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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Lakewide monitoring of suspended solids using satellite data

In anticipation of using LANDSAT and Nimbus 7 coastal zone color scanner data to observe the decrease in suspended solids in Lake Superior following cessation of the dumping of taconite tailings, a series of lakewide sampling cruises was conducted to make radiometric measurements at a lake level. A means for identifying particulates and measuring their concentration from LANDSAT data was developed. The initial distribution of chemical parameters in the extreme western arm of the lake, where the concentration gradients are high, is to be based on the LANDSAT data. Subsequent lakewide dispersal and distribution is to be based on the coastal zone color scanner data.

Sydor, M.↗
NASA NTRS1988

Test results on re-use of reclaimed shower water: Summary

A microgravity whole body shower (WBS) and waste water recovery systems (WWRS) were evaluated in three separate closed loop tests. Following a protocol similar to that anticipated for the U.S. Space Station, test subjects showered in a prototype whole body shower. The WWRS processes evaluated during the test series were phase change and reverse osmosis (RO). A preprototype Thermoelectric Integrated Hollow Fiber Membrane Evaporation Subsystem phase change process was used for the initial test with chemical pretreatment of the shower water waste input. The second and third tests concentrated on RO technologies. The second test evaluated a dynamic RO membrane consisting of zirconium oxide polyacrylic acid (ZOPA) membranes deposited on the interior diameter of 316L porous stainless steel tubes while the final test employed a thin semipermeable RO membrane deposited on the interior surface of polysulfone hollow fibers. All reclaimed water was post-treated for purity using ion exchange and granular activated carbon beds immediately followed by microbial control treatment using both heat and iodine. The test hardware, controls exercised for whole body showering, types of soaps evaluated, shower subject response to reclaimed water showering, and shower water collection and chemical pretreatment (if required) for microbial control are described. The WWRS recovered water performance and the effectiveness of the reclaimed water post-treatment techniques used for maintaining water purity and microorganism control are compared. Results on chemical and microbial impurity content of the water samples obtained from various locations in the shower water reuse system are summarized.

Verostko, C. E.↗
NASA NTRS1991

Scalar dissipation and mixing in turbulent reacting flows

The mixing term that appears in probability density function-based formulations of the statistical behavior of turbulent reacting flows was studied with the use of direct numerical simulations of an irreversible, second-order, isothermal chemical reaction between initially segregated reactants in decaying, homogeneous turbulence. Three-dimensional, time-dependent pseudospectral calculations with 64-cubed Fourier modes were made as well as were Monte Carlo simulations of the joint concentration pdf equations for coalescence-dispersion (C/D) models. It was found that the development of the scalar microscales depends largely on the initial concentration distributions (both isotropic and nonisotropic distributions were used) and is relatively independent of the reaction rate constant. Joint concentration probability density functions were compared to predictions of D/D models that make use of parameters evaluated from the nonreacting or inert system.

Leonard, Andy D.↗
NASA NTRS1992

Application of computational fluid dynamics to the design of the film cooled STME subscale nozzle for the National Launch System

The status of computational fluid dynamics (CFD) calculations for the Space Transportation Main Engine (STME) film/dump cooled nozzle design is presented, with an emphasis on the timely impact of CFD on the design of the sub-scale nozzle coolant system. The following aspects of the sub-scale coolant delivery system were analyzed with CFD: 1) a design trade study of a mechanical flow splitting device for uniform distribution of the subsonic cavity flow, 2) a design trade study of the subsonic cavity lip to achieve film integrity, and 3) an analysis of the primary flow interaction with the core/secondary coolant streams. All design calculations were performed with the Generalized Aerodynamic Simulation Program (GASP), a 3-D, multi-block, generalized Navier-Stokes code capable of solving with frozen, finite-rate or equilibrium chemical kinetics. The initial design of the subsonic cavity flow used square posts to distribute the sonic orifice jets into a uniform flow. Calculations for this design indicated that an unacceptable mal-distribution of film occurred. Design modifications involving curved and slotted posts were computed in an effort to uniformly distribute the secondary coolant flow. Analysis of these configurations showed that although the flowfield improved in uniformity, it was still unacceptable, especially at higher feed pressures. Results from these studies were then incorporated into a design that resulted in the insertion of a porous metal ring into the subsonic cavity. Subsequent water flow model studies showed that this concept was successful in uniformly distributing flow exiting the cavity. In addition to the design of the subsonic cavity, CFD was also used to analyze the secondary coolant lip and the primary flow interaction with the core/secondary coolant streams. A series of calculations were first performed to modify the subsonic cavity lip contour. The flow over the modified lip was then computed simultaneously with the primary injectors to determine the impact of the subsonic coolant stream on the primary slot jets. Pressure, temperature, velocity, and coolant mass fraction contours are presented for these configurations. Information is given in viewgraph form.

Garrett, Joseph L.↗
NASA NTRS1994

Transportation of volatile elements in thermally evolving planetesimals: An important role of metallic iron

Ordinary chondrites are considered to have experienced thermal metamorphism in small bodies. We are interested in behaviors of volatile elements in such a kind of thermally evolving planetesimals. Volatile elements generally have high vapor pressures at high temperature. In porous bodies, with a high gas permeability, volatile elements are transported efficiently over a long range. Behavior of volatile elements transported by permeable gas flow can be handled by an equation whose form is similar to that of the equation of thermal diffusion. We can follow transportation of heats and volatile elements in planetesimals, when parameters in these equations, initial conditions and chemical behavior of volatile elements are given. Recently, we discovered that nitrogen in equilibrated H-chondrites is mainly trapped in taenite (f.c.c. Fe-Ni), probably dissolved in interstitial sites. Fegley suggests that metallic iron cannot trap nitrogen in the solar nebula gas due to its very low nitrogen partial pressure. Approximately 1 bar of nitrogen pressure is required to explain the nitrogen content in taenite. We may expect high nitrogen gas partial pressure (possibly produced by vaporization of nitrogen-bearing solids such as organic materials) at the interior of thermally evolving planetesimals. Kinetic behavior of nitrogen in taenite suggests that it can easily be equilibrated with the ambient nitrogen gas at temperatures of approximately 500 C or higher. We consider that nitrogen is trapped in taenite through a nitrogen redistribution process occurred during the thermal metamorphic event.

Hashizume, K.↗
NASA NTRS1996

Chlorine Deactivation in the Lower Stratospheric Polar Regions during late Winter: Results from UARS

Recovery from enhanced chlorine conditions in the lower stratospheric polar regions of both hemispheres is investigated using data from the Upper Atmosphere Research Satellite (UARS). Microwave Limb Sounder (MLS) measurements of ClO within the polar vortices are used to infer ClO(sub x) (ClO + 2Cl202) abundances that are then correlated with simultaneous Cryogenic Limb Array Etalon Spectrometer (CLAES) measurements of ClON02 and Halogen Occultation Experiment (HALOE) measurements of HCl obtained starting within 5 days of the end of the MLS and CLAES high-latitude observing periods in each hemisphere. Time series of vortex-averaged mixing ratios are calculated on two potential temperature surfaces (585 K and 465 K) in the lower stratosphere for approximately month-long intervals during late winter: August 17 - September 17, 1992, in the southern hemisphere and February 12 - March 16, 1993, in the northern hemisphere. The observed mixing ratios are adjusted for the effects of vertical transport using diabatic vertical velocities estimated from CLAES tracer data. In the northern hemisphere, the decrease in ClO, is balanced on both surfaces by an increase in ClON02- In the southern hemisphere, continuing polar stratospheric cloud activity prevents ClO from undergoing sustained decline until about September 3. In contrast to the northern hemisphere, there is no significant chemical change in vortex-averaged ClON02 at 465 K, and there is an apparent decrease in ClON02 at 585 K, even after the enhanced ClO abundances have started to recede. Results from the SLIMCAT chemical transport model initialized with UARS data and run with OH + ClO yields HCl + 02 as an 8% channel suggest that the primary recovery product in the south during this time period is not ClON02, but HCl. HALOE HCl mixing ratios are extrapolated back to the time of the MLS and CLAES data. At 585 K, the chlorine budget can be made to balance by extrapolating HCl back to a value of 0.6 parts per billion by volume (ppbv) at the beginning of the study period; at 465 K, the contribution from extrapolated HCl is not sufficient to offset the loss in ClOx, and there is a slight imbalance between the decrease in reactive chlorine and the change in chlorine reservoirs. The difficulty in closing the chlorine budget in the southern hemisphere may arise from complications caused by ongoing activation, incomplete photochemical assumptions, and/or inadequate data quality.

Santee, M. L.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Meteorites

The session "Meteorites" included the following reports:Description of a New Stony Meteorite Find from Bulloch County, Georgia; Meteorite Ablation Derived from Cosmic Ray Track Data Dhofar 732: A Mg-rich Orthopyroxenitic Achondrite Halogens, Carbon and Sulfur in the Tagish Lake Meteorite: Implications for Classification and Terrestrial Alteration; Electromagnetic Scrape of Meteorites and Probably Columbia Tiles; Pre-Atmospheric Sizes and Orbits of Several Chondrites; Research of Shock-Thermal History of the Enstatite Chondrites by Track, Thermoluminescence and Neutron-Activation (NAA) Methods; Radiation and Shock-thermal History of the Kaidun CR2 Chondrite Glass Inclusions; On the Problem of Search for Super-Heavy Element Traces in the Meteorites: Probability of Their Discovery by Three-Prong Tracks due to Nuclear Spontaneous Fission Trace Element Abundances in Separated Phases of Pesyanoe, Enstatite Achondrite; Evaluation of Cooling Rate Calculated by Diffusional Modification of Chemical Zoning: Different Initial Profiles for Diffusion Calculation; Mineralogical Features and REE Distribution in Ortho- and Clinopyroxenes of the HaH 317 Enstatite Chondrite Dhofar 311, 730 and 731: New Lunar Meteorites from Oman; The Deuterium Content of Individual Murchison Amino Acids; Clues to the Formation of PV1, an Enigmatic Carbon-rich Chondritic Clast from the Plainview H-Chondrite Regolith Breccia ;Numerical Simulations of the Production of Extinct Radionuclides and ProtoCAIs by Magnetic Flaring.

Source record↗
NASA NTRS2013

Attribution of Trends and Variability in Surface Ozone over the United States

Concentrations of tropospheric ozone, a greenhouse gas and air pollutant, are impacted by changes in precursor emissions as well meteorology and influx from the stratosphere. Observations show a decreasing trend in summertime surface ozone at rural stations in the eastern United States, while some western stations show increasing trends, particularly in springtime. We use the Global Modeling Initiative (GMI) global chemical transport model to investigate the roles of precursor emission changes, meteorological variability, and stratosphere-troposphere exchange (STE) in explaining observed trends in surface ozone from rural sites in the United States from 1991-2010. The model's interannual variability shows significant correlations with observations from many of the surface sites. We also compare the simulated ozone to ozonesonde data for several locations with sufficiently long records. We compare a simulation with time-dependent precursor emissions, including emission reductions over the United States and Europe and increases over Asia, to a simulation with fixed emissions to quantify the impact of changing emissions on the surface trends. The simulation with varying emissions reproduces much of the east-west difference in summertime ozone over the U.S., although it generally underestimates the negative trend in the East. In contrast, the fixed-emission simulation shows increasing ozone at both eastern and western sites. We will discuss possible causes of this behavior, including long-range transport and STE.

ozone↗
NASA NTRSDate not supplied

Gateway bi-propellant refueling development testing and model validation activities

The Gateway is an upcoming long term lunar exploration program to be completed by NASA in partnership with ESA and other US and international partners. The system design of the Gateway contains both a high performance Xenon based Solar Electric Propulsion system, as well as a bi-propellant attitude control system. Both propulsion systems are designed for on-orbit refueling to enable long life performance of the Gateway. The ESPRIT-RM is a module which will expand the pressurized volume of Gateway, while also providing refueling capability for both the Xenon and Bipropellant propulsion systems, therefore extending the Gateway life on orbit. As part of the Gateway bi-propellant refueling system development, a simplified fluidic breadboard system was created to evaluate system performance and response using simulant fluids. The test plan includes verification activities with simulant (water, HFE-7100) to verify joined subsystem behavior in the critical operations, including propellant transfer demonstration between modules, transient tests and venting tests. Integrated testing occurred at TASUK in collaboration with NASA to support joint verification activities to de-risk the major functions of the ESPRIT BTS and the overall CONOPS of the refueling of the Gateway chemical propulsion system. Initially collected test data from the system testing is presented, as well as initial model validation, and correlated to collected high frequency test data and system response is shown. Initially collected data has shown the architected system performance is closing initial design assumptions, but much forward work remains to characterize and develop the system.

Christopher Daniel Radke↗
NASA NTRSDate not supplied

Joint Development Testing of the Integrated Gateway-Esprit Bipropellant Refuelling System

The Gateway is an upcoming long term lunar exploration program to be completed by NASA in partnership with ESA and other US and international partners. The system design of the Gateway contains both a high performance Xenon based Solar Electric Propulsion system, as well as a bi-propellant attitude control system. Both propulsion systems are designed for on-orbit refuelling to enable long life performance of the Gateway. The ESPRIT-RM is a module which will expand the pressurized volume of Gateway, while also providing refuelling capability for both the Xenon and Bipropellant propulsion systems, therefore extending the Gateway life on orbit. As part of the Gateway bi-propellant refuelling system development, a simplified fluidic breadboard system was created to evaluate system performance and response using simulant fluids. The test plan includes verification activities with simulant (water, HFE-7100) to verify joined subsystem behaviour in the critical operations, including propellant transfer demonstration between modules, transient tests and venting tests. Integrated testing will occur at TASUK in collaboration with NASA to support joint verification activities to de-risk the major functions of the ESPRIT Bipropellant Transfer Subsystem (BTS) and the overall CONOPS of the refuelling of the Gateway chemical propulsion system. Initially collected test data is presented and has shown the architected system performance is closing initial design assumptions, but much forward work is identified to continue to characterize and develop the system.

Sebastian Hill↗
NASA NTRSDate not supplied

Dynamics of Solar Energetic Particles in Geospace

Solar energetic particles (SEPs) penetrate deep into the geospace and the Earth's atmosphere, initiating nuclear and chemical reactions. These reactions produce secondary hadrons, leptons, and photons, posing radiation hazards at commercial aviation altitudes, particularly during high-latitude flights. During solar particle events, protons with energies above 10 MeV can reach below 100 km altitude, causing ionization that disrupts HF communication and navigation in polar regions. Galactic Cosmic Rays (GCRs) and Solar Energetic Particles (SEPs) pose radiation risks to satellites, astronauts, and ground infrastructure. High-energy particles can lead to single-event effects in spacecraft electronics, such as upsets, latch-ups, and burnouts. These particles also interact with the Earth's atmosphere, generating ionization and secondary particles like hadrons, leptons, and photons, creating hazards for astronauts, especially during extravehicular activities. The work presented in the paper is focused on characterizing the SEP population in geospace in the altitude range starting from that of LEO through MEO and GEO, and up to the magnetopause accounting for the realistic geomagnetic field. The dynamics of SEPs are studied during quiet and geomagnetically active times using Monte Carlo simulations. The paper discusses the variability of the SEP population in geospace in response to geomagnetic activity. The former manifests in the temporal trapping of SEPs in geospace and the suppression of rigidity cutoff during geomagnetic storms.

Valeriy Tenishev↗
DOE OSTI2023

Graphene nanoribbons grown from aromatic molecular seeds

Methods for the bottom-up growth of graphene nanoribbons are provided. The methods utilize small aromatic molecular seeds to initiate the anisotropic chemical vapor deposition (CVD) growth of graphene nanoribbons having low size polydispersities on the surface of a growth substrate. The aromatic molecular seeds include polycyclic aromatic hydrocarbons (PAHs), functionalized derivatives of PAHs, heterocyclic aromatic molecules, and metal complexes of heterocyclic aromatic molecules.

Arnold, Michael Scott↗
DOE OSTI2025

Chemical Activation of Frontal Ring-Opening Metathesis Polymerization

In this study, we present an innovative approach to frontal ring-opening metathesis polymerization (FROMP) through chemical activation. By locally concentrating Grubbs-type initiators, we accelerate exothermic polymerization at the activation site. Sufficient thermal energy initiates a polymerization front that travels through the remainder of the sample even with reduced initiator concentrations in the bulk resin. Initiation location and timing are controlled by adjusting the initiator reactivity, the properties of the transport solvent, and the air–resin interface. Our technique enables multipoint front activation, either through synchronized injection or by timing the relative reactivity of various initiators. This accessible method of chemical activation enables on-demand production of polymer and composite materials using only the thermal energy generated by the reaction, removing the need for external power sources and enabling deployment in remote or infrastructure-limited environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Adaptive, problem-tailored variational quantum eigensolver mitigates rough parameter landscapes and barren plateaus

Abstract Variational quantum eigensolvers (VQEs) represent a powerful class of hybrid quantum-classical algorithms for computing molecular energies. Various numerical issues exist for these methods, however, including barren plateaus and large numbers of local minima. In this work, we consider the Adaptive, Problem-Tailored Variational Quantum Eiegensolver (ADAPT-VQE) ansätze, and examine how they are impacted by these local minima. We find that while ADAPT-VQE does not remove local minima, the gradient-informed, one-operator-at-a-time circuit construction accomplishes two things: First, it provides an initialization strategy that can yield solutions with over an order of magnitude smaller error compared to random initialization, and which is applicable in situations where chemical intuition cannot help with initialization, i.e., when Hartree-Fock is a poor approximation to the ground state. Second, even if an ADAPT-VQE iteration converges to a local trap at one step, it can still “burrow” toward the exact solution by adding more operators, which preferentially deepens the occupied trap. This same mechanism helps highlight a surprising feature of ADAPT-VQE: It should not suffer optimization problems due to barren plateaus and random initialization. Even if such barren plateaus appear in the parameter landscape, our analysis suggests that ADAPT-VQE avoids such regions by design.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1980

Studies of the chemical basis of the origin of protein synthesis Initiation and direction of peptide growth

The data presented in this paper show that the ease of nonenzymatic activation of carboxylic acids by ATP at pH 5 varies directly with the pKa of the carboxyl group, and is consistent with the idea that it is the protonated form of the carboxyl group which participates in the activation reaction. Consequently, since most N-blocked amino acids have higher pKas than do their unblocked forms, they are activated more readily, and it has been demonstrated that this principle applies to peptides as well, which are activated more rapidly than single amino acids. It is proposed that this fact may be partly responsible for the origin of two important features still observed in contemporary protein synthesis: (1) initiation in prokaryotes is accomplished with an N-blocked amino acid, and (2) elongation in all living systems occurs at the carboxyl end of the growing peptide.

Mullins, D. W., Jr.↗
NASA NTRS1994

Venusian atmospheric equilibrium chemistry at the Pioneer Venus anomalous event altitude

No convincing explanation for the anomalous behavior of the Atmospheric Structure Experiment temperature sensors at approximately 13 km altitude has been found. It occurred on all of the widely-spaced probes, in a similar fashion. A preliminary effort has been made to determine atmospheric chemical species which might be present at 13 km. The purpose of this effort is to initiate suggestions of possible chemical interactions and to explore the effects of the presence of possible metal reactants including condensation. Equilibrium fractions of chemical species were calculated at a variety of conditions. Baseline calculations were made for the altitudes near 13 km. For comparison calculations were also made at 13 km but with the introduction of plausible metal atoms.

Craig, Roger A.↗
DOE OSTI2022

Thermoelectric power generation in the core of a nuclear reactor

Thermoelectric energy converters offer a promising solution to generate electrical power using heat in the nuclear reactor core. Despite significant improvements in thermoelectric efficiency of nanostructured materials, the performance of these advanced materials has yet to be demonstrated in the harsh radiation environment of a reactor core. Herein, we demonstrate a thermoelectric generator (TEG) made from nanostructured bulk half-Heusler (HH) materials generating stable electrical power density > 1140 W/m 2 after 30 days in the MIT Nuclear Research Reactor under an unprecedented fast-neutron (>1 MeV) fluence of 1.5 × 10 20 n/cm 2 . Despite an initial degradation due to irradiation damage when operating under relatively low temperatures, our TEG showed a 20-fold increase in power output when operating under high temperature due to in-situ annealing and resulting thermoelectric property recovery. First-principles modeling indicates that a chemically disordered metallic phase was formed under irradiation at lower temperatures, resulting in a drastic degradation in thermoelectric properties, while at sufficiently high temperatures the system returned to the initial chemically ordered HH phase and the thermoelectric properties recovered. Transmission electron microscopy and electron diffraction demonstrated that the chemically disordered phase was formed upon ion irradiation, confirming the prediction from first-principles simulations. Furthermore, the results suggest that with proper control over the TEG operating temperatures, the nanostructured bulk TEGs could produce stable electrical power and operate indefinitely in the core of a nuclear reactor.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1999

High-Resolution Spectroscopy of Mars: Recent Results and Implications for Atmospheric Evolution

It is believed that Earth, Venus, and Mars were formed by the same rocky and icy planetesimals, which resembled meteorites and comets in their composition, respectively. These planets are thus expected to have initially had the same chemical and isotope composition. Scaling the mass of the terrestrial ocean by the planetary mass ratio, the expected initial H2O abundance on Mars is a layer of about 1 km thick. Scaling the abundance of CO2 on Venus, the expected initial CO2 abundance on Mars is 15 bars. Evidently, significant parts of the initial H2O and CO2 abundances have been lost. Intense meteorite impact erosion and hydrodynamic escape of hydrogen (which could drag to escape more heavy species) were dominant loss processes in the first 0.8 Byr. Later, atmospheric sputtering by O+ ions resulted in the dissociation of CO2 and massive losses of O, C, and H. Formation of carbonates also reduced CO2 to its present abundance which currently exists in the atmosphere, on the polar caps, and is absorbed by regolith. Water loss is currently due to thermal escape of H and nonthermal escape of O, both formed by photodissociation of H2O. All loss processes resulted in fractionation of the H, O, and C isotopes. Therefore, the current isotope ratios in H2O and CO2 are clues to the history of volatiles on Mars. There are three tools to study H2O and CO2 isotopes in the martian atmosphere: (i) mass spectrometry from landing probes, (ii) analyses of Mars' gases trapped in the SNC meteorites which were ejected from Mars, and (iii) high-resolution spectroscopy of the H2O andCO2 bands. Method (i) is the best but is the most expensive. Mass spectrometers to be used should be designed for high-precision isotope measurements. Method (ii) makes it possible to reach an uncertainty +/- 0.1%. However, the obtained results are affected by some uncontrolled interactions: isotope fractionations of (1) trapped gases and (2) those released in pyrolysis, (3) contribution of the impactor, isotope exchanges (4) in the terrestrial environment and (5) with the host rock during pyrolysis. Therefore, the spectroscopic data are of great interest, though their formal accuracy is lower. High-resolution spectroscopy is also a tool to study the current atmosphere of Mars by mapping of some photochemically important species and searching for some minor constituents and their variations. Additional information is contained in the original extended abstract.

Krasnopolsky, V. A.↗