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At least 127 records · Page 7

Characterization of Dendritic Spatially Extended 3D Patterns in Directional Solidification: Microgravity Experiments in DECLIC-DSI onboard ISS and 3D Phase-field Simulations

To clarify and characterize the fundamental physical mechanisms active in the dynamical formation of three-dimensional (3D) arrays of dendrites under diffusive growth conditions, in situ monitoring of series of experiments on transparent model alloy succinonitrile – 0.46 wt% camphor was carried out under low gravity in the DECLIC Directional Solidification Insert onboard the International Space Station. These experiments offer the very unique opportunity to observe in situ and characterize the dynamics of the microstructure formation and evolution in extended 3D patterns under microgravity environment. The analyses of the dendritic patterns for a broad range of growth velocities displaying different levels of sidebranching will be presented. Especially, the time evolution of primary spacing, in case of solidifications at constant pulling rate as well as for experiments with pulling rate jump, will be compared to 3D phase-field simulations, and the results will be discussed in terms of stable spacing range.

Kaihua Ji

Characterization of Dendritic Spatially Extended 3D Patterns in Directional Solidification: Microgravity Experiments in DECLIC-DSI Onboard ISS and 3D Phase-field Simulations

To clarify and characterize the fundamental physical mechanisms active in the dynamical formation of three-dimensional (3D) arrays of dendrites under diffusive growth conditions, in situ monitoring of series of experiments on transparent model alloy succinonitrile – 0.46 wt% camphor was carried out under low gravity in the DECLIC Directional Solidification Insert onboard the International Space Station. These experiments offer the very unique opportunity to observe in situ and characterize the dynamics of the microstructure formation and evolution in extended 3D patterns under microgravity environment. The analyses of the dendritic patterns for a broad range of growth velocities displaying different levels of sidebranching will be presented. Especially, the time evolution of primary spacing, in case of solidifications at constant pulling rate as well as for experiments with pulling rate jump, will be compared to 3D phase-field simulations, and the results will be discussed in terms of stable spacing range.

Kaihua Ji

On the two-dimensional modelling of horizontal CVD reactors and its limitations

In order to clarify under what conditions two-dimensional theoretical models can realistically account for the actual growth rate distribution in horizontal CVD reactors, a systematic numerical study was performed, and the results were compared with published experimental data for the MOCVD of gallium arsenide. Three models of increasing complexity were studied. It is shown that two-dimensional models can produce realistic predictions only for reactors with large width-to-height (aspect) ratios, that are operated at subcritical Rayleigh number,i.e., under dominant forced flow conditions. But even then, depending on the carrier gas, thermal (Soret) diffusion must be included in the model. Furthermore, velocity corrections for finite aspect ratios must be made, and buoyancy effects can be significant in the entrance region. On the other hand, the results are relatively insensitive to axial diffusion, temperature dependence of transport properties (versus averaged properties), and an assumed Poiseuille velocity profile (versus a rigorous solution of the velocity field). Yet, boundary layer approximations are prone to give unrealistic results at the low Reynolds numbers typical for CVD operations.

Ouazzani, Jalil

Simplified calculation of the area specific impedance for solid-state battery design

Simplified algebraic area specific impedance (ASI) correlations have been developed for solid-state composite battery electrodes made of a single ion conducting electrolyte, conductive additive, and intercalation active material. Two ASI expressions were developed, one for short times ( i.e. , pulsed power operation) and another for the pseudo steady state operation (i.e., sustained discharge for energy estimation). A full electrochemical model based on porous electrode theory was developed to examine the accuracy of the simplified ASI expressions. The simplified expressions agree favorably with full model results over a wide range of parameters (i.e. , electrode thicknesses, electrolyte conductivities, solid-state diffusion coefficients, specific surface areas, etc.) and conditions (i.e. , C-rates, states of charge, and pulse times). Under most conditions, the error between the full model and the correlations is well below 7 %. Higher errors were observed for the pseudo steady state expression at high/ low states of charge where the assumption of uniform reaction distributions loses validity. Here, the short time ASI has higher error at low states of charge due to the nonlinearity of the open circuit voltage equation, which is assumed linear in the formulation of the simplified algebraic expression.

25 ENERGY STORAGE

A computational investigation of high-flux, plate-and-frame membrane modules for industrial carbon capture

In this work, we study the application of membrane-based separation systems for carbon capture, considering plate-and-frame membrane modules. The successful deployment of membrane CO 2 capture system relies on high-performing membranes as well as effective membrane modules that can fully exploit the developed membranes. A plate-and-frame membrane module is especially attractive for CO 2 capture from industrial flue gas due to its lower pressure drop compared to its counterparts such as spiral wound modules and hollow fiber modules. To design better plate-and-frame modules, we investigate their basic unit - a single membrane stack through a combination of computational modeling and experimental investigations. The modeling approach is based on Computational Fluid Dynamics (CFD) to represent a multiphysics problem, including the fluid flow and diffusion processes within a membrane module. We use experimental data collected under different operating conditions to validate the CFD model. Numerical results suggest a good agreement between experiments and model outputs for the CO 2 recovery, CO 2 mole fraction in the retentate and permeate, and stage-cut. The CFD model is able to predict accurately the flow behavior, providing valuable insights on the effects of fluid dynamics on mass transfer of CO 2 . We also carry out a sensitivity analysis to identify the effect of key parameters on the CO 2 recovery and the CO 2 purity of the outlet streams.

CFD simulation

CFD modeling of high-flux plate-and-frame membrane modules for industrial carbon capture

In this work, we study the application of membrane-based separation systems for carbon capture, considering plate-and-frame membrane modules. The successful deployment of membrane CO2 capture system relies on high-performing membranes as well as effective membrane modules that can fully exploit the developed membranes. A plate-and-frame membrane module is especially attractive for CO2 capture from industrial flue gas due to its lower pressure drop compared to its counterparts such as spiral wound modules and hollow fiber modules. To design better plate-and-frame modules, we investigate their basic unit - a single membrane stack through a combination of computational modeling and experimental investigations. The modeling approach is based on Computational Fluid Dynamics (CFD) to represent a multiphysics problem, including the fluid flow and diffusion processes within a membrane module. We use experimental data collected under different operating conditions to validate the CFD model. Numerical results suggest a good agreement between experiments and model outputs for the CO2 recovery, CO2 mole fraction in the retentate and permeate, and stage-cut. The CFD model is able to predict accurately the flow behavior, providing valuable insights on the effects of fluid dynamics on mass transfer of CO2. We also carry out a sensitivity analysis to identify the effect of key parameters on the CO2 recovery and the CO2 purity of the outlet streams.

Dosso, Cheick

Numerical Determination of Critical Conditions for Thermal Ignition

The determination of ignition or thermal explosion in an oxidizing porous body of material, as described by a dimensionless reaction-diffusion equation of the form .tu = .2u + .e-1/u over the bounded region O, is critically reexamined from a modern perspective using numerical methodologies. First, the classic stationary model is revisited to establish the proper reference frame for the steady-state solution space, and it is demonstrated how the resulting nonlinear two-point boundary value problem can be reexpressed as an initial value problem for a system of first-order differential equations, which may be readily solved using standard algorithms. Then, the numerical procedure is implemented and thoroughly validated against previous computational results based on sophisticated path-following techniques. Next, the transient nonstationary model is attacked, and the full nonlinear form of the reaction-diffusion equation, including a generalized convective boundary condition, is discretized and expressed as a system of linear algebraic equations. The numerical methodology is implemented as a computer algorithm, and validation computations are carried out as a prelude to a broad-ranging evaluation of the assembly problem and identification of the watershed critical initial temperature conditions for thermal ignition. This numerical methodology is then used as the basis for studying the relationship between the shape of the critical initial temperature distribution and the corresponding spatial moments of its energy content integral and an attempt to forge a fundamental conjecture governing this relation. Finally, the effects of dynamic boundary conditions on the classic storage problem are investigated and the groundwork is laid for the development of an approximate solution methodology based on adaptation of the standard stationary model.

Luo, W.

Parameters Impacting Columnated Granular Soil Pneumatic Seal Performance

The ability of a column of loose granular soil to form a pneumatic seal was investigated by varying the diameter of the soil column, the effective column height, and the level of compaction in the soil. The soil column diameter was tested at three levels using pipes with inner diameters measuring 5.08, 10.16, and 15.24 centimeters (2, 4, and 6 inches). Soil was filled in each pipe to form 15, 30, and 45 centimeter (6, 12, and 18 inch) tall soil columns. Each diameter/height configuration was also tested at three levels of soil compaction, compared by calculating the bulk density of the soil with mass and volume measurements. GRC-1a simulant was used, with approximate low/medium/high bulk densities of 1.6, 1.75, and 1.9 g/cc achieved with a combination of vibration and tamping. The order of tests for a given column diameter was randomized and repeated three times. With the top of the soil open to atmosphere at room temperature, compressed air was injected through a small diffuser at the column base with several small downward-facing holes. The number and size of these holes was scaled such that a constant total inlet orifice area to column cross sectional area ratio was maintained for each column diameter. Inlet air pressure was slowly increased via a precision regulator to preserve quasi-static equilibrium in the soil column to minimize the impact of dynamics. Air pressure was increased all the way through the static and bubbling regimes until slugging or turbulent behavior was observed in the soil to ensure that the entire static regime had been captured during data collection. A three-factor, three-level analysis of variance (ANOVA) statistical analysis was performed on the resulting data to determine the extent to which each physical parameter impacted the soil column seal performance. It was concluded that there is statistically significant evidence that column height, and the interaction between column height and diameter impact soil seal performance. In all other cases there was insufficient data to identify a statistically significant causal relationship. Additionally, plots were generated comparing experimental data to the predictive formula developed by Ogino et al. for fluidized beds in 1993. Because this model was developed for industrial spouted fluidized beds, the accuracy of its output prior to fluidization in the static seal ‘edge case’ is unknown, especially considering in this application the working gas was diffused across the column base rather than being injected through a spout. Further, the fidelity of the model had not yet been tested with lunar soil simulants. Plotting the Ogino et al. model alongside test data allows for a more intuitive sense of the impact of test parameters on soil seal performance, as well as providing a quick means to further tune this predictive model for more accurate use with static seals across granular lunar soil simulants. The model provided by Ogino et al. was further tuned using test data to determine the degree to which a spouted bed model could be applied to a slightly modified set of testing conditions: lunar soil simulants and a more diffuse, homogeneous application of pneumatic pressure. A Matlab script was created to test different values for the leading coefficient and exponents in Ogino’s formula. The script swept preset ranges, then iterated with higher resolutions across narrower ranges to converge on the optimal value for each parameter. The resulting adjusted model was compared to the original, as well as test data with noticeable improvements across the entire test domain.

Jack Stewart

Solvability condition for needle crystals at large undercooling in a nonlocal model of solidification

It is explicitly shown that, in a realistic model of diffusion-controlled dendritic solidification, Ivantsov's continuous family of steady-state needle crystals is destroyed by the addition of surface tension. The starting point is in the exact integro-differential equation for the one-sided model, in two dimensions, in a moving frame of reference. In the limit of large undercooling, where the range of the diffusion field is much smaller than the radius of curvature of the tip of the needle, this problem is reduced to a linear, inhomogeneous differential equation of infinite order. A solvability condition for this equation is derived and it is shown that solutions cease to exist for arbitrarily small but finite isotropic surface tension.

Caroli, B.

Design of a variable area diffuser for a 15-inch Mach 6 open-jet tunnel

The Langley 15-inch Mach 6 High Temperature Tunnel was recently converted from a Mach 10 Hypersonic Flow Apparatus. This conversion was effected to improve the capability of testing in Mach 6 air at relatively high reservoir temperatures not previously possible at Langley. Elevated temperatures allow the matching of the Mach numbers, Reynolds numbers, and ratio of wall-to-adiabatic-wall temperatures (TW/Taw) between this and the Langley 20-inch Mach 6 CF4 Tunnel. This ratio is also matched for Langley's 31-inch Mach 10 Tunnel and is an important parameter useful in the simulation of slender bodies such as National Aerospace Plane (NASP) configurations currently being studied. Having established the nozzle's operating characteristics, the decision was made to install another test section to provide model injection capability. This test section is an open-jet type, with an injection system capable of injecting a model from retracted position to nozzle centerline between 0.5 and 2 seconds. Preliminary calibrations with the new test section resulted in Tunnel blockage. This blockage phenomenon was eliminated when the conical center body in the diffuser was replaced. The issue then, is to provide a new and more efficient variable area diffuser configuration with the capability to withstand testing of larger models without sending the Tunnel into an unstart condition. Use of the 1-dimensional steady flow equation with due regard to friction and heat transfer was employed to estimate the required area ratios (exit area / throat area) in a variable area diffuser. Correlations between diffuser exit Mach number and area ratios, relative to the stagnation pressure ratios and diffuser inlet Mach number were derived. From these correlations, one can set upper and lower operating pressures and temperatures for a given diffuser throat area. In addition, they will provide appropriate input conditions for the full 3-dimensional computational fluid dynamics (CFD) code for further simulation studies.

Loney, Norman W.

Wind enhanced planetary escape: Collisional modifications

The problem of thermal escape is considered in which both the effects of thermospheric winds at the exobase and collisions below the exobase are included in a Monte Carlo calculation. The collisions are included by means of a collisional relaxation layer of a background gas which models the transition region between the exosphere and the thermosphere. The wind effects are considered in the limiting cases of vertical and horizontal flows. Two species are considered: terrestrial hydrogen and terrestrial helium. In the cases of terrestrial hydrogen the escape fluxes were found to be strongly filtered or throttled by collisions at high exospheric temperatures. The model is applied to molecular hydrogen diffusing through a methane relaxation layer under conditions possible on Titan. The results are similar to the case of terrestrial hydrogen with wind enhanced escape being strongly suppressed by collisions. It is concluded that wind enhanced escape is not an important process on Titan.

Curtis, S. A.

Antennas in plasmas - The problem of boundaries

This paper discusses some of the difficulties associated with definition of appropriate boundary conditions for use in analyses of antennas and other structures immersed in plasmas. Distinctions may be made according to whether cold plasma, microscopic, or macroscopic theory is to be employed; whether the plasma is to be considered uniform or inhomogeneous, and whether or not there is a static magnetic field. The properties and limitations of these models, and the commonly-used boundary conditions of specular reflection and velocity diffusion (for opaque boundaries), and transparency (for grids or wires) are discussed. As a specific illustrative example, a series of approximations to the impedance of a magnetoplasma capacitor are reviewed.

Crawford, F. W.

A surface temperature and moisture parameterization for use in mesoscale numerical models

A modified multi-level soil moisture and surface temperature model is presented for use as in defining lower boundary conditions in mesoscale weather models. Account is taken of the hydraulic and thermal diffusion properties of the soil, their variations with soil type, and the mixing ratio at the surface. Techniques are defined for integrating the surface input into the multi-level scheme. Sample simulation runs were performed with the modified model and the original model defined by Pielke, et al. (1977, 1981). The models were applied to regional weather forecasting over soils composed of sand and clay loam. The new form of the model avoided iterations necessary in the earlier version of the model and achieved convergence at reasonable profiles for surface temperature and moisture in regions where the earlier version of the model failed.

Tremback, C. J.

Numerical solution of a three-dimensional cubic cavity flow by using the Boltzmann equation

A three-dimensional cubic cavity flow has been analyzed for diatomic gases by using the Boltzmann equation with the Bhatnagar-Gross-Krook (B-G-K) model. The method of discrete ordinate was applied, and the diffuse reflection boundary condition was assumed. The results, which show a consistent trend toward the Navier-Stokes solution as the Knudson number is reduced, give us confidence to apply the method to a three-dimensional geometry for practical predictions of rarefied-flow characteristics. The CPU time and the main memory required for a three-dimensional geometry using this method seem reasonable.

Hwang, Danny P.

Aerodynamic heating in hypersonic flows

Aerodynamic heating in hypersonic space vehicles is an important factor to be considered in their design. Therefore the designers of such vehicles need reliable heat transfer data in this respect for a successful design. Such data is usually produced by testing the models of hypersonic surfaces in wind tunnels. Most of the hypersonic test facilities at present are conventional blow-down tunnels whose run times are of the order of several seconds. The surface temperatures on such models are obtained using standard techniques such as thin-film resistance gages, thin-skin transient calorimeter gages and coaxial thermocouple or video acquisition systems such as phosphor thermography and infrared thermography. The data are usually reduced assuming that the model behaves like a semi-infinite solid (SIS) with constant properties and that heat transfer is by one-dimensional conduction only. This simplifying assumption may be valid in cases where models are thick, run-times short, and thermal diffusivities small. In many instances, however, when these conditions are not met, the assumption may lead to significant errors in the heat transfer results. The purpose of the present paper is to investigate this aspect. Specifically, the objectives are as follows: (1) to determine the limiting conditions under which a model can be considered a semi-infinite body; (2) to estimate the extent of errors involved in the reduction of the data if the models violate the assumption; and (3) to come up with correlation factors which when multiplied by the results obtained under the SIS assumption will provide the results under the actual conditions.

Reddy, C. Subba

Radiative Heat Transfer in Finite Cylindrical Enclosures with Nonhomogeneous Participating Media

Results of a numerical solution for radiative heat transfer in homogeneous and nonhomogeneous participating media are presented. The geometry of interest is a finite axisymmetric cylindrical enclosure. The integral formulation for radiative transport is solved by the YIX method. A three-dimensional solution scheme is applied to two-dimensional axisymmetric geometry to simplify kernel calculations and to avoid difficulties associated with treating boundary conditions. As part of the effort to improve modeling capabilities for turbulent jet diffusion flames, predicted distributions for flame temperature and soot volume fraction are used to calculate radiative heat transfer from soot particles in such flames. It is shown that the nonhomogeneity of radiative property has very significant effects. The peak value of the divergence of radiative heat flux could be underestimated by 2 factor of 7 if a mean homogeneous radiative property is used. Since recent studies have shown that scattering by soot agglomerates is significant in flames, the effect of magnitude of scattering is also investigated and found to be nonnegligible.

Hsu, Pei-Feng

An Ecosystem Simulation Model for Methane Production and Emission from Wetlands

Previous experimental studies suggest that methane emission from wetland is influenced by multiple interactive pathways of gas production and transport through soil and sediment layers to the atmosphere. The objective of this study is to evaluate a new simulation model of methane production and emission in wetland soils that was developed initially to help identify key processes that regulate methanogenesis and net flux of CH4 to the air, but which is designed ultimately for regional simulation using remotely sensed inputs for land cover characteristics. The foundation for these computer simulations is based on a well-documented model (CASA) of ecosystem production and carbon cycling in the terrestrial blaspheme. Modifications to represent flooded wetland soils and anaerobic decomposition include three new sub-models for: (1) layered soil temperature and water table depth (WTD) as a function of daily climate drivers, (2) CH4 production within the anoxic soil layer as a function of WTD and CO2 production under poorly drained conditions, and (3) CH4 gaseous transport pathways (molecular diffusion, ebullition, and plant vascular transport) as a function of WTD and ecosystem type. The model was applied and tested using climate and ecological data to characterize tundra wetland sites near Fairbanks, Alaska studied previously by Whalen and Reeburgh. Comparison of model predictions to measurements of soil temperature and thaw depth, water-table depth, and CH4 emissions over a two year period suggest that inter-site differences in soil physical conditions and methane fluxes could be reproduced accurately for selected periods. Day-to-day comparison of predicted emissions to measured CH4 flux rates reveals good agreement during the early part of the thaw season, but the model tends to underestimate production of CH4 during the months of July and August in both test years. Important seasonal effects, including that of falling WTD during these periods, are apparently overlooked in the model formulation. Nevertheless, reasonably close agreement was achieved between the model's mean daily and seasonal estimates of CH4 flux and observed emission rates for northern wetland ecosystems. Several features of the model are identified as crucial to more accurate prediction of wetland methane emission, including the capacity to incorporate influences of localized topographic and hydrologic features on site-specific soil temperature and WTD dynamics, and mechanistic simulation of methane emission transport pathways from within the soil profile.

Potter, C. S.

Modification of the Two-equation Turbulence Model in NPARC to a Chien Low Reynolds Number K-epsilon Formulation

This report documents the changes that were made to the two-equation k-epsilon turbulence model in the NPARC (National-PARC) code. The previous model based on the low Reynolds number model of Speziale, was replaced with the low Reynolds number k-epsilon model of Chien. The most significant difference was in the turbulent Prandtl numbers appearing in the diffusion terms of the k and epsilon transport equations. A new inflow boundary condition and stability enhancements were also implemented into the turbulence model within NPARC. The report provides the rationale for making the change to the Chien model, code modifications required, and comparisons of the performances of the new model with the previous k-epsilon model and algebraic models used most often in PARC/NPARC. The comparisons show that the Chien k-epsilon model installed here improves the capability of NPARC to calculate turbulent flows.

Georgiadis, Nicholas J.