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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Fast neutron background characterization of the future Ricochet experiment at the ILL research nuclear reactor

Abstract The future Ricochet experiment aims at searching for new physics in the electroweak sector by providing a high precision measurement of the Coherent Elastic Neutrino-Nucleus Scattering (CENNS) process down to the sub-100 eV nuclear recoil energy range. The experiment will deploy a kg-scale low-energy-threshold detector array combining Ge and Zn target crystals 8.8 m away from the 58 MW research nuclear reactor core of the Institut Laue Langevin (ILL) in Grenoble, France. Currently, the Ricochet Collaboration is characterizing the backgrounds at its future experimental site in order to optimize the experiment’s shielding design. The most threatening background component, which cannot be actively rejected by particle identification, consists of keV-scale neutron-induced nuclear recoils. These initial fast neutrons are generated by the reactor core and surrounding experiments (reactogenics), and by the cosmic rays producing primary neutrons and muon-induced neutrons in the surrounding materials. In this paper, we present the Ricochet neutron background characterization using $$^3$$ 3 He proportional counters which exhibit a high sensitivity to thermal, epithermal and fast neutrons. We compare these measurements to the Ricochet Geant4 simulations to validate our reactogenic and cosmogenic neutron background estimations. Eventually, we present our estimated neutron background for the future Ricochet experiment and the resulting CENNS detection significance. Our results show that depending on the effectiveness of the muon veto, we expect a total nuclear recoil background rate between 44 ± 3 and 9 ± 2 events/day/kg in the CENNS region of interest, i.e. between 50 eV and 1 keV. We therefore found that the Ricochet experiment should reach a statistical significance of 4.6 to 13.6 $$\sigma $$ σ for the detection of CENNS after one reactor cycle, when only the limiting neutron background is considered.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Measurement of coherent exclusive J/ψ → μ+μ− production in ultraperipheral Pb+Pb collisions at sNN=5.36 TeV with the ATLAS detector

The ATLAS experiment has performed a measurement of coherent exclusive J/ψ → μ+μ− production in ultraperipheral Pb+Pb collisions at sNN=5.36$$ \sqrt{s_{\textrm{NN}}}=5.36 $$ TeV. The data was recorded at the Large Hadron Collider (LHC) during 2023, and corresponds to an integrated luminosity of 79 μb−1. Exclusive J/ψ candidates were selected with a dedicated track-sensitive trigger based on the ATLAS transition radiation tracker. The analysis involves reconstruction of the dimuon invariant mass based on muon tracks from the inner detector, as the muon transverse momentum range of interest precludes the use of the standard muon reconstruction and identification algorithms. Differential cross sections are measured as a function of J/ψ rapidity and are compared with theoretical predictions. After extrapolation to sNN=5.02$$ \sqrt{s_{\textrm{NN}}}=5.02 $$ TeV, they are also compared with previous measurements performed by other experiments using data from LHC Run 2. While the results agree reasonably well with theoretical predictions, they are in tension with previous Run-2 results for the central rapidity region.

Aad, G↗
DOE OSTI2020

2D HSQC Chemical Shifts of Impurities from Biomass Pretreatment

Two dimensional (2D) heteronuclear single quantum coherence (HSQC) nuclear magnetic resonance (NMR) is a powerful analytical method which can be used to elucidate the structure of biomass. During processing, biomass is typically subjected to some form of chemical treatment which can be performed with a variety of compounds. The presence of these compounds, even in trace amounts, has the potential to contaminate the sample and lead to misinterpretation of the HSQC spectra. Here we report the chemical shifts of 29 compounds commonly used in biomass processing which have the potential to contaminate the biomass samples and lead to the misinterpretation of peaks associated with biomass (Populus trichocarpa ) pretreated via autohydrolysis. The identification of these chemical shifts could serve as a valuable tool in preventing errors in characterizing biomass via HSQC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1994

Preliminary identification of buffet problems in high speed civil transport

In the present study, some effort is made to identify whether empennage buffet is a relevant factor in the design and operation of the High Speed Civil Transport (HSCT). Based on some results of the only operational supersonic transport, Concorde and the innumerable studies that exist on the tail buffet of high performance airplanes, CFD analyses on the HSCT as well as low speed wind tunnel tests on models, it appears as though buffet will be a factor that needs attention in the proper design of empennage structure. Utilizing the existing empirical relation between the reduced frequency of the leading edge vortices and the geometric parameters, it is estimated that the characteristic frequencies of the vortices from the wing cranks are in the range of certain fundamental frequencies of the wing-fuselage-empennage structure. Buffet is believed to be critical during take-off, climb, descent and landing. Computational and experimental data available in open literature indicate coherent vortex flow structure in the empennage region at supersonic cruise speeds. This raises further concern on the fatigue life of the empennage structure. Three second generation supersonic transport designs taken from open literature are briefly compared with the 'empennage buffet' in mind. Future research efforts relating to buffet studies on the HSCT are summarized. A bibliography pertaining to the present research, including relevant studies on the first generation supersonic transport is presented. The effect of rounded wing leading edges on the present frequency estimates needs further study. The effect of engine exhaust on the flow field in the empennage region also needs further study.

Ravindra, Krishnaswamy↗
DOE OSTI2025

An NV − center in magnesium oxide as a spin qubit for hybrid quantum technologies

Recent predictions suggest that oxides, such as MgO and CaO, could serve as hosts of spin defects with long coherence times and thus be promising materials for quantum applications. However, in most cases, specific defects have not yet been identified. Here, by using a high-throughput first-principles framework and advanced electronic structure methods, we identify a negatively charged complex between a nitrogen interstitial and a magnesium vacancy in MgO with favorable electronic and optical properties for hybrid quantum technologies. We show that this NV − center has stable triplet ground and excited states, with singlet shelving states enabling optical initialization and spin-dependent readout. We predict several properties, including absorption, emission, and zero-phonon line energies, as well as zero-field splitting tensor, and hyperfine interaction parameters, which can aid in the experimental identification of this defect. Our calculations show that due to a strong pseudo-Jahn Teller effect and low-frequency phonon modes, the NV − center in MgO is subject to a substantial vibronic coupling. We discuss design strategies to reduce such coupling and increase the Debye-Waller factor, including the effect of strain and the localization of the defect states. We propose that the favorable properties of the NV − defect, along with the technological maturity of MgO, could enable hybrid classical-quantum applications, such as spintronic quantum sensors and single qubit gates.

36 MATERIALS SCIENCE↗
NASA NTRS2012

Measurement Via Optical Near-Nulling and Subaperture Stitching

A subaperture stitching interferometer system provides near-nulling of a subaperture wavefront reflected from an object of interest over a portion of a surface of the object. A variable optical element located in the radiation path adjustably provides near-nulling to facilitate stitching of subaperture interferograms, creating an interferogram representative of the entire surface of interest. This enables testing of aspheric surfaces without null optics customized for each surface prescription. The surface shapes of objects such as lenses and other precision components are often measured with interferometry. However, interferometers have a limited capture range, and thus the test wavefront cannot be too different from the reference or the interference cannot be analyzed. Furthermore, the performance of the interferometer is usually best when the test and reference wavefronts are nearly identical (referred to as a null condition). Thus, it is necessary when performing such measurements to correct for known variations in shape to ensure that unintended variations are within the capture range of the interferometer and accurately measured. This invention is a system for nearnulling within a subaperture stitching interferometer, although in principle, the concept can be employed by wavefront measuring gauges other than interferometers. The system employs a light source for providing coherent radiation of a subaperture extent. An object of interest is placed to modify the radiation (e.g., to reflect or pass the radiation), and a variable optical element is located to interact with, and nearly null, the affected radiation. A detector or imaging device is situated to obtain interference patterns in the modified radiation. Multiple subaperture interferograms are taken and are stitched, or joined, to provide an interferogram representative of the entire surface of the object of interest. The primary aspect of the invention is the use of adjustable corrective optics in the context of subaperture stitching near-nulling interferometry, wherein a complex surface is analyzed via multiple, separate, overlapping interferograms. For complex surfaces, the problem of managing the identification and placement of corrective optics becomes even more pronounced, to the extent that in most cases the null corrector optics are specific to the particular asphere prescription and no others (i.e. another asphere requires completely different null correction optics). In principle, the near-nulling technique does not require subaperture stitching at all. Building a near-null system that is practically useful relies on two key features: simplicity and universality. If the system is too complex, it will be difficult to calibrate and model its manufacturing errors, rendering it useless as a precision metrology tool and/or prohibitively expensive. If the system is not applicable to a wide range of test parts, then it does not provide significant value over conventional null-correction technology. Subaperture stitching enables simpler and more universal near-null systems to be effective, because a fraction of a surface is necessarily less complex than the whole surface (excepting the extreme case of a fractal surface description). The technique of near-nulling can significantly enhance aspheric subaperture stitching capability by allowing the interferometer to capture a wider range of aspheres. More over, subaperture stitching is essential to a truly effective near-nulling system, since looking at a fraction of the surface keeps the wavefront complexity within the capability of a relatively simple nearnull apparatus. Furthermore, by reducing the subaperture size, the complexity of the measured wavefront can be reduced until it is within the capability of the near-null design.

Forbes, Greg↗
DOE OSTI2020

Identification of a network of nonlinear interactions as a mechanism triggering the onset of edge localized modes

Edge localized modes (ELMs) remain a critical issue for the lifetime of in-vessel components of fusion reactors such as ITER. We study ELMs triggered when the pedestal parameters are below the peeling-ballooning limit. These ELMs occur while the pedestal recovers after an ELM crash. We identify a mechanism by which a non-linear perturbation involving many active triads—a network of non-linear interactions – leads to the triggering of these ELMs. Each active triad leads to the non-linear transfer of energy between three waves, such that the network of non-linear interactions lead to a transfer of energy between many waves. The triggering of this non-linear perturbation systematically coincides with a pedestal perturbation induced by the neutral beam injection beams and localized near the magnetic surface of safety factor q = 5. Among the non-linear interactions detected during the ELM by a bi-coherence analysis, the most active triad involves a slow frequency that is qualitatively consistent with a geodesic acoustic mode located at the same location, i.e., near the q = 5 surface.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Quasiparticle excitations in a one-dimensional interacting topological insulator: Application for dopant-based quantum simulation

Here, we study the effects of electron-electron interactions on the charge excitation spectrum of the spinful Su-Schrieffer-Heeger (SSH) model, a prototype of a one-dimensional bulk obstructed topological insulator. In view of recent progress in the fabrication of dopant-based quantum simulators we focus on experimentally detectable signatures of interacting topology in finite lattices. To this end we use Lanczos-based exact diagonalization to calculate the single-particle spectral function in real space which generalizes the local density of states to interacting systems. Its spatial and spectral resolution allows for the direct investigation and identification of edge states. By studying the noninteracting limit, we demonstrate that the topological in-gap states on the boundary are robust against both finite-size effects as well as random bond and onsite disorder which suggests the feasibility of simulating the SSH model in engineered dopant arrays in silicon. While edge excitations become zero-energy spinlike for any finite interaction strength, our analysis of the spectral function shows that the single-particle charge excitations are gapped out on the boundary. Despite the loss of topological protection, we find that these edge excitations are quasiparticlelike as long as they remain within the bulk gap. Above a critical interaction strength of U c ≈5t these quasiparticles on the boundary lose their coherence which is explained by the merging of edge and bulk states. This is in contrast to the many-body edge excitations which survive the limit of strong coupling, as established in the literature. Our findings show that for moderate repulsive interactions the nontrivial phase of the interacting SSH model can be detected through remnant signatures of topological single-particle states using single-particle local measurement techniques such as scanning tunneling spectroscopy.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Towards Content Authenticity: Multimodal Fake News Detection and AI-Generated Text Identification

In today’s digital world, the spread of fake news and the rise of AI-generated text have become major threats to content authenticity and public trust. This thesis addresses both challenges through two complementary research directions: detecting fake news using multimodal features, and identifying AI-generated text using semantic and structural reasoning. The first part of the work focuses on fake news detection by introducing a novel model that combines text and image features through a unique rotational attention mechanism. Unlike traditional attention methods, this approach rotates the roles of query, key, and value across modalities to capture deeper interactions. Additionally, the model incorporates external domain information by linking news posts to top-ranked websites from Google search results, which helps assess the credibility of content based on its broader web context. This results in a more reliable and accurate fake news detection system that outperforms existing state-of-the-art methods. The second part presents SGG-ATD, a new framework for detecting AI-generated text. It uses masked language modeling to measure sentence coherence, followed by constructing a graph where keywords—both original and predicted—are connected based on semantic and contextual similarity. A Graph Convolutional Network (GCN) is then used to learn structural relationships within the text for final classification. Experimental results demonstrate that SGG-ATD achieves high F1-scores and consistently outperforms strong baselines. This method contributes to robust AI text detection, supporting accountability and resilience against AI-driven misinformation.

Gupta, Nidhi↗
DOE OSTI2025

Single-shot in-line x-ray phase-contrast imaging of void-shockwave interactions in fusion energy materials

Recent breakthroughs in nuclear fusion, specifically the report of reactions exceeding scientific breakeven at the National Ignition Facility (NIF), highlight the potential of inertial fusion energy (IFE) as a sustainable and virtually limitless energy source. However, further progress in IFE requires characterization of defects in ablator materials and how they affect fuel capsule compression. Voids within the ablator can degrade energy yield, but their impact on the density distribution has primarily been studied through simulations, with limited high-resolution experimental validation. To address this, we used the x-ray free-electron laser (XFEL) at the matter in extreme conditions (MECs) instrument at the Linac coherent light source (LCLS) to capture 2D x-ray phase-contrast (XPC) images of a void-bearing sample with a composition similar to inertial confinement fusion (ICF) ablators. By driving a compressive shockwave through the sample using MEC's long-pulse laser system, we analyzed how voids influence shockwave propagation and density distribution during compression. To quantify this impact, we extracted phase information using two phase retrieval algorithms. First, we applied the contrast transfer function (CTF) method, paired with Tikhonov regularization and a fast optimization approach to generate an initial phase estimate. We then refined the result using a projected gradient descent (PGD) method that works directly with the sample's refractive index. Comparing these results with radiation adaptive grid Eulerian (xRAGE) radiation hydrodynamic simulations enables identification of model validation needs or improvements. By calculating phase maps in situ, it becomes possible to reconstruct areal density maps, improving understanding of laser-capsule interactions and advancing IFE research.

Hodge, D. S. [Colorado State Univ., Fort Collins, ↗
NASA NTRS2014

NASA's Asteroid Redirect Mission: A Robotic Boulder Capture Option for Science, Human Exploration, Resource Utilization, and Planetary Defense

NASA is examining two options for the Asteroid Redirect Mission (ARM), which will return asteroid material to a Lunar Distant Retrograde Orbit (LDRO) using a robotic solar electric propulsion spacecraft, called the Asteroid Redirect Vehicle (ARV). Once the ARV places the asteroid material into the LDRO, a piloted mission will rendezvous and dock with the ARV. After docking, astronauts will conduct two extravehicular activities (EVAs) to inspect and sample the asteroid material before returning to Earth. One option involves capturing an entire small (~4 - 10 m diameter) near-Earth asteroid (NEA) inside a large inflatable bag. However, NASA is also examining another option that entails retrieving a boulder (~1 - 5 m) via robotic manipulators from the surface of a larger (~100+ m) pre-characterized NEA. The Robotic Boulder Capture (RBC) option can leverage robotic mission data to help ensure success by targeting previously (or soon to be) well- characterized NEAs. For example, the data from the Japan Aerospace Exploration Agency's (JAXA) Hayabusa mission has been utilized to develop detailed mission designs that assess options and risks associated with proximity and surface operations. Hayabusa's target NEA, Itokawa, has been identified as a valid target and is known to possess hundreds of appropriately sized boulders on its surface. Further robotic characterization of additional NEAs (e.g., Bennu and 1999 JU3) by NASA's OSIRIS REx and JAXA's Hayabusa 2 missions is planned to begin in 2018. This ARM option reduces mission risk and provides increased benefits for science, human exploration, resource utilization, and planetary defense. Science: The RBC option is an extremely large sample-return mission with the prospect of bringing back many tons of well-characterized asteroid material to the Earth-Moon system. The candidate boulder from the target NEA can be selected based on inputs from the world-wide science community, ensuring that the most scientifically interesting boulder be returned for subsequent sampling. In addition, the material surrounding the boulder can be collected from the surface, thus providing geological contextual information and additional samples of NEA regolith. The robotic manipulators used for capturing the boulder will ensure some of the surface remains undisturbed and that the boulder will retain its structural integrity, which will preserve the context of any samples collected by the astronauts and ensure a high level of science return. Human Exploration: Due to the coherent nature of the boulder that will be collected, entire encapsulation of the asteroid material is not required. This facilitates exploration and sample collection of the boulder by astronauts in a variety of ways. The total time for EVA during the crew portion of the mission is very limited. Current estimates are that each of the two EVAs will only last four hours. The RBC option will allow crew members to have good situational awareness of the work site and quickly identify sample sites of interest. In addition, the samples to be collected can be readily accessed without having to deal with removal of an encapsulation system, which adds extra complexity and risk for the astronauts during EVA. Resource Utilization: One of the most crucial aspects for resource utilization is the identification and collection of appropriate materials (e.g., volatiles, organics, metals, etc.) that contain components of interest. Prior characterization of NEAs is required in order to increase the likelihood that appropriate materials will be returned. Ground-based observations of small (<10 m) NEAs are challenging, but characterization efforts of larger targets have demonstrated that NEAs with volatiles and organics have been identified. Two potential targets for the RBC option (Bennu and 1999 JU3) have been previously identified as potentially rich in resources, and both are already targets of currently planned robotic missions that will characterize their physical properties in great detail. Planetary Defense: The RBC option involves interaction with a well- characterized potentially hazardoussized NEA that would enable NASA to conduct one or more planetary defense demonstrations. The primary method would use the collected boulder to augment the mass of the ARV and perform an Enhanced Gravity Tractor (EGT) demonstration on the NEA. Additionally, other approaches could be demonstrated during the mission, such as Ion Beam Deflection (IBD) and/or observation of a Kinetic Impactor (KI). The relative effectiveness of a slow push-pull method such as the EGT or IBD could be directly compared and contrasted with the results of the more energetic KI method on the target NEA. Conclusions: This boulder option for NASA's ARM can leverage knowledge of previously characterized NEAs from prior robotic missions, which provides more certainty of the target NEA's physical characteristics and reduces mission risk. This increases the return on investment for NASA's future activities with respect to human exploration, resource utilization, and planetary defense.

Abell, P.↗
DOE OSTI2020

Strong spin–orbit quenching via the product Jahn–Teller effect in neutral group IV qubits in diamond

Abstract Artificial atom qubits in diamond have emerged as leading candidates for a range of solid-state quantum systems, from quantum sensors to repeater nodes in memory-enhanced quantum communication. Inversion-symmetric group IV vacancy centers, comprised of Si, Ge, Sn, and Pb dopants, hold particular promise as their neutrally charged electronic configuration results in a ground-state spin triplet, enabling long spin coherence above cryogenic temperatures. However, despite the tremendous interest in these defects, a theoretical understanding of the electronic and spin structure of these centers remains elusive. In this context, we predict the ground-state and excited-state properties of the neutral group IV color centers from first principles. We capture the product Jahn–Teller effect found in the excited state manifold to second order in electron–phonon coupling, and present a nonperturbative treatment of the effect of spin–orbit coupling. Importantly, we find that spin–orbit splitting is strongly quenched due to the dominant Jahn–Teller effect, with the lowest optically-active 3 E u state weakly split into m s -resolved states. The predicted complex vibronic spectra of the neutral group IV color centers are essential for their experimental identification and have key implications for use of these systems in quantum information science.

Materials Science↗
DOE OSTI2024

High-throughput single-cell sorting by stimulated Raman-activated cell ejection

Raman-activated cell sorting isolates single cells in a nondestructive and label-free manner, but its throughput is limited by small spontaneous Raman scattering cross section. Coherent Raman scattering integrated with microfluidics enables high-throughput cell analysis, but faces challenges with small cells (<3 μm) and tissue sections. Here, we report stimulated Raman-activated cell ejection (S-RACE) that enables high-throughput single-cell sorting by integrating stimulated Raman imaging, in situ image decomposition, and laser-induced cell ejection. S-RACE allows ejection of live bacteria or fungi guided by their Raman signatures. Furthermore, S-RACE successfully sorted lipid-richRhodotorula glutiniscells from a cell mixture with a throughput of ~13 cells per second, and the sorting results were confirmed by downstream quantitative polymerase chain reaction. Beyond single cells, S-RACE shows high compatibility with tissue sections. Incorporating a closed-loop feedback control circuit further enables real-time SRS imaging-identification-ejection. In summary, S-RACE opens exciting opportunities for diverse single-cell sorting applications.

Science & Technology - Other Topics↗
DOE OSTI2022

Creep Behavior and Phase Equilibria in Model Precipitate Strengthened Alumina-Forming Austenitic Alloys

Abstract Creep-rupture behavior and microstructural response in alumina-forming austenitic (AFA) alloys with two different precipitation strengthening mechanisms, “Laves-phase + M 23 C 6 carbide” and “coherent L1 2 γ′-Ni 3 (Al,Ti),” were explored as “model” cases of multi-phase, multi-scale heat-resistant AFA alloys for 650–750°C use. These alloys will be used to guide and verify computational alloy design and life-prediction modeling under an on-going eXtremeMAT project through the Office of Fossil Energy and Carbon Management, US Department of Energy. Computational thermodynamics were used to design and predict the amounts of strengthening and deteriorating secondary phases at 750°C. Creep-rupture lives of the alloys tested at 750°C and 100 MPa were in a range of 4000–9000 h, and the microstructure at the gage/grip after creep-rupture testing was compared with isothermally aged alloys for 1500 h, as well as the calculated phases. Detailed microstructure characterization includes phase identification, volume fraction measurement, and compositional analysis, which were correlated with the creep-rupture properties. High-temperature oxidation resistance was also screened and compared with commercial, chromia-forming heat-resistant steels. These model alloys also provide the basis for further design and optimization of next generation AFA alloys with improved creep resistance.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Acoustic Observations of the OSIRIS-REx Sample Return Capsule Re-Entry from Wendover Airport

The Origins, Spectral Interpretation, Resource Identification, and Security‐Regolith Explorer sample return capsule (SRC) re‐entered the Earth’s atmosphere at hypersonic speeds from interplanetary space on 24 September 2023. The current work reports on 18 ground‐based acoustic sensors deployed at Wendover Airport, the same location that the Genesis and Stardust SRC re‐entries were recorded. Four different sensors (Chaparral Physics, Gem, Wilson Engineering Research and Development [WERD], and RedVox) were deployed in close proximity to compare their performance. All the sensors captured an N‐wave signal associated with the SRC re‐entry shock wave followed by a broadband coda. The Chaparral Physics array served as the high‐fidelity reference measurement. The N‐wave signal had a peak‐to‐peak amplitude of 4.07 Pa with a fundamental frequency of 4.98 Hz from 167.5° measured clockwise from north, nearly perpendicular to the SRC trajectory. In addition, high coherence in the coda was shown to be associated reflections from the surrounding mountains. In general, the more economical sensors (Gem, WERD, and RedVox) produced results that were consistent with these observations and sensor specifications. Beamforming with these single sensors arranged as an array showed agreement with the high‐fidelity array to within a couple of degrees. Furthermore, the current high‐fidelity results were compared with the measurements during the Genesis and Stardust SRC re‐entries. All three entries produced a broadband fundamental peak at a frequency that was inversely related to the SRC diameter as well as evidence of reflections from the surrounding topography.

KC, Real J. [Oklahoma State University, Stillwater↗
DOE OSTI2021

Spatially co-registered wide-field nonlinear optical imaging of living and complex biosystems in a total internal reflection geometry

Nonlinear optical microscopy that leverages an objective based total internal reflection (TIR) excitation scheme is an attractive means for rapid, wide-field imaging with enhanced surface sensitivity. Through select combinations of distinct modalities, one can, in principle, access complementary chemical and structural information for various chemical species near interfaces. Here, we report a successful implementation of such a wide-field nonlinear optical microscope system, which combines coherent anti-Stokes Raman scattering (CARS), two-photon fluorescence (TPF), second harmonic generation (SHG), and sum frequency generation (SFG) modalities on the same platform. The intense optical fields needed to drive these high order nonlinear optical processes are achieved through the use of femtosecond pulsed light in combination with the intrinsic field confinement induced by TIR over a large field of view. The performance of our multimodal microscope was first assessed through the experimental determination of its chemical fidelity, intensity and polarization dependences, and spatial resolution using a set of well-defined model systems. Subsequently, its unique capabilities were validated through imaging complex biological systems, including Hydrangea quercifolia pollen grains and Pantoea sp. YR343 bacterial cells. Specifically, the spatial distribution of different molecular groups in the former was visualized via vibrational contrast mechanisms of CARS, whereas co-registered TPF imaging allowed the identification of spatially localized intrinsic fluorophores. We further demonstrate the feasibility of our microscope for wide-field CARS imaging on live cells through independent characterization of cell viability using spatially co-registered TPF imaging. Overall, this approach to TIR enabled wide-field imaging is expected to provide new insights into bacterial strains and their interactions with other species in the rhizosphere in a time-resolved and chemically selective manner.

47 OTHER INSTRUMENTATION↗
NASA NTRS2012

Geologic Structures in Crater Walls on Vesta

The Framing Camera (FC) on the Dawn spacecraft has imaged most of the illuminated surface of Vesta with a resolution of apporpx. 20 m/pixel through different wavelength filters that allow for identification of lithologic units. The Visible and Infrared Mapping Spectrometer (VIR) has imaged the surface at lower spatial resolution but high spectral resolution from 0.25 to 5 micron that allows for detailed mineralogical interpretation. The FC has imaged geologic structures in the walls of fresh craters and on scarps on the margin of the Rheasilvia basin that consist of cliff-forming, competent units, either as blocks or semi-continuous layers, hundreds of m to km below the rims. Different units have different albedos, FC color ratios and VIR spectral characteristics, and different units can be juxtaposed in individual craters. We will describe different examples of these competent units and present preliminary interpretations of the structures. A common occurrence is of blocks several hundred m in size of high albedo (bright) and low albedo (dark) materials protruding from crater walls. In many examples, dark material deposits lie below coherent bright material blocks. In FC Clementine color ratios, bright material is green indicating deeper 1 m pyroxene absorption band. VIR spectra show these to have deeper and wider 1 and 2 micron pyroxene absorption bands than the average vestan surface. The associated dark material has subdued pyroxene absorption features compared to the average vestan surface. Some dark material deposits are consistent with mixtures of HED materials with carbonaceous chondrites. This would indicate that some dark material deposits in crater walls are megabreccia blocks. The same would hold for bright material blocks found above them. Thus, these are not intact crustal units. Marcia crater is atypical in that the dark material forms a semi-continuous, thin layer immediately below bright material. Bright material occurs as one or more layers. In one region, there is an apparent angular unconformity between the bright material and the dark material where bright material layers appear to be truncated against the underlying dark layer. One crater within the Rheasilvia basin contains two distinct types of bright materials outcropping on its walls, one like that found elsewhere on Vesta and the other an anomalous block ~200 m across. This material has the highest albedo; almost twice that of the vestan average. Unlike all other bright materials, this block has a subdued 1 micron pyroxene absorption band in FC color ratios. These data indicate that this block represents a distinct vestan lithology that is rarely exposed.

Mittlefehldt, David W.↗
NASA NTRS1998

Continuing Studies of Planetary Atmospheres Associated with Experiments on the Galileo Jupiter Probe and Infrared Observations of Venus

The results of the nephelometer experiment conducted aboard the Probe of the Galileo mission to Jupiter are presented. The tenuous clouds and sparse particulate matter in the relatively particle-free 5-micron "hot spot" region of the Probe's descent were documented from about 0.46 bars to about 12 bars. Three regions of apparent coherent structure were noted, in addition to many indications of extremely small particle concentrations along the descent path. From the first valid measurement at about 0.46 bars down to about 0.55 bars a feeble decaying lower portion of a cloud, corresponding with the predicted ammonia particle cloud, was encountered. A denser, but still very modest, particle structure was present in the pressure regime extending from about 0.76 to a distinctive base at 1.34 bars, and is compatible with the expected ammonium hydrosulfide cloud. No massive water cloud was encountered, although below the second structure, a small, vertically thin layer at about 1.65 bars may be detached from the cloud above, but may also be water condensation, compatible with reported measurements of water abundance from other Galileo Mission experiments. A third small signal region, extending from about 1.9 to 4.5 bars, exhibited quite weak but still distinctive structure, and, although the identification of the light scatterers in this region is uncertain, may also be a water cloud perhaps associated with lateral atmospheric motion and/or reduced to a small mass density by atmospheric subsidence or other explanations. Rough descriptions of the particle size distributions and cloud properties in these regions have been derived, although they may be imprecise because of the small signals and experimental difficulties. These descriptions document the small number densities of particles, the moderate particle sizes, generally in the slightly submicron to few micron range, and the resulting small optical depths, mass densities due to particles, column particle number loading and column mass loading in the atmosphere encountered by the Galileo Probe during its descent.

Ragent, Boris↗