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126 records · Page 7

Opportunities for Process Intensification with Membranes to Promote Circular Economy Development for Critical Minerals

Critical minerals are essential to the future of clean energy, especially energy storage, electric vehicles, and advanced electronics. In this paper, we argue that process systems engineering (PSE) paradigms provide essential frameworks for enhancing the sustainability and efficiency of critical mineral processing pathways. As a concrete example, we review challenges and opportu-nities across material-to-infrastructure scales for process intensification (PI) with membranes. Within critical mineral processing, there is a need to reduce environmental impact, especially con-cerning chemical reagent usage. Feed concentrations and product demand variability require flex-ible, intensified processes. Further, unique feedstocks require unique processes (i.e., no one-size-fits-all recycling or refining system exists). Membrane materials span a vast design space that allows significant optimization. Therefore, there is a need to rapidly identify the best opportunities for membrane implementation, thus informing materials optimization with process and infrastructure scale performance targets. Finally, scale-up must be accelerated and de-risked across the materials-to-process levels to fully realize the opportunity presented by membranes, thereby fostering the development of a circular economy for critical minerals. Tackling these challenges requires integrating efforts across diverse disciplines. We advocate for a holistic molecular-to-systems perspective for fully realizing PI with membranes to address sustainability challenges in critical mineral processing. The opportunities for PI with membranes are excellent applications for emerging research in machine learning, data science, automation, and optimization.

Dougher, Molly↗

Grid Service Values of Generic Marginal Building Flexibility in Modeled 2030 U.S. Power Systems

The datasets include the capacity, energy, and ancillary service values of a marginal kilowatt-hour (kWh) of generic, daily, shiftable building flexibility as a presumed market entrant in the 2030 U.S. power systems. The results should be interpreted along with the caveats listed in "Valuation of Building Flexibility: Grid Service Value for Initial Market Entrants in Projected 2030 United States Power Systems", which also documents the methods used for the study. The factors examined in the study include: grid scenario, region, original usage hour in the day (local time), and building flexibility parameters - efficiency, dissipation, and shifting window include max pre-shift and max post-shift. Filenames in the datasets: The filenames contain information on the grid scenario, and the building flexibility efficiency and dissipation. For example: MidCase_2030_efficiency1.25_dissipation0.05_value.csv contains all results under Mid RE 2020, efficiency = 1.25, and dissipation = 0.05. * MidCase = Mid RE Each .csv file contains: region: The location of the building flexibility, aligned with U.S. Energy Information Administration (EIA) National Energy Modeling System (NEMS) Electricity Market Module regions. max_pre_shift: Part of building flexibility shifting window parameter, indicates the max number of hours the building flexibility can shift earlier. max_post_shift: Part of building flexibility shifting window parameter, indicates the max number of hours the building flexibility can shift later. local_datetime: Original datetime of 1kWh of building energy consumption. local_orig_h: Original usage hour (1-24) of building energy consumption, ignores daylight saving. local_shift_to: The datetime to when building energy consumption shifts, if shifting happens. If no shifting occurs, this cell is left blank. energy: Net energy value of energy shifting. capacity: Net capacity value of energy shifting. shifting_value: Net energy plus capacity value of energy shifting. spin: Spin reserve value at the original datetime of consumption. flex: Flexible reserve value at the original datetime of consumption. reg: Regulation reserve value at the original datetime of consumption. total_profit: Assuming the building flexibility is capable of providing energy, capacity, and ancillary services, total profit is the maximum value of energy shifting value, spin reserve value, flexible reserve value, and regulation reserve value - one of the four choices at any given hour - because we do not allow its value to be double-counted.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Studies on the Encapsulation of Brine Generated from a Process Using Selective Electrodialysis Reversal

This topical report summarizes the laboratory testing, geochemical modeling, and mineralogical testing conducted to examine the efficacy of wastewater encapsulation for the brine generated from the Saltworks Flex electrodialysis reversal technology. Within the laboratory testing, the short- and long-term physical properties of seven separate mix designs were examined along with the leaching of each mix design. Additionally, geochemical thermodynamic modeling was used along with mineralogical analyses to help gain a fundamental understanding of the chemistry involved in the encapsulation process. Encapsulation is a process that results in the immobilization of constituents of interest by creating an engineered material that contains the waste within its matrix, both physically and chemically, in such a manner that the receiving environment is protected from adverse effects. Within the context of this study, encapsulation mix designs involved mixing the Saltworks brine with fly ash and various additives, principally lime (calcium oxide) and cement, to form a paste that eventually sets and hardens into a monolith upon placement in a landfill. Moisture conditioning fly ash with wastewater sources for on-site landfill disposal is a process that is in use at some sites and has been presented as a viable option to dispose of liquid wastes. However, because chemical reactions that can lead to sequestration of constituents of interest are not optimized, leaching can occur. Therefore, in this study, mixes were created to mimic moisture conditioning, as well as engineered pastes of varying mix designs. The study found that engineered encapsulation mixes provide significant resistance to leaching compared to moisture conditioning alone. The best performing encapsulation mix used lime as the additive, which proved superior to the use of cement. After 90 days of curing, this encapsulated mix was 5.5 times stronger than the moisture conditioned mix. Additionally, this mix exhibited an approximate 2.5 order of magnitude drop in hydraulic conductivity compared to the moisture conditioned mix. When comparing leaching, nearly all the chloride was found to evolve from the moisture conditioned mix, whereas only 6.7% of the chlorine contained in the best performing encapsulated mix leached out. Mineralogical analysis via X-ray diffraction (XRD) showed a significant concentration of the chloride sequestering mineral, Friedel’s salt, in the best performing encapsulation mix, whereas none was observed in the moisture conditioned mix, pointing to it being the primary chemical mechanism for chloride retention, along with the physical impermeability of the material. With respect to the modeling study, the model was successful in predicting the presence of most mineral phases observed in the XRD analysis.

01 COAL, LIGNITE, AND PEAT↗

Tank Bottom Corrosion Induced by Anode-Generated Oxygen

Cathodic protection system using aclose coupled mixed metal oxide (MMO) anode is the corrosion prevention technique for soil-side of the aboveground storage tank (AST) bottoms. MMO anodes generate oxygen at its surfacesdue to water electrolysis at polarized potentials above a threshold; oxygen from the MMO anodes can depolarize the bottoms’polarized potentials. Further, when the tank bottom plate loses contact with the sand pad due to flexing, oxygen can accumulate in the void space and accelerate corrosion. This paper provides information on preventive measures that can be adopted to prevent oxygen concentration corrosion of the AST soil-side bottoms

36 MATERIALS SCIENCE↗

Consumer Guide to Ethanol and Flexible-Fuel Vehicles

Learn how ethanol is used in transportation fuels and about the different ethanol blends you may find at fueling stations. This fact sheet from Energy Saver includes information on the history of ethanol in the United States, what fuel ethanol is, the three categories of ethanol blends, and flex-fuel vehicles.

ethanol, flexible-fuel vehicles, E10, E15, E85, En↗

SO3/H2SO4 continuous real-time sensor demonstration at a power plant

We present results from field testing of a new, innovative sensor developed to measure SO3/H2SO4 continuously and in real time at a coal-fired power plant. The system utilizes the sensitivity, specificity, and real-time capabilities of mid-infrared (Mid-IR) laser-based sensor technology, along with a heated, close-coupled cell mounted directly to a power plant duct. Measurements were made by the laser sensor over a 2-day period and compared to results from the accepted method, EPA 8A, which requires a 30-minute collection, labor intensive processing, and off-site analysis at a lab. In contrast to the condensation method, the laser sensor continuously samples flue gas and reports measurements of the concentration of SO3/H2SO4, SO2 ever second with unattended operation. This initial demonstration proved the sensor concept and paves the way for its use for optimizing sorbent injection used to neutralize SO3/H2SO4. Optimized sorbent injection will enable significant cost savings associated with efforts to mitigate the presence and effects of SO3/H2SO4 such as “Blue Plume”, air heater fouling, and duct corrosion. In particular, the real-time, actionable information will enable better control of additive injection in flex conditions and variable fuels.

20 FOSSIL-FUELED POWER PLANTS↗

Flexible wave energy converter

Disclosed herein are flexible wave energy converters that actuate electrical generators with dynamic strain (e.g., flexing, stretching, twisting, distension) to convert wave energy to electrical energy. The flexible wave energy converter utilizes flexible electric generators embedded throughout the wave-energy converter's flexible body.

16 TIDAL AND WAVE POWER↗

The design and test results of A Giga-Bit Cable Receiver (GBCR) for the ATLAS Inner Tracker Pixel Detector

This paper presents the design and test results of a Gigabit Cable Receiver ASIC called GBCR for the HL-LHC upgrade of the ATLAS Inner Tracker (ITk) pixel detector. Three prototypes (GBCR1, GBCR2, and GBCR3) have been designed in the CERN-identified 65 nm CMOS technology. GBCR receives seven (GBCR2) or six (GBCR3) channels (RX) each at 1.28 Gbps from the front-end readout chip RD53B via flex cables up to 1 meter and Twinax cables up to 5 meters and sends the equalized and retimed signals to lpGBT. Both GBCR2 and GBCR3 ASICs have two transmitting channels (TX) that pre-emphasize the signals from lpGBT before sending them to RD53B through the same cables. No Single-Event Upset (SEU) is observed in any tested channels of GBCR2 in a 400 MeV proton beam. The extrapolated bit error rate for the future HL-LHC application is below 8*10^(-16), significantly below the specified BER criterion. GBCR3 is designed to improve the immunity to single-event-upset by applying the Triple Modular Redundancy (TMR) technology to all RX channels. The retimed signals from GBCR3 have less total jitter than those from GBCR2 (35 ps versus 79 ps). Each receiver channel of GBCR3 consumes 75% more power than that of GBCR2.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

RF signature detection for waveguide deformation

A radio frequency (RF) based waveguide health monitoring system is disclosed. The system employs an RF transmitter for launching a probe RF waveform into a waveguide. Reflections, etc., from the interior of the waveguide of the probe RF waveform create a signature RF waveform, with a health RF receiver receiving this resultant signature RF waveform. A health processing system analyzes the signature RF waveform, and when it detects a change indicative of a deformation of the waveguide, generates a warning signal. This change may be due to bends, flexes, vibrations (or changes in vibrations), or separations of the waveguide. The system may have low frequency, high frequency, or high frequency imaging modes. The system may employ a high-power probe RF waveform, thereby enabling a wireless charging system with power RF receivers located along the length of the waveguide providing additional functionality.

Curtis, Shane Keawe↗

Heat exchanger

A heat exchanger includes a shell housing a plurality of tubes and defining an exhaust fluid flow path within a first volume enclosed by the shell. The outer surfaces of the plurality of tubes are in fluid communication with the exhaust fluid flow path. The heat exchanger includes a cap attached to a first end of the shell and defining a second volume. A header is configured to separate the first volume from the second volume, flex with thermal expansion, and define tube inlet and outlet positions. The tube inlets and outlets are in fluid communication with a source fluid flow path, and each tube is substantially U-shaped and defines a flow path of the source fluid within the exhaust fluid flow path. The heat exchanger includes at least one longitudinal flow baffle within the shell configured to reduce an amount of exhaust fluid that may bypass the tubes.

Borghese, Joseph↗

Flexible wave energy converter

Disclosed herein are flexible wave energy converters that actuate electrical generators with dynamic strain (e.g., flexing, stretching, twisting, distension) to convert wave energy to electrical energy. The flexible wave energy converter utilizes flexible electric generators embedded throughout the wave-energy converter's flexible body.

30 DIRECT ENERGY CONVERSION↗

Characterizing The Mechanical Properties of Polyurethane Foams

The Department of Energy has many radioactive facilities that are on the path of deactivation and decommissioning (D and D). These facilities can sit cold and dark for many years before final disposition, and must be maintained to ensure no radiological release occurs in the interim. Improvements and additions to D and D tool sets can greatly: Save time and money, Reduce worker risk. Conventional fixatives widely used often take the form of paints or films that are not readily applicable to 3-dimensional void spaces. Foams are one promising platform that may offer solutions to a number of contaminated problem sets such as: Gloveboxes, Pipes, Tanks. SRNL is working to characterize various commercial foams that would encapsulate the interior volume of a given space and are capable of immobilizing any remaining contamination. One key performance metric of these foams is how well they will perform in an accident scenario. To this end, SRNL is researching the mechanical properties of these foams to ensure that the material can withstand the environment of application while maintaining structural integrity. ASTM standard E3191-18 served as a guiding document for this project, outlining the requirements that foaming fixatives used for the mitigation of radioactive contamination need to meet before being implemented. Objective: Quantification of the mechanical properties of 6 commercial polyurethane foams was performed using multiple ASTM standards to record measurements for: Compression testing: Flexible Foams, Force required to produce 50% compression, Rigid Foams, Compressive and apparent modulus, Point of 10% core deformation, The 'Zero Deformation' point, Compressive strength, Yield point. Tensile testing: Tensile strength, Tensile stress, Percent elongation. Experiment 1: An electromechanical compressive tester (MTS Criterion Series 43) was used to evaluate 6 foams (4 flexible, 2 rigid). Per ASTM D1621, each rigid foam was compressed at 10% of the measured thickness per minute until the sample was 13% of it's original thickness. Per ASTM D35/4, each flexible foam was pre-flexed twice to 80% original thickness at a rate of 250 mm/min, then compressed to 80% original thickness at a rate of 50 mm/min. Experiment 2: An electromechanical tensile tester (MTS Criterion Series 43) was used to evaluate 6 foams (4 flexible, 2 rigid). Per ASTM D1623, rigid foams were pulled apart at a rate of 1.27 mm/min until the sample broke. Per ASTM D35/4, flexible foams were pulled apart at a rate of 500 mm/min until the sample broke. The strongest material in both compression and tensile testing scenarios was found to be the rigid intumescent polyurethane Hilti foam. The experiments revealed that the Hilti foam in a tensile scenario had a peak stress value that was larger than the closest competitor by a factor of 2.3 and a compressive yield point that was larger than the closest competitor by a factor of 1.4, indicating that the Hilti foam is the best choice for implementation in mechanically harsh environments. The performance metrics measured can serve as a basis for future mechanical tests that would help set relevant ASTM standards (E3191) for intumescent polyurethane foams in fixating applications. Tests like surface adhesion, impact, and flame tests would serve as a better indicator as to how this material would perform in environmentally harsh scenarios often found in decommissioned nuclear facilities. Further tests of the foams' intumescent properties would also be important should these foams be implemented in environmentally harsh scenarios.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Packaging a 650V/400A GaN Half-bridge Power Module with Ultra-low Parasitics for Electric Vehicle Drive Applications

This paper proposes a compact and efficient half-bridge power module with three 650 V / 150 A GaN dies in parallel. The power module incorporates a main power printed circuit board (PCB), an interface PCB, and a flex PCB to achieve low parasitics in both power loop and gate-side connection, resolving the issue of high parasitics typically encountered with wire bonding in high-current applications. Additionally, the interface PCB decouples the design constraints between the power loop and the gate loops. The proposed design is optimized with a vertical loop configuration to reduce power loop inductance through magnetic flux cancellation. Finite element analysis indicates that the power loop inductance is 0.58 nH at 100 MHz, while the maximum die junction temperature reaches 131 °C under an ambient temperature of 65 °C and a load current of 385 A. The proposed multi-piece PCB structure reduces the inductance of the drive circuit to minimize EMI and to mitigate false triggering. At the same time, it reduces impedance mismatches across different driver circuits, thereby achieving dynamic current sharing in multi-chip parallel configurations. Under simulation conditions of 400 V / 385 A, the current imbalance among chips was limited to 5 A. A 400 V / 385 A double-pulse test was conducted to experimentally validate the performance of the proposed power module.

30 DIRECT ENERGY CONVERSION↗

Rewarding Grid-Friendly Behavior: Estimating the Potential Bill Reduction and Load Shifting Benefits of Dynamic Prices

Shifting electric load from times of peak demand can be a key strategy to slow price growth as reducing peak demand avoids the cost of upgrading generation, transmission and distribution infrastructure. Utilities are releasing time-varying prices, such as time of use rates or dynamic prices, to incentivize grid-friendly load shifting. New dynamic price programs provide insight into the true cost of operating electricity grids and the potential economic benefits of load shifting. Program developers and device manufacturers need to understand the economic opportunities in terms of 1) the variation in prices across hours, days, and seasons; 2) the change in utility bills for customers who don’t shift load; and 3) the potential load shifted and economic value of different technologies if manufacturers or aggregators deploy price-responsive controls. This paper estimates possible impacts of dynamic price adoption and load shifting controls if customers paid the dynamic rate from one pilot program. Statistical analysis of historical prices identified annual and seasonal metrics as well as representative price curves for each circuit in the pilot. Simulations for residential technologies with price-responsive controls including unitary heat pump water heaters, central multifamily heat pump water heaters, heating & cooling + storage systems, and pool pumps estimated the potential impacts of highly dynamic prices both with and without load shifting controls. Results showed the potential to reduce electricity costs on representative days by 42-94% and reduce consumption during times of high electricity prices by 63-100% compared to baseline operation for those flex-friendly devices.

Grant, Peter↗

Harmonizing solar induced fluorescence across spatial scales, instruments, and extraction methods using proximal and airborne remote sensing: A multi-scale study in a soybean field

Solar-induced chlorophyll fluorescence (SIF) has been widely used to track vegetation photosynthesis at different scales ranging from in-situ measurements to satellite products. Airborne platforms sample SIF data at a spatial scale intermediate between in-situ and satellite, matching that of ground measurement (e.g. flux tower footprints and other field sampling), enabling us to explore causes of SIF variation and validate satellite-based SIF products. However, harmonizing SIF across sensors and platforms (correcting for systematic errors to yield a consistent, comparable SIF product) is challenging because SIF can be retrieved in different absorption windows, with different instruments and methods complicating the comparison between different observational levels (i.e., ground, airborne, satellites) and between sites equipped with different instruments with varying optical properties (spectral resolution and sampling intervals, spatial resolution). Additionally, the spatial and temporal variability of atmospheric properties can influence the retrieval of the weak SIF signal. Because of these complications, direct comparisons of airborne and ground SIF across scales are rarely attempted. Here, in this study, we combined airborne SIF data with simultaneous ‘ground truth’ data collected by stationary and mobile platforms in a soybean field in Nebraska, USA. In this effort, we tested several SIF extraction methods, including Fraunhofer Line Discrimination (FLD), improved Fraunhofer Line Discrimination (iFLD), Spectral Fitting Method (SFM), SpecFit, and a Singular Vector Decomposition (SVD) method. The SpecFit method was sensitive to the 715–740 nm water bands and removing the water bands in the fitting process yielded better agreement between the airborne and ground SIF spectra. Accurate estimation of the ground level downwelling irradiance obtained by ground measurements over a calibration target improved agreement between airborne and ground SIF retrievals at the O 2 A band, and allowed us to derive a SIF dataset with improved agreement across platforms and sampling scales. This experimental approach provided a method for generating comparable SIF signals across instruments, methods and platforms, which is critical to understanding the SIF-GPP relationship at different scales and to cross-validate the diversity of platforms used for satellite products calibration and validation.

54 ENVIRONMENTAL SCIENCES↗

Mixing-Controlled Combustion of Ethanol Enabled by Prechamber Ignition (PC-MCC): A Preliminary Experimental Demonstration

This experimental study presents preliminary investigations of prechamber-enabled mixing-controlled combustion (PC-MCC) at −2 bar brake mean effective pressure (BMEP) and 2200 rpm with fuel-grade ethanol (E98). Experimental results are conducted on a prechamber retrofitted single-cylinder Caterpillar C9.3B test engine. First, a series of prechamber-only experiments were conducted with a motored engine to evaluate the salient combustion trends in response to relevant prechamber operating parameters. Under firing conditions, the prechamber operating strategy was assessed with respect to the impact on ignition assistance of direct-injected E98 and overall engine performance. The preliminary results indicate the jet-induced ignition process is robust and prompts diffusion combustion of E98 at diesel-like boundary conditions. Here, the effect of external exhaust gas recirculation (EGR) on the residual tolerance of the prechamber combustion process was also investigated and showed stable combustion in both the main chamber and prechamber up to 30% EGR. Experiments were also conducted with the stock diesel engine for baseline comparison. At matched combustion phasing, mixing-controlled combustion of ethanol enabled by prechamber ignition was able to achieve heightened gross thermal efficiency while simultaneously reducing NOx and practically eliminating smoke emissions relative to diesel combustion. In addition, the covariance of load and standard deviation of combustion phasing was diesel-like and less than 2% and 1 CAD, respectively.

PC-MCC↗

An Approach to Dynamic Human Reliability Analysis using EMRALD Dynamic Risk Assessment Tool

Research for dynamic human reliability analysis (HRA) (a.k.a., simulation-based or computation-based HRA) has been required, as many researchers have emphasized the importance of dynamic approaches to probabilistic safety assessment (PSA). This study proposes the PRocedure-based Investigation Method of EMRALD Risk Assessment – Human Reliability Analysis (PRIMERA-HRA) method, which is an approach to dynamic HRA using the Event Modeling Risk Assessment using Linked Diagram (EMRALD) software developed by Idaho National Laboratory (INL). In this study, how to model human actions using the software and evaluate the error probabilities is suggested. The applicability of this approach will be also investigated through an extended loss of AC power (ELAP) scenario. Then, major insights from this dynamic HRA approach against the static one will be discussed in the paper.

99 GENERAL AND MISCELLANEOUS↗