, and glasses isolated from Apollo 11, 12, 14, and 15 rock and dust samples, and for grains in Apollo 14 polished butt samples. From the vibrational data, specification substitutions were determined for the predominant silicate minerals of plagioclase, pyroxene, and olivine. Unique spectral variations for grains of K-feldspar, orthopyroxene, pyroxenoid, and ilmenite were observed to exceed the ranges of terrestrial samples, and these variations may be correlatable with formation histories. Alpha-quartz was isolated as pure single grains, in granitic grains composited with sanidine, and in unique grains that were intimately mixed with varying amounts of glass. Accessory minerals of chromite and ulvospinel were isolated as pure grains and structurally characterized from their distinctive infrared spectra. Fundamental vibrations of the SiO4 tetrahedra in silicate minerals were used to classify bulk compositions in dust sieved fractions, basalt grains and glass particles, and to compare modal characteristics for maria, highland and rille samples. No hydrated minerals were found in any of the samples studied, indicating anhydrous formation conditions.

Estep, P. A.↗

Apollo 14 - Nature and origin of rock types in soil from the Fra Mauro formation.

Compositions of glasses in the Apollo 14 soil correspond to four types of Fra Mauro basalts, to mare basalts and soils, and, in minor amounts, to gabbroic anorthosite and potash granite. The Fra Mauro basalts can be related by simple low pressure crystal-liquid fractionation that implies a parent composition like that of Apollo 14 sample 14310.

Aitken, F. K.↗

U-Pb ages for sphene in a contact metamorphic zone.

U-Pb ages have been determined on sphene concentrates from the 2700 my old Giants Range Granite at varying distances from the contact with the 1100 my old Duluth gabbro. As the contact is approached the sphene ages become more discordant and plot along a chord between 1100 and 2700 my on a concordia diagram. The U-Pb ages for sphene in the contact aureole are more resistant to thermal metamorphism than are K-Ar ages for hornblende and biotite. The resistance relative to U-Pb ages for zircon is more difficult to interpret because the zircon U-Pb ages may have become discordant prior to or after 1100 my ago, whereas the U-Pb ages for sphene appear to have had episodic discordance only at 1100 my ago.

Hanson, G. N.↗

Fungal leaching of titanium from rock.

Penicillium simplicissimum is found to solubilize up to 80% of the titanium in granitic rocks but less than 2% of the titanium in basaltic rocks. These findings were made in investigating the interactions of microorganisms with rocks and minerals of the biosphere in studies aimed at developing experiments for the detection of extraterrestrial life.

Silverman, M. P.↗

Emission polarization study on quartz and calcite.

Calculation of the spectral emission polarization of quartz and calcite polished plates for observation angles of 20 and 70 deg by the substitution of complex index of refraction values for each mineral into Fresnel's equations. The emission polarization is shown to be quite wavelength-dependent, demonstrating that selected narrow or medium-width spectral bands exhibit a significantly higher percentage of polarization than a broad spectral band for these two minerals. Field measurements with a broadband infrared radiometer yield polarizations on the order of 2% for a coarse-grained granite rock and beach sand (both quartz-rich). This implies that a more sensitive detector with a selected medium-width filter may be capable of measuring emission polarization accurately enough to make this parameter useful as a remote sensing tool for discrimination among rocks on the basis of texture.

Vincent, R. K.↗