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At least 127 records · Page 7

Regulatory Testing of RPP-WTP HLW Glasses to Support Delisting Compliance, VSL-04R4780-1, Rev. 0 (Sep 2004)

The primary goal of the testing described in this report was to collect data to demonstrate compliance of the immobilized high-level waste (IHLW) glasses with delisting requirements. The collected data will be used to support a petition to delist the IHLW glasses destined for the national disposal facility. The Delisting Data Quality Objectives (DQO) (Cook and Blumenkranz 2003) identified a list of (16) inorganic constituents of potential concern (COPCs) and their associated limits for delisting. These COPCs can be divided into three groups, Cases 1, 2, and 3, based on their Toxicity Characteristic Leaching Procedure (TCLP) responses versus their respective delisting limits. To briefly summarize, Case 1 COPCs are those that, when loaded at their highest expected concentration in Waste Treatment Plant (WTP) glasses, are not expected to leach at their respective delisting limits when the glasses are exposed to the TCLP. Case 2 COPCs may reach the delisting limits in TCLP leachates of WTP glasses if loaded to concentrations near their maximum expected concentrations in glass. Finally, Case 3 COPCs are components that are likely to be present in concentrations sufficient to exceed their respective delisting limits in TCLP leachates of some possible glasses. The test objective was to show that, for (i) the expected range of inorganic contents in the waste feed to the Hanford WTP high level waste (HLW) vitrification facility, (ii) the expected range of glass product compositions, and (iii) the Case 1 and Case 2 COPCs identified by the DQO, the IHLW glasses meet all the relevant requirements for delisting. For Case 3 COPCs (i.e., Cd), the testing was to demonstrate the relationship between glass composition and TCLP cadmium (Cd) release, and then employ the results to develop TCLP-composition response models. During WTP operations, TCLP-composition models can be used to predict, within the required statistical uncertainties, TCLP responses of IHLW production glasses that are within the compositional region used to develop the model.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Compliance of NNSS Activities with P322-4 Issues Management and NNSSWAC Requirements

The Institutional Quality and Performance Assurance Division's Quality Support Services Group conducted a surveillance of the compliance of Waste Management Program activities to Issues Management/Corrective Action requirements communicated in P322-4 and the Nevada National Security Site Waste Acceptance criteria (NNSSWAC). All corrective actions reviewed and records examined were found to be compliant with appropriate and relevant procedures. There were no Findings or Opportunities for Improvement noted.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

On evaluating compliance with air pollution levels not to be exceeded more than once per year

The adequacy is considered of currently practiced monitoring and data reduction techniques for assessing compliance with 24-hour Air Quality Standards (AQS) not to be exceeded more than once per year. The present situation for suspended particulates is discussed. The following conclusions are reached: (1) For typical less than daily sampling (i.e., 60 to 120 24-hour samples per year) the deviation from independence of the data set should not be substantial. (2) The interchange of exponentiation and expectation operations in the EPA data reduction model, underestimates the second highest level by about 4 to 8 percent for typical sigma values. (3) Estimates of the second highest pollution level have associated with them a large statistical variability arising from the finite size of the sample. The 0.95 confidence interval ranges from + or - 40 percent for 120 samples per year to + or - 84 percent for 30 samples per year. (4) The design value suggested by EPA for abatement and/or control planning purposes typically gives a margin of safety of 60 to 120 percent.

Neustadter, H. E.↗

A study of fatigue crack closure using electric potential and compliance techniques

Compared are closure data produced on the same specimen by the crack tip compliance gage and electric potential techniques. Experiments on 7075-T651 aluminum center cracked panels produced equivalent results on closure using the two techniques. The results also indicated that closure is a function of stress ratio, specimen thickness and maximum applied stress intensity. Maximum stress intensity had a strong effect on closure in the range of applied stresses used. This dependence of closure on specimen thickness and maximum stress intensity accounts for many of the discrepencies in closure behavior reported in the literature.

Clarke, C. K.↗

A study of fatigue crack closure using electric potential and compliance techniques

The objective of this study was to compare closure data obtained on the same specimen with crack tip compliance gage and electric potential techniques. Equivalent results on closure using the two techniques were obtained on 7075-T651 aluminum center cracked panels. The results also indicated that closure was a function of stress ratio, specimen thickness and maximum applied stress intensity. Maximum stress intensity had a particularly strong effect on closure in the range of applied stresses used. This observed dependence of closure on specimen thickness and maximum stress intensity should account for many of the discrepancies in closure behavior found in the literature. Observations on potential system behavior during closure measurements are also reported.

Clarke, C. K.↗

Comparison tests and experimental compliance calibration of the proposed standard round compact plane strain fracture toughness specimen

Standard round specimen fracture test results compared satisfactorily with results from standard rectangular compact specimens machined from the same material. The location of the loading pin holes was found to provide adequate strength in the load bearing region for plane strain fracture toughness testing. Excellent agreement was found between the stress intensity coefficient values obtained from compliance measurements and the analytic solution proposed for inclusion in the standard test method. Load displacement measurements were made using long armed displacement gages and hollow loading cylinders. Gage points registered on the loading hole surfaces through small holes in the walls of the loading cylinders.

Fisher, D. M.↗

Compliance and stress intensity coefficients for short bar specimens with chevron notches

For the determination of fracture toughness especially with brittle materials, a short bar specimen with rectangular cross section and chevron notch can be used. As the crack propagates from the tip of the triangular notch, the load increases to a maximum then decreases. To obtain the relation between the fracture toughness and maximum load, calculations of Srawley and Gross for specimens with a straight-through crack were applied to the specimens with chevron notches. For the specimens with a straight-through crack, an analytical expression was obtained. This expression was used for the calculation of the fracture toughness versus maximum load relation under the assumption that the change of the compliance with crack length for the specimen with a chevron notch is the same as for a specimen with a straight-through crack.

Munz, D.↗