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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Asphaltene-induced spontaneous emulsification: Effects of interfacial co-adsorption and viscoelasticity

Asphaltenes are a class of high molecular weight aromatic compounds found in crude oil. They adsorb onto toluene-water interfaces and induce a spontaneous emulsification phenomenon, whereby stable water-in-oil emulsions form without the need of an external energy input. This work aims to control and understand the factors affecting spontaneous droplet formation in the presence of asphaltene adsorption. This is particularly useful for crude oil refining, where the presence of a stable emulsion hampers the efficiency of downstream processing operations. We explore the effect of the addition of copolymers designed as crude oil flow improvers as a means to control the extent of emulsion formation. We find that the polymers competitively adsorb onto the toluene-water interface and diminish spontaneous emulsification. Additionally, we conduct fluorescence microscopy experiments and measurements of the interfacial energy to determine the mechanism of spontaneous emulsification in asphaltene systems. We conclude that an emulsion forms via the diffusion of molecular water into the oil phase and subsequent binding with asphaltene aggregates, leading to the nucleation of micrometer-sized water droplets. We find that the polymer forms complexes with the dissolved asphaltenes, possibly hampering the ability of diffused water to bind to the asphaltenes and reducing the extent of spontaneous emulsification. Finally, we investigate the role of interfacial shear and dilatational viscoelasticity to better understand which fundamental interfacial properties are important in the emulsification of asphaltene-laden systems. We find that the rate of formation of an interfacial microstructural network is inversely correlated with the extent and rate of spontaneous emulsification.

42 ENGINEERING↗
DOE OSTI2023

Model simulations of Plum Island Ecosystems LTER low marsh site using ELM-PFLOTRAN

Model simulations using the E3SM Land Model (ELM) coupled to the PFLOTRAN reactive transport model via the Alquimia interface. The simulations were conducted for a tidal salt marsh at the Plum Island Ecosystems LTER near Rowley, Massachusetts, USA. Model simulations were forced using site-specific tidal cycles and salinity, and the simulations used a biogeochemical reaction network including aerobic decomposition, sulfate reduction, iron reduction, and methanogenesis. Model outputs include simulated carbon stocks, carbon dioxide and methane fluxes, and porewater concentrations of key solutes related to sulfur, iron, and carbon cycling. The model simulations included a saline simulation (with tidal sulfate inputs), a fresh simulation (with low salinity and low sulfate inputs), and a saline simulation with lower vegetation productivity to represent the effect of salinity on vegetation. These simulations were conducted to demonstrate that a new model framework incorporating subsurface redox and biogeochemical interactions into a land surface model could reproduce measured surface greenhouse gas fluxes and biogeochemical dynamics in tidal marsh ecosystems, and to test whether including redox interactions in a land surface model would allow the model to resolve contrasts in biogeochemical cycling and greenhouse gas production between saline and freshwater wetlands.The data package includes gzipped tar archives (which can be expanded using standard tar and gzip utilities) of model outputs from three model configurations: saline subsurface and reduced vegetation productivity related to salinity; saline subsurface with vegetation productivity not reduced; and freshwater. Also included are code for the modified E3SM model, Alquimia interface, and PFLOTRAN reactive transport simulator in gzipped tar format; plain text parameter and configuration files; python code files for visualizing model output and defining model configurations; and model output, tide and salinity forcing, and configuration files in netCDF format. See the README.md file in the data package for a detailed description of all files contained in the package. All files are in netCDF (.nc), gzipped tar archive (.tar.gz or .tgz), or text (all other files).Updated: May 13, 2024. Model output, E3SM code, PFLOTRAN input files, and python codes for visualizing results were updated to reflect changes made for the manuscript revision. The updated archive reflects the code and model output from the final accepted manuscript. Changes included updated reaction parameters reflecting improved parameterization and additional comparisons with field measurements. E3SM code changes included better support for multiple grid cells and improved flow and transport parameterization.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Fluid – Fluid Interfacial Area and Its Impact on Relative Permeability - A Pore Network Modeling Study

Abstract Relative permeability (kr) is commonly modeled as an empirical function of phase saturation. Although current empirical models can provide a good match of one or two measured relative permeabilities using saturation alone, they are unable to predict relative permeabilities well when there is hysteresis or when physical properties such as wettability change. Further, current models often result in relative permeability discontinuities that can cause convergence and accuracy problems in simulation. To overcome these problems, recent research has modeled relative permeability as a state function of both saturation (S) and phase connectivity (X). Pore network modeling (PNM) data, however, shows small differences in relative permeability for the same S-X value when approached from a different flow direction. This paper examines the impact of one additional Minkowski parameter (Mecke and Arns, 2005), the fluid-fluid interfacial area, on relative permeability to identify if that satisfactorily explains this discrepancy. We calculate the total fluid-fluid interfacial areas (IA) during two-phase (oil/water) flow in porous media using pore network modeling. The area is calculated from PNM simulations using the areas associated with corners and throats in pore elements of different shapes. The pore network is modeled after a Bentheimer sandstone, using square, triangular, and circular pore shapes. Simulations were conducted for numerous primary drainage and imbibition cycles at a constant contact angle of 0° for the wetting phase. Simultaneous measurements of capillary pressure, relative permeability, saturation, and phase connectivity are made for each displacement. Fluid-fluid interfacial area is calculated from the PNM capillary pressure, the fluid location in the pore elements, and the pore element dimensional data. The results show that differences in the relative permeability at the same (S,X) point is explained well by differences in the fluid-fluid interfacial area (IA). That is, for a larger change in IA at these intersection points, the permeability difference is greater. That difference in relative permeability approaches zero as the difference in IA approaches zero. This confirms that relative permeability can be modeled better as a unique function of S, X, and IA. The results also show that an increase in IA restricts flow decreasing the nonwetting (oil) phase permeability. This decrease is caused by an increase in the throat area fraction compared to the corner area as the total area IA increases. The wetting phase relative permeability, however, shows the inverse trend, in that its relative permeability is greater when IA becomes larger owing to a greater fraction of the total area associated with the corners. The area IA, however, impacts the nonwetting phase relative permeability more than the wetting phase relative permeability. Corner flow improves the wetting phase relative permeability because the wetting phase is continuous there. Finally, a sensitivity analysis shows that relative permeability a is more sensitive to change in S than they are for IA for the case studied implying that if only two parameters are used to model relative permeability it is better to choose S and X.

Engineering↗
DOE OSTI2014

SECA Coal-Based Systems - LGFCS

LGFCS is developing an integrated planar (IP) SOFC technology for mega-watt scale power generation including the potential for use in highly efficient, economically competitive central generation power plant facilities fuel by coal synthesis gas. This Department of Energy Solid-State Energy Conversion Alliance (SECA) program has been aimed at achieving further cell and stack technical advancements and assessing the readiness of the LGFCS SOFC stack technology to be scaled to larger-scale demonstrations as a path to commercialization. Significant progress was achieved in reducing to practice a higher performance and lower cost cell technology, identifying and overcoming degradation mechanisms, confirming the structural capability of the porous substrate for reliability, maturing the strip design for improved flow to allow high fuel utilization operation while minimizing degradation mechanisms and obtaining full scale block testing at 19 kW under representative conditions for eventual product and meeting SECA degradation metrics. The SECA program has played a key role within the overall LGFCS development program in setting the foundation of the technology to justify the progression of the technology to the next level of technology readiness testing.

Goettler, Richard↗
DOE OSTI2019

Community Project for Accelerator Science and Simulation-3

The focus of the Rensselaer efforts for COMPASS-3 was the development of parallel mesh adaptation procedures for high-order unstructured meshes where elements must be curved to properly approximate the domain geometry. The procedures developed were integrated into the ACE3P accelerator modeling code. Areas of development included: High order curved mesh representations that can provide the orders of geometric approximation needed. A curved mesh adaptation procedure that can match an adaptively defined anisotropic mesh metric field. In-memory integration of these procedures with the Omega3P code to provide an effective parallel adaptive simulation work flow. Improved dynamic load balancing tools that account for the degrees of freedom associated with the various order mesh entities (vertices, edges, faces and regions).

42 ENGINEERING↗
NASA NTRS1974

Vented vectoring-nozzle for STOL and V/STOL aircraft

Vented vectoring-nozzle has superior thrust coefficient and is lighter in weight because it does not require completely enclosed elbow duct ordinarily used to deflect nozzle flow. Improved nozzle has primary nozzle and three-sided elbow deflector.

Esker, D. W.↗
NASA NTRS1974

Centrifugal lyophobic separator

A centrifugal separator is described using a lyophobic filter for removing liquid particles from a mixed stream of gas and liquid under various negative or positive external acceleration conditions as well as zero g or weightless conditions. Rotating the lyophobic filter and inclining the filter to the entering flow improves the lyophobic properties of the filter, provides gross separation of larger liquid particles, and prevents prolonged contact of liquid droplets with the spinning filter which might change the filter properties or block the filter.

Booth, F. W.↗
NASA NTRS1975

A comparison of a shock-capturing technique with experimental data for three-dimensional internal flows

Shock-capturing solutions for an axisymmetric supersonic inlet at small angles of attack are obtained. Good overall agreement between the shock-capturing solutions and experimental data is shown except in regions of strong viscous effects or boundary-layer removal. Although the results indicate a strong potential for the use of shock-capturing or finite-difference solutions for internal flows, improvement in the ability to handle the reflection of strong shockwaves having downstream Mach numbers near 1 is needed.

Presley, L. L.↗
NASA NTRS1978

Performance of a short annular dump diffuser using suction-stabilized vortices at inlet Mach numbers to 0.41

A short, annular dump diffuser was designed to use suction to establish stabilized vortices on both walls for improved flow expansion in the region of an abrupt area change. The diffuser was tested at near ambient inlet pressure and temperature. The overall diffuser area ratio was 4.0. The inlet height was 2.54 cm and the exit pitot-static rakes were located at a distance from the vortex fence equal to two or six times the inlet height. Performance data were taken at near ambient temperature and pressure for nominal inlet Mach numbers of 0.18 to 0.41 with suction rates of 0 to 18 percent of the total inlet airflow. The exit velocity profile could be shifted toward either wall by adjusting the inner- or outer-wall suction rate. Symmetrical exit velocity profiles were unstable, with a tendency to shift back to hub- or tip-weighted profile. Diffuser effectiveness was increased from about 47 percent without suction to over 85 percent at a total suction rate of about 14 percent. The diffuser total pressure losses at inlet Mach numbers of 0.18 and 0.41 decreased from 1.1 and 5.6 percent without suction to 0.48 and 5.2 percent at total suction rates of 14.4 and 5.6 percent, respectively.

Smith, J. M.↗
NASA NTRS1980

The development of a self-streamlining flexible walled transonic test section

This design eliminates the uncertainties in data from conventional transonic test sections. Sidewalls are rigid, and the flexible floor and ceiling are positioned by motorized jacks controlled by on-line computer to minimize run times. The tunnel-computer combination is self-streamlining without reference to the model. Data is taken from the model only when the walls are good streamlines, and is corrected for the small, known but inevitable residual interferences. Two-dimensional validation testing in the Mach range up to about 0.85 where the walls are just supercritical shows good agreement with reference data using a height:chord ratio of 1.5. Techniques are under development to extend Mach number above 1. This work has demonstrated the feasibility of almost eliminating wall interferences, improving flow quality, and reducing power requirements or increasing Reynolds number. Extensions to three-dimensional testing are outlined.

Goodyer, M. J.↗
NASA NTRS1983

Computation of turbulent flows over backward-facing step

A numerical method for computing incompressible turbulent flows is presented. The method is tested by calculating laminar recirculating flows and is applied in conjunction with a modified Kappa-epsilon model to compute the flow over a backward-facing step. In the laminar regime, the computational results are in good agreement with the experimental data. The turbulent flow study shows that the reattachment length is underpredicted by the standard Kappa-epsilon model. The addition of a term to the standard model that accounts for the effects of rotation on turbulent flow improves the results in the recirculation region and increases the computed reattachment length.

Mansour, N. N.↗
NASA NTRS1984

Experimental evaluation of an advanced Space Shuttle Main Engine hot-gas manifold design concept

The Space Shuttle Main Engine's hot gas manifold (HGM) has been the subject of an experimental study aimed at the establishment of an aerodynamic data base to support the development of an advanced, three-dimensional, fluid dynamic analysis computer model. The advanced HGM design used in the study demonstrated improved flow uniformity in the fuel-side turbine exit and transfer duct exit regions. Major modifications were incorporated in the HGM flow test article model, using two large transfer ducts on the fuel turbine side in place of the three small transfer ducts of the present design. The HGM flow field data were found to be essentially independent of Reynolds number over the range examined.

Pelaccio, D. G.↗
NASA NTRS1985

Experimental evaluation of an advanced Space Shuttle main engine hot-gas manifold design concept

This study, using an extensively modified, full-scale space shuttle main engine (SSME) hot-gas manifold (HGM), established a detailed aerodynamic data base to support development of an advanced, three-dimensional, fluid-dynamic analysis computer model. In addition, the advanced SSME hot-gas manifold design used in this study demonstrated improved flow environment (uniformity) in the fuel side turbine exit and transfer duct exit regions. Major modifications were incorporated in the full-scale HGM flow test article model using two large transfer ducts on the fuel turbine side of the HGM in place of the three small transfer ducts in the present design. Other model features included an increases in the flow areas downstream of the 180-degree turn and in the fishbowl regions.

Pelaccio, D. G.↗
NASA NTRS1986

Langley hypersonic facilities complex - Description and application

The Langley Hypersonic Facilities Complex (HFC) consists of hypersonic, blowdown wind tunnels developed and put into operation between the late 1950's and early 1970's. These facilities complement one another to presently provide ranges of Mach number from 6 to 22, unit Reynolds number from 0.1 to 15 million per foot, and normal shock density ratio from 4 to 12. Descriptions of these facilities are presented along with the testing techniques routinely used. Examples of the application of the HFC to generate data bases for proposed entry vehicles and for the verification of computer codes are given. Plans to upgrade the facilities to improve flow quality, productivity, capability and reliability are discussed.

Miller, C. G.↗
NASA NTRS1988

SSME hot gas manifold flow comparison test

An account is given of the High Pressure Fuel Turbopump (HPFT) component of NASA's Alternate Turbopump Development effort, which is aimed at the proper aerodynamic integration of the current Phase II three-duct SSME Hot Gas Manifold (HGM) and the future 'Phase II-plus' two-duct HGM. Half-scale water flow tests of both HGM geometries were conducted to provide initial design data for the HPFT. The results reveal flowfield results and furnish insight into the performance differences between the two HGM flowpaths. Proper design of the HPFT can potentially secure significant flow improvements in either HGM configuration.

Cox, G. B., Jr.↗
NASA NTRS1991

Holographic interferometry at the NASA-Ames Hypervelocity Free-Flight Aerodynamic Facility

A laser holographic interferometer has been designed and developed to improve flow visualization for models in free-flight at high velocities and low freestream static pressures. Of special interest is the flow structure due to high-temperature effects in the post-shock region of models traveling at hypervelocity. A dual-plate technique with a double-pass, Michelson-type configuration has been incorporated in an existing hypervelocity ballistic range. Holograms of 5-deg blunt conical models traveling at 5 km/sec in air at a freestream static pressure of 0.08 atm have been made. Finite- and infinite-fringe interferograms were reconstructed from the holograms and provided qualitative flowfield results. In addition, a digital scanning technique was also used to produce a 'synthetic' infinite-fringe interferogram from the analysis of an experimental finite-fringe interferogram. A 'synthetic' infinite-fringe interferogram shows detail in the wake region not found in the experimental interferograms.

Tam, Tim C.↗
NASA NTRS1932

Considerations of Air Flow in Combustion Chambers of High-Speed Compression-Ignition Engines

The air flow in combustion chambers is divided into three fundamental classes - induced, forced, and residual. A generalized resume is given of the present status of air flow investigations and of the work done at this and other laboratories to determine the direction and velocity of air movement in auxiliary and integral combustion chambers. The effects of air flow on engine performance are mentioned to show that although air flow improves the combustion efficiency, considerable induction, friction, and thermal losses must be guarded against.

Spanogle, J A↗
NASA NTRS1950

Investigation of Operating Pressure Ratio of a Supersonic Wind Tunnel Utilizing Distributed Boundary-layer Suction in Test Section

Effect of distributed boundary-layer suction on operating pressure ratio of a supersonic wind tunnel was investigated. Investigation was made in 3.84- by 10-inch supersonic tunnel operating at Mach number 2.0 and suction was applied in neighborhood of the normal shock to two walls of a constant-area extension of test section. A reduction of 4 percent of operating pressure ratio was attributed to improved flow conditions at subsonic-diffuser inlet. The theoretical normal shock was, in practice, replaced by a multiple-branch shock configuration across which the flow parameters changed in approximate accordance with the Rankine-Hugoniot values.

Cohen, C B↗