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At least 127 records · Page 7

High-Speed OH-PLIF Diagnostics of Flame Flashback in Low Swirl Hydrogen-Enriched Flames

Hydrogen-enrichment is a potential strategy to reduce carbon emissions for the development of next-generation lean premixed combustors. However, the higher flashback propensity with hydrogen enrichment owing to the faster chemical kinetics is one of the key challenges in existing natural gas turbine combustors. The fundamentals of stabilized flame dynamics and flashback events in a premixed low swirl burner (LSB) configuration are visualized experimentally using nanosecond (ns)-based high-speed hydroxyl radical planar laser-induced fluorescence (OH-PLIF). Swirlers with two different turning angles, 26 and 33 and three different center-body hole diameters, 1.08, 1.12 and 1.16 mm with measured swirl numbers varying from 0.43 to 0.49 are tested in this study at atmospheric temperature and pressure inlet conditions. The inlet conditions are varied systematically with respect to pre-mixer velocities (V), flame equivalence ratio (ϕ) and hydrogen content (X_(H_2 )) for 50%-90% (H2, by mole) H2/ CH4 reactant mixtures and OH-PLIF characterization is performed in a stable flame at 20 kHz repetition rate. An increase in flashback propensity is observed with increasing ϕ, X_(H_2 ) and decreasing V via detailed investigation of flame lift-off length (L) above the burner rim.

Parajuli, Pradeep↗

FLAMES IN TYPE Ia SUPERNOVA: DEFLAGRATION-DETONATION TRANSITION IN THE OXYGEN-BURNING FLAME

The flame in a Type Ia supernova is a conglomerate structure that, depending on density, may involve separate regions of carbon, oxygen, and silicon burning, all propagating in a self-similar, subsonic front. The separation between these three burning regions increases as the density declines until eventually, below about 2 x 10{sup 7} g cm{sup -3}, only carbon burning remains active, the other two burning phases having 'frozen out' on stellar scales. Between 2 and 3 x 10{sup 7} g cm{sup -3}, however, there remains an energetic oxygen-burning region that trails the carbon burning by an amount that is sensitive to the turbulence intensity. As the carbon flame makes a transition to the distributed regime (Karlovitz number {approx}> 10), the characteristic separation between the carbon- and oxygen-burning regions increases dramatically, from a fraction of a meter to many kilometers. The oxygen-rich mixture between the two flames is created at a nearly constant temperature, and turbulence helps to maintain islands of well-mixed isothermal fuel as the temperature increases. The delayed burning of these regions can be supersonic and could initiate a detonation.

79 ASTRONOMY AND ASTROPHYSICS↗

Prediction of flame velocities of hydrocarbon flames

The laminar-flame-velocity data previously reported by the Lewis Laboratory are surveyed with respect to the correspondence between experimental flame velocities and values predicted by semitheoretical and empirical methods. The combustible mixture variables covered are hydrocarbon structure (56 hydrocarbons), equivalence ratio of fuel-air mixture, mole fraction of oxygen in the primary oxygen-nitrogen mixture (0.17 to 0.50), and initial mixture temperature (200 degrees to 615 degrees k). The semitheoretical method of prediction considered are based on three approximate theoretical equations for flame velocity: the Semenov equation, the Tanford-Pease equation, and the Manson equation.

Dugger, Gordon L↗

Refractory Materials for Flame Deflector Protection System Corrosion Control: Flame Deflector Protection System Life Cycle Cost Analysis Report

A 20-year life cycle cost analysis was performed to compare the operational life cycle cost, processing/turnaround timelines, and operations manpower inspection/repair/refurbishment requirements for corrosion protection of the Kennedy Space Center launch pad flame deflector associated with the existing cast-in-place materials and a newer advanced refractory ceramic material. The analysis compared the estimated costs of(1) continuing to use of the current refractory material without any changes; (2) completely reconstructing the flame trench using the current refractory material; and (3) completely reconstructing the flame trench with a new high-performance refractory material. Cost estimates were based on an analysis of the amount of damage that occurs after each launch and an estimate of the average repair cost. Alternative 3 was found to save $32M compared to alternative 1 and $17M compared to alternative 2 over a 20-year life cycle.

Calle, Luz Marina↗

Increasing flame ionization detector (FID) sensitivity using post-column oxidation–methanation

The flame ionization detector (FID) is a robust tool in gas chromatography (GC) due to its sensitivity and linear response in the detection of common organic compounds. However, FID response to oxygenated or highly functionalized organic molecules is low, or in some cases non-existent, making it difficult or impossible to detect and quantify some organic compounds. In this work, the combination of a GC/FID system with a catalytic microreactor, which performs post-column combustion–methanation to convert organic compounds to methane, is shown to be an effective approach for quantifying low-response organic compounds. Molecules that were previously undetectable by conventional FID, including carbon monoxide and carbon dioxide, respond with the same high response of methane in the FID. Low-response molecules, including formaldehyde, formic acid, formamide, and ten other oxygenates also demonstrated enhanced detector response equivalent to that of methane in the FID. Here, the linear response of the FID to these molecules and the equivalent sensitivity to methane indicate that accurate quantification is possible without the usual calibration-corrections (e.g., response factors or correction factors) to the FID response.

99 GENERAL AND MISCELLANEOUS↗

Comparison of Center Nozzle Staging to Outer Nozzle Staging in a Multi-Flame Combustor

Combustion instability in gas turbines is often mitigated using fuel staging, a strategy where the fuel is split unevenly between different nozzles of a multiple-nozzle combustor. This work examines the efficacy of different fuel staging configurations by comparing axisymmetric and non-axisymmetric fuel staging in a four-around-one model gas turbine combustor. Fuel staging is accomplished by increasing the equivalence ratio of the center nozzle (axisymmetric staging) or an outer nozzle (non-axisymmetric staging). When the global equivalence ratio is ϕ = 0.70 and all nozzles are fueled equally, the combustor undergoes longitudinal, self-excited oscillations. These oscillations are suppressed when the center nozzle equivalence ratio is increased above ϕ Staging = 0.79. This bifurcation equivalence ratio varies between ϕ Staging = 0.86 and ϕ Staging = 0.76 for the outer nozzles, and is attributed to minor hardware differences between each nozzle. High speed CH* chemiluminescence images in combination with dynamic pressure measurements are used to determine the instantaneous phase difference between the heat release rate fluctuation and the combustor pressure fluctuation throughout the combustor. This analysis shows that the staged flame has similar phase relationships for all staging configurations. It is found that axisymmetric staging can be as effective as non-axisymmetric staging; however, the aforementioned hardware variations can impact both the bifurcation equivalence ratio and the effectiveness of staging.

Culler, Wyatt↗

An active particle diffusion theory of flame quenching for laminar flames / Dorothy M. Simon and Frank E. Belles

An equation for quenching distance based on the destruction of chain carriers by the surface is derived. The equation expresses the quenching distance in terms of the diffusion coefficients and partial pressures of the chain carriers and gas phase molecules, the efficiency of the surface as a chain breaker, the total pressure of the mixture, and a constant which depends on the geometry of the quenching surface. Quenching distances measured by flashback for propane-air flames are shown to be consistent with the mechanism. The derived equation is used with the lean inflammability limit and a rate constant calculated from burning velocity data to estimate quenching distances for propane-air (hydrocarbon lean) flames satisfactorily.

Simon, Dorothy M↗

Triple flames in microgravity flame spread

The purpose of this project is to examine in detail the influence of the triple flame structure on the flame spread problem. It is with an eye to the practical implications that this fundamental research project must be carried out. The microgravity configuration is preferable because buoyancy-induced stratification and vorticity generation are suppressed. A more convincing case can be made for comparing our predictions, which are zero-g, and any projected experiments. Our research into the basic aspects will employ two models. In one, flows of fuel and oxidizer from the lower wall are not considered. In the other, a convective flow is allowed. The non-flow model allows us to develop combined analytical and numerical solution methods that may be used in the more complicated convective-flow model.

Wichman, Indrek S.↗