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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture

Powders of a Sn2S3 chalcogen-based aerogel (chalcogel) were combined with powdered polyacrylonitrile (PAN) in different mass ratios (SnS33, SnS50, and SnS70 in mass% of chalcogel), dissolved into dimethyl sulfoxide, and dropped into deionized water to form pellets of a porous PAN-chalcogel hybrid material. Pellets of these hybrid sorbents, along with pure powdered (SnSp) and granular (SnSg) forms of the chalcogel, were then used to adsorb iodine gas under both concentrated and dilute conditions. Both the SnSp and SnSg chalcogels showed very high maximum iodine loadings at 67.2 and 68.3 mass%. The maximum iodine loadings in the SnS33 and SnS50 were high at 32.8 and 53.5 mass%. In all cases, X-ray diffraction results showed the formation of Sn-I phases of SnI4 and SnI4(S8)2 revealing that the iodine binding in these materials is mainly due to a chemisorption process although some evidence also exists that supports a physisorption process.

chalcogel↗
DOE OSTI2018

Textural properties determined CO 2 capture of tetraethylenepentamine loaded SiO 2 nanowires from α-sepiolite

To understand the effect of porous parameters and chemical components on CO 2 capturing performance of solid state amine absorbents and their kinetic parameters, a clay mineral-based CO 2 absorbent was prepared by impregnating five different liquid amines onto SiO 2 nanowire clusters from fibrous sepiolite (Sep). Characterization was conducted by XRD, SEM, FTIR, and N 2 adsorption–desorption isotherm, CO 2 adsorption performances were measured by TGA. After acid treatment, the raw Sep mineral changed into amorphous silica nanowires, and the largest S BET of the obtained SiO 2 nanowires reached 320 m 2 /g, which was 8 times larger than the pristine mineral. Amongst the adapted amines, tetraethylenepentamine (TEPA) showed superiority in the CO 2 adsorption capacity. The optimized adsorption capacity reached 3.7 mmol/g at 75 °C from a CO 2 + N 2 mixture on a ~50 wt% TEPA loaded SiO 2 sample, and the capacity remained 3.6 mmol/g after ten circles of adsorption/desorption tests. The pore size and pore structure of the matrix, rather than the surface area, will obviously affect the adsorption ability of the product. Kinetic parameters for the CO 2 adsorption process fitted well with a fractional-order model, confirming that the CO 2 adsorption process by the solid absorbent should be a combination of both physical and chemical reactions. Results in this article provide detailed parameters for preparing and understanding these clay mineral based solid state CO 2 absorbents.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Electron capture decay of 58-min U-229(92) and levels in Pa-229(91)

Electron capture decay of U-229 is investigated by measuring the gamma-ray and conversion electron spectra of mass-separated and unseparated U-229 sources with high-resolution germanium and silicon detectors, respectively. Gamma-gamma coincidence measurements are also performed using germanium detectors. These studies provide level energies and level ordering in Pa-229. Single-particle assignments are given to these levels which are in agreement with the systematics in this region and also with theory. In a previous study, we report the observation of a 5/2(+/-) parity doublet in the Pa-229 ground state, which is a signature of octupole deformation. The present analysis of the data still shows a splitting of 60 +/- 50 eV, but with this large uncertainty the existence of the doublet is not certain.

Ahmad, I.↗
DOE OSTI2018

First Observation of 𝑃-odd 𝛾 Asymmetry in Polarized Neutron Capture on Hydrogen

Here, we report the first observation of the parity-violating gamma-ray asymmetry 𝐴$^{𝑛⁢𝑝}_{𝛾}$ in neutron-proton capture using polarized cold neutrons incident on a liquid parahydrogen target at the Spallation Neutron Source at Oak Ridge National Laboratory. 𝐴$^{𝑛⁢𝑝}_{𝛾}$ isolates the Δ⁢𝐼 =1, 3 𝑆 1 → 3 𝑃 1 component of the weak nucleon-nucleon interaction, which is dominated by pion exchange and can be directly related to a single coupling constant in either the DDH meson exchange model or pionless effective field theory. We measured 𝐴$^{𝑛⁢𝑝}_{𝛾}$=[−3.0±1.4⁢(stat)±0.2⁢(syst)]×10 −8 , which implies a DDH weak 𝜋⁢𝑁⁢𝑁 coupling of ℎ$^1_𝜋$=[2.6±1.2⁢(stat)±0.2⁢(syst)]×10 −7 and a pionless EFT constant of 𝐶 3 𝑆 1 → 3 𝑃 1 /𝐶 0 =[−7.4±3.5⁢(stat)±0.5⁢(syst)]×10 −11 MeV −1 . We describe the experiment, data analysis, systematic uncertainties, and implications of the result.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗