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Magnetron sputter deposition of ultrathick boron carbide coatings on spherical substrates for inertial confinement fusion
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Potent Inhibition of Mandelate Racemase by Boronic Acids: Boron as a Mimic of a Carbon Acid Center
Abstract not provided
From Carbene-Dithiolene Zwitterion Mediated B–H Bond Activation to BH 3 ·SMe 2 -Assisted Boron–Boron Bond Formation
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Boron rich nanotube drug carrier system is suited for boron neutron capture therapy
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Aminopolymer functionalization of boron nitride nanosheets for highly efficient capture of carbon dioxide
Here, BN nanosheets were functionalized with polyethyleneimine (PEI) which is rich in amine density, through simple impregnation to improve their performance for CO 2 capture.
Polyvinyl alcohol–boronate gel for sodium hydroxide extraction
We report that gels formed from commercially available polyvinyl alcohol ( PVA ) and 1,4-benzene diboronic acid (BdBA) in DMSO absorb NaOH efficiently from a bulk aqueous solution decreasing its pH.
Confinement boosts CO oxidation on an Ni atom embedded inside boron nitride nanotubes
Because of the confinement effect, Ni embedded on the interior surface of BNNT exhibits a much higher catalytic activity for CO oxidation by comparing with that embedded in h-BN or on the outside surface of BNNT.
Filling the gap with a bulky diaryl boron group: fluorinated and non-fluorinated copper pyrazolates fitted with a dimesityl boron moiety on the backbone
Successful synthesis has been reported of 4-Mes 2 B-3,5-(CF 3 ) 2 PzH and 4-Mes 2 B-3,5-(CF 3 ) 2 PzH bearing sterically demanding diarylboron moieties at the pyrazole ring 4-position, and their corresponding copper(I) pyrazolate complexes. They show visible blue photoluminescence in solution. The X-ray crystal structures revealed that the fluorinated {[4-BMes 2 -3,5-(CF 3 ) 2 Pz]Cu} 3 crystallizes as discrete trinuclear molecules whereas as the non-fluorinated {[4-BMes 2 -3,5-(CH 3 ) 2 Pz]Cu} 3 forms dimers of trimers with two close inter-trimer Cu···Cu separations. The solid {[4-BMes 2 -3,5-(CF 3 ) 2 Pz]Cu} 3 featuring a sterically confined Cu 3 N 6 core displays bright blue phosphorescence while {[4-BMes 2 -3,5-(CH 3 ) 2 Pz]Cu} 3 , which is a dimer of a trimer, is a red phosphor at room temperature. Here, this work illustrates the modulation of photo-physical properties of metal pyrazolates by adjusting the supporting ligand steric features and introducing secondary diarylboron luminophores. Computational analysis of the structures and photophysical properties of copper complexes are also presented.
Novel boron channel-based structure of boron carbide at high pressures
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Formation and stability of dense arrays of Au nanoclusters on hexagonal boron nitride/Rh(111)
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Structural impact on the eigenenergy renormalization for carbon and silicon allotropes and boron nitride polymorphs
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Theory of oxygen-boron vacancy defect in cubic boron nitride: A diamond NV – isoelectronic center
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