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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Deployment of Multifidelity Uncertainty Quantification for Thermal Battery Assessment Part I: Algorithms and Single Cell Results

This report documents the results of an FY22 ASC V&V level 2 milestone demonstrating new algorithms for multifidelity uncertainty quantification. Part I of the report describes the algorithms, studies their performance on a simple model problem, and then deploys the methods to a thermal battery example from the open literature. Part II (restricted distribution) applies the multifidelity UQ methods to specific thermal batteries of interest to the NNSA/ASC program.

25 ENERGY STORAGE↗

State of battery health estimation based on swelling characteristics

There is disclosed an electrical device including a battery, and a battery management system. The battery management system includes a controller in electrical communication with a pressure sensor to monitor the state of health of the battery. The controller applies a method for determining the state of health that uses a non-electrical (mechanical) signal of force measurements combined with incremental capacity analysis to estimate the capacity fading and other health indicators of the battery with better precision than existing methods. The pressure sensor may provide the force measurement signal to the controller, which may determine which incremental capacity curve based on force to use for the particular battery. The controller then executes a program utilizing the data from the pressure sensor and the stored incremental capacity curves based on force to estimate the capacity fading and signal a user with the state of health percentage.

Stefanopoulou, Anna G.↗

Energy storage system

A system, a method, and a computer program product for providing heterogeneous unifying battery storage. A state-of-health value of a battery is determined. The state-of-health value of the battery is less than an original capacity value of the battery. The battery is connected to an electrical power source for re-conditioning. A target state-of-health value for the battery and a number of cycles required to achieve the target state-of-health value of the battery are determined. Each cycle in the number of cycles includes at least one of: a charging the battery and a discharging the battery. The battery is re-conditioned by cycling the battery using the determined number of cycles. Cycling includes drawing electrical power from the electrical power source.

Tong, Shijie↗

Low-Temperature Plasma-Based Metrology of Lithium-Ion Battery Electrode Materials (CRADA Final Report)

As part of the Cyclotron Road program, SirenOpt Inc. evaluated its low-temperature plasma-based metrology sensor prototype for measuring multiple critical properties of lithium-ion battery electrode materials in parallel and in real-time. Cost-effective, minimal-waste manufacturing of high-performance battery electrode materials will be vital for achieving society’s net-zero carbon emission goals. Because existing electrode metrology sensors cannot operate within most sections of manufacturing lines, manufacturers often complete hundreds of processing steps before they can test their products and detect problems. When manufacturers perform these offline tests, they typically only test a small portion of the manufactured products. Current electrode manufacturing thus often yields many low-quality products, or off-spec products that must be thrown away all together. For example, at least 6% of the total lithium-ion battery manufacturing cost (i.e., over $250 million/year for the average gigafactory) is devoted to processing defective electrodes that are not scrapped until performance tests are failed during late-stage quality control checks. Electrode variability also leads manufacturers to build extra cells into battery packs to reduce the risk of poor performance. For example, many electric vehicle (EV) manufacturers include up to 10% more cells than needed, which substantially increases the cost and weight of the final EV product. The SirenOpt sensor can potentially enable early detection of poorly manufactured electrodes and allow them to be removed earlier from manufacturing lines, which can save battery manufacturers (hundreds of) millions of dollars per year. The sensor can further be used to improve product quality by accelerating R&D and process optimization, improving quality control, and enabling real-time process control. Overall, a real-time, in-situ metrology strategy can create unprecedented opportunities for implementation of smart manufacturing practices and advanced quality and process control solutions to realize higher battery electrode throughput and performance.

25 ENERGY STORAGE↗

DP-Based Optimization of BESS to Substitute RICE Reserves for Improved Economic Benefits

In regions with a significant proportion of renewable energy sources, reciprocating internal combustion engines (RICE or IC) are frequently employed as grid reserve solutions. This study suggests a scheduling technique for battery energy storage systems (BESS) that utilizes dynamic programming (DP) to replace IC units, adding versatility to the total reserve capacity and resulting in higher BESS earnings compared to traditional scheduling approaches. The capacity sweeping approach to optimize BESS’s revenue sometimes leads to operation which is counter intuitive to conventional battery sizing approaches.

25 ENERGY STORAGE↗

Office of Electricity Delivery and Energy Reliability (OE) National Energy Technology Laboratory (NETL) American Recovery and Reinvestment Act 2009 United States Department of Energy

The purpose of this project was for Seeo to deliver the first ever large-scale or grid-scale prototype of a new class of advanced lithium-ion rechargeable batteries. The technology combines unprecedented energy density, lifetime, safety, and cost. The goal was to demonstrate Seeo’s entirely new class of lithium-based batteries based on Seeo’s proprietary nanostructured polymer electrolyte. This technology can enable the widespread deployment in Smart Grid applications and was demonstrated through the development and testing of a 10 kilowatt-hour (kWh) prototype battery system. This development effort, supported by the United States Department of Energy (DOE) enabled Seeo to pursue and validate the transformational performance advantages of its technology for use in grid-tied energy storage applications. The focus of this project and Seeo’s goal as demonstrated through the efforts made under this project is to address the utility market needs for energy storage systems applications, especially for residential and commercial customers tied to solar photovoltaic installations. In addition to grid energy storage opportunities Seeo’s technology has been tested with automotive drive cycles and is seen as equally applicable for battery packs for electric vehicles. The goals of the project were outlined and achieved through a series of specific tasks, which encompassed materials development, scaling up of cells, demonstrating the performance of the cells, designing, building and demonstrating a pack prototype, and providing an economic and environmental assessment. Nearly all of the tasks were achieved over the duration of the program, with only the full demonstration of the battery system and a complete economic and environmental analysis not able to be fully completed. A timeline over the duration of the program is shown in figure 1.

25 ENERGY STORAGE↗

FY2011 Progress Report for Energy Storage Research & Development

The FY 2011 Progress Report for Energy Storage R&D focuses on advancing the development of batteries to enable a large market penetration of hybrid and electric vehicles. Program targets focus on overcoming technical barriers to enable market success including: (1) significantly reducing battery cost, (2) increasing battery performance (power, energy, durability), (3) reducing battery weight & volume, and (4) increasing battery tolerance to abusive conditions such as short circuit, overcharge, and crush.

ARRA↗

FY2013 Energy Storage R&D Progress Report

The FY 2013 Progress Report for Energy Storage R&D focuses on advancing the development of batteries to enable a large market penetration of hybrid and electric vehicles. Program targets focus on overcoming technical barriers to enable market success including: (1) significantly reducing battery cost, (2) increasing battery performance (power, energy, durability), (3) reducing battery weight & volume, and (4) increasing battery tolerance to abusive conditions such as short circuit, overcharge, and crush.

battery development↗

Delivery drone route planning over a battery swapping network

Many enterprises invest on drone delivery research and development to drop off packages at consumers’ doorsteps in a matter of minutes. We study delivery drone route planning over a battery swapping network allowing farther reach by penetrating current battery capacity constraints. A mixed-integer nonlinear programming model is created to plan efficient drone routing over the swapping machines by minimizing the delivery lead time. We develop an exact solution method, evaluate its performance, and compare it with a straightforward nonlinear solver application. A case study highlights the applicability of the model. Data and source code to the solver are publicly shared.

drone battery swapping↗

Development of a Hydrogen Energy System as a Grid Frequency Management Tool

The Hawai‘i Natural Energy Institute (HNEI) is conducting research to assess the technical potential of using an electrolyzer-based hydrogen (H2) production and storage system as a grid demand response tool using battery data from a 200 MW grid to show the kind of response required. The hydrogen produced by the electrolyzer is used for transportation. A 65 kg/day hydrogen energy system (HES) consisting of a PEM electrolyzer, 35 bar buffer tank, 450 bar compressor, and associated chiller systems was purchased and installed at the Hawaii Natural Energy Laboratory Hawaii Authority (NELHA) to demonstrate long-term durability of the electrolyzer under cyclic operation required for frequency regulation on an island grid system. The excess hydrogen was stored for use by three fuel-cell buses to be operated at Hawai‘i Volcanoes National Park (HAVO) and by the County of Hawai‘i Mass Transit Agency (MTA). This paper describes the site selection and equipment commissioning, plus a comprehensive test plan that was developed to characterize the performance and durability of the electrolyzer under dynamic load conditions. The controls were modified for the operating envelope and dynamic limits of the electrolyzer. While the data showed these modifications significantly improved the system response time, it is not fast enough to match a BESS response time for grid frequency management. The electrolyzer can only be used for slower acting changes (1 to 0.5 Hz). A potential solution is to design an electrolyzer/BESS hybrid system and develop a modeling program to find the optimum mix of battery and electrolyzer to provide the maximum grid regulation services at minimum cost.

08 HYDROGEN↗

BLAST aka: BLAST-Py see also BLAST-Lite (Battery Lifetime Analysis and Simulation Tool Suite - Python) [SWR-22-69]

Battery Lifetime Analysis and Simulation Tool Suite (BLAST or BLAST-Py) developed in the Python programming language. BLAST-Py predicts the evolution of lithium-ion battery performance metrics over their lifetime, using models trained on lab-based accelerated aging data to predict battery performance in dynamic, real-world use. BLAST-Py contains existing models for a variety of lithium-ion battery chemistries (NMC/Gr and LFP/Gr). See also the open-source version of this software tool known as "BLAST-Lite" at: https://github.com/NREL/BLAST-Lite

Smith, Kandler↗

Impact of electrolyte solutions on carbon dioxide fixation in single chamber Al–CO 2 battery

Governments and research & development (R&D) organizations are actively initiating various programs and research strategies for CO 2 capture, its utilization, and integration with long duration energy storage from renewable sources worldwide. In line with the carbon capture goals, here we report a novel electrochemical Al-CO 2 battery cell, that can simultaneously capture CO 2 and convert it into value-added products, in addition to long-duration energy generation and storage. Here, this innovative approach employs cost-effective Al metal as an anode and an in-house synthesized Ni–Fe based bimetallic double hydroxide catalyst as the cathode, with meticulously optimized compositions and morphologies. We explore the impact of different aqueous electrolyte solutions compositions on the cell performance, demonstrating up to 10 h of stable long duration energy storage with a stable voltage profile. The cell exhibits low polarization even at high current densities of up to 12 mA cm -2 and maintains stable cycling over 500 h. Through Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray Diffraction and X-ray photoelectron spectroscopy (XPS) analysis, we determined that the discharge product is either NaAlCO 3 (OH) 2 or KAlCO 3 (OH) 2 , distinct from the Al 2 (CO 3 ) 3 typically reported in conventional Al–CO 2 batteries.

25 ENERGY STORAGE↗

Real-Time Acoustic Analysis of Batteries

The project explored development and commercialization of an acoustical approach to battery diagnostics. The technology has significant potential impacts for battery manufacturing and quality assurance, battery management during operation, and could be an enabler for the second-life battery market. Research was focused on inspecting and analyzing the physical condition of batteries using ultrasound. This consisted of designing and building hardware for gathering high-quality acoustic data, as well as using battery charge-discharge cyclers and temperature chambers to operate and age the batteries. Over the course of the 2-year program, we were able to build our first prototypes that are robust enough to be used by industry partners to evaluate our technology. Using the same prototypes, we also showed preliminary evidence that our acoustic inspection method may have distinct advantages over standard electrical methods in terms of detecting differences in the physical quality of battery cells. The project also expanded the participant’s core capabilities beyond time-of-flight acoustic measurements.

25 ENERGY STORAGE↗

Interfacial Engineering and Modeling of High Energy Li Batteries

In the past 6 years, the UW team have collaborated extensively with the Battery500 Consortium team members, including The Pacific Northwest National Lab, The Idaho National Lab, Binghamton University, and UT Austin. We have accomplished all milestones and deliverables at the end of the program.

25 ENERGY STORAGE↗

CRADA Final Report: Ultralong Cycle Life and Ultrafast Charging Batteries to Electrify High Duty-Cycle, Mobile Platforms

As part of the Cyclotron Road program, Tyfast Energy Corp. aimed to investigate the Li 3 V 2 O 5 (LVO) anode material for next generation lithium batteries. State of the art and fast charging lithium-ion batteries are based on the lithium titanate or Li 4 Ti 5 O 12 (LTO) anode chemistry. LTO cells demonstrate fast charging times (<6 mins), long cycle life (>20,000 cycles), but at the expense of very low energy density (<200Wh/L, <80Wh/kg). Silicon anodes have the promise of achieving fast charging times, however, issues with cycling stability in combination with fast charging is unknown. LVO has unique properties that enable new performance window for lithium batteries. First, LVO operates at an average potential of 0.6V vs. Li/Li + , well above the Li-metal plating region allowing ultrafast charge capability without sacrificing safety. Second, the LVO has a high specific capacity of 250 mAh/g making battery pack energy density equivalent with current high-energy Li-ion chemistries.

25 ENERGY STORAGE↗

Control and Optimization of Energy Storage System in Power Distribution System

The widespread adoption of electric vehicles (EVs) and transportation electrification is encumbered by two chief barriers: i) the limited driving range of EVs in the market today and ii) inadequate fast-charging infrastructure for long-distance trips. Extreme fast charging (XFC) technology can recharge EVs in less than 10 minutes for 200 miles range. Firstly, a novel robust optimization-based mixed integer linear programming model is proposed to size a battery energy storage system (BESS) and PV system in an XFCS. In this part, it is assumed that the sizing and location of the XFCS are known. Secondly, the aforesaid assumption is relaxed, and a strategic multi-period coordinated planning model is proposed to optimally site and size BESS-assisted charging stations in a highway transportation network and PV systems in a power distribution network by considering the coupling between both networks. Optimal operation and control of BESS-assisted EV charging stations are vital to alleviate the adverse impact of extreme fast charging of EVs on the host power network. A joint solution is proposed to mitigate the steady state and transient impact of extremefast charging of EVs and ensure grid-friendly integration of XFCSs with the host grid. Lastly, to make the operation of the XFCS cost-effective, a multi-layered energy management framework is proposed for the XFCS by considering forecast uncertainties, monthly demand charges reduction, and BESS degradation.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Process design tools and techno-economic analysis for capacitive deionization

Capacitive deionization (CDI) devices use cyclical electrosorption on porous electrode surfaces to achieve water desalination. Process modeling and design of CDI systems requires accurate treatment of the coupling among input electrical forcing, input flow rates, and system responses including salt removal dynamics, water recovery, energy storage, and dissipation. Techno-economic analyses of CDI further require a method to calculate and compare between a produced commodity (e.g. desalted water) versus capital and operational costs of the system. In this work, we demonstrate a new modeling and analysis tool for CDI developed as an installable Matlab program that allows direct numerical simulation of CDI dynamics and calculation of key performance and cost parameters. The program is provided for free and is used to run open-source Simulink models. The Simulink environment sends information to the program and allows for a drag and drop design space where users can connect CDI cells to relevant periphery blocks such as grid energy, battery, solar panel, waste disposal, and maintenance/labor cost streams. The program allows for simulation of arbitrary current forcing and arbitrary flow rate forcing of one or more CDI cells. We employ validated well-mixed reactor formulations together with a non-linear circuit model formulation that can accommodate a variety of electric double layer sub-models (e.g. for charge efficiency). The program includes a graphical user interface (GUI) to specify CDI plant parameters, specify operating conditions, run individual tests or parameter batch-mode simulations, and plot relevant results. The techno-economic models convert among dimensional streams of species (e.g. feed, desalted water, and brine), energy, and cost and enable a variety of economic estimates including levelized water costs.

42 ENGINEERING↗