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At least 127 records · Page 7

Investigating ultrafine aerosol turbulent fluxes during atmospheric new particle formation events

New particle formation (NPF) is an important source of atmospheric aerosols, yet quantitatively predicting its occurrence remains challenging, partly because ground-based measurements cannot capture NPF accurately if they occur in the upper atmosphere. While observations have confirmed the presence of new particles near the top of the planetary boundary layer (PBL), their origins and the direction of their vertical transport have remained ambiguous. Here, we propose and validate an analytical framework using airborne eddy-covariance (EC) and continuous wavelet transform (CWT) to directly quantify the vertical flux of newly formed particles and determine its dominant vertical transportation direction. Analyzing data from a dedicated airborne campaign over the Southern Great Plains, we observed a persistent and strong downward particle flux during NPF events, with a mean value of 133.8 cm?3 m s?¹ downward flux in the entrainment zone, whereas fluxes on non-NPF days were negligible. Our spectral analysis further confirms that these directional fluxes can be reliably captured using standard 1 Hz aerosol instrumentation. These findings suggest that new particle formation, driven by the entrainment of air from the overlying residual/stable layer during PBL growth, is a significant and potentially understudied source of boundary layer aerosols. The framework presented here provides a methodology to correctly attribute NPF events to specific altitudes, thereby improving the mechanistic understanding required for accurate atmospheric models.

Zhang, Ruoyu↗

Accelerating flux balance calculations in genome-scale metabolic models by localizing the application of loopless constraints

Abstract Background Genome-scale metabolic network models and constraint-based modeling techniques have become important tools for analyzing cellular metabolism. Thermodynamically infeasible cycles (TICs) causing unbounded metabolic flux ranges are often encountered. TICs satisfy the mass balance and directionality constraints but violate the second law of thermodynamics. Current practices involve implementing additional constraints to ensure not only optimal but also loopless flux distributions. However, the mixed integer linear programming problems required to solve become computationally intractable for genome-scale metabolic models. Results We aimed to identify the fewest needed constraints sufficient for optimality under the loopless requirement. We found that loopless constraints are required only for the reactions that share elementary flux modes representing TICs with reactions that are part of the objective function. We put forth the concept of localized loopless constraints (LLCs) to enforce this minimal required set of loopless constraints. By combining with a novel procedure for minimal null-space calculation, the computational time for loopless flux variability analysis (ll-FVA) is reduced by a factor of 10–150 compared to the original loopless constraints and by 4–20 times compared to the current fastest method Fast-SNP with the percent improvement increasing with model size. Importantly, LLCs offer a scalable strategy for loopless flux calculations for multi-compartment/multi-organism models of large sizes, for example, shortening the CPU time for ll-FVA from 35 h to less than 2 h for a model with more than104 reactions. Availability and implementation Matlab functions are available in the Supplementary Material or at https://github.com/maranasgroup/lll-FVA Supplementary information Supplementary data are available at Bioinformatics online.

Chan, Siu H. J. (ORCID:000000027707656X)↗

High Flux Through the Oxidative Pentose Phosphate Pathway Lowers Efficiency in Developing Camelina Seeds

Many seeds are green during development, and light has been shown to play a role in the efficiency with which maternally supplied substrates are converted into storage compounds. However, the effects of light on the fluxes through central metabolism that determine this efficiency are poorly understood. Here, we used metabolic flux analysis to determine the effects of light on central metabolism in developing embryos of false flax (Camelina sativa). Metabolic efficiency in C. sativa is of interest because, despite its growing importance as a model oilseed and engineering target and its potential as a biofuel crop, its yields are lower than other major oilseed species. Culture conditions under which steady-state growth and composition of developing embryos match those in planta were used to quantify substrate uptake and respiration rates. The carbon conversion efficiency (CCE) was 21% 6 3% in the dark and 42% 6 4% under high light. Under physiological illumination, the CCE (32% 6 2%) was substantially lower than in green and nongreen oilseeds studied previously. 13C and 14C isotopic labeling experiments were used together with computer-aided modeling to map fluxes through central metabolism. Fluxes through the oxidative pentose phosphate pathway (OPPP) were the principal source of CO2 production and strongly negatively correlated with CCE across light levels. OPPP fluxes were greatly in excess of demand for NAD(P)H for biosynthesis and larger than those measured in other systems. Excess reductant appears to be dissipated via cyanide-insensitive respiration. OPPP enzymes therefore represent a potential target for increasing efficiency and yield in C. sativa.

09 BIOMASS FUELS↗

Fabrication and Testing of Micro Flux Monitors in the High Flux Isotope Reactor

Neutron dosimetry is a critical technique to measure the neutron flux, fluence, and energy spectrum of nuclear reactors and can be used to indicate fuel reloading, high-power operations, or changes in cycle length. This work presents results of a novel device named the micro flux monitor, which is a miniaturized neutron dosimeter made from small quantities (100s of nanograms) of Ti, Al, Ni, and Au metals deposited on Si and high-purity fused silica substrates using standard semiconductor fabrication techniques. Approximately 1,250 of these devices were produced, and 40 were irradiated in the pneumatic tube facility of the Neutron Activation Analysis Laboratory at the High Flux Isotope Reactor. Testing demonstrated that dosimeter metals can be deposited predictably and repeatedly in multiple geometries, including as quick response (QR) codes. Neutron flux measurements with these devices were within 3% of measurements made using standard flux monitors, demonstrating the efficacy of these devices. Devices were also tested at 500°C under a N2 atmosphere and showed minimal degradation, suggesting they could be deployed for neutron dosimetry measurements in high-temperature advanced reactors.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Flux-flow voltages during guided flux collapse from hollow superconducting cylinders

Voltages across diametrically opposite contact pairs on the outer surface of superconducting Nb tubes are found to depend dramatically upon the spatial configuration of the voltage-measuring leads relative to the positions of the moving magnetic flux lines. Experiments have been conducted to study these voltages for different wall thicknesses and for a variety of arrangements of the leads when flux in the hole and the wall of the Nb tube is made to exit or enter, completely or partially, by applying heat at a narrow strip along its length. Using the critical-state concept, a model for the change of flux and the resulting electric fields in the Nb tube on application of a heat pulse is presented. The resulting time-dependent and time-integrated voltages are calculated in excellent quantitative agreement with the experimental results. These results show that the flux-flow voltages across two contact points on a superconductor arise from the generation of an induced electric field over a chosen path in the superconductor between the contact points and from a change of magnetic flux through the surface bounded by the measuring leads and the chosen path in the superconductor.

Khanna, S. M.↗

An observational test of the quasi-geostrophic relation between eddy momentum flux convergence and eddy fluxes of potential vorticity and potential temperature

The quasi-geostrophic relation between the fluxes of momentum, potential vorticity and potential temperature is tested with atmospheric data by computing the convergence of momentum flux as a residual of the potential temperature and potential vorticity flux and comparing it to the momentum flux convergence computed directly. It is shown that in the troposphere between 18 and 74 deg N the observed momentum flux convergence differs from the quasi-geostrophic convergence by 25-60% depending on tropospheric level and season.

Heck, W. J.↗

Differences in the temporal variations of solar UV flux, 10.7-cm solar radio flux, sunspot number, and Ca-K plage data caused by solar rotation and active region evolution

Attention is given to two types of temporal variations in the solar UV spectral irradiance caused by solar rotation and active region evolution. It is noted that the first type of dissimilar temporal behavior occurs when concentrations of solar active regions evolve at solar longitudes nearly 180 deg apart. Both the UV observations and modeled UV fluxes based on Ca-K plage data then exhibit pronounced 13-day periodicity, whereas the 10.7-cm solar radio flux and sunspot number exhibit quite dissimilar temporal variations. This type of dissimilarity is related to the modeled UV flux and has a dependence on the solar central meridian distance that is narrower than that for the 10.7-cm radio flux or for sunspot numbers. A second case of marked dissimilarity is seen when major new solar active regions arise and dominate the full-disk fluxes for several rotations. It is found that the strongest peaks in 10.7 cm and sunspot numbers tend to occur on their first rotation, for example, during major dips in the total solar irradiance, whereas the Ca-K plages and UV enhancements peak on the next rotation and then decay more slowly on subsequent rotations.

Donnelly, R. F.↗

Enhancement of surface-atmosphere fluxes by desert-fringe vegetation through reduction of surface albedo and of soil heat flux

Under the arid conditions prevailing at the end of the dry season in the western Negev/northern Sinai region, vegetation causes a sharp increase relative to bare soil in the daytime sensible heat flux from the surface to the atmosphere. Two mechanisms are involved: the increase in the surface absorptivity and a decrease in the surface heat flux. By increasing the sensible heat flux to the atmosphere through the albedo and the soil heat flux reductions, the desert-fringe vegetation increases the daytime convection and the growth of the planetary boundary layer. Removal of vegetation by overgrazing, by reducing the sensible heat flux, tends to reduce daytime convective precipitation, producing higher probabilities of drought conditions. This assessment of overgrazing is based on observations in the Sinai/Negev, where the soil albedo is high and where overgrazing produces an essential bare soil. Even if the assessment for the Sinai/Negev does not quantitatively apply throughout Africa, the current practice in many African countries of maintaining a large population of grazing animals, can contribute through the mesoscale mechanisms described to reduce daytime convective precipitation, perpetuating higher probabilities of drought. Time-of-day analysis of precipitation in Africa appears worthwhile, to better assess the role of the surface conditions in contributing to drought.

Otterman, J.↗

C 4 fluxes from the sun as a star and the correlation with magnetic flux

A total of 144 C 4 wavelength 1548 SMM-UVSP spectroheliograms of solar plages were analyzed, some of which are series of exposures of the same region on the same day. Also analyzed were C 4 wavelength 1551 rasters of plages and C 4 1548 rasters of the quiet sun. The sample contains data on 17 different plages, observed on 50 different days. The center-to-limb variations of the active regions show that the optical thickness effects in the C 4 wavelength 1548 line can be neglected in the conversion from intensity to flux density. As expected for the nearly optically thin situation, the C 4 1548 line is twice as bright as the C 4 wavelength 1551 line. The average C 4 wavelength 1548 flux density for a quiet is 2700 erg/cm/s and, with surprisingly little scatter, 18,000 erg/cm/s for plages. The intensity histograms of rasters obtained at disk centers can be separated into characteristic plage and quiet-sun contributions with variable relative filling factors. The disk-averaged flux density in the C 4 doublet and the disk-averaged magnitude of the magnetic flux density are related. The relationship between the C 4 and magnetic flux densities for spatially resolved data is inferred to be almost the same, with only an additional factor of order unity in the constant of proportionality.

Schrijver, C. J.↗

Footprint prediction of scalar fluxes - Reliability and implications for airborne flux measurements over the FIFE site

Estimates of the location and extension of the upwind ground area that affects flux observations most directly are examined to determine the reliability of airborne versus near-ground flux measurements. The theoretical issues regarding the 'footprint' are examined, and specific observations are analyzed by studying the data over a grid regarding sensible heat, latent heat, CO2, and greenness. The grid is footprint-corrected to correlate better with independently observed surface characteristics, and an optimized footprint is developed that satisfies the relationships between the observed variables. Optimized mapping of the surface flux is given which demonstrates the importance of considering local advection to correlate airborne and ground-based flux observations. The technique is particularly applicable to situations in which significant variations in the surface flux density exist.

Schuepp, P. H.↗

Achieving Zero Current for Polar Wind Outflow on Open Flux Tubes Subjected to Large Photoelectron Fluxes

In this study we investigate how the condition of zero current on open flux tubes with polar wind outflow, subjected to large photoelectron fluxes, can be achieved. We employ a steady state collisionless semikinetic model to determine the density profiles of O(+), H(+), thermal electrons and photoelectrons coming from the ionosphere along with H(+), ions and electrons coming from the magnetosphere. The model solution attains a potential distribution which both satisfies the condition of charge neutrality and zero current. For the range of parameters considered in this study we find that a 45-60 volt discontinuous potential drop may develop to reflect most of the photoelectrons back toward the ionosphere. This develops because the downward flux of electrons from the magnetosphere to the ionosphere on typical open flux tubes (e.g. the polar rain) appears to be insufficient to balance the photoelectron flux from the ionosphere.

Wilson, G. R.↗

A Comparison of Latent Heat Fluxes over Global Oceans for Four Flux Products

To improve our understanding of global energy and water cycle variability, and to improve model simulations of climate variations, it is vital to have accurate latent heat fluxes (LHF) over global oceans. Monthly LHF, 10-m wind speed (U10m), 10-m specific humidity (Q10h), and sea-air humidity difference (Qs-Q10m) of GSSTF2 (version 2 Goddard Satellite-based Surface Turbulent Fluxes) over global Oceans during 1992-93 are compared with those of HOAPS (Hamburg Ocean Atmosphere Parameters and Fluxes from Satellite Data), NCEP (NCEP/NCAR reanalysis). The mean differences, standard deviations of differences, and temporal correlation of these monthly variables over global Oceans during 1992-93 between GSSTF2 and each of the three datasets are analyzed. The large-scale patterns of the 2yr-mean fields for these variables are similar among these four datasets, but significant quantitative differences are found. The temporal correlation is higher in the northern extratropics than in the south for all variables, with the contrast being especially large for da Silva as a result of more missing ship data in the south. The da Silva has extremely low temporal correlation and large differences with GSSTF2 for all variables in the southern extratropics, indicating that da Silva hardly produces a realistic variability in these variables. The NCEP has extremely low temporal correlation (0.27) and large spatial variations of differences with GSSTF2 for Qs-Q10m in the tropics, which causes the low correlation for LHF. Over the tropics, the HOAPS LHF is significantly smaller than GSSTF2 by approx. 31% (37 W/sq m), whereas the other two datasets are comparable to GSSTF2. This is because the HOAPS has systematically smaller LHF than GSSTF2 in space, while the other two datasets have very large spatial variations of large positive and negative LHF differences with GSSTF2 to cancel and to produce smaller regional-mean differences. Our analyses suggest that the GSSTF2 latent heat flux, surface air humidity, and winds are likely to be more realistic than the other three flux datasets examined, although those of GSSTF2 are still subject to regional biases.

Chou, Shu-Hsien↗

Beyond carbon flux partitioning: Carbon allocation and nonstructural carbon dynamics inferred from continuous fluxes

Carbon (C) allocation and nonstructural carbon (NSC) dynamics play essential roles in plant growth and survival under stress and disturbance. However, quantitative understanding of these processes remains limited. Here, in this work, we propose a framework where we connect commonly measured carbon cycle components (eddy covariance fluxes of canopy CO 2 exchange, soil CO 2 efflux, and allometry-based biomass and net primary production) by a simple mass balance model to derive ecosystem-level NSC dynamics (NSC i ), C translocation (dC i ), and the biomass production efficiency (BPE i ) in above- and belowground plant (i = agp and bgp) compartments. We applied this framework to two long-term monitored loblolly pine (Pinus taeda) plantations of different ages in North Carolina and characterized the variations of NSC and allocation in years under normal and drought conditions. The results indicated that the young stand did not have net NSC flux at the annual scale, whereas the mature stand stored a near-constant proportion of new assimilates as NSC every year under normal conditions, which was comparable in magnitude to new structural growth. Roots consumed NSC in drought and stored a significant amount of NSC post drought. The above- and belowground dC i and BPE i varied more from year to year in the young stand and approached a relatively stable pattern in the mature stand. The belowground BPE bgp differed the most between the young and mature stands and was most responsive to drought. With the internal C dynamics quantified, this framework may also improve biomass production estimation, which reveals the variations resulting from droughts. Overall, these quantified ecosystem-scale dynamics were consistent with existing evidence from tree-based manipulative experiments and measurements and demonstrated that combining the continuous fluxes as proposed here can provide additional information about plant internal C dynamics. Given that it is based on broadly available flux data, the proposed framework is promising to improve the allocation algorithms in ecosystem C cycle models and offers new insights into observed variability in soil–plant–climate interactions.

54 ENVIRONMENTAL SCIENCES↗

A Kinetic Inductance Ammeter with Coplanar Waveguide Input Structure for Magnetic Flux Focusing

We propose a multiplexible kinetic inductance ammeter, which uses a high-quality-factor, superconducting, lumped-element, kinetic inductance resonator as a current sensor, a short, superconducting coplanar waveguide (CPW) for current input, and a CPW transmission line for the sensor readout. The resonator consists of an interdigitated capacitor and a superconducting loop that inductively couples to the input CPW. Current running through the central line of the input CPW generates magnetic fields which are focused into the gaps of the input CPW. These magnetic fields can be measured collectively as the magnetic flux through the superconducting loop. The kinetic inductance of the superconducting loop depends on the screening current for the magnetic flux, so the input current is converted to a change in the frequency of the resonator. We analyze the response and noise of a kinetic inductance ammeter with a high-resistivity NbN loop.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Temporal Dynamics of Aerodynamic Canopy Height Derived From Eddy Covariance Momentum Flux Data Across North American Flux Networks

Aerodynamic canopy height ( h a ) is the effective height of vegetation canopy for its influence on atmospheric fluxes and is a key parameter of surface-atmosphere coupling. However, methods to estimate h a from data are limited. This synthesis evaluates the applicability and robustness of the calculation of h a from eddy covariance momentum-flux data. At 69 forest sites, annual h a robustly predicted site-to-site and year-to-year differences in canopy heights ( R 2 = 0.88, 111 site-years). At 23 cropland/grassland sites, weekly h a successfully captured the dynamics of vegetation canopies over growing seasons ( R 2 > 0.70 in 74 site-years). Our results demonstrate the potential of flux-derived h a determination for tracking the seasonal, interannual, and/or decadal dynamics of vegetation canopies including growth, harvest, land use change, and disturbance. The large-scale and time-varying h a derived from flux networks worldwide provides a new benchmark for regional and global Earth system models and satellite remote sensing of canopy structure.

54 ENVIRONMENTAL SCIENCES↗

Efficient expulsion of magnetic flux in superconducting radiofrequency cavities for high Q{sub 0} applications

Even when cooled through its transition temperature in the presence of an external magnetic field, a superconductor can expel nearly all external magnetic flux. This paper presents an experimental study to identify the parameters that most strongly influence flux trapping in high purity niobium during cooldown. This is critical to the operation of superconducting radiofrequency cavities, in which trapped flux degrades the quality factor and therefore cryogenic efficiency. Flux expulsion was measured on a large survey of 1.3 GHz cavities prepared in various ways. It is shown that both spatial thermal gradient and high temperature treatment are critical to expelling external magnetic fields, while surface treatment has minimal effect. For the first time, it is shown that a cavity can be converted from poor expulsion behavior to strong expulsion behavior after furnace treatment, resulting in a substantial improvement in quality factor. Microscopic investigations are performed to study the relevant changes in the material from this treatment. Future plans are described to build on this result in order to optimize treatment for future cavities.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

ERUPTING FILAMENTS WITH LARGE ENCLOSING FLUX TUBES AS SOURCES OF HIGH-MASS THREE-PART CMEs, AND ERUPTING FILAMENTS IN THE ABSENCE OF ENCLOSING FLUX TUBES AS SOURCES OF LOW-MASS UNSTRUCTURED CMEs

The 3-part appearance of many coronal mass ejections (CMEs) arising from erupting filaments emerges from a large magnetic flux tube structure, consistent with the form of the erupting filament system. Other CMEs arising from erupting filaments lack a clear 3-part structure and reasons for this have not been researched in detail. This paper aims to further establish the link between CME structure and the structure of the erupting filament system and to investigate whether CMEs which lack a 3-part structure have different eruption characteristics. A survey is made of 221 near-limb filament eruptions observed from 2013 May 03 to 2014 June 30 by Extreme UltraViolet (EUV) imagers and coronagraphs. Ninety-two filament eruptions are associated with 3-part structured CMEs, 41 eruptions are associated with unstructured CMEs. The remaining 88 are categorized as failed eruptions. For 34% of the 3-part CMEs, processing applied to EUV images reveals the erupting front edge is a pre-existing loop structure surrounding the filament, which subsequently erupts with the filament to form the leading bright front edge of the CME. This connection is confirmed by a flux-rope density model. Furthermore, the unstructured CMEs have a narrower distribution of mass compared to structured CMEs, with total mass comparable to the mass of 3-part CME cores. This study supports the interpretation of 3-part CME leading fronts as the outer boundaries of a large pre-existing flux tube. Unstructured (non 3-part) CMEs are a different family to structured CMEs, arising from the eruption of filaments which are compact flux tubes in the absence of a large system of enclosing closed field.

79 ASTRONOMY AND ASTROPHYSICS↗