Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Carbon monoxide”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

The dissociation of shock-heated carbon monoxide

Investigation of the dissociation kinetics of undiluted carbon monoxide over the 5,600 to 12,000 K temperature range. Data are presented that have been obtained as time-resolved pressure measurements on the end wall of a shock tube and radiation emission of a C2 Swan system (0-0 band) behind incident shock waves. The decomposition of CO is complex and includes a chain with C2 as an intermediate species. The dissociation rate for the overall process has been found to be independent of the proportions of the collision partners M = CO, C, and O. The rate constant found is on the average about 10 times that previously measured with argon as the collision partner.

Hanson, R. K.↗
NASA NTRS1977

Research and development of a luminol-carbon monoxide flow system

Adaption of the luminol-carbon monoxide injection system to a flowing type system is reported. Analysis of actual wastewater samples was carried out and revealed that bacteria can be associated with particles greater than 10 microns in size in samples such as mixed liquor. Research into the luminol reactive oxidation state indicates that oxidized iron porphyrins, cytochrome-c in particular, produce more luminol chemiluminescence than the reduced form. Correlation exists between the extent of porphyrin oxidation and relative chemiluminescence. In addition, the porphyrin nucleus is apparently destroyed under the current chemiluminescent reaction conditions.

Thomas, R. R.↗
NASA NTRS1978

DACOM - A rapid, high sensitivity airborne carbon monoxide monitor

A rapid, high sensitivity differential absorption carbon monoxide monitor (DACOM) has been developed to measure CO from an aircraft. The differential absorption measurement is accomplished by rapidly current tuning the wavelength of a PbSSe diode laser across a single 4.7 micron CO absorption line. As the laser wavelength sweeps periodically across the absorption line, the laser beam is amplitude modulated and is then synchronously detected. With this technique a minimum detectable differential transmission of 0.02% is obtained for a 1 second integration time. This performance is equivalent to a CO sensitivity of 5 ppb for a 10 meter absorption path. The techniques used to achieve this high sensitivity will be discussed. In the aircraft installation a 10 meter absorption path is located in the airstream along the fuselage of a C-54 aircraft. During flight tests of DACOM, a sensitivity of 20 ppb for a 1-second integration time has been achieved.

Sachse, G. W.↗
NASA NTRS1981

Detection of the J = 6 - 5 transition of carbon monoxide

The J = 6 - 5 rotational transition of carbon monoxide has been detected in emission from the KL 'plateau source' in the Orion molecular cloud. The corrected peak antenna temperature is 100 K, and the FWHM line width is 26 km/sec. These observations were carried out using the 3 m telescope of the NASA IRTF (Infrared Telescope Facility) on Mauna Kea, Hawaii, and constitute the first astronomical data obtained at submillimeter wavelengths with a heterodyne system using a laser local oscillator. The data support the idea that the high-velocity dispersion CO in Orion is optically thin and set a lower limit to its temperature of approximately 180 K.

Goldsmith, P. F.↗
NASA NTRS1982

The relationship between carbon monoxide abundance and visual extinction in interstellar clouds

Carbon monoxide column densities are compared to visual extinctions toward field stars in the rho Oph and Taurus molecular cloud complexes. The relationship of C(0-18) column density to extinction is established, and new determinations for (C-13)O column densities are given for a range of visual extinctions extended to beyond 20 mag. A prescription for determining hydrogen column densities and masses of molecular clouds from observations of CO isotopes is presented and discussed critically. These measurements agree well with the predictions of gas phase chemistry models which include chemical fractionation and selective isotopic photodestruction. The functional dependence of the C(O-18) column density on extinction is characterized by two different regimes separated by a distinct transition observed to occur at 4 mag in both molecular cloud complexes, whereas the functional dependence of (C-13)O is quite different in the two regions. Some saturation is found to occur for C(O-18) emission at high visual extinction and use the rarer isotopic species C(O-17) and (C-13)(O-18) to correct for it.

Frerking, M. A.↗
NASA NTRS1994

Carbon monoxide and methane over Canada: July - August 1990

Carbon monoxide (CO) and methane (CH4) were measured in the 0.15- to 6-km portion of the troposphere over subarctic and boreal landscapes of midcontinent and eastern Canada during July - August 1990. In the mid-continent region, Arctic air entering the region was characterized by relatively uniform CO concentrations (86-108 parts per billion by volume (ppbv)) and CH4 concentrations (1729-1764 ppbv). Local biomass burning and long-range transport of CO into the area from industrial/urban sources and distant fires did frequently produce enhanced and variable concentrations. Emissions of CH4 from the Hudson Bay lowlands was the primary source for enhanced and variable concentrations, especially at altitudes of 0.15-1 km. In eastern Canada, most of the observed variability in CO and CH4 was similar in origin to the phenomena described for the midcontinent region. However, unexpectedly low concentrations of CO (51 ppbv) and CH4 (1688 ppbv) were measured in the midtroposphere on several flights. Combined meteorological and chemical data indicated that the low CO-CH4 events were the result of long-range transport of tropical Pacific marine air to subarctic latitudes.

Harriss, R. C.↗
NASA NTRS1999

Carbon Monoxide Formation in SN 1987A

The formation of carbon monoxide in the supernova SN 1987A at 200 days is investigated. Rather than the one-zone that have previous been employed, this work utilizes a radially dependent radiative transport model to compute the temperature and ionization structure and the destruction of CO and CO+ by ultraviolet radiation. The CO profile is computed assuming chemical equilibrium. Two models for the density and abundance profiles are examined: model 10H (unmixed) and model 10HMM (mixed) of Pinto & Woosley. Sensitivity to adopted rates and temperature as it might be affected by CO cooling is examined. The models give a total mass of 10-4 M_sun at 200 days for the unmixed model, which is comparable with the estimated observed abundance by Syromilio et al. but nearly 2 orders of magnitude less than the estimated observed and that computed in thermal-chemical models by Liu & Dalgarno. The effect of different model assumptions and results concerning ionization structure and radiative transfer are discussed. We confirm that CO+ is not expected to be produced in significant amounts and that the amount of CO is sensitive to the degree of the mixing of the composition of various elements present in the ejecta.

Gearhart, Rob A.↗
NASA NTRS1989

Feasibility of determining the vertical profile of carbon monoxide from a space platform

The results of a feasibility study conducted to determine the possibility of passively measuring the vertical profile of carbon monoxide in the troposphere on a global basis are presented. The instrument considered is a nadir-viewing gas correlation filter radiometer (GCFR). The basic instrument concept and radiative transfer equations are presented. The calculated signal functions, signal levels, sensitivity, and system noise levels of a spaceborne GCFR instrument are presented and discussed. It is concluded that a three- or four-level measurement of the atmospheric carbon monoxide mixing ratio in the troposphere is possible with this type of instrument.

Reichle, Henry, Jr.↗
NASA NTRS2018

Solar Cycle Variations in Mesospheric Carbon Monoxide

As an extension of Lee et al. (2013), solar cycle variation of carbon monoxide (CO) is analyzed with MLS observation, which covers more than thirteen years (2004-2017) including maximum of solar cycle 24. Being produced primarily by the carbon dioxide (CO2) photolysis in the lower thermosphere, the variations of the mesospheric CO concentration are largely driven by the solar cycle modulated ultraviolet (UV) variation. This solar signal extends down to the lower altitudes by the dynamical descent in the winter polar vortex, showing a time lag that is consistent with the average descent velocity. To characterize a global distribution of the solar impact, MLS CO is correlated with the SORCE measured total solar irradiance (TSI) and UV. As high as 0.8 in most of the polar mesosphere, the linear correlation coefficients between CO and UV/TSI are more robust than those found in the previous work. The photochemical contribution explains most (68%) of the total variance of CO while the dynamical contribution accounts for 21% of the total variance at upper mesosphere. The photochemistry driven CO anomaly signal is extended in the tropics by vertical mixing. The solar cycle signal in CO is further examined with the Whole Atmosphere Community Climate Model (WACCM) 3.5 simulation by implementing two different modeled Spectral Solar Irradiances (SSIs): SRPM 2012 and NRLSSI. The model simulations underestimate the mean CO amount and solar cycle variations of CO, by a factor of 3, compared to those obtained from MLS observation. Different inputs of the solar spectrum have small impacts on CO variation.

MLS↗
NASA NTRS1977

Effect of carbon monoxide and nitrogen dioxide on ICR mice

Times to incapacitation and death and LC(50) values were determined for male ICR mice exposed to different concentration of carbon monoxide for 30 min and of nitrogen dioxide for 10 min in a 4.2 liter hemispherical chamber. The data indicate that ICR mice are more resistant to these two toxicants than Swiss albino mice. The carbon monoxide LC(50) for a 30-min exposure was about 8,000 ppm for ICR mice compared to 3,570 ppm for Swiss albino mice. The nitrogen dioxide LC(50) for a 10-min exposure was above 2,000 ppm for ICR mice compared to about 1,000 ppm for Swiss albino mice.

Hilado, C. J.↗
NASA NTRS1981

Fourier Transform Spectrometer observations of solar carbon monoxide. I - The fundamental and first overtone bands in the quiet sun

Measurements of the 2200/cm fundamental and 4300/cm first overtone vibration-rotation band systems of solar carbon monoxide, were obtained with the Fourier Transform Spectrometer of the McMath telescope at Kitt Peak. The overtone measurements were taken at the east, north, and west heliocentric limbs, and at disk center. Observations of the strong fundamental bands were obtained at disk center and near the north limb. The low core brightness temperatures of the strongest fundamental carbon monoxide lines near the limb, reported previously by Noyes (1972) and Hall (1974), are confirmed. The possibility that thermal inhomogeneities might be responsible for the unusual behavior of the fundamental carbon dioxide lines have been examined. The somewhat discordant behavior of the fundamental lines at disk center compared with the north limb seems to favor a limb shadowing effect. The first overtone limb equivalent widths and the best-fit thermal and microvelocity models indicate a solar carbon abundance of 0.004 (on the scale with A sub H = 1) for an oxygen-to-carbon abundance ratio of 2.

Ayres, T. R.↗
NASA NTRS1998

Satellite Investigations of Fire, Smoke, and Carbon Monoxide during April 1994 MAPS Mission: Case Studies over Tropical Asia

During April 9-19, 1994, the Measurement of Air Pollution from Satellites (MAPS) measured free tropospheric carbon monoxide (CO) concentrations on a near-global basis. For these eleven days the global lkm advanced very high resolution radiometer (AVHRR) Pathfinder data are used to detect fires and smoke over the Indo-Burma region (85 degrees E - 110 degrees E; 10 degrees N -30 degrees N). The fire activities are categorized for four major ecosystems that include (1) cropland/natural vegetation mosaic (CNVM), (2) evergreen broadleaf forest (EBF), (3) mixed forest (MFD), and (4) grassland (GL). Using published emission rates between particulate matter and carbon monoxide concentrations from temperate areas, the fire counts along with other information are used to obtain estimates of CO concentrations from the AVERR data. More than 7000 fires are detected during the study period with 23%, 43%, 24%, and 10% fires in the CNVM, EBF, MFD, and GL ecosystems, respectively. The enhanced CO concentrations over the area of study are either over or downwind of the fires detected by the AVHRR. The preliminary AVHRR estimates of CO concentrations are smaller than the MAPS-measured values by a factor of 4 to 5 for fire counts areater than 200. The differences are attributed to the lack of transport mechanisms and other assumptions in the current model. However, these results show a good potential for usino the AVHRR measurements to detect fires and smoke and also to estimate CO concentrations.

Christopher, Sundar A.↗
NASA NTRS1988

A study of carbon monoxide distribution determinations for a global transport model

The primary objective of this grant was to further the development of a global transport/chemistry model that simulates the physico-chemical behavior of methane and carbon monoxide in the troposphere. The computer simulation model is designed to analyze the processes that occur as methane and carbon monoxide are transported from their respective sources to their ultimate fate, e.g., final conversion to CO2, transport to the stratosphere, deposition at ground level, etc.

Peters, Leonard K.↗
NASA NTRS2010

Advanced Catalysts for the Ambient Temperature Oxidation of Carbon Monoxide and Formaldehyde

The primary applications for ambient temperature carbon monoxide (CO) oxidation catalysts include emergency breathing masks and confined volume life support systems, such as those employed on the Shuttle. While Hopcalite is typically used in emergency breathing masks for terrestrial applications, in the 1970s, NASA selected a 2% platinum (Pt) on carbon for use on the Shuttle since it is more active and also more tolerant to water vapor. In the last 10-15 years there have been significant advances in ambient temperature CO oxidation catalysts. Langley Research Center developed a monolithic catalyst for ambient temperature CO oxidation operating under stoichiometric conditions for closed loop carbon dioxide (CO2) laser applications which is also advertised as having the potential to oxidize formaldehyde (HCHO) at ambient temperatures. In the last decade it has been discovered that appropriate sized nano-particles of gold are highly active for CO oxidation, even at sub-ambient temperatures, and as a result there has been a wealth of data reported in the literature relating to ambient/low temperature CO oxidation. In the shorter term missions where CO concentrations are typically controlled via ambient temperature oxidation catalysts, formaldehyde is also a contaminant of concern, and requires specially treated carbons such as Calgon Formasorb as untreated activated carbon has effectively no HCHO capacity. This paper examines the activity of some of the newer ambient temperature CO and formaldehyde (HCHO) oxidation catalysts, and measures the performance of the catalysts relative to the NASA baseline Ambient Temperature Catalytic Oxidizer (ATCO) catalyst at conditions of interest for closed loop trace contaminant control systems.

Nalette, Tim↗
NASA NTRS1936

The Effect of Water Vapor on Flame Velocity in Equivalent Carbon Monoxide and Oxygen Mixtures

This report presents the results of an investigation to study the effect of water vapor upon the spatial speed of flame in equivalent mixtures of carbon monoxide and oxygen at various total pressures from 100 to 780 mm.hg. These results show that, within this pressure range, an increase in flame speed is produced by increasing the mole fraction of water vapor at least as far as saturation at 25 degrees c., and that the rate of this increase is greater the higher the pressure. It is evident that water vapor plays an important part in the explosive oxidation of carbon monoxide; the need for further experimental evidence as to the nature of its action is indicated.

Fiock, Ernest F↗
NASA NTRS1976

Some observations on the oscillatory behavior of carbon monoxide oxidation

The oscillatory behavior of the oxidation of carbon monoxide was experimentally studied in an attempt to further elucidate the reaction at low pressure. The phenomenon is observed as multiple explosions and involves successive flashes of light accompanying the slow reaction in a static system, including over 450 flashes in one case. Electronically excited hydroxyl radicals (water impurity) and carbon dioxide have been identified as components of the emission. The phase difference between the two was seen to be negligible. The nature of the temperature and pressure changes during a cycle indicates that the oscillation is purely kinetic rather than thermokinetic. A procedure is presented whereby sustained oscillations can be obtained for particular regions in the pressure-temperature plane, vessel surface pretreatments, and H2O-containing reactants.

Mccaffrey, B. J.↗