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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Hydrogen emission-line spectra in quasars and active galactic nuclei

An attempt is made to account for the observational fact that the intensity ratios of the lower Balmer lines seen in emission from QSOs, type 1 Seyfert galaxies, and other related active galaxies are not what would be expected from the conventional picture of lines generated in a recombining hydrogen plasma. Previous observations of emission-line intensities in QSOs and Seyfert galaxies are reviewed. The various processes included in the rate coefficients of the calculations are then described, viz., free-free, bound-free, and bound-bound transitions, radiative transfer, and angular-momentum mixing. The strengths of the various emission lines are calculated by using more accurate values for the transition rates, including excitation and deexcitation simultaneously, and providing for finite rates in optically forbidden transitions. Numerical results are presented for the cases of ground-state collisional excitation, reabsorption of the upper Balmer lines, and collisional deexcitation. The results are applied to construct a model for the emission-line gas in a QSO and to discuss limits on models of Seyfert galaxies.

Krolik, J. H.↗
NASA NTRS1986

Analysis of far-infrared emission Fourier transform spectra

An analysis method that uses the nonlinear least-squares fit technique has been developed for emission spectra obtained with a Fourier transform spectrometer. This method is used for the analysis of submillimeter-region atmospheric emission spectra obtained with a balloon-borne FT spectrometer that was carried out as a correlative measurement for the Limb IR Monitor of the Stratosphere (LIMS) satellite experiment. The retrieved mixing ratios of H2O and O3 in the stratosphere from four spectral intervals have standard deviations of about 10 percent, and the average values agree to within 10 percent of corresponding results from the LIMS satellite experiment which used a broadband emission radiometer in the IR region.

Park, J. H.↗
NASA NTRS1991

Mapping compositional and particle size variations across Silver Lake Playa: Relevance to analyses of Mars TIR data

The high spectral and spatial resolution thermal infrared (TIR) data to be acquired from the upcoming Mars Observer-Thermal Emission Spectra (TES) mission will map the composition and texture of the Martian sediments. To prepare for these data, portions of two remote sensing experiments were conducted to test procedures for extracting surface property information from TIR data. Reported here is the continuing analysis of Thermal Infrared Multispectral Scanner (TIMS) data, field emission spectra, laboratory Fourier Transform Infrared (FTIR) reflectance spectra, and field observations with respect to the physical characteristics (composition, emissivity, etc.) of Silver Lake playa in southern California.

Petroy, S. B.↗
NASA NTRS2011

Radiation Modeling for the Reentry of the Hayabusa Sample Return Capsule

Predicted shock-layer emission signatures of the Japanese Hayabusa capsule during its reentry are presented for comparison with flight measurements made during an airborne observation mission using NASA s DC-8 Airborne Laboratory. For each altitude, lines of sight were extracted from flow field solutions computed using an inhouse high-fidelity CFD code, DPLR, at 11 points along the flight trajectory of the capsule. These lines of sight were used as inputs for the line-by-line radiation code NEQAIR, and emission spectra of the air plasma were computed in the wavelength range from 300 nm to 1600 nm, a range which covers all of the different experiments onboard the DC-8. In addition, the computed flow field solutions were post-processed with the material thermal response code FIAT, and the resulting surface temperatures of the heat shield were used to generate thermal emission spectra based on Planck radiation. Both spectra were summed and integrated over the flow field. The resulting emission at each trajectory point was propagated to the DC-8 position and transformed into incident irradiance. Comparisons with experimental data are shown.

Winter, Michael W.↗
NASA NTRS2019

Radiation Modeling for the Reentry of the Hayabusa Sample Return Capsule

Predicted shock-layer emission signatures during the reentry of the Japanese Hayabusa capsule are presented and compared with flight measurements conducted during an airborne observation mission in NASA's DC-8 Airborne Laboratory. For selected altitudes at 11 points along the flight trajectory of the capsule, lines of sight were extracted from flow field solutions computed using the in-house high-fidelity CFD code, DPLR. These lines of sight were used as inputs for the line-by-line radiation code NEQAIR, and emission spectra of the air plasma were computed in the wavelength range from 300 nm to 1600 nm, a range which covers all of the different experiments onboard the DC-8. In addition, the computed flow field solutions were post-processed with the material thermal response code FIAT, and the resulting surface temperatures of the heat shield were used to generate thermal emission spectra based on Planck radiation. Both spectra were summed and integrated over the flow field. The resulting emission at each trajectory point was propagated to the DC-8 position and transformed into incident irradiance to be finally compared with experimental data.

shock-layer radiation↗
NASA NTRS2003

Foliar Reflectance and Fluorescence Responses for Corn and Soybean Plants Under Nitrogen Stress

We are investigating the use of spectral indices derived from actively induced fluorescence spectra and passive optical spectra. We examined the influence of photosynthetic pigment, carbon (C) and nitrogen (N) content on the spectral fluorescence and passive optical property characteristics of mature, upper leaves from plants provided different N fertilizer application rates: 20%, 50%, 100% and 150% of recommended N levels. A suite of optical, fluorescence, and biophysical measurements were collected on leaves from field grown corn (Zea mays L.) and soybean plants (Glycine max L.) grown in pots (greenhouse + ambient sunlight. Steady state laser-induced fluorescence emission spectra (5 nm resolution) were obtained from adaxial and abaxial surfaces resulting from excitation at single wavelengths (280, 380 or 360, and 532 nm). For emission spectra produced by each of these excitation wavelengths, ratios of emission peaks were calculated, including the red far-red chlorophyll fluorescence (ChlF) ratio (F685/F740) and the far-red/green (F740/F525) ratio. High resolution (< 3 nm) optical spectra (350-2500 nm) of reflectance, transmittance, and absorptance were also acquired for both adaxial and abaxial leaf surfaces. Species differences were demonstrated for several optical parameters. A 'red edge' derivative ratio determined from transmittance spectra [as the maximum first deivative, between 650-750 nm, normalized to the value at 744 nm, or Dmax/D744], was strongly associated with the C/N ratio (r(exp 2) = 0.90, P +/- 0.001). This ratio, calculated from reflectance spectra, was inversely related to chlorophyll b content (r(exp 2) = 0.91, P +/- 0.001) as was the ChlF (F685/F740) ratio obtained with 532 nm excitation (r(exp 2) = 0.76, P +/- 0.01). Discrimination of N treatment groups was possible with specific fluorescence band ratios (e.g., F740/F525 obtained with 380 nm excitation). Higher ChlF and blue-green emissions were measured from the abaxial leaf surfaces. Abaxial surfaces also produced higher reflectances, in general, in the 400-800 nm spectrum.

Middleton, E. M.↗
NASA NTRS1992

X-ray emission-line spectra of photoionized plasmas - Density sensitivity of the Fe L-shell series

The circumsource environments of accretion-powered X-ray sources are likely to support relatively dense (greater than 10 exp 11/cu cm) photoionized X-ray emission-line regions. The Fe L-shell ions provide a versatile class of plasma diagnostics in this regime, their multielectron structures resulting in diverse spectral phenomena. Attention is given to the spectral response of Fe L-shell ions to variations in electron density over the range 10 exp 11 to 10 exp 16/cu cm. It is found that density-sensitive line ratios exist in the wavelength interval 12-17 A for the ions Fe XVII-XXI. The prominent role of radiative recombination in the population kinetics distinguishes the density-sensitive Fe lines in photoionized plasmas from those which operate in coronal equilibrium plasmas. The results of detailed atomic modeling of these ions are presented and applications to spectroscopic observations of accretion-driven X-ray sources are discussed.

Liedahl, Duane A.↗
NASA NTRS2000

Peripherally hydrogenated neutral polycyclic aromatic hydrocarbons as carriers of the 3 micron interstellar infrared emission complex: results from single-photon infrared emission spectroscopy

Infrared emission spectra of five gas-phase UV laser-excited polycyclic aromatic hydrocarbons (PAHs) containing aliphatic hydrogens are compared with the main 3.3 microns and associated interstellar unidentified infrared emission bands (UIRs). We show that neutral PAHs can account for the majority of the 3 microns emission complex while making little contribution to the other UIR bands; peripherally hydrogenated PAHs produce a better match to astrophysical data than do those containing methyl side groups; 3.4 microns plateau emission is shown to be a general spectral feature of vibrationally excited PAHs containing aliphatic hydrogens, especially those containing methyl groups; and finally, hot-band and overtone emissions arising from aromatic C-H vibrations are not observed in laboratory emission spectra, and therefore, in contrast to current assignments, are not expected to be observed in the UIRs.

NASA Discipline Exobiology↗
NASA NTRS1989

A user-friendly, menu-driven, language-free laser characteristics curves graphing program for desk-top IBM PC compatible computers

A facility was established that uses collected data and feeds it into mathematical models that generate improved data arrays by correcting for various losses, base line drift, and conversion to unity scaling. These developed data arrays have headers and other identifying information affixed and are subsequently stored in a Laser Materials and Characteristics data base which is accessible to various users. The two part data base: absorption - emission spectra and tabulated data, is developed around twelve laser models. The tabulated section of the data base is divided into several parts: crystalline, optical, mechanical, and thermal properties; aborption and emission spectra information; chemical name and formulas; and miscellaneous. A menu-driven, language-free graphing program will reduce and/or remove the requirement that users become competent FORTRAN programmers and the concomitant requirement that they also spend several days to a few weeks becoming conversant with the GEOGRAF library and sequence of calls and the continual refreshers of both. The work included becoming thoroughly conversant with or at least very familiar with GEOGRAF by GEOCOMP Corp. The development of the graphing program involved trial runs of the various callable library routines on dummy data in order to become familiar with actual implementation and sequencing. This was followed by trial runs with actual data base files and some additional data from current research that was not in the data base but currently needed graphs. After successful runs, with dummy and real data, using actual FORTRAN instructions steps were undertaken to develop the menu-driven language-free implementation of a program which would require the user only know how to use microcomputers. The user would simply be responding to items displayed on the video screen. To assist the user in arriving at the optimum values needed for a specific graph, a paper, and pencil check list was made available to use on the trial runs.

Klutz, Glenn↗
NASA NTRS1988

Far-infrared measurement of stratospheric carbon monoxide

The stratospheric vertical distribution of CO is obtained from balloon-based FIR limb thermal emission spectra by analyzing several limb sequences of the R8 and R1 spectral lines at 34.588 and 49.932/cm, respectively. This constitutes the first determination of the stratospheric CO profile from IR thermal emission spectra. The results, indicating 24.6 + or - 7.6 ppbv at 21 km and 34.4 + or - 10.1 ppbv at 37 km, are compared with the remote-sensing and in situ measurements by other groups and with photochemical-dynamical model calculations.

Abbas, M. M.↗
NASA NTRS1989

F.T. spectroscopy of OH produced in a microwave surface plasma

Emission spectra of the hydroxyl radical have been recorded between 450 and 4200/cm at 0.0027/cm unapodized resolution from an air+oxygen+water vapor plasma, using a surface microwave discharge. The characteristics of the source are described. The emission spectra were recorded with the F.T. spectrometer using a GeCu detector and KCl beams plitter. High J values were observed both for the pure rotational transition in v=0 and v=1 vibrational levels, and for the rovibrational transition in the 0-1 and 1-2 bands. The set of line intensity data will be used to compute the electric dipole moment function of OH.

Benidar, A.↗
NASA NTRS1988

Determination of rock type on Mercury and the moon through remote sensing in the thermal infrared

Thermal infrared emission spectra of the moon and Mercury have been obtained using the Si:As photoconductor and circular variable filter at the NASA Infrared Telescope Facility on Mauna Kea, Hawaii. Lunar spectra from 7.2 to 12.2 microns for two different locations in the south polar highlands have Christiansen frequency peaks at 8.1 microns and 7.9 microns, respectively. This indicates different compositions at the two locations; mafic in the first case, more felsic in the second. Emission spectra from Mercury are not as spatially localized,; however, the longitude of maximum contribution to the spectrum can be calculated from thermal models of the earth-facing disk. Results for areas centered at two longitudes have been obtained. Two locations in the intercrater plains were observed. At 40-deg longitude (very near the crater Homer), a peak at 7.9 microns indicates mafic igneous rock type. Spectra emanating from 46-deg longitude have peaks at 7.8 microns, indicating a region borderline between mafic and intermediate composition.

Tyler, Ann L.↗
NASA NTRS2012

Multiple Asteroid Systems: Dimensions and Thermal Properties from Spitzer Space Telescope and Ground-based Observations

We collected mid-IR spectra from 5.2 to 38 microns using the Spitzer Space Telescope Infrared Spectrograph of 28 asteroids representative of all established types of binary groups. Photometric light curves were also obtained for 14 of them during the Spitzer observations to provide the context of the observations and reliable estimates of their absolute magnitudes. The extracted mid-IR spectra were analyzed using a modified standard thermal model (STM) and a thermophysical model (TPM) that takes into account the shape and geometry of the large primary at the time of the Spitzer observation. We derived a reliable estimate of the size, albedo, and beaming factor for each of these asteroids, representing three main taxonomic groups: C, S, and X. For large (volume-equivalent system diameter Deq > 130 km) binary asteroids, the TPM analysis indicates a low thermal inertia (Lambda < or = approx.100 J/1/2 s/K/sq m2) and their emissivity spectra display strong mineral features, implying that they are covered with a thick layer of thermally insulating regolith. The smaller (surface-equivalent system diameter Deff < 17 km) asteroids also show some emission lines of minerals, but they are significantly weaker, consistent with regoliths with coarser grains, than those of the large binary asteroids. The average bulk densities of these multiple asteroids vary from 0.7-1.7 g/cu cm (P-, C-type) to approx. 2 g/cu cm (S-type). The highest density is estimated for the M-type (22) Kalliope (3.2 +/- 0.9 g/cu cm). The spectral energy distributions (SEDs) and emissivity spectra, made available as a supplement document, could help to constrain the surface compositions of these asteroids.

Marchis, F.↗
NASA NTRS1994

Passive microwave observations of the Wedell Sea during austral winter and early spring

The results of multispectral passive microwave observations (6.7 to 90-GHz) are presented from the cruises of the FS Polarstern in the Weddell Sea from July to December 1986. This paper includes primarily the analysis of radiometric observations taken at ice station sites. Averaged emissivity spectra for first-year (FY) ice were relatively constant throughout the experiment and were not statistically different from FY ice signatures in the Arctic. Detailed ice characterization was carried out at each site to compare the microwave signatures of the ice with the physical properties. Absorption optical depths of FY ice were found to be sufficiently high that only the structure in the upper portions of the ice contributed significantly to interstation emissivity variations. The emissivities at 90-GHz, e(90), had the greatest variance. Both e(90) at vertical polarization and GR(sub e)(90, 18.7)(defined as (e(sub V)(90)-e(sub V)(18.7))/e(sub V)(90 + e(sub V)(18.7)) depended on the scattering optical depth which is a function of the snow grain diameter and layer thickness. The variance showed a latitude dependence and is probably due to an increase in the strength of snow metamorphism nearer the northern edge of the ice pack. The contribution of variations of near-surface brine volume to the emissivity was not significant over the range of values encountered at the station sites. Emissivity spectra are presented for a range of thin ice types. Unsupervised principal component analysis produced three significant eigenvectors and showed a separation among four different surface types: open water, thin ice, FY ice, and FY ice with a thick snow cover. A comparison with SMMR satellite data showed that average ice concentrations derived from the ship's ice watch log were consistent with the satellite concentrations. The surface based emissivities for FY ice were also compared with emissivities calculated from scanning multichannel microwave radiometer (SMMR) satellite radiances. Best agreement was found at 6.7 and 10-GHz, while at 18 and 37-GHz, SMMR emissivities were slightly lower than surface based results. For the three lower frequencies agreement was found within a confidence limit of 95% and for 37-GHz within about 90%.

Grenfell, T. C.↗
NASA NTRS1993

Wavelength-resolved emission spectroscopy of the alkoxy and alkylthio radicals in a supersonic jet

Wavelength-resolved emission spectra of methoxy (CH3O) and methylthio (CH3S) radicals have been obtained in a supersonic jet environment with a resolution of 0.3 nm by dispersing the total laser-induced fluorescence with a 0.6 m monochromator. A detailed analysis of the single vibronic level dispersed fluorescence spectra yields the following vibrational frequencies for CH3O in the X(2)E state; nu(sub 1 double prime) = 2953/cm, nu(sub 2 double prime) = 1375/cm, nu(sub 3 double prime) = 1062/cm, nu(sub 4 double prime) = 2869/cm, nu(sub 5 double prime) = 1528/cm and nu(sub 6 double prime) = 688/cm. A similar analysis of the wavelength-resolved emission spectra of CH3S provides the following ground state vibrational frequencies: nu(sub 2 double prime) = 1329/cm, nu(sub 3 double prime) = 739/cm and nu(sub 6 double prime) = 601/cm. An experimental uncertainty of 20/cm is estimated for the assigned frequencies.

Misra, Prabhakar↗
NASA NTRS1982

The ultraviolet continuous and emission-line spectra of the Herbig-Haro objects HH 2 and HH 1

Recent studies of the continuous spectrum of Herbig-Haro (HH) objects at optical and near-infrared wavelengths and the observation of continuous radiation in the ultraviolet have shown an unexpectedly steep increase of the flux toward shorter wavelengths. The present investigation provides the results of ultraviolet observations of HH 2. The obtained data are compared with the HH 1 data. It is found that HH 2 has an ultraviolet continuous and emission-line spectrum which is similar to that of HH 1. The UV line spectrum of HH 2H indicates an even somewhat larger ionization than does the HH 1 spectrum. As in HH1, the UV emission-line spectrum shows a much higher degree of ionization than that derived from the optical spectrum. Consequently, the same difficulty arises as in the case of HH 1. The complete UV plus optical spectrum cannot be explained by a single plane-parallel shock-wave model.

Boehm-Vitense, E.↗
NASA NTRS2001

Distribution and Spectroscopy of Green Fluorescent Protein and Acyl-CoA: Cholesterol Acytransferase in Sf21 Insect Cells

Acyl-CoA: cholesterol acyltransferase (ACAT) is thought to significantly participate in the pathway of cholesterol esterification that underlies the pathology of artherosclerosis. This enzyme is a membrane protein known to be preferentially bound within the endoplasmic reticulum of mammalian cells, from which location it esterifies cholesterol derived from low density lipoprotein. Cultures of insect cells were separately infected with baculovirus containing the gene for green fluroescent protein (GFP) and with baculovirus containing tandem genes for GFP and ACAT. These infected cultures expressed GFP and the fusion protein GCAT, respectively, with maximum expression occurring on the fourth day after infection. Extraction of GFP- and of GCAT-expressing cells with urea and detergent resulted in recovery of fluorescent protein in aqueous solution. Fluorescence spectra at neutral pH were identical for both GFP and GCAT extracts in aqueous solution, indicating unperturbed tertiary structure for the GFP moiety within GCAT. In a cholesterol esterification assay, GCAT demonstrated ACAT activity, but with less efficiency compared to native ACAT. It was hypothesized that the membrane protein ACAT would lead to differences in localization of GCAT compared to GFP within the respective expressing insect cells. The GFP marker directly and also within the fusion protein GCAT was accordingly used as the intracellular probe that was fluorescently analyzed by the new biophotonics technique of hyperspectral imaging. In that technique, fluorescence imaging was obtained from two dimensional arrays of cells, and regions of interest from within those images were then retrospectively analyzed for the emission spectra that comprises the image. Results of hyperspectral imaging of insect cells on day 4 postinfection showed that GCAT was preferentially localized to the cytoplasm of these cells compared to GFP. Furthermore, the emission spectra obtained for the localized GCAT displayed a peak blue shift from 518nm obtained in neutral aqueous solution to 505nm obtained in localized regions within the cells. This blue shift indicates change in the fluorescence coupling of the GFP moiety of GCAT. It is hypothesized that change in tertiary environment of GCAT, coincident with intracellular deposition of GCAT, follows from intracellular trafficking of GCAT leading to membrane interactions with the ACAT moiety, and/or self-assembly of GCAT, that alters the chromophore environment of the GFP moiety of GCAT. These findings introduce a new technique of biophotonic imaging to studies of intracellular protein trafficking and interactions. This technique of hyperspectral imaging could contribute to advancing the emergent field of proteomics. Because of the noninvasive nature of this technique, kinetic processes associated with intracellular protein trafficking, and interactions of proteins within cellular domains, can be considered for investigation within a single cell as well as a cell population.

Richmond, R. C.↗