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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Degradation of Spacesuit Fabrics Exposed to Low Earth Orbit

Two different outer spacesuit fabrics were exposed to the wake-side low Earth orbit (LEO) environment for two years in order to determine their long term durability in the space environment. One sample each of the Teflon fabrics that covered Apollo spacesuits and the Orthofabric that covers the Space Shuttle and ISS suits was flown on the ISS as part of the ORMatE-III experiment. Results were compared with previous experiment on MISSE-7 which had similar exposure conditions on the ISS for 18 months, as well as β-cloth exposures on the LDEF for 5.7 years and an ISS battery ORU that was exposed for 8 years. Both ORMatE-III samples darkened considerably, probably due to UV and high energy particle radiation. Spectral analysis showed increased absorption in the shorter than 500 nm portion of the spectrum, but became more reflective in the 500 to 1800 nm region, and as a result, there was little change in the absorptance of the fabrics. Measurement of the 2.5 to 25 μm spectra indicated that there was only a small change in the emittance of the fabrics in the 250 to 700 K. Thus, although on long exposure the spacesuits are expected to darken to the eye, their thermal properties will likely remain nearly constant for the Apollo FEP fabric, and will degrade only slowly for the Orthofabric. Although these sample were too small to characterize their mechanical properties, degradation of the MISSE-7 samples as well as metalized FEP films on the Hubble Space Telescope thermal shields suggest that long term exposure of these fabrics to the space radiation environments will cause them to embrittle.

Atomic Oxygen↗

Systematic determination of a material’s magnetic ground state from first principles

Abstract We present a self-consistent method based on first-principles calculations to determine the magnetic ground state of materials, regardless of their dimensionality. Our methodology is founded on satisfying the stability conditions derived from the linear spin wave theory (LSWT) by optimizing the magnetic structure iteratively. We demonstrate the effectiveness of our method by successfully predicting the experimental magnetic structures of NiO, FePS 3 , FeP, MnF 2 , FeCl 2 , and CuO. In each case, we compared our results with available experimental data and existing theoretical calculations reported in the literature. Finally, we discuss the validity of the method and the possible extensions.

Chemistry↗

Synthesis and Crystal Structures of Alkali (Na, Rb, Cs) Iron Phosphate Crystals

Three alkali-containing diphosphate crystals of A FeP 2 O 7 (A = Na, Rb, Cs) were synthesized through melt-crystallization. The crystal structures were determined using single-crystal X-ray diffraction (XRD) data. The synthesized diphosphates crystallized within the P 2 1 /c space group, and the structural parameters were compared to literature data of other A FeP 2 O 7 crystals within the P 2 1 /c space group.

36 MATERIALS SCIENCE↗

Investigation of space stable thermal control coating properties

A capability to study the nuclear magnetic resonance of spacecraft thermal control coating has been built utilizing an electromagnet and V-series and Wl-series electronics. The electronics associated with the electromagnet had to be modified to make it compatible with the resonance measuring system. Resonance measurements have been performed on ZnO, Zn2TiO4 and FEP Teflon. The failure to observe resonance in ZnO and Zn2TiO4 has been theoretically explained. The linewidth and second moment measurements on ultraviolet irradiated FEP Teflon showed that there was no measurable degradation of the material due to short term irradiation.

Mookherji, T.↗

Measured current drainage through holes in various dielectrics up to 2 kilovolts in a dilute plasma

The electron current drained from a plasma through approximately 0.05 cm diameter holes in eight possible space applicable dielectrics placed on a probe biased at voltages up to 2000 V dc have been determined both theoretically and experimentally. The dielectrics tested were Parylene C and N, Teflon FEP type C, Teflon TFE, Nomex, quartz 7940 Corning Glass, Mylar A, and Kapton H polymide film. A Laplace field was used to predict an upper limit for the drainage current. The measured current was less than the computed current for quartz, Teflon FEP, and the 0.0123 cm thick sample of Parylene N for all voltages tested. The drainage current through the other dielectrics became equal to or greater than the computed current at a voltage below 2000 V. The magnitudes of the currents were between 0.1 and 10 microamperes for most of the dielectrics.

Grier, N. T.↗

Evaluation of advanced bladder technology

Research conducted during this period is reported. Studies presented include: (1) diffusion and permeation of CO2, O2, N2, and NO2 through polytetra fluoroethylene; (2) diffusion, permeation and solubility of simple gases (CO2, O2, N2, CH4, C2H6, C3H8, and C2H4) through a copolymer of hexafluoro propylene and tetrafluoro ethylene (FEP); (3) viscous flow and diffusion of gases throug small apertures; (4) diffusion and permeation of O2, N2, CO2, CH4, C2H6, and C3H8 through nitroso rubber; and (5) results of gas transport studies with carborane siloxane, nitroso rubber, silicone membrane, krytox coating on teflon, and FEP coated glass cloth. Publications generated under this program are listed.

Christensen, M. V.↗

Current drainage to a high voltage probe in a dilute plasma.

The current drainage from a plasma through approximately 0.05 cm diameter holes in Kapton H polymide film, FEP type C, and quartz (7940 Corning glass) placed on a probe at voltages up to 2000 volts dc have been determined both analytically and experimentally. A Laplace field was used to numerically predict an upper limit for the drainage current. The measured current was less than the calculated current for the FEP and quartz, and the two were approximately in agreement for Kapton H. The measured currents were on the order of 5 microamperes with the calculated currents on the order of 10 microamperes.

Grier, N. T.↗

Design and development of pressure and repressurization purge system for reusable space shuttle multilayer insulation system

The experimental determination of purge bag materials properties, development of purge bag manufacturing techniques, experimental evaluation of a subscale purge bag under simulated operating conditions and the experimental evaluation of the purge pin concept for MLI purging are discussed. The basic purge bag material, epoxy fiberglass bounded by skins of FEP Teflon, showed no significant permeability to helium flow under normal operating conditions. Purge bag small scale manufacturing tests were conducted to develop tooling and fabrication techniques for use in full scale bag manufacture. A purge bag material layup technique was developed whereby the two plys of epoxy fiberglass enclosed between skins of FEP Teflon are vacuum bag cured in an oven in a single operation. The material is cured on a tool with the shape of a purge bag half. Plastic tooling was selected for use in bag fabrication. A model purge bag 0.6 m in diameter was fabricated and subjected to a series of structural and environmental tests simulating various flight type environments. Pressure cycling tests at high (450 K) and low (200 K) temperature as well as acoustic loading tests were performed. The purge bag concept proved to be structurally sound and was used for the full scale bag detailed design model.

Source record↗

Method of producing a storage bulb for an atomic hydrogen maser

A storage bulb for an atomic hydrogen maser is produced by coating its internal surface with an emulsion containing both TFE and FEP particles. The emulsion is produced by mixing a first quantity of TFE in an aqueous dispersion with a second quantity of FEP in an aqueous dispersion, with a third quantity of distilled water. The emulsion is poured into the bulb to coat it uniformly so as to form a thin film of emulsion on the bulb's internal surface. After excess emulsion is drained out of the bulb the emulsion in the bulb is dried to remove the water and most of the aqueous matter therefrom. The remaining emulsion is then cured by heating the bulb to a temperature of at least 380 C.

Erpenbach, H.↗

Early results of the ATS-6 solar cell flight experiment

This paper presents preliminary ATS-6 solar-cell flight-experiment data through the first 247 days in synchronous orbit. The experiment is transmitting data on forty 2 x 2-cm solar cells representing 16 solar-cell configurations. The experiment is designed to study the effect of this orbit on select solar cells and cover-glass parameters such as solar-cell thickness and base resistivity, cover-glass thickness variation, new cover processes, and materials such as 7940 and 7070 integral covers as well as the FEP covers, the COMSAT 'violet' cell, and backside irradiation effects. The in-space solar-cell data indicate short-circuit currents are running higher by 1% to 8% than in measurements made with solar simulations; maximum power varied between -1% and +6%. Degradation of short-circuit current due to ultraviolet effects was determined to be about 2% after 50 days in orbit. All cells performed well through 247 days in orbit except the FEP-covered cells, which appear to have increased their rate of degradation during the eclipse season.

Goldhammer, L. J.↗

Preliminary results of accelerated exposure testing of solar cell system components

Plastic samples and solar cell sub modules were exposed to an accelerated outdoor environment in Arizona and an accelerated simulated environment in a cyclic ultraviolet exposure tester which included humidity exposure. These tests were for preliminary screening of materials suitable for use in the manufacture of solar cell modules which are to have a 20-year lifetime. The samples were exposed for various times up to six months, equivalent to a real time exposure of four years. Suitable materials were found to be FEP-A, FEP-C, PFA, acrylic, silicone compounds and adhesives and possibly parylene. The method of packaging the sub modules was also found to be important to their performance.

Anagnostou, E.↗

Optical and electrical properties of ion beam textured Kapton and Teflon

An electron bombardment argon ion source was used to ion etch polyimide (Kapton) and fluorinated ethylene, FEP (Teflon). Samples of polyimide and FEP were exposed to (0.5-1.0) keV Ar ions at ion current densities of (1.0-1/8) mA/sq cm for various exposure times. Changes in the optical and electrical properties of the samples were used to characterize the exposure. Spectral reflectance and transmittance measurements were made between 0.33 and 2.16 micron m using an integrating sphere after each exposure. From these measurements, values of solar absorptance were obtained. Total emittance measurements were also recorded for some samples. Surface resistivity was used to determine changes in the electrical conductivity of the etched samples. A scanning electron microscope recorded surface structure after exposure. Spectral optical data, resistivity measurements, calculated absorptance and emittance measurements are presented along with photomicrographs of the surface structure for the various exposures to Ar ions.

Mirtich, M. J.↗

The SYSGEN user package

The user documentation of the SYSGEN model and its links with other simulations is described. The SYSGEN is a production costing and reliability model of electric utility systems. Hydroelectric, storage, and time dependent generating units are modeled in addition to conventional generating plants. Input variables, modeling options, output variables, and reports formats are explained. SYSGEN also can be run interactively by using a program called FEPS (Front End Program for SYSGEN). A format for SYSGEN input variables which is designed for use with FEPS is presented.

Carlson, C. R.↗

Accelerated Alpha-s deterioration in a geostationary orbit

Between the Teflon substrate and the interference filter a 2 micron varnish layer was sandwiched in. The bending radius of the SSM, measured on a cone, decreased from about 13 mm to 6 mm prior to interference filter fracture, due to increased tensile strength of its substrate. These samples, and for comparison samples of the same make but without varnish and a conductive layer were included in the test. Additionally 2 Teflon FEP samples without the protective interference filter, one of them with a conductive layer, were tested. The sample substrate was 125 micron Teflon FEP, with vapor deposited silver reflector and a thin Inconel film for corrosion protection.

Husmann, O. K.↗

Solar array system for solar maximum mission

The paper describes the design of the solar array system (SAS) for the Solar Maximum Mission, the unique features of the SAS, and the results of its successful in-orbit operation. It is noted that the array was unique in that: (1) major weight concessions were made to produce a dynamically stiff array; (2) it was the first array designed to be compatible with the NASA Multimission Modular Spacecraft; (3) it is the first jettisonable solar array; and (4) it represents the first use of FEP-bonded overslides on a prime power array. It is concluded that the array performed as predicted with no evidence of the FEP causing any unusual array power degradations. In addition, the deployment and telemetry systems performed as designed.

Meese, R. A.↗

Thermal components for 1.8 K space cryogenics

Work of the summer 1986 is summarized in three areas. First, conceptual design of a laboratory system for heat exchanger evaluation in conjunction with the operation of a thermally activated fountain effect pump (FEP) is presented. Second, Knudsen effect evaluation of fine porous media useful for the pressurization plug which forms the main component of the FEP is described. Third, proof-of-principle test of the lab system selected on the basis of the evaluation is summarized.

Chen, W. E. W.↗

Temperature rise in superfluid helium pumps

The temperature rise of a fountain effect pump (FEP) and of a centrifugal pump (CP) are compared. Calculations and estimates presented here show that under the operating conditions expected during the resupply of superfluid helium in space, a centrifugal pump will produce a smaller temperature rise than will a fountain effect pump. The temperature rise for the FEP is calculated assuming an ideal pump, while the temperature rise of the CP is estimated from the measured performance of a prototype pump. As a result of this smaller temperature rise and of the different operating characteristics of the two types of pumps, transfers will be more effective using a centrifugal pump.

Kittel, Peter↗

Performance test of a laboratory pump liquid transfer based on the fountain effect

A laboratory scale pump has been tested in detail in order to determine the flow characteristics of a heater-activated all-metal thermomechanical pump (fountain effect pump, FEP). The emphasis is on the functional dependence of the fountain pressure difference versus mass throughput. A modified Vote et al. (1971) power law approximation is employed for a simplified description of the flow rate as a function of the driving force. Flow rates of up to 10 liters/(hr/sq cm) have been obtained despite a large nominal pore size of the porous plug of 2 microns (filtration rating) used for the FEP.

Chen, W. E. W.↗